RbSr and KAr ages of paleozoic glauconites from Ohio—Indiana and Missouri,U.S.A.     

Norman K. Grant  Thomas E. Laskowski  K.A. Foland 《Chemical Geology》1984,46(3):217-239

Glauconite pellets from the Lower Silurian Brassfield Formation on both limbs of the Cincinnati Arch in Ohio and Indiana give a RbSr age of 370 ± 11 Ma, which is substantially younger than the stratigraphic age of the formation. The age is concordantcwith conventional KAr ages of 355 ± 6 and 368 ± 5 Ma for two of the same glauconites. Concordant ages were also obtained from the Viburnum Trend in Missouri, where glauconite pellets from the Davis Formation in an ore-zone collapse structure into the underlying Bonneterre Formation give a RbSr age of 387 ± 21 Ma and conventional KAr ages of 368 ± 5 and 369 ± 5 and 369 ± 5 Ma. A third suite of glauconite from the Bonneterre Formation in the Old Lead Belt ～ 10 km from the nearest ore body has given a RbSr age of 423 ± 7 Ma and slightly older conventional KAr ages of 434 ± 6, 445 ± 6 and 441 ± 11 Ma.Because these glauconite-bearing rocks have been buried to depths of less than 1 km, thermal resetting of the RbSr and KAr systematics appears unlikely. The initial ${}^{87}\text{Sr}{}^{86}\text{Sr}$ ratios of the RbSr isochrons are similar to the ratios for vein- and vug-filling dolomite and calcite. This is consistent with resetting of the RbSr and KAr systems during diagenetic changes which included the isotopic equilibration (perhaps by cation exchange) of the Sr in the glauconite with that in the diagenetic and Mississippi Valley-type ore fluids. This interpretation implies that the age of the Mississippi Valley-type mineralization in the Viburnum Trend is Devonian rather than Carboniferous—Permian as has been inferred from paleomagnetic measurements.Cation-exchange experiments with a dilute Sr-bearing solution and an artificial oilfield brine indicate that glauconite adsorbs large amounts of Sr, some of which is sufficiently strongly attached to the glauconite lattice as to resist leaching with ammonium acetate. The introduction of this strongly attached Sr may be the first step in the resetting of the RbSr systematics of glauconite by cation exchange.  相似文献   

The increasing CO2 concentration in the atmosphere and its implication on agricultural productivity II. Effects through CO2-induced climatic change     

Norman J. Rosenberg 《Climatic change》1982,4(3):239-254

In a prior paper (Part I), the point was made that, assuming an unchanged climate, water use efficiency in agricultural crop production will likely be favored by the increase in CO₂ concentration projected to occur within the next half century. Since climatic changeis likely to result from the CO₂ concentration increase, its possible impacts on agricultural productivity must also be considered. An attempt to do so, using the Great Plains region of North America as a case study, is reported in this paper (Part II). A number of climatic models predict significant increases in surface temperature. Manabe and Wetherald's (1980) model provides the most specific projections for a hypothetical Northern hemisphere continent. That model also predicts an intensification of the hydrologic cycle with rainfall distribution altered so that some zones will receive more and some less as a result of a doubling in the atmospheric CO₂ concentration. The zone between 37 and 47° N latitude will suffer a reduction in availability of soil moisture. A number of regression models of grain yield as a function of temperature and precipitation have been used to anticipate the impacts of the projected climatic changes. The value of this approach is questioned. An alternative approach - the study of the migration of major agricultural crops across strong climatic gradients - is proposed. Changes in the geographical distribution of the hard red winter wheat zone in North America provide an example. The point is also made that factorscurrently limiting food production must be considered in order to predict the possible impacts of any given climatic change. In the central Great Plains today, the energy consumed by evapotranspiration often exceeds that supplied by net radiation since sensible heat advection from dryer regions to the south and west provides a major additional input of energy. If, as models project, the excess of precipitation over evaporation increases south of 37° N, the advection of sensible heat and, hence, the rates of evapotranspiration and degree of water stress on growing plants could be reduced in the adjacent regions to the north. Published as Paper No. 6123, Journal Series, Nebraska Agricultural Experiment Station. The work reported was conducted under Regional Research Project 11-033 and Nebraska Agricultural Station Project 11-049. George Holmes Professor of Agricultural Meteorology, Center for Agricultural Meteorology and Climatology, Institute of Agriculture and Natural Resources, University of Nebraska, Lincoln, Nebraska, 68583-0728.  相似文献   

