Theoretical studies on metal thioarsenites and thioantimonides: synergistic interactions between transition metals and heavy metalloids     

JA Tossell 《Geochemical transactions》2000,1(1):16-7

Recently we established that the ternary complex, CuAsS(SH)(OH) has an unusually high stability and makes a large contribution to the total concentrations of both Cu and As in sulfidic solutions equilibrated with Cu and As sulfide minerals. This ternary complex has an unusual structure, containing a bond which is formally Cu(I)–As(III), along with a broken As–S bond. We have now found that complexes with similar structures exist for Au⁺ and Tl⁺ coordinated to AsS(SH)(OH)^-. However, such a direct metal–metalloid bond is not a requirement for stability. In fact, TlAsS(SH)(OH) is unstable while AuAsS(SH)(OH) is highly stable (compared to the aquo ion). Zn²⁺, Cd²⁺, Hg²⁺ and Pb²⁺ also form bonds to the As of AsS(SH)(OH), but without breaking any As–S bonds, and HgAsS(SH)(OH)⁺ and PbAsS(SH)(OH)⁺ are particularly stable complexes. Calculated structures are shown for these complexes, gas-phase energies are calculated, and formation constants in aqueous solution are estimated. The SbS(SH)(OH)^- ion forms analogous complexes, with similar stabilities. However, the Au⁺ complex of SbS(SH)(OH)^- is slightly less stable than the Cu⁺ complex, opposite to the order found for the AsS(SH)(OH)^- ligand. The Au⁺ and AuSH complexes of AsSSHOH^- or AsS(SH)₂ ^- may be implicated in "invisible gold" in arsenian pyrites. Vibrational frequencies are given for the AuAsS(SH)₃ ^- complex and the XANES energies of this complex and Au(SH)₂ ^- are compared. The existence of such strong complexes may explain the many correlations observed between the concentrations of coinage metals and metalloids.  相似文献   

Book review     

R. E. Munn 《Boundary-Layer Meteorology》1989,46(3):305-308

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From the editor-in-chief     

R. E. Munn 《Boundary-Layer Meteorology》1995,72(1-2):1-2

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A felsic dyke swarm formed under the sea: the Archean Hunter Mine Group,south-central Abitibi Belt,Quebec, Canada     

W Mueller  JA Donaldson 《Bulletin of Volcanology》1992,54(7):602-610

An extensive rhyolitic dyke swarm has intruded subaqueous pyroclastic deposits, iron-formations, hyaloclastite breccias and lava flows of the 2730 Ma Hunter Mine Group (HMG) in the south-central part of the Archean Abitibi belt, Quebec. The dyke swarm has a minimum width of 500 m and can be traced perpendicular to the section for 2.4 km. Based on crosscutting relationships, chilled margins, quartz content and colour, five distinct dyke generations have been established. Each dyke generation has several magmatic pulses as indicated by parallel rows of columnar joints. Absence of brecciation between parallel rows suggests extremely brief intervals between magma pulses. The central parts of most dykes display inverted V-shaped patterns of columnar-joint convergence, inferred to indicate differential cooling during the late stages of dyke propagation. The dykes commonly display delicate spherulites suggesting rapid cooling, solidification temperatures between 400 and 600°C and penecontemporaneous devitrification. Quartz-feldspar aggregates in the groundmass have locally developed microgranophyric textures. Large spherulites near the chilled margins probably formed at temperatures below 400°C. Percolation of abundant water throughout the dyke complex is suggested by ubiquitous prominent chilled dyke margins. Development of a chilled margin 500 m along one dyke suggests that water percolated at least 500 m below the water/rock interface. Because the dykes intruded subaqueous pyroclastic deposits of similar composition, dyke emplacement below the sea floor is inferred. Interstratification of pillowed flows and brecciated pillowed flows containing rhyolite fragments at the top of the 4–5-km-thick sequence indicates that the central felsic complex probably never emerged during its evolutionary history, supporting the contention that the felsic dyke complex was emplaced beneath the Archean sea floor.  相似文献   

Book reviews     

R. E. Munn  Zhu Ruizhao  Zhang Jiacheng 《Boundary-Layer Meteorology》1994,68(1-2):215-216

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Magnetically enhanced coagulation of very small iron grains   总被引：3，自引：0，他引：3  

Nuth JA rd  Berg O  Faris J  Wasilewski P 《Icarus》1994,107(1):155-163

Laboratory experiments, in which very small (approximately 20 nm) grains are produced in the presence of a magnetic field on the order of 100 Gauss in a low-pressure hydrogen atmosphere, have demonstrated that such smokes can become permanently magnetized. We show that magnetization results in an enormous enhancement in the coagulation efficiency of such materials even in the absence of external magnetic fields. Small iron grains should have been produced in the solar nebula by thermal processing of preexisting interstellar grains. If such processing occurred via high-energy electromagnetic events then the resultant magnetized grains could have triggered the formation of centimeter- to meter-sized protoplanetessimals by acting as "nets" capable of sweeping up nonconductive silicates suspended in the gas. It is possible that the presence of conductive fractal aggregates observed in modern-day protostellar disks could be explained by the enhanced coagulation efficiency of very small magnetized iron particles.  相似文献   

Riverine influence determines nearshore heterogeneity of nutrient (C,N, P) content and stoichiometry in the KwaZulu-Natal Bight,South Africa     

