In situ measurement of Re-Os isotopes in mantle sulfides by laser ablation multicollector-inductively coupled plasma mass spectrometry: analytical methods and preliminary results     

Norman J. Pearson  Olivier AlardWilliam L. Griffin  Simon E. JacksonSuzanne Y. O’Reilly 《Geochimica et cosmochimica acta》2002,66(6):1037-1050

A method has been developed for the in situ determination of Re-Os isotopes in single grains of sulfides in mantle-derived peridotites using a laser ablation microprobe attached to a multicollector-induced coupled plasma mass spectrometer (MC-ICPMS). High-precision Os isotope analysis by MC-ICPMS is demonstrated by the measurement of interlaboratory Os standards. Evaluation of mass bias correction procedures shows that the exponential law provides the best fit to the Os isotope data and that the ratio of the mass fractionation coefficients for Re and Os remains constant for the range of typical instrument operating conditions. This relationship enables the accurate and precise correction of the isobaric interference of ¹⁸⁷Re on ¹⁸⁷Os for ¹⁸⁷Re/¹⁸⁸Os values up to 1.6.Results are presented for single sulfide inclusions in olivine macrocryts from kimberlites in the Siberian and Slave Cratons, and sulfides enclosed in silicates and interstitial to silicates in peridotite xenoliths from the Slave Craton and Massif Central, France. Enclosed sulfides larger than 50 μm in diameter and with Os contents ≥40 ppm give ¹⁸⁷Os/¹⁸⁸Os ratios with a precision of 0.1% (2 SE), which is equivalent to N-TIMS whole-rock data. Interstitial sulfides typically have lower Os (10 to 30 ppm) and give analyses with lower precision (∼1 to 2%) but still provide valuable information on the movement of Os within the lithosphere. The sulfide inclusions in silicates preserve significantly less radiogenic Os isotopic compositions than interstitial sulfides and accordingly produce significantly older and more realistic Re-Os age information. Whole-rock Os isotope compositions reflect the proportions of different generations of enclosed and interstitial sulfides; this calls into question the significance of many published “depletion ages.”  相似文献   

Monitoring in coastal environments using foraminifera and thecamoebian indicators, D.B. Scott, F.S. Medioli, C.T. Schafer; Cambridge University Press, Cambridge, 2001, 177pp. Hardback, ISBN 0-521-56173-6     

John Murray 《Marine pollution bulletin》2002,44(1):83-84

  相似文献   

Modelling of oxygen and nitrogen cycling as a function of macrophyte community in the Thau lagoon     

M. Plus  A. Chapelle  P. Lazure  I. Auby  G. Levavasseur  M. Verlaque  T. Belsher  J. -M. Deslous-Paoli  J. -M. Zaldívar  C. N. Murray 《Continental Shelf Research》2003,23(17-19):1877

A three-dimensional model coupling physical and biological processes for the whole Thau lagoon (Mediterranean coast of France) was developed in order to assess the relationships between macrophytes and the oxygen and nitrogen cycles. Ten species have been inserted as forcing variables in the model. Plankton dynamics, shellfish cultivation impact and mineralization of organic matter are also considered, as well as nutrient and oxygen exchanges between the sediment and the water column.Simulations with and without the macrophytes have shown that the system can be characterized as having a highly structured pattern involving lagoon nitrogen and oxygen cycles. This pattern is created by the combined influence of macrophytes, watershed and oyster farming.The model has been also used to assess the total annual macrophyte production at the whole lagoon scale. Comparisons with phytoplankton production and with results from other temperate lagoons have underlined the high productivity of the Thau lagoon supported by active nutrient regeneration.  相似文献   

Recent advances in accessibility research: Representation,methodology and applications   总被引：22，自引：0，他引：22  

Mei-Po Kwan  Alan T. Murray  Morton E. O'Kelly  Michael Tiefelsdorf 《Journal of Geographical Systems》2003,5(1):129-138

