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1.
High primary productivity on the Pacific coast of the Baja California Peninsula is usually related to coastal upwelling activity that injects nutrients into the euphotic zone in response to prevailing longshore winds (from the northwest to north). The upwelling process has maximum intensity from April to June, with the coastal upwelling index varying from 50 to 300 m3/s per 100 m of coastline. Along the entire coast of the peninsula, the upwelling intensity changes in accordance with local wind conditions and bottom topography. Spatial variability can also be modulated by the influence of mesoscale meanders of the California Current. We have identified the seasonal and synoptic variability of upwelling signatures on the Baja California shelf, using averaged monthly and weekly sea surface temperature (SST) distributions obtained from remote sensing imagery from the Advanced Very High Resolution Radiometer in the period from 1996 to 2001. Analysis of SST distribution and direct experimental data on temperature and nutrient concentration shows that the areas with the coldest SST anomalies were closely related to the bottom slope, shelf width, and coastline orientation relating to wind direction. We also assume that the nutrient transport into the coastal lagoons may be forced by the coupling of coastal upwelling and tidal pumping of surface waters into the lagoon system. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   
2.
The Eskay Creek, British Columbia, Canada, is a polymetallic, gold- and silver-rich, volcanic-hosted, massive sulfide deposit. The ore in the deposit is divided into subzones distinguished by mineralogy, texture, grade and metallurgical characteristics. This study presents the results of a mineralogical examination of three composite field samples, with emphasis on the chemistry of sphalerite. Sphalerite is associated with variable amounts of Hg-tetrahedrite and cinnabar, and an array of sulfides, sulphosalts and non-opaque minerals. Electron micro probe analyses of sphalerite in the three composite samples reveal wide variations in compositions. The Hg content in sphalerite in the three samples varies between 0.08 and 16.35 wt%, whereas the Fe content ranges from 0.33 to 2.29 wt%. The chemical formula of the sphalerite shows the compositional range (Zn0.89–0.98Hg0.01–0.09.Fe0.005–0.02)S. Sphalerite exhibits an almost perfect substitution of Hg and Zn, as shown by the negative covariance between them. Sphalerite with the highest Hg contents tends to have the lowest Fe concentrations. The highest Hg contents in sphalerite are recorded in the samples with the highest bulk Hg concentrations and with the highest cinnabar contents.

The compositional variations of sphalerite are important because they can be used in mapping ore forming fluids and indicate possible temporal variations. Second, determination of the compositional variation of the sphalerite in the mine has metallurgical implications because the mineral is an important Zn source. The mineralogical data indicate that non-physical processes (e.g. pyrometallurgy) must be used to separate Hg from Zn concentrates, with direct environmental implications, that is, release of metals, such as Hg, into the environment during mining and processing.  相似文献   

3.
The influence of aqueous silica on gallium(III) hydrolysis in dilute (2 × 10−4mGa ≤ 5 × 10−3) and moderately concentrated (0.02 ≤ mGa ≤ 0.3) aqueous solutions was studied at ambient temperature, using high resolution X-ray absorption fine structure (XAFS) and nuclear magnetic resonance (NMR) spectroscopies, respectively. Results show that, in Si-free acidic solutions (pH < 3), Ga is hexa-coordinated with oxygens of H2O molecules and/or OH groups in the first coordination sphere of the metal. With increasing pH, these hydroxyl groups are progressively replaced by bridging oxygens (-O-), and polymerized Ga-hydroxide complexes form via Ga-O-Ga chemical bonds. In the 2.5-3.5 pH range, both XAFS and NMR spectra are consistent with the dominant presence of the Ga13 Keggin polycation, which has the same local structure as A113. Under basic pH (pH > 8), Ga exhibits a tetrahedral coordination, corresponding to Ga(OH)4 species, in agreement with previous NMR and potentiometric studies. Major changes in Ga hydrolysis have been detected in the presence of aqueous silica. Ga is tetra-coordinated, both in basic and acid (i.e., at pH > 2.7) Si-bearing solutions (0.01 ≤ mSi ≤ 0.2), and forms stable gallium-silicate complexes. In these species, Ga binds via bridging oxygen to 2 ± 1 silicons, with an average Ga-Si distance of 3.16 ± 0.05 Å, and to 2 ± 1 silicons, with an average Ga-Si distance of 3.39 ± 0.03 Å. These two sets of Ga-Si distances imply the formation of two types of Ga-silicate aqueous complex, cyclic Ga-Si2-3 species (formed by the substitution of Si in its tri-, tetra- or hexa-cyclic polymers by Ga atoms), and chainlike GaSi2-4 species (similar to those found for A1), respectively. The increase in the number of Si neighbors (a measure of the complex concentration and stability), in alkaline media, with increasing SiO2(aq) content and decreasing pH is similar to that for A1-Si complexes found in neutral to basic solutions. At very acid pH and moderate silica concentrations, the presence of another type of Ga-Si complex, in which Ga remains hexa-coordinated and binds to the silicon tetrahedra via the GaO6 octahedron corners, has also been detected. These species are similar to those found for Al3+ in acid solutions. Thus, as for aluminum, silicic acid greatly hampers Ga hydrolysis and enhances Ga mobility in natural waters via the formation of gallium-silicate complexes.  相似文献   
4.
