Persistent Organic Pollutants (POPs) in Bottom Sediments of the Vistula River,Poland     

Urszula Dmitruk  Marek Piašcik  Barbara Taboryska  Jan Dojlido 《洁净——土壤、空气、水》2008,36(2):222-229

The Vistula (Wisla) river, the biggest river in Poland, is 1038 km long and has a drainage area of 168 689 km². The river is strongly polluted by wastewaters. Big industrial plants are situated mainly in the upper part of the river, where it is slow‐flowing. This paper presents the results of the analysis of bottom sediment samples gathered from different locations along the Vistula river, from Kraków to Gdansk. The study was conducted in 2005. The following parameters were determined: chloroorganic pesticides, polychlorinated biphenyls (PCBs), chlorophenols, polycyclic aromatic hydrocarbons (PAHs), total organic carbon (TOC). The sum of chloroorganic pesticides was in the range of 2.0 to 77.5 ng/g d.w. (dry wet) with the highest values in the upper part of the river. p,p′‐DDT was found in the highest concentration. The sum of PCBs was in the range of 0.9 to 64.2 ng/g d.w. The sum of chlorophenols varied from 0.48 to 14.3 ng/g d.w. 2,4‐Dichlorophenol and pentachlorophenol occurred in the highest concentration. The sum of PAHs was in the range of 1552 to 7832 ng/g d.w. Phenantren was found in the highest concentration and antracen in the lowest. TOC values varied from 4.3 to 43.9 g/kg d.w. The concentrations of pesticides and PCBs were the highest in the upper part of the river and decreased along the course of the river, but the other determined compounds did not show this trend. However, the highest values occurred always in the upper part of the river.  相似文献   

破裂井筒侧摩阻力分析   总被引：1，自引：1，他引：0  

周治安  杨为民 《煤田地质与勘探》2003,31(5):37-39

根据有效应力原理,对破裂井筒详细调查,建立由多个含、隔水层组成的厚表土底部固结沉降井壁侧摩阻力的概化模型。指出这类井壁不仅有负阻力,同时还有正阻力及零阻力井段,它们的分布决定了井壁挤压破裂及拉伸的部位。从有效应力的变化阐明了井壁破坏与降水季节的关系   相似文献   

SARS对中国入境旅游人数影响的研究   总被引：31，自引：5，他引：26  

朱迎波  葛全胜  魏小安  董培南  何连生  彭唬 《地理研究》2003,22(5):551-559

今年爆发的SARS对中国旅游业冲击很大。本文利用双变量ARIMA模型,结合突发事件后人的心理发展变化曲线研究本次突发事件对入境旅游人数的影响。根据同类事件旅游心理恢复期的研究,结合中国实际情况,笔者讨论了恢复期分别为12、18、24个月时,SARS对入境旅游人数的影响。当恢复期为12个月时,入境旅游同比增长率平均降幅为1796%,入境旅游人数共减少238493万人次;当恢复期为18个月时,入境旅游同比增长率平均降幅为1707%,入境旅游人数共减少311703万人次;当恢复期为24个月时,入境旅游同比增长率平均降幅为1655%,入境旅游人数共减少385233万人次。  相似文献   

Intrusive lherzolites within the basalts of Küre ophiolite (Turkey): an occurrence in the Tethyan suprasubduction marginal basin     