 In this article we examine recent advances in accessibility research and their implications for future studies. We base our discussion on three intersecting dimensions that are useful for evaluating the contribution of recent studies: representation, methodology and applications. Various examples are selected to show that research concerned with representation and methodological problem solving is often applied to issues of broad concern in policy and planning. It is, however, not clear that the simultaneous treatment of representation, methodological and application issues has ever been fully worked out. The questions raised in this article may serve as a foundation for addressing issues pertinent to accurate representation, improved model building, and more rigorous applications in accessibility research. Received: 9 December 2002 / Accepted: 10 February 2003  相似文献   

Geochemical evidence for abrupt changes in relative strength of the Arabian monsoons during a stadial/interstadial climate transition   总被引：1，自引：0，他引：1  

Matthew J. Higginson  Mark A. Altabet  Richard W. Murray 《Geochimica et cosmochimica acta》2004,68(19):3807-3826

The occurrence and propagation of abrupt climate change between the high and low-latitudes has become an important focus of paleoclimatic and paleoceanographic research. The causes of abrupt change have significant implications for understanding future manifestations of similar forcings under late Holocene (‘Anthropocene’) boundary conditions. Of particular interest are signals indicative of sub-millennial scale climate change in the sub-tropics of similar magnitude and frequency to those recorded in Greenland ice cores. Earlier research in the Arabian Sea has highlighted the sensitivity of sedimentary organic carbon and nitrogen isotope measurements for recording the state of the SW monsoon and associated Arabian Sea Oxygen Minimum Zone. In this study, we exploit the unprecedented fidelity of the sedimentary δ¹⁵N record to identify a 20 cm interval at ODP Site 723 containing a stadial/inter-stadial interval between 43-42 Kyr BP. We employ sedimentary nitrogen isotopes, chlorin pigment and alkenone abundances, major and minor element analyses of highly-resolved (2 mm ≈ 10 yr) samples across this interval to compare a comprehensive, multi-proxy data set to understand (a) the processes contributing to the δ¹⁵N signal in the longer records of denitrification; and (b) the associated climatic events, especially the relative intensity of summer and winter monsoons at these times. A lack of evidence for bioturbation in excess of our 2 mm sampling resolution facilitates decadal-scale oceanographic and climatic reconstructions. Using a four-component flux-dilution model, we show that the deposition of carbonate decreased in parallel with an increase in Total Organic Matter flux from stadial to inter-stadial time. This interval is also marked by a significant drop in lithogenic (dust) accumulation, analogous to a similar decrease noted during deglaciation in the Western Arabian Sea. Combined with alkenone U₃₇^K′-derived estimates for sea surface temperature (SST), we conclude that the climatological shift from stadial to inter-stadial conditions at low latitudes was characterized by repeated switches in mean monsoon state approximately every 200 yr. The winter monsoon was the dominant mode during maximum stadial conditions; conversely the summer monsoon was dominant during maximum interstadial-like conditions. However, each interval was separated by a distinct ‘inter-monsoon’ mode, indicated by a higher continental dust flux but warmer SST. Proxy records for changing bottom-water oxygenation show near-identical results down to the mm-scale, but hint at increased export production leading the onset of anoxia during the stadial/inter-stadial transition. The coherence of all sedimentary signals depicts a wholesale reorganization of the Arabian Sea climate and marine ecosystem over approximately 200 years, a period that may be associated with monsoon modulation by small oscillations in solar irradiance.  相似文献   

Rhenium and chalcophile elements in basaltic glasses from Ko’olau and Moloka’i volcanoes: Magmatic outgassing and composition of the Hawaiian plume     

Marc D. Norman  Michael O. Garcia 《Geochimica et cosmochimica acta》2004,68(18):3761-3777

