Visualization of Volcanic Rock Geochemical Data and Classification with Artificial Neural Networks   总被引：1，自引：0，他引：1  

Juan Pablo Lacassie  Javier Ruiz del Solar  Barry Roser  Francisco Hervé 《Mathematical Geology》2006,38(6):697-710

An unsupervised neural network technique, Growing Cell Structures (GCS) was used to visualize geochemical differences between four different island arc volcanic rock types: basalts, andesites, dacites and rhyolites. The output of the method shows the cluster structure of the dataset clearly, and the relevant geochemical patterns and relationships between its variables. The data can be separated into four clusters, each associated with a specific volcanic rock type (basalt, andesite, dacite and rhyolite), according to a unique combination of major element concentrations. Following clustering, performance of the trained GCS network as a classifier of volcanic rock type was tested using two test datasets with major element concentration data for 312 and 496 island arc volcanic rock samples of known volcanic type. Preliminary classification results are promising. In the first test dataset 94% of basalts, 76% of andesites, 83% of dacites and 100% of the rhyolites were classified correctly. Successful classification rates in the second dataset were 100%, 80%, 77%, and 98% respectively. The success of the analysis suggests that neural networks analysis constitutes a useful analytical tool for identification of natural clusters and examination of the relationships between numeric variables in large datasets, and that can be used for automatic classification of new data.  相似文献   

Early Paleozoic Structural and Metamorphic Evolution of Western Sierra de San Luis (Argentina), in Relation to Cuyania Accretion     

Pablo Diego GonzAlez  Ana Maria Sato  Eduardo Jorge Llambias  Miguel A.S. Basei  Silvio R.F. Vlach 《Gondwana Research》2004,7(4):1157-1170

Structural, metamorphic and isotopic data obtained from the Nogoli Metamorphic Complex of western Sierra de San Luis indicate that the Early Paleozoic Famatinian Orogeny overprinted an already structured and metamorphosed older basement. The older geological features are relict NW trending fabric associated with high-grade (amphibolite facies) regional metamorphism preserved within thin strips of schists and paragneisses and in the core of mafic to ultramafic lenses. Arc magmatism, medium P (Barrovian type)/high T (amphibolite to granulite facies) regional metamorphism and penetrative NNE to NE trending foliation are related to the building of the Famatinian orogenic belt. The P-T conditions of the Famatinian prograde metamorphism reached a pressure peak of ca. 8 kb, with a thermal peak from -750°C up to -820°C. U-Pb conventional and chemical dating and Ar-Ar plateau ages constrain the peak of the main orogenic phase related to the Famatinian belt to 470–457 Ma (Early to Mid-Ordovician). Greenschist facies retrograde metamorphism closely associated with shear zones and secondary Ar-Ar plateau and Sm-Nd ages suggest that a late to post-orogenic phase of the Famatinian belt was active at least since -445 Ma. This phase continued during the Silurian to Late Devonian times through multiple reactivation of early shear zones. The Famatinian Orogeny reset a previous thermal history and therefore, the timing of the relict fabric could not be constrained conclusively with radiometric dates. Despite this difficulty, a range of 520 to 490 Ma suggests some inheritance from Pampean events registered by the older NW-SE fabric. The Early to Mid-Ordovician regional metamorphism and ductile deformation of the western Sierra de San Luis is interpreted as the orogenic effects of the collision of the allochthonous Cuyania terrane with the autochthonous proto-Pacific margin of Gondwana during the Famatinian Orogeny.  相似文献   

Magma degassing and basaltic eruption styles: a case study of 2000 year BP Xitle volcano in central Mexico   总被引：1，自引：0，他引：1  

Pablo Cervantes  Paul Wallace   《Journal of Volcanology and Geothermal Research》2003,120(3-4):249-270

To investigate the relationship between volatile abundances and eruption style, we have analyzed major element and volatile (H₂O, CO₂, S) concentrations in olivine-hosted melt inclusions in tephra from the 2000 yr BP eruption of Xitle volcano in the central Trans-Mexican Volcanic Belt. The Xitle eruption was dominantly effusive, with fluid lava flows accounting for 95% of the total dense rock erupted material (1.1 km³). However, in addition to the initial, Strombolian, cinder cone-building phase, there was a later explosive phase that interrupted effusive activity and deposited three widespread ash fall layers. Major element compositions of olivine-hosted melt inclusions from these ash layers range from 52 to 58 wt.% SiO₂, and olivine host compositions are Fo_84–86. Water concentrations in the melt inclusions are variable (0.2–1.3 wt.% H₂O), with an average of 0.45±0.3 (1σ) wt.% H₂O. Sulfur concentrations vary from below detection (50 ppm) to 1000 ppm but are mostly ≤200 ppm and show little correlation with H₂O. Only the two inclusions with the highest H₂O have detectable CO₂ (310–340 ppm), indicating inclusion entrapment at higher pressures (700–900 bars) than for the other inclusions (≤80 bars). The low and variable H₂O and S contents of melt inclusions combined with the absence of less soluble CO₂ indicates shallow-level degassing before olivine crystallization and melt inclusion formation. Olivine morphologies are consistent with the interpretation that most crystallization occurred rapidly during near-surface H₂O loss. During cinder cone eruptions, the switch from initial explosive activity to effusive eruption probably occurs when the ascent velocity of magma becomes slow enough to allow near-complete degassing of magma at shallow depths within the cone as a result of buoyantly rising gas bubbles. This allows degassed lavas to flow laterally and exit near the base of the cone while gas escapes through bubbly magma in the uppermost part of the conduit just below the crater. The major element compositions of melt inclusions at Xitle show that the short-lived phase of renewed explosive activity was triggered by a magma recharge event, which could have increased overpressure in the storage reservoir beneath Xitle, leading to increased ascent velocities and decreased time available for degassing during ascent.  相似文献   

Uptake of dissolved Cd by biogenic and abiogenic aragonite: a comparison with sorption onto calcite   总被引：3，自引：0，他引：3  

Manuel Prieto  Pablo Cubillas 《Geochimica et cosmochimica acta》2003,67(20):3859-3869

The uptake of Cd²⁺ by aragonite and calcite is investigated by combining macroscopic measurements with some qualitative sorption experiments performed in a hydrogel medium. Both biogenic and abiogenic aragonites were studied in order to evaluate the process on materials with different textures. Assuming that sorption occurs by surface precipitation of metal-bearing solids, the gel produces a drastic decrease in the nucleation density, which allows for the precipitation of crystallites that are large enough to be analysed by scanning electron microscopy and characterized by glancing-incidence X-ray techniques. The macroscopic study reveals that aragonite is a powerful sorbent for cadmium in aqueous environments. Microscopic observations indicate that cadmium is sorbed onto aragonite by surface precipitation of (Cd, Ca)CO₃ solid solutions with a calcite-type structure. The precipitating individuals grow randomly oriented on the surface to reach sizes in the micrometre range. As a consequence, the concentration of cadmium in the aqueous solution decreