Monitoring of mercury and other metals mobility by sequential fractionation in soils nearby an abandoned chlor-alkali plant in Managua (Nicaragua)     

Rodolfo Fernández-Martínez  Belén Gómez-Mancebo  Emilio J. Peña  Pilar Galán  Akito Matsuyama  Fernando García  Isabel Rucandio 《Environmental Earth Sciences》2016,75(6):538

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Natural radioactivity and elemental composition of beach sands in the Calabria region,south of Italy     

F. Caridi  S. Marguccio  A. Belvedere  G. Belmusto  G. Marcianò  G. Sabatino  A. Mottese 《Environmental Earth Sciences》2016,75(7):629

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Caprock analysis from the Mihályi-Répcelak natural CO<Subscript>2</Subscript> occurrence,Western Hungary     

Csilla Király  Ágnes Szamosfalvi  László Zilahi-Sebess  Péter Kónya  István János Kovács  Eszter Sendula  Csaba Szabó  György Falus 《Environmental Earth Sciences》2016,75(8):635

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Estimating airborne heavy metal concentrations in Dunkerque (northern France)     

Germán?SantosEmail author  Ignacio?Fernández-Olmo  ángel?Irabien  Frédéric?Ledoux  Dominique?Courcot 《Arabian Journal of Geosciences》2016,9(3):231

This work aims to estimate the levels of lead (Pb), nickel (Ni), manganese (Mn), vanadium (V) and chromium (Cr) corresponding to a 3-month PM₁₀ sampling campaign conducted in 2008 in the city of Dunkerque (northern France) by means of statistical models based on partial least squares regression (PLSR), artificial neural networks (ANNs) and principal component analysis (PCA) coupled with ANN. According to the European Air Quality Directives, because the levels of these pollutants are sufficiently below the European Union (EU) limit/target values and other air quality guidelines, they may be used for air quality assessment purposes as an alternative to experimental measurements. An external validation of the models has been conducted, and the results indicate that PLSR and ANNs, with comparable performance, provide adequate mean concentration estimations for Pb, Ni, Mn and V, fulfilling the EU uncertainty requirements for objective estimation techniques, although ANNs seem to present better generalization ability. However, in accordance with the European regulation, both techniques can be considered acceptable air quality assessment tools for heavy metals in the studied area. Furthermore, the application of factor analysis prior to ANNs did not yield any improvements in the performance of the ANNs.  相似文献   

Geochemical mobility of arsenic in the surficial waters from Argentina     

Alicia Daniela Robles  Paula Polizzi  María Belén Romero  Leila Natalia Chiodi Boudet  Sandra Medici  Agustín Costas  Marcela Gerpe 《Environmental Earth Sciences》2016,75(23):1479

The presence of arsenic (As) in surface water constitutes an important environmental risk, where mobility and adsorption processes are responsible for its behavior in the sediment–water interface. Therefore, the assessment of adsorption, mobility and water availability of arsenic in freshwater sediments, with agricultural, livestock and urban soil uses was performed. Arsenic concentrations in sediments ranged from 5.4 to 15.9 mg kg^?1 (total) and 2.8 to 6.5 mg kg^?1 (labile), and those of iron and manganese were 11,563–23,500 and 140.6–662.1 mg kg^?1, respectively. The As levels in water were significantly lower than those of sediments. Results would suggest that As co-precipitation and adsorption on Fe oxides are probably the major route of immobilization, determining its low lability. Manganese did not present an outstanding contribution to the retention, and cation-exchange capacity, pH and organic matter of sediments did not show an influence on the mobility of As.  相似文献   

A New Approach for Conditioning Process-Based Geologic Models to Well Data     

David Wingate  Jonathan Kane  Matt Wolinsky  Zoltán Sylvester 《Mathematical Geosciences》2016,48(4):371-397

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Horizon Restoration by Best Fitting of Finite Elements and Rotation Constraints: Sensitivity to the Mesh Geometry and Pin-Element Location     

María José Ramón  José Luis Briz  Emilio L. Pueyo  Oscar Fernández 《Mathematical Geosciences》2016,48(4):419-437

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Evidence of episodic long-lived eruptions in the Yuma,Ginsburg, Jesús Baraza and Tasyo mud volcanoes,Gulf of Cádiz     

María H. Toyos  Teresa Medialdea  Ricardo León  Luis Somoza  Francisco Javier González  Nieves Meléndez 《Geo-Marine Letters》2016,36(3):197-214