Üner akir  Yurdal Gen  Doan Paktun 《Geological Journal》2006,41(2):123-143

  相似文献   

Secondary consolidation of clay as an anomalous diffusion process     

Philippe Cosenza  Dean Korošak 《国际地质力学数值与分析法杂志》2014,38(12):1231-1246

Secondary consolidation of clay soil is considered as a result of anomalous diffusion of pore water pressure from the micropores to the macropores. By using simplified pore geometry, a heuristic approach allows us to infer the expression of the associated rate of vertical secondary deformation written as a fractional derivative of the pore pressure. The insertion of this expression into the 1D Terzaghi's theory leads to a particular type of time‐fractional diffusion equation of the pore pressure that is solved semi‐analytically. The advantage of such theoretical approach stems from the concise and compact way of treating the secondary consolidation. Only two additional parameters are needed: the fractional order, ν, and the fractional viscosity factor, θ, both accounting for the physicochemical interactions between pore fluid and clay particles. This theoretical approach is tested on experimental data obtained from the Cubzac‐les‐Ponts clay soil intensively studied for secondary consolidation. This application shows a good agreement between the data and the predicted values confirming the interest of the initial assumption and the use of the fractional derivatives formalism. Moreover, good correlations between the inverted fractional parameters and the empirical secondary consolidation index C_α measured independently are obtained: the fractional order ν, if experimentally calibrated, can be used as a reasonable estimator of the slope of the secondary consolidation portion of consolidation curve. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Grenvillian remnants in the Northern Andes: Rodinian and Phanerozoic paleogeographic perspectives     

A. Cardona  D. Chew  V.A. Valencia  G. Bayona  A. Mišković  M. Ibañez-Mejía 《Journal of South American Earth Sciences》2010,29(1):92-104

Grenvillian crust is encountered in several basement inliers in the northern Andes of Colombia, Ecuador and Peru and is also represented as a major detrital or inherited component within Neoproterozoic to Paleozoic sedimentary and magmatic rocks. This review of the tectonic and geochronological record of the Grenvillian belt in the northern Andes suggests that these crustal segments probably formed on an active continental margin in which associated arc and back-arc magmatism evolved from ca. 1.25 to 1.16 Ga, possibly extending to as young as 1.08 Ga.The lithostratigraphic and tectonic history of the Grenvillian belt in the northern Andes differs from that of the Sunsas belt on the southwest Amazonian Craton and from the Grenvillian belt of Eastern Laurentia. It is considered that this belt, along with similar terranes of Grenvillian age in Middle America and Mexico define a separate composite orogen which formed on the northwestern margin of the Amazonian Craton. Microcontinent accretion and interaction with the Sveconorwegian province on Baltica is a feasible tectonic scenario, in line with recent paleogeographic reconstructions of the Rodinian supercontinent. Although Phanerozoic tectonics may have redistributed some of these terranes, they are still viewed as para-autocthonous domains that remained in proximity to the margin of Amazonia. Paleogeographic data derived from Phanerozoic rocks suggest that some of the Colombian Grenvillian fragments were connected to northernmost Peru and Ecuador until the Mesozoic, whereas the Mexican terranes where attached to the Colombian margin until Pangea fragmentation in Late Triassic times.  相似文献   

油源对比微量元素地球化学研究进展   总被引：2，自引：0，他引：2  

曹剑  吴明  王绪龙  胡文瑄  向宝力  孙平安  施春华  鲍海娟 《地球科学进展》2012,27(9):925-937

原油中的微量元素地球化学组成可以应用于油源对比,指标可以归纳为3类:①所含元素的聚类分析及其所反映的元素分布总体特征;②不同族、不同类型元素的组成,特别是过渡族金属元素;③稀土元素。但对于哪些微量元素可以应用于油源对比,哪些具有普遍意义,在不同地区是否具有适用性,影响其油源对比应用有效性的因素有哪些,主控因素是什么,仍然不甚清楚,由此导致很多方面的认识还不甚成熟,成功应用的实例相对常规的有机地球化学研究不多。原油中的微量元素主要来源于外部成油和运聚环境,在原油生成和运聚过程中,通过烃—水—岩之间的复杂有机—无机相互作用以金属卟啉螯合物、有机络合物或吸附态的形式聚集于原油中,并且沥青质是原油中微量元素的主要载体,元素组成在此过程中发生分异。此外,原油在自身形成与演化过程中也会发生元素组成的分异,影响因素包括油源母质类型、成熟度、次生变化等。在这些过程中,元素地球化学性质的不同会使原油中的元素组成出现差异,基本不发生/少发生变化的元素即可能是好的油源对比指标,这是应用微量元素进行油源对比的原理和理论基础。  相似文献   