Nutrient pore water chemistry,Great Bay,New Hampshire: Benthic fluxes     

William Berry Lyons  Theodore C. Loder  Susan M. Murray 《Estuaries and Coasts》1982,5(3):230-233

Benthic fluxes of C, N, P and Si have been measured at two sites in Great Bay Estuary, New Hampshire. Higher fluxes of reactive phosphate, nitrate and reactive silicate were observed at the site where bioturbation is known to occur and the fluxes of NH₄ ⁺, PO₄ ^?3 and reactive silicate at this location were from 3 to 6 times higher than that calculated by simple pore water diffusion models. *** DIRECT SUPPORT *** A01BY019 00010  相似文献   

The oxidation states of cobalt and selected metals in Pacific ferromanganese nodules     

J.G. Dillard  D.L. Crowther  J.W. Murray 《Geochimica et cosmochimica acta》1982,46(5):755-759

A study of the oxidation states of metals in selected Pacific ferromanganese nodules by x-ray photoelectron spectroscopy (XPS) indicates the presence of Co(III), Pb(II), Pb(IV), Fe(III) and Ti(IV). These findings are based on measurements of core electron binding energies and an evaluation of the core electron shake-up satellite features.  相似文献   

The surface chemistry of δMnO2 in major ion sea water     

L.S Balistrieri  J.W Murray 《Geochimica et cosmochimica acta》1982,46(6):1041-1052

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Characteristics of air flow above and within soybean canopies     

Dennis D. Baldocchi  Shashi B. Verma  Norman J. Rosenberg 《Boundary-Layer Meteorology》1983,25(1):43-54

Air flow was observed above and within canopies of a number of kinds of soybeans. The Clark cultivar and two isolines of the Harosoy cultivar were studied in 1979 and 1980, respectively. Wind speed above the canopy was measured with cup anemometers. Heated thermistor anemometers were used to measure air flow within the canopy. Above-canopy air flow was characterized in terms of the zero-plane displacement (d), roughness parameter (z _o) and drag coefficient (C _d). d and z _o were dependent on canopy height but were independent of friction velocity in the range 0.55 to 0.75 m s^?1 · C _d for the various canopies ranged from 0.027 to 0.035. Greater C _d values were measured over an erectophile canopy than over a planophile canopy. C _d was not measurably affected by differences in leaf pubescence. Within-canopy wind profiles were measured at two locations: within and between rows. The wind profile was characterized by a region of great wind shear in the upper canopy and by a region of relatively weak wind shear in the middle canopy. Considerable spatial variability in wind speed was evident, however. This result has significant implications for canopy flow modeling efforts aimed at evaluating transport in the canopy. In the lower canopy, wind speed within a row increased with depth whereas wind speed between two rows decreased with depth. The wind speeds at the two locations tended to converge to a common value at a height near 0.10 m. The attenuation of within-canopy air flow was stronger in canopies with greater foliage density. Canopy flow attenuation seemed to decrease with increasing wind speed, suggesting that high winds distorted the shape of the canopy in such a manner that the penetration of wind into the canopy increased.  相似文献   

Radiocarbon dating of Danube Delta deposits     

Nicolae Panin  Stefana Panin  Norman Herz  John E. Noakes 《Quaternary Research》1983,19(2):249-255

The Holocene history of the Danube Delta has been studied using ¹⁴C analyses of faunal material. The principal phases of development include: (1) initial Letea Caroarman spit, 11,700–9800 yr B.P. in its central part, 8800-5500 yr B.P. in its southern part; (2) Sf. Gheorghe I Delta, 8900-7200 yr B.P.; (3) Sulina Delta, 7200-2000 yr B.P., and (4) Sf. Gheorghe II Delta-Chilia Delta 2000 yr B.P.-present. Other smaller-scale features have also been dated, including secondary deltas (Co?na and Sinoe Deltas) and littoral bars. Age determinations carried out on whole samples were erratic and it was found that individual species had to be separated and dated. In all cases, the older dates were of transported material whereas the younger dates gave the true age of the formation.  相似文献   