The extent of the Barents-Kara Ice Sheet during the eastern Last Glacial Maximum (LGM) is not yet fully known. A detailed echo-sounding survey performed during the Boris Petrov Expedition 2001 permitted the detailed mapping of part of it. Based on the profiling results, a southern connection between the LGM Barents-Kara Ice Sheet and a local ice sheet on Taymyr Peninsula appears to be unlikely. Based on sediment core data and profiling results, most of the terrigenous river-derived material accumulated in the estuaries during late Holocene times, whereas during early Holocene times of lowered sea level major amounts were transported further offshore and accumulated on the shelf. During the post-glacial sea level rise, the main depocentre migrated southward, reaching its present position no earlier than about 6 cal. Ky BP (or 5.2 Kya). Future studies of accelerator mass spectrometry (AMS) 14C-dated sediment cores will allow a detailed reconstruction of the variability of fluvial sediment discharge and the history of glaciation in the Kara Sea during late Quaternary times.  相似文献   
5.
Time-domain electromagnetic migration in the solution of inverse problems   总被引:5,自引:0,他引:5  
Time-domain electromagnetic (TDEM) migration is based on downward extrapolation of the observed field in reverse time. In fact, the migrated EM field is the solution of the boundary-value problem for the adjoint Maxwell's equations. The important question is how this imaging technique can be related to the solution of the geoelectrical inverse problem. In this paper we introduce a new formulation of the inverse problem, based on the minimization of the residual-field energy flow through the surface or profile of observations. We demonstrate that TDEM migration can be interpreted as the first step in the solution of this specially formulated TDEM inverse problem. However, in many practical situations this first step produces a very efficient approximation to the geoelectrical model, which makes electromagnetic migration so attractive for practical applications. We demonstrate the effectiveness of this approach in inverting synthetic and practical TDEM data.  相似文献   
6.
International Journal of Earth Sciences - Early diagenetic carbonates are rare in Lake Baikal. Siderite (Fe carbonate) concretions in the sediments were discovered only recently. Here, we discuss...  相似文献   
7.
Mineralogy and Petrology - The new mineral ziminaite, ideally Fe3+VO4, was found in fumarole sublimates at the Bezymyannyi volcano, Kamchatka, Russia. Ziminaite occurs as lamellar, tabular or...  相似文献   
8.
Analysis of Argo float trajectories at 1 000 m and temperature at 950 m in the North Atlantic between November 2003 and January 2005 demonstrates the existence of two different circulation modes with fast transition between them. Each mode has a pair of cyclonic - anticyclonic gyres. The difference is the location of the cyclonic gyre. The cyclonic gyre stretches from southeast to northwest in the first mode and from the southwest to the northeast in the second mode. The observed modes strongly affect the heat and salt transport in the North Atlantic. In particular, the second mode slows down the westward transport of the warm and saline water from the Mediterranean Sea.  相似文献   
9.
The interplanetary mission, Venera-D, which is currently being planned, includes a lander. For a successful landing, it is necessary to estimate the frequency distributions of slopes of the Venusian surface at baselines that are comparable with the horizontal dimensions of lander (1–3 m). The available data on the topographic variations on Venus preclude estimates of the frequency of the short-wavelength slopes. In our study, we applied high-resolution digital terrain models (DTM) for specific areas in Iceland to estimate the slopes on Venus. The Iceland DTMs have 0.5 m spatial and 0.1 m vertical resolution. From the set of these DTMs, we have selected those that morphologically resemble typical landscapes on Venus such as tessera, shield, regional, lobate, and smooth plains. The mode of the frequency distribution of slopes on the model tessera terrain is within a 30°–40° range and a fraction of the surface has slopes <7°, which is considered as the upper safety limit. This is the primary interest. The frequency distribution of slopes on the model tessera is not changed significantly as the baseline is changed from 1 m to 3 m. The terrestrial surfaces that model shield and regional plains on Venus have a prominent slope distribution mode between 8°–20° and the fraction of the surfaces with slopes <7° is less than 30% on both 1 m and 3 m baselines. A narrow, left-shifted histogram characterizes the model smooth plains surfaces. The fraction of surfaces with slopes <7° is about 65–75% for the shorter baseline (1 m). At the longer baseline, the fraction of the shallow-sloped surfaces is increased and fraction of the steep slopes is decreased significantly. The fraction of surfaces with slopes <7° for the 3-m baseline is about 75–88% for the terrains that model both lobate and smooth plains.  相似文献   
10.
We discuss a change in the resurfacing regimes of Venus and probable ways of forming the terrain types that make up the surface of the planet. The interpretation of the nature of the terrain types and their morphologic features allows us to characterize their scientific priority and the risk of landing on their surface to be estimated. From the scientific point of view, two terrain types are of special interest and represent easily achievable targets: the lower unit of regional plains and the smooth plains associated with impact craters. Regional plains are probably a melting from the upper fertile mantle. The material of smooth plains of impact origin is a well-mixed and representative sample of the Venusian crust. The lower unit of regional plains is the most widespread one on the surface of Venus, and it occurs within the boundaries of all of the precalculated approach trajectories of the lander. Smooth plains of impact origin are crossed by the approach trajectories precalculated for 2018 and 2026.  相似文献   
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