Rapid quantification of humic and fulvic acids by HPLC in natural waters     

F.C. Wu  R.D. Evans  P.J. Dillon  Y.R. Cai 《Applied Geochemistry》2007

A simple method based on high-performance size-exclusion chromatography (HPSEC) has been developed for rapid quantification of humic and fulvic acids (HA and FA) in stream waters. A Tsk-gel column was used to separate natural dissolved organic matter (DOM) into two components: peak A and B. In terms of HPSEC chromatograms and fluorescence patterns, peak A and B were similar to the corresponding XAD-extracted HA and FA, respectively. It is suggested that peak A fraction mainly consisted of HA, and peak B fraction FA. The similar separation of HA and FA using HPSEC and a conventional XAD method suggests the consistency of molecular size distribution and physical–chemical properties of DOM. HPSEC offers a simple and rapid method for the quantification of HA and FA instead of tedious extractions of humic substances. Analyses of natural water samples show that the calculation of HA/FA based on UV absorbance was under- or over-estimated, the calibration using the extracted HS allows a more accurate quantification. The fast screening of HA and FA provides useful quantitative and qualitative information that can be used in environmental or monitoring studies.  相似文献   

Anglo-Saxon animal husbandry techniques revealed though isotope and chemical variations in cattle teeth     

J.A. Evans  S. Tatham  S.R. Chenery  C.A. Chenery 《Applied Geochemistry》2007

The Sr concentration and isotope composition of tooth enamel from domesticated animals from two neighbouring Anglo-Saxon settlements, at Empingham (6–7th century) and Ketton (10–12th century) in Rutland, central England, are compared both with each other, and with associated human populations. Data from the Empingham II site form discrete fields in Sr concentration and isotope composition space for cattle, pig and sheep with a partial overlap of the human and pig fields. By contrast there is significant overlap in all the animal and human data fields from the Ketton site. The differences in data distribution between the two sites are attributed to animal husbandry techniques, as the surface geology of the two areas is very similar, implying geological factors are an unlikely cause of the difference. It is suggested that the grazing and feeding patterns of animals at the Empingham II site were controlled and restricted, whereas at the Ketton site the animals grazed and foraged freely over a common area.  相似文献   

Stability of power-law discs — II. The global spiral modes     

N. W. Evans  & J. C. A. Read 《Monthly notices of the Royal Astronomical Society》1998,300(1):106-130

This paper reports on the in-plane normal modes in the self-consistent and the cut-out power-law discs. Although the cut-out discs are remarkably stable to bisymmetric perturbations, they are very susceptible to one-armed modes. For this harmonic, there is no inner Lindblad resonance, thus removing a powerful stabilizing influence. A physical mechanism for the generation of the one-armed instabilities is put forward. Incoming trailing waves are reflected as leading waves at the inner cut-out, thus completing the feedback for the swing-amplifier. Growing three-armed and four-armed modes occur only at very low temperatures. However, neutral m  = 3 and m  = 4 modes are possible at higher temperatures for some discs. The rotation curve index β has a marked effect on stability. For all azimuthal wavenumbers, any unstable modes persist to higher temperatures and grow more vigorously if the rotation curve is rising (β < 0) than if the rotation curve is falling (β > 0). If the central regions or outer parts of the disc are carved out more abruptly, any instabilities become more virulent. The self-consistent power-law discs possess a number of unusual stability properties. There is no natural time-scale in the self-consistent disc. If a mode is admitted at some pattern speed and growth rate, then it must be present at all pattern speeds and growth rates. Our analysis — although falling short of a complete proof — suggests that such a two-dimensional continuum of non-axisymmetric modes does not occur and that the self-consistent power-law discs admit no global non-axisymmetric normal modes whatsoever. Without reflecting boundaries or cut-outs, there is no resonant cavity and no possibility of unstable growing modes. The self-consistent power-law discs certainly admit equi-angular spirals as neutral modes, together with a one-dimensional continuum of growing axisymmetric modes.  相似文献   

Geochemistry of high-grade eclogites and metarodingites from the Central Alps     

Bernard W. Evans  Volkmar Trommsdorff  Gordon G. Goles 《Contributions to Mineralogy and Petrology》1981,76(3):301-311

