Chondrites with peculiar rare-earth patterns     

Noboru Nakamura  Akimasa Masuda 《Earth and Planetary Science Letters》1973,19(4):429-437

Rare-earth elements and Ba in Khohar, Abee, Indarch, Atlanta, Jajh deh Kot Lalu, and Nakhla were determined accurately by isotope dilution technique; for Atlanta only, Fe (total), Mg and Ca were also determined. Khohar shows in two aliquants a strikingly large, positive anomaly for Ce. A fragment of Abee is outstanding in having a large positive Yb anomaly and a zigzag RE pattern. It is considered that the Yb anomaly is not necessarily associated with the zigzaggedness in question. Anyway, these facts corroborate our previous observations that abundances of Ce and/or Yb could be sometimes anomalous in meteoritic and lunar materials.Atlanta also has a significant negative Eu anomaly, similar to the Eu depletions observed in lunar basalts and Ca-poor achondrites by other workers. Besides, this enstatite chondrite has a RE pattern which indicates that this meteorite is cumulate-type (solid-type) material separated perhaps from a considerably fractionated melt. Accordingly, it is suggested that it is not always appropriate to classify this type II enstatite chondrite as “chondrite”. Two fragments from Abee and Atlanta show different RE patterns. It is also observed that Ba abundances are sometimes sporadically and irregularly high.  相似文献   

The orientation of the OH− dipole in an optically anisotropie crystal: An application to the OH− dipole in topaz     

Keiji Shinoda  Nobuyuki Aikawa 《Physics and Chemistry of Minerals》1994,21(1-2):24-28

For the purpose of determining the orientation of the OH^? dipole in an optically anisotropic crystal, distribution of polarized IR absorbance is formulated under Fourier transform microspectroscopy. The formulatd absorbance distribution suggests that the degree of pleochroism of absorbance depends on the angle between the orientation of the OH^? dipole and the principal orientation of the optically anisotropic crystal. As its application, the general orientation of the OH^? dipole in topaz is determined to be inclined 27.3° from the c-axis in (010).  相似文献   

REE Tetrad Effects in Rare—metal Granites   总被引：1，自引：1，他引：1  

赵振华  AKIMASAMASUDA 《中国地球化学学报》1993,12(3):206-219

Described in this paper are the characteristics of tetrad effects of REE in rare-metal granites.Based on the analytical data and experimental geochemical data available,it is pointed out that the tetrad effects of REE in the granites are produced in the metal-fluid system.Intense fractional crystallization of granitic melt(containing REE accessary minerals)and its interaction with volatile-rich(F,Cl)fluid are the major factors leading to the tetrad effects of REE.From this,this paper presents a composite genetic model for high-degree fractional crystallization-volatile-rich fluid metasomatism of rare-metal granites.With the model,quantitative calculations have been made.Meanwhile,it is pointed out that the tetrad effects of REE can be used as an important indicator to distinguish mineralized granites from barren ones.  相似文献   

A Microstructural sequence of quartz schists in central Shikoku, south-west Japan     

Toshiaki Masuda 《Tectonophysics》1982,83(3-4)

This paper describes a microstructural sequence of quartz schists (metamorphosed chert) in the Asemi river region of the Sambagawa metamorphic terrain in central Shikoku, southwest Japan. The Asemi river region is divided into three areas on the basis of characteristics of microstructures of quartz schists observed under the optical microscope: areas I, II and III, in ascending order of metamorphic grade. Microstructures in area I consist of finer, equant, equidimensional and polygonal quartz grains free from internal deformation features. Microstructures in area II are characterized by oblate or elliptical grains with remarkable undulatory extinction surrounded by serrated grain boundaries. Microstructures in area III consist mainly of coarser and equant grains without distinct internal deformation features.The formation conditions of these microstructures are discussed in the light of recent experimental results.  相似文献   

Trace element variations in the volcanic rocks from the Nasu zone,northeast Japan     

Yasuyuki Masuda  Ken-Ichiro Aoki 《Earth and Planetary Science Letters》1979,44(1):139-149

  相似文献   

Recognition of conjugate solid-type and liquid-type relationship among the oceanic basalts,with respect to REE     

Masuda  A.  Shimokawa  T.  Jibiki  H.  Nagawa  T. 《Contributions to Mineralogy and Petrology》1974,48(4):265-274

The REE abundances and their chondrite-normalized pattern lead one to consider that the basalt from the Caroline ridge area southeast of the Marianas Arc and the one from the Puerto Rico Trench happen to be equivalent to conjugate liquid-type and solid-type materials, respectively, reflecting an equilibrium of a 20% partial melting. This line of interpretation enables us not only to assess the REE abundances in the original solid-type material (M), but also to estimate the corresponding values in the product (¯L) of a very small (say, less than 1 %) extent of a partial melting. It is also found that the relative REE abundances in a basalt from directly east of the Marianas Trench are quite the same as those thus estimated. Alternatively, it is possible to interpret this basalt as representing the residual liquid left after the primary fractional differentiation of the mantle.It is suggested that the straight-type bulk partition coefficients, the absence of the apparent europium anomaly, and the higher pressure are closely associated.  相似文献   

Evolution of lunar materials in light of the abundance variation of oxyphile trace elements     

Akimasa Masuda  Noboru Nakamura 《Contributions to Mineralogy and Petrology》1970,29(1):11-27