The behavior of chalcophile metals in volcanic environments is important for a variety of economic and environmental applications, and for understanding large-scale processes such as crustal recycling into the mantle. In order to better define the behavior of chalcophile metals in ocean island volcanoes, we measured the concentrations of Re, Cd, Bi, Cu, Pb, Zn, Pt, S, and a suite of major elements and lithophile trace elements in moderately evolved (6-7% MgO) tholeiitic glasses from Ko’olau and Moloka’i volcanoes. Correlated variations in the Re, Cd, and S contents of these glasses are consistent with loss of these elements as volatile species during magmatic outgassing. Bismuth also shows a good correlation with S in the Ko’olau glasses, but undegassed glasses from Moloka’i have unexpectedly low Bi contents. Rhenium appears to have been more volatile than either Cd or Bi in these magmas.Undegassed glasses with 880-1400 ppm S have 1.2-1.5 ppb Re and 130-145 ppb Cd. In contrast, outgassed melts with low S (<200 ppm) are depleted in these elements by factors of 2-5. Key ratios such as Re/Yb and Cu/Re are fractionated significantly from mantle values. Copper, Pb, and Pt contents of these glasses show no correlation with S, ruling out segregation of an immiscible magmatic sulfide phase as the cause of these variations. Undegassed Hawaiian tholeiites have Re/Yb ratios significantly higher than those of MORB, and extend to values greater than that of the primitive mantle. Loss of Re during outgassing of ocean island volcanoes, may help resolve the apparent paradox of low Re/Os ratios in ocean island basalts with radiogenic Os isotopic compositions. Plume source regions with Re/Yb ratios greater than that of the primitive mantle may provide at least a partial solution to the “missing Re” problem in which one or more reservoirs with high Re/Yb are required to balance the low Re/Yb of MORB.Lithophile trace element compositions of most Ko’olau and Moloka’i tholeiites are consistent with variable degrees of melting of fertile mantle peridotite. However, light rare earth element (LREE)-enriched glasses have trace element compositions more consistent with a garnet-rich source having a distinctive trace element composition. This provides additional evidence for a unique source component possibly related to recycled oceanic crust contributing to Ko’olau tholeiites.  相似文献   

Effects of peat on the shapes of alluvial channels: examples from the Cumberland Marshes, Saskatchewan, Canada     

Norman D. Smith  Marta Prez-Arlucea 《Geomorphology》2004,61(3-4):323-335

An avulsion of the lower Saskatchewan River in the 1870s inundated a large segment of peat-covered floodplain that subsequently has become aggraded with a broad (500 km²) belt of alluvium deposited by the redirected flow. Routing of water and sediment discharge through the avulsion-affected area has been accomplished mainly by networks of sandy bedded anastomosed channels that have formed, evolved, and abandoned as the alluvial belt prograded down the floodplain slope. These processes continue today, though at a much-reduced rate. New channels, formed by crevassing and basinward extension of distributaries, are initially small and shallow, with bottom elevations situated within the avulsive alluvium but above the pre-avulsion peat (floodplain) surface. Subsequent enlargement and downcutting of many of these channels eventually uncovers the underlying peat layer whose resistance to erosion exerts significant influence on cross-sectional shape and further channel development. Peat-floored channels tend to have rectangular cross-sections, high ratios of average to maximum depth (D/D_max), and a large range of width-to-depth ratios. If the channel continues to enlarge, the peat layer eventually becomes breached, commonly leading to temporarily irregular cross-sections caused by localized scouring at the breach sites. Eventually, the peat layer is completely eroded from the channel floor by undercutting and slumping, after which channel shape becomes governed mainly by other perimeter characteristics. Channels unaffected by peat, either before the peat layer is encountered during early channel development or after it is entirely removed, tend to have low width/depth ratios and a large range of D/D_max values.  相似文献   

Chronology and stratigraphy of the Magdalen Islands archipelago from the last glaciation to the early Holocene: new insights into the glacial and sea‐level history of eastern Canada          下载免费PDF全文

Audrey M. Rémillard  Guillaume St‐Onge  Pascal Bernatchez  Bernard Hétu  Jan‐Pieter Buylaert  Andrew S. Murray  Benoit Vigneault 《Boreas: An International Journal of Quaternary Research》2016,45(4):604-628

  相似文献   

Dating megafaunal extinction on the Pleistocene Darling Downs,eastern Australia: the promise and pitfalls of dating as a test of extinction hypotheses     

Gilbert J. Price  Gregory E. Webb  Jian-xin Zhao  Yue-xing Feng  Andrew S. Murray  Bernard N. Cooke  Scott A. Hocknull  Ian H. Sobbe 《Quaternary Science Reviews》2011,30(7-8):899-914