Reducing model complexity for explanation and prediction   总被引：1，自引：1，他引：1  

A. Brad Murray   《Geomorphology》2007,90(3-4):178

Numerical models can be useful for explaining poorly understood phenomena or for reliable quantitative predictions. When modeling a multi-scale system, a ‘top-down’ approach—basing models on emergent variables and interactions, rather than explicitly on the much faster and smaller scale processes that give rise to them—facilitates both goals. Parameterizations representing emergent interactions range from highly simplified and abstracted to more quantitatively accurate. Empirically based large-scale parameterizations lead more reliably to accurate large-scale behavior than do parameterizations of much smaller scale processes. Conversely, purposefully simplified representations of model interactions can enhance a model's utility for explanation, clarifying the key feedbacks leading to an enigmatic behavior. For such potential insights to be relevant, the interactions in the model need to correspond to those in the ‘real’ system in some straightforward way. Such a correspondence usually holds for models constructed for predictive purposes, although this is not a requirement. The goals motivating a modeling endeavor help determine the most appropriate modeling strategies, as well as the most appropriate criteria for judging model usefulness.  相似文献   

Lithosphere formation in the central Slave Craton (Canada): plume subcretion or lithosphere accretion?     

Sonja Aulbach  William L. Griffin  Norman J. Pearson  Suzanne Y. O’Reilly  Buddy J. Doyle 《Contributions to Mineralogy and Petrology》2007,154(4):409-427

Major-element compositions of minerals in peridotite xenoliths from the Lac de Gras kimberlites provide constraints on the mode of lithosphere formation beneath the central Slave Craton, Canada. Magnesia contents of reconstructed whole rocks correlate positively with NiO and negatively with CaO contents, consistent with variable partial melt extraction. Alumina and Cr₂O₃ contents are broadly positively correlated, suggestive of melt depletion in the absence of a Cr–Al phase. Garnet modes are high at a given Al₂O₃ content (a proxy for melt depletion), falling about a 7 GPa melt depletion model. These observations, combined with high olivine Mg# and major-element relationships of FeO-poor peridotites (<7.5 wt%) indicative of melt loss at pressures >3 GPa (residual FeO content being a sensitive indicator of melt extraction pressure), and similar high pressures of last equilibration (∼4.2 to 5.8 GPa), provide multiple lines of evidence that the mantle beneath the central Slave Craton has originated as a residue from high-pressure melting, possibly during plume subcretion. Apparent low melt depletion pressures for high-FeO peridotites (>7.5 wt%) could suggest formation in an oceanic setting, followed by subduction to their depth of entrainment. However, these rocks, which are characterised by low SiO₂ contents (<43 wt%), are more likely to be the result of post-melting FeO-addition, leading to spuriously low estimates of melt extraction pressures. They may have reacted with a silica-undersaturated melt that dissolved orthopyroxene, or experienced olivine injection by crystallising melts. A secular FeO-enrichment of parts of the deep mantle lithosphere is supported by lower average Mg# in xenolithic olivine (91.7) compared to olivine inclusions in diamond (92.6).  相似文献   

Characterizing groundwater flow in a faulted karst system using optical brighteners from septic systems as tracers     

K. E. Murray  D. R. Straud  W. W. Hammond 《Environmental Geology》2007,53(4):769-776

This study used optical brighteners (OB) released from septic systems to show that groundwater flow direction is largely controlled by the structural framework in a faulted karst groundwater system. Effective protection of groundwater resources requires that groundwater systems are adequately characterized and source water protection areas (SWPA) are developed for drinking water wells. Karst aquifers are among the most sensitive to contamination due to high recharge rates, and among the most difficult aquifers to characterize due to heterogeneity, and anisotropy. Because septic systems may be used to treat wastewater within SWPAs for karst aquifers there is a need to characterize these groundwater systems using tracers. The objective of this study was to characterize groundwater flow in a faulted portion of the Edwards aquifer in Bexar County, Texas using OB that are released as incidental tracers from septic systems. This study included measurement of water levels, sampling of groundwater and surface water, analysis for OB, and spatial analysis in a GIS. Results show that OB intensities were highest to the southwest of the septic area, a direction that is sub-parallel to the fault and fracture orientation and nearly perpendicular to the hydraulic gradient. This indicates that movement of OB, solutes, or non-aqueous liquids/solids in a faulted karst system can be largely controlled by fault/fracture orientation and structural relay ramps.  相似文献