Based on the lunar data on lanthanides, U, Th, Ba, and Sr, the partition coefficients for fractional solidification were estimated for these elements. The resultant values suggest the removal of solids with perhaps pyroxenic composition. The partition coefficient for europium can be judged to be normal as divalent europium dominantly present in the melt. When we go back following the trend of fractionation of abundances, we can reach the stage where there is no europium anomaly and where the thorium concentration level is chondritic. It can be imagined that the material corresponding to this stage was the directly original lunar material system. As a possibility, a zone melting is thought to be a possible process for the derivation of that material from chondritic material. The chondrite-normalized lanthanide patterns for silicate materials of two stony-irons appear to provide us with an intriguing clue to this problem.  相似文献   

Chronic effects of tributyltin on the caprellid amphipod Caprella danilevskii   总被引：2，自引：0，他引：2  

Ohji M  Arai T  Miyazaki N 《Marine pollution bulletin》2003,46(10):1263-1272

In order to examine the biological effects by TBT exposure, experiments involving the exposure of five levels of TBT concentrations (0, 10, 100, 1000 and 10,000 ngl(-1)) were conducted on the caprellid amphipod Caprella danilevskii, over a generation after hatching. Marked delays in growth and molting during the early developmental stage and maturation were found in both 100 and 1000 ng TBTCl l(-1) concentrations in spite of the sex. All specimens died in 10,000 ng TBTCl l(-1) within 4 days after hatching. Inhibition of maturation and reproduction such as delaying in the achievement of maturity and a decrease in the number of juveniles hatched was apparent in 10 and 100 ng TBTCl l(-1) concentrations. Furthermore, brood loss, and failure in egg formation and hatching were observed as the TBT concentration became higher. No significant changes in sex ratio were seen at any of the TBT exposure levels during hatching and maturation in the present study. This phenomenon was different from a previous study in which the proportion of females was increased with an increase in TBT concentrations in the embryonic exposure experiment. This suggests that sex disturbance is induced during the embryonic stage of the species. A drastic decrease in survival rate was observed at 10 ng TBTCl l(-1) (25%) which corresponds to the mean level in coastal waters. Therefore, the present encountering ambient TBT concentration may influence populations of C. danilevskii in the coastal environment.  相似文献   

Trace element characteristics of the fluid liberated from amphibolite-facies slab: Inference from the metamorphic sole beneath the Oman ophiolite and implication for boninite genesis   总被引：3，自引：0，他引：3  

Tsuyoshi Ishikawa  Shiori Fujisawa  Kazuya Nagaishi  Toshiaki Masuda 《Earth and Planetary Science Letters》2005,240(2):355-377

Major and trace element compositions of amphibolites and quartzose rocks in the 230-m-thick metamorphic sole underlying the mantle section of the Oman ophiolite in Wadi Tayin area were determined to investigate the chemical characteristics of the hydrous fluid released from subducted amphiboltie-facies slab. The fluid-immobile element compositions indicate that protoliths of these rocks are mid-ocean ridge basalt-like tholeiite and deep-sea chert, which is consistent with the idea that these rocks represent Tethyan oceanic crust overridden during the early, intraoceanic thrusting stage of the Oman ophiolite emplacement. The rare-earth element (REE) and high field-strength element concentrations of the amphibolites show limited variations, within a factor of two except for a few evolved samples, throughout transect of the sole. On the other hand, concentrations of fluid-mobile elements, especially B, Rb, K and Ba, in amphibolites are highly elevated in upper 30 m of the sole (> 600 °C in peak metamorphic temperature), suggesting the equilibration with evolved, B-Rb-K-Ba-rich fluids during prograde metamorphism. The comparison with amphibolites in the lower 150 m (500 to 550 °C) demonstrates that the trace element spectra of the fluids equilibrated with the high-level amphibolites may vary as a function of metamorphic temperature. The fluids are characterized by striking enrichments of B, Rb, K and Ba and moderate to minor enrichments of Sr, Li, Be and Pb. At higher temperature (up to 700 °C), the fluids become considerably enriched in light REE and Nb in addition to the above elements. The estimated trace element spectra of the fluids do not coincide with the compositions of basalts from matured intra-oceanic arcs, but satisfactorily explain the characteristics of the low-Pb andesites and boninites found in the Oman ophiolite. Compositional similarity between the boninites of Oman and other localities suggests that the fluids estimated here well represent the amphibolite-derived fluids involved in the magmatism of immatured, hot, shallow subduction zones.  相似文献   

汉诺坝玄武岩中地幔岩捕掳体REE和Sr,Nd同位素地球化学   总被引：20，自引：3，他引：20  

刘丛强  解广轰 《岩石学报》1996,12(3):382-389

本文报道汉诺坝玄武岩中地幔岩捕掳体的ＲＥＥ丰度和Ｓｒ、Ｎｄ同位素组成。不同岩石类型的ＲＥＥ配分模式和同位素组成反映地幔部分熔融程度和交代作用过程。二辉橄榄岩亏损轻稀土，是原始地幔经不同程度部分熔融的残留体。方辉橄榄岩具Ｕ型ＲＥＥ配分模式，是强烈亏损的地幔岩被熔体非化学平衡交代的结果。二辉岩脉状体富轻、中稀土，它同与脉状体接触的二辉橄榄岩可达化学平衡或近于化学平衡，而二辉岩脉状体的形成与玄武岩岩浆无成因关系。据对二辉岩脉状体和不含脉状体橄榄岩的Ｓｍ－Ｎｄ同位素定年，这种脉状体形成于３００Ｍａ左右。  相似文献