The separate production of H₂S from the thermal reaction of hydrocarbons with magnesium sulfate and sulfur: Implications for thermal sulfate reduction     

Hong Lu  Paul Greenwood  Tengshui Chen  Jinzhong Liu  Ping’an Peng 《Applied Geochemistry》2012

The yields and stable C and H isotopic composition of gaseous products from the reactions of pure n-C₂₄ with (1) MgSO₄; and (2) elemental S in sealed Au-tubes at a series of temperatures over the range 220–600 °C were monitored to better resolve the reaction mechanisms. Hydrogen sulfide formation from thermochemical sulfate reduction (TSR) of n-C₂₄ with MgSO₄ was initiated at 431 °C, coincident with the evolution of C₂–C₅ hydrocarbons. Whereas the yields of H₂S increased progressively with pyrolysis temperature, the hydrocarbon yields decreased sharply above 490 °C due to subsequent S consumption. Ethane and propane were initially very ¹³C depleted, but became progressively heavier with pyrolysis temperature and were more ¹³C enriched than the values of a control treatment conducted on just n-C₂₄ above 475 °C. TSR of MgSO₄ also led to progressively higher concentrations of CO₂ showing relatively low δ¹³C values, possibly due to input of isotopically light CO₂ derived from gaseous hydrocarbon oxidation (e.g., more depleted CH₄).  相似文献   

Environmental aspect of radon potential in terra rossa and eutric cambisol in Slovenia     

J. Vaupotič  P. Žvab Rožič  D. Barišić 《Environmental Earth Sciences》2012,66(1):223-229

Terra rossa and eutric cambisol soils were surveyed in Slovenia. At both sites, 6–13 boreholes were drilled in a regular 24 m × 24 m square grid. Soil samples from various depths were taken for gamma spectrometric analysis, and radon in soil gas was measured at a depth of 80 cm using an AlphaGuard instrument. The following ranges of activity concentration (Bq kg⁻¹) were obtained for ²³⁸U, ²²⁶Ra, ²²⁸Ra, ⁴⁰K and ¹³⁷Cs: in terra rossa, 64–74, 70–84, 45–49, 293–345, 20–30 and, in eutric cambisol, 55–80, 132–147, 50–57, 473–529, 106–272. Radon activity concentrations in both soils ranged from about 100 kBq m⁻³ to 370 kBq m⁻³.  相似文献   

Karstological study of the new Kunming airport building area (Yunnan, China)     

Martin Knez  Janja Kogovšek  Hong Liu  Janez Mulec  Metka Petrič  Nataša Ravbar  Tadej Slabe 《Environmental Earth Sciences》2012,67(1):273-283

In Kunming area (6.8 mio population), two big interventions are in progress: construction of a new airport, the 23 km² area of which will extend across karst terrain northeast of the city, and extensive uptake of water from karst aquifers for drinking and agricultural use. In the study, an interdisciplinary approach was utilized to demonstrate the need for holistic karstology studies prior to performing extensive interferences in the karst environment. This study included survey of surface karst features and microscopic analyses of rock samples in the area of the new airport location, accompanied by hydrogeological studies and microbiological analyses of two karst drinking water sources in its vicinity (Qinglongdong, Huanglongdong). Results showed the specific characteristics of the subsoil stone forest that indicated a high level of karstification. The direction and characteristics of groundwater flow from the sinking Qiaotou Stream at the margin of the new airport area toward the Huanglongdong Spring were defined with a single tracer test. Additional information about hydrogeological characteristics of the karst aquifer was obtained by individual measurements of physical and chemical parameters of the springs and sinking stream. Selected chemical and bacteriological parameters showed substantial pollution of both springs due to various types of human activities in the catchments. The results of the study pointed to the necessity of taking immediate measures for the springs’ protection and showed the importance of interdisciplinary research when planning anthropogenic activities in the karst.  相似文献