UM Scharler  MJ Ayers  AM de Lecea  M Pretorius  ST Fennessy  JA Huggett 《African Journal of Marine Science》2016,38(1):S193-S203

Riverine influences on nearshore oceanic habitats often have detrimental consequences leading to algal blooms and hypoxia. In oligo- to mesotrophic systems, however, nutrient delivery via rivers may stimulate production and even be a vital source of nutrients, as may nutrient supplements from upwelling. We investigated the nutrient content (C, N, P) and stoichiometry of sediment, and several pelagic, benthopelagic and benthic species in the KwaZulu-Natal (KZN) Bight, a narrow shelf area on the south-east coast of South Africa, bordering the Agulhas Current. Three suggested nutrient sources to the bight are the Thukela River in the central region of the bight, upwelling in the northern part and a semi-permanent eddy (Durban Eddy) in the southern part. Elemental content of the various groups studied showed significantly higher values for most groups at the site near the Thukela River. C:P and N:P were highest in the southern part of the bight, and lowest near the Thukela Mouth or at Richards Bay in the north, indicating the latter were the P-richer sites. Sediment organic matter showed lowest elemental content, as expected, and zooplankton stoichiometry was highest compared to all other biotic groups. Environmental heterogeneity played a greater role in organismal C, N and P content and stoichiometry compared to phylogeny, with the exception of the differences in C:P and N:P of zooplankton. From this bight-wide study, the higher elemental content and lower ratios at the Thukela Mouth site supported previous findings of the importance of coastal nutrient sources to the bight ecosystem. Reductions in river flow for water use in the catchment areas may therefore have negative consequences for the productivity of the entire ecosystem.  相似文献   

Characterisation of the dietary relationships of two sympatric hake species,Merluccius capensis and M. paradoxus,in the northern Benguela region using fatty acid profiles     

JA Iitembu  NB Richoux 《African Journal of Marine Science》2016,38(1):39-48

The two sympatric species of Cape hake, Merluccius capensis and M. paradoxus, have been the main targets of bottom-trawl fisheries off Namibia for several decades. The feeding ecology of these hakes has been studied mainly using stomach content analyses and thus there remain some gaps in our knowledge about food assimilated over the longer term. In this study, we used fatty acid (FA) profiles to characterise the dietary relationships of M. capensis and M. paradoxus. Muscle samples from hake (n=110) and their known prey (n=68) were collected during trawl surveys off Namibia during 2011. Significant differences between the neutral FA profiles of the hake populations were detected in December 2011 but not in January 2011, an indication of temporal variations in diet and resource partitioning. Comparisons of the neutral FAs in hake and the total FAs of potential prey showed no clear trophic connections, with the exception of flying squid Todarodes sagittatus, which had FA profiles very similar to those of M. paradoxus in December 2011. Our results highlight the complex and temporally shifting relationships that exist between hake and the large pool of prey available to them, and between the two hake species that overlap in their feeding habits and distribution within the highly productive Benguela Current region.  相似文献   

Mixing and transport near the shallow-crested Rumble III seamount and the implications for plankton distribution     

CL Stevens  M Consalvey  JA Devine  MR Clark 《新西兰海洋与淡水研究杂志》2013,47(2):194-215

Vessel-based observations of water column structure and flow near a shallow-crested seamount are used to quantify the physical disturbance induced by that seamount. The implications of this disturbance on the ‘feeding hole’ hypothesis are then examined based on data from moored thermistors and acoustic current profilers, as well as vessel-based acoustic sounding-derived biomass estimates, currents, and conductivity-temperature-depth profiles from a 55 km square grid of stations around the crest. Mean currents in the region of 0.2 m s^?1 are comparable to observations from surface drifters whereas the semidiurnal tidal flow amplitude was one third of this. Thorpe Scale-based estimates of energy dissipation rate were in the range 10^?9 to 2.10^?8 W kg^?1 and vertical diffusivities K_z were in the range 10^?4 to 10^?3 m² s^?1. Turbulence levels were higher upstream of the seamount–likely due to the influence of nearby seamounts Rumble IV and V. There was no evidence of a Taylor Cap in the Rumble III velocity field. The sounder data provide some evidence of a feeding hole and analysis based on diffusivities suggests that this might persist downstream of the seamount for as much as 7 days.  相似文献   

Gabriel T. Csanady: Understanding the physics of the ocean     

J.L. Pelegrí  J.H. Churchill  A.D. Kirwan  Jr.  S.-K. Lee  R.E. Munn  N.R. Pettigrew 《Progress in Oceanography》2006,70(2-4):91

Gabriel T. Csanady turned 80 in December 2005 and we celebrate it with this special Progress in Oceanography issue. It comprises 20 papers covering some of the many areas that Gabe contributed significantly throughout his professional career. In this introductory paper we briefly review Gabe’s career as an engineer, meteorologist and oceanographer, and highlight some of his major contributions to oceanography, both as a scientist as well as an educator. But we also use this opportunity to remember and thank Gabe, and his wife Joyce, for being such good friends and mentors to several generations of oceanographers. The authors of the collection of papers in this volume deserve special thanks for their efforts. We also are pleased to acknowledge the support of Progress in Oceanography’s editor, Detlef Quadfasel, and the many anonymous reviewers who generously contributed their time and expertise.  相似文献