High-resolution single channel and multichannel seismic reflection profiles and multibeam bathymetric and backscatter data collected during several cruises over the period 1999 to 2007 have enabled characterising not only the seabed morphology but also the subsurface structural elements of the Yuma, Ginsburg, Jesús Baraza and Tasyo mud volcanoes (MVs) in the Gulf of Cádiz at 1,050–1,250 m water depth. These MVs vary strongly in morphology and size. The data reveal elongated cone-shaped edifices, rimmed depressions, and scarps interpreted as flank failures developed by collapse, faulting, compaction and gravitational processes. MV architecture is characterised by both extrusive and intrusive complexes, comprising stacked edifices (including seabed cones and up to four buried bicones) underlain by chaotic vertical zones and downward-tapering cones suggesting feeder systems. These intrusive structures represent the upper layer of the feeder system linking the fluid mud sources with the constructional edifices. The overall architecture is interpreted to be the result of successive events of mud extrusion and outbuilding alternating with periods of dormancy. Each mud extrusion phase is connected with the development of an edifice, represented by a seabed cone or a buried bicone. In all four MVs, the stacked edifices and the intrusive complexes penetrate Late Miocene–Quaternary units and are rooted in the Gulf of Cádiz wedge emplaced during the late Tortonian. Major phases of mud extrusion and outbuilding took place since the Late Pliocene, even though in the Yuma and Jesús Baraza MVs mud volcanism started in the Late Miocene shortly after the emplacement of the Gulf of Cádiz wedge. This study shows that fluid venting in the eastern sector of the Gulf of Cádiz promoted the outbuilding of large long-lived mud volcanoes active since the Late Miocene, and which have been reactivated repeatedly until recent times.  相似文献   

Can light intensity cause shifts in natural product and bacterial profiles of the sponge Aplysina aerophoba?          下载免费PDF全文

Oriol Sacristán‐Soriano  Bernard Banaigs  Mikel A. Becerro 《Marine Ecology》2016,37(1):88-105

The potential role of microbial consortia on sponge chemistry is well known. However, how environmental factors affect microbial and chemical profiles and how these shifts affect the sponge holobiont are far from being understood. This study experimentally investigated the effect of light on both the concentration of secondary metabolites and the bacterial assemblages of the sponge Aplysina aerophoba. We quantified major brominated alkaloids (BAs) using a high‐performance liquid chromatography system coupled with a UV‐detector and analysed sponge‐associated bacteria using denaturing gradient gel electrophoresis of 16S rRNA gene amplicons. We identified distinct chemical and bacterial profiles between the ectosome and the choanosome of A. aerophoba. The abundance of most secondary metabolites increased regardless of the illumination regime. We found that the probability of occurrence of three microbial phylotypes (operational taxonomic units 84, 86 and 87) was strongly associated with increasing concentrations of three brominated compounds (aerophobin‐1, aplysinamisin‐1 and isofistularin‐3). Although the role of these bacteria remains uninvestigated, these associations between natural products and specific microbial phylotypes outline further hypotheses that will improve our understanding of the organization and functioning of these complex host–symbiont interactions.  相似文献   

Submerged vegetation complexity modifies benthic infauna communities: the hidden role of the belowground system          下载免费PDF全文

Vanessa González‐Ortiz  Luis Gonzalo Egea  Rocio Jiménez‐Ramos  Francisco Moreno‐Marín  José Lucas Pérez‐Lloréns  Tjeerd Bouma  Fernando Brun 《Marine Ecology》2016,37(3):543-552

Marine plants provide a variety of functions with high economic and ecological values in ecosystems. The above‐ (AG) and below‐ground (BG) systems increase the structural complexity of plants, which also enhance faunal abundance and diversity. The ecological role of the AG compartment in structuring inter‐tidal macrobenthic communities has been widely studied; however, this is not the case for the BG compartment. This study addressed the effects of variation in vegetation complexity (in both AG and BG systems) on associated macrobenthic infauna with respect to abundance, species richness, composition, weight and body type. To achieve this aim, a field experiment using artificial vegetation mimics was carried out using replicated treatments with different AG‐BG complexity ratios. We found a significant increase in the density and the number of taxa of macrobenthic infaunal species in plots with vegetation mimics compared with unvegetated areas, regardless of either AG or BG complexity. This effect was found even when AG parts were not present (i.e. when only BG parts were used). Furthermore, a positive relationship between structural complexity and diversity was recorded. Variation in one or both plant compartments was strongly related to diversity changes in the associated macrobenthic infauna. In conclusion, our experimental set‐up provides the first evidence that the BG compartment is at least as important as the AG compartment in controlling diversity in inter‐tidal vegetated areas because it was able to strongly affect community structure even when the AG system was totally absent.  相似文献