Analyses for major, minor, and trace element contents of metamorphosed, variably rodingitized mafic rocks demonstrate substantial removal of Na and as much as three-fold gains in Ca as a consequence of rodingitization. Modest declines in Si and Fe can be explained in terms of dilution effects. Losses in K and Ba do not correlate with Ca% and may have been caused by an alteration process not related to the rodingitization. The Ca-metasomatism was not accompanied by a gain in Sr. The relative contents of Ti, Zr, Hf, Y, Co, Sc, and heavy REE show no readily detectable changes, despite the rodingitization (±other alteration) and subsequent metamorphisms, namely, eclogite facies (T800° C, P 20kbar) followed by amphibolite facies, sillimanite zone. Protoliths were tholeiitic basalt or diabase, and gabbro, with trace element contents indicative of a spreading center origin. Trace element and REE patterns indicate low-pressure fractionation of this magma, with plagioclase stable. This petrogenesis is consistent with prior conclusions on the shallow crustal origin of the protolith of the eclogite-metarodingite-garnet lherzolite suite in the Cima Lunga-Adula nappe, Central Alps. Based on their bulk chemical composition, the mafic rocks in this suite could be the equivalent of Mesozoic ophiolitic rocks in the more external parts of the Alps.  相似文献   

57Fe NCR of Fe phases in “magnetic cassiterites”     

B. J. Evans  E. W. Sergent Jr. 《Contributions to Mineralogy and Petrology》1975,53(3):183-194

A pyralspite garnet from an anomalously magnetic concentrate of a pegmatitic cassiterite ore has been investigated using ⁵⁷Fe nuclear gamma-ray resonance spectroscopy. The quadrupole splitting and isomer shift values of 3.6 mm/s and 1.4 mm/s, respectively, are among the largest observed for Fe²⁺ ions and indicate a very low covalency of the dodecahedral Fe²⁺ — O²-bonds. These data support the more recent and lower value (10.2–10.1 kcal/ mole) of White and Moore (1972) for the CFSE of the dodecahedral Fe²⁺ ion and suggest that the CFSE should be a useful approximation to the site preference energy of Fe²⁺ for this site.  相似文献   

Long base line tilt and strain measurement     

Paul Davis  Keith Evans  John Hosfall  Geoffrey King 《Tectonophysics》1979,52(1-4)

Two types of noise afflict strain and tilt measurement. They may be categorized as “active” noise, which is due to atmospheric pressure variations, temperature variations, water-table variations and so forth; and “passive” or signal-generated noise which is a consequence of the interaction of the strain field of interest with inhomogeneities of material properties local to the measurement site.The reason why both types of noise are normally reduced by the use of long base line instruments is explained and a simple, practical long base line tiltmeter is described.  相似文献   

On the behaviour of dumped dredger spoil     

John Joyce 《Marine pollution bulletin》1979,10(6):158-160

Observations carried out on the dredger dumping grounds at Lowestoft have shown that fine particulate dredger spoil consists of two phases, one semi-fluid and the other a solid. Once introduced into the marine environment these two phases behave differently. The solid phase falls directly to the bed where it forms a persistent deposit with a localized effect while the semifluid phase is carried by the prevailing currents in the form of a turbid cloud. The possible significance of this twin-phase behaviour is discussed.  相似文献   

Evidence for zonally-trapped propagating waves in the eastern atlantic from satellite sea surface temperature observations     

Otis B. Brown  Robert H. Evans 《Boundary-Layer Meteorology》1980,18(2):145-157

It has been hypothesized (Moore et al., 1978; O'Brien et al., 1978), that equatorial upwelling and subsequent coastal upwelling on the eastern boundary of the Atlantic Ocean are the result of eastward propagating equatorially trapped Kelvin waves in the Atlantic. Concurrent satellite and ship sea surface temperature observations taken during the GATE experiment permit validation of the satellite data as well as relating sea surface temperature (SST) variability to the local current dynamics. A method based on cross-correlations and cross-spectra of the SST field at various locations is utilized to test the Kelvin wave hypothesis. Significant periodic variation of time lags in the SST variability in the eastern Atlantic is observed by the spectral techniques. Satellite data for the 1974 summer show periodic variability which fits either eastward or westward propagating waves with 1 m s^-1 phase speed, i.e., SST supports the quasi-continuous presence of Kelvin or Yanai waves. We find no evidence for a seasonally solitary eastward propagating signal in the eastern Atlantic from SST.  相似文献   