A key to understanding Late Pleistocene megafaunal extinction dynamics is knowledge of megafaunal ecological response(s) to long-term environmental perturbations. Strategically, that requires targeting fossil deposits that accumulated during glacial and interglacial intervals both before and after human arrival, with subsequent palaeoecological models underpinned by robust and reliable chronologies. Late Pleistocene vertebrate fossil localities from the Darling Downs, eastern Australia, provide stratigraphically-intact, abundant megafaunal sequences, which allows for testing of anthropogenic versus climate change megafauna extinction hypotheses. Each stratigraphic unit at site QML796, Kings Creek Catchment, was previously shown to have had similar sampling potential, and the basal units contain both small-sized taxa (e.g., land snails, frogs, bandicoots, rodents) and megafauna. Importantly, sequential faunal horizons show stepwise decrease in taxonomic diversity with the loss of some, but not all, megafauna in the geographically-small palaeocatchment. The purpose of this paper is to present the results of our intensive, multidisciplinary dating study of the deposits (>40 dates). Dating by means of accelerator mass spectrometry (AMS) ¹⁴C (targeting bone, freshwater molluscs, and charcoal) and thermal ionisation mass spectrometry U/Th (targeting teeth and freshwater molluscs) do not agree with each other and, in the case of AMS ¹⁴C dating, lack internal consistency. Scanning electron microscopy and rare earth element analyses demonstrate that the dated molluscs are diagenetically altered and contain aragonite cements that incorporated secondary young C, suggesting that such dates should be regarded as minimum ages. AMS ¹⁴C dated charcoals provide ages that occur out of stratigraphic order, and cluster in the upper chronological limits of the technique (～40–48 ka). Again, we suggest that such results should be regarded as suspicious and only minimum ages. Subsequent OSL and U/Th (teeth) dating provide complimentary results and demonstrate that the faunal sequences actually span ～120–83 ka, thus occurring beyond the AMS ¹⁴C dating window. Importantly, the dates suggest that the local decline in biological diversity was initiated ～75,000 years before the colonisation of humans on the continent. Collectively, the data are most parsimoniously consistent with a pre-human climate change model for local habitat change and megafauna extinction, but not with a nearly simultaneous extinction of megafauna as required by the human-induced blitzkrieg extinction hypothesis. This study demonstrates the problems inherent in dating deposits that lie near the chronological limits of the radiocarbon dating technique, and highlights the need to cross-check previously-dated archaeological and megafauna deposits within the timeframe of earliest human colonisation and latest megafaunal survival.  相似文献   

Community‐Derived Standards for LA‐ICP‐MS U‐(Th‐)Pb Geochronology – Uncertainty Propagation,Age Interpretation and Data Reporting          下载免费PDF全文

Matthew S. A. Horstwood  George Gehrels  Simon E. Jackson  Noah M. McLean  Chad Paton  Norman J. Pearson  Keith Sircombe  Paul Sylvester  Pieter Vermeesch  James F. Bowring  Daniel J. Condon  Blair Schoene 《Geostandards and Geoanalytical Research》2016,40(3):311-332

The LA‐ICP‐MS U‐(Th‐)Pb geochronology international community has defined new standards for the determination of U‐(Th‐)Pb ages. A new workflow defines the appropriate propagation of uncertainties for these data, identifying random and systematic components. Only data with uncertainties relating to random error should be used in weighted mean calculations of population ages; uncertainty components for systematic errors are propagated after this stage, preventing their erroneous reduction. Following this improved uncertainty propagation protocol, data can be compared at different uncertainty levels to better resolve age differences. New reference values for commonly used zircon, monazite and titanite reference materials are defined (based on ID‐TIMS) after removing corrections for common lead and the effects of excess ²³⁰Th. These values more accurately reflect the material sampled during the determination of calibration factors by LA‐ICP‐MS analysis. Recommendations are made to graphically represent data only with uncertainty ellipses at 2s and to submit or cite validation data with sample data when submitting data for publication. New data‐reporting standards are defined to help improve the peer‐review process. With these improvements, LA‐ICP‐MS U‐(Th‐)Pb data can be considered more robust, accurate, better documented and quantified, directly contributing to their improved scientific interpretation.  相似文献