Petrogenesis of garnet lherzolite, Cima di Gagnone, Lepontine Alps   总被引：10，自引：0，他引：10  

Bernard W. Evans  Volkmar Trommsdorff 《Earth and Planetary Science Letters》1978,40(3):333-348

Garnet lherzolite at Cima di Gagnone has chemical and mineralogical properties similar to those of other garnet lherzolites in the lower Pennine Adula/Cima Lunga Nappe (Alpe Arami, Monte Duria). The Cima di Gagnone occurrence encloses mafic boudins that belong to an eclogite-metarodingite suite common in the numerous neighboring ultramafic lenses. The ultramafic rocks at Cima di Gagnone, including the garnet lherzolite, are interpreted as tectonic fragments of an originally larger lherzolite body that underwent at least partial serpentinization prior to regional metamorphism. This lherzolite body cycled through at least three metamorphic facies: greenschist or blue-schist (as antigorite serpentinite) → eclogite (as garnet lherzolite), pre-Alpine or early Alpine → amphibolite facies (as chlorite-enstatite-tremolite peridotite), Lepontine metamorphism. Relics of titanoclinohumite in the garnet peridotite, as also recorded by Möckel near Alpe Arami, are consistent with this metamorphic history, since they indicate a possible connection with Pennine antigorite serpentinites, e.g., Liguria, Piedmont, Zermatt-Saas, Malenco, Pustertal, all of which have widespread titanoclinohumite belonging to the antigorite paragenesis. Estimated pressures in excess of 20 kbar and temperatures of 800°±50°C for the garnet lherzolite assemblage are not inconsistent with conditions inferred for Gagnone and Arami eclogites. These conditions could have been reached during deep subduction zone metamorphism. It is shown by calculation that the effects of Fe and Cr on the location of the garnet lherzolite/spinel lherzolite phase boundary largely counter-balance each other.  相似文献   

Trace element distribution in mineral separates of the Allende inclusions and their genetic implications     

Hiroshi Nagasawa  Douglas P Blanchard  Jeffrey W Jacobs  Joyce C Brannon  John A Philpotts  Naoki Onuma 《Geochimica et cosmochimica acta》1977,41(11):1587-1600

Concentrations of the REE, Sc, Co, Fe, Zn, Ir, Na and Cr were determined by instrumental neutron activation and mass spectrometric isotope dilution analysis for mineral separates of the coarseand fine-grained types (group I and II of Martin and Mason's classification) of the Allende inclusions.These data, combined with data on mineral/liquid partition coefficients, oxygen isotope distributions and diffusion calculations, suggest the following: (1) Minerals in the coarse-grained inclusions (group I) crystallized in a closed system with respect to refractory elements. On the other hand, differences in oxygen isotope distributions among minerals preclude a totally molten stage in the history of the inclusion. Group I inclusions were formed by rapid condensation (either to liquid or solid) in a supercooled solar nebula; extrasolar pyroxene and spinel dust were included but not melted in the condensing inclusions, thus preserving their extrasolar oxygen isotope composition. REE were distributed by diffusion during the subsequent heating at subsolidus temperatures; because oxygen diffuses much more slowly at these temperatures, the oxygen isotope anomalies were preserved. (2) The fine-grained (group II) inclusions were also formed by condensation from a super-cooled nebular gas; however, REE-rich clinopyroxene and spinel were formed early and REE-poor sodalite and nepheline were formed later and mechanically mixed with clinopyroxene and spinel to form the inclusions. The REE patterns of the bulk inclusions and the mineral separates are fractionated, indicating that REE abundances in the gaseous phase were already fractionated at the time of condensation of the minerals. (3) Pre-existing Mg isotope anomalies in the coarse-grained inclusions must have been erased during the heating stage thus resetting the ²⁶Al-²⁶Mg chronometer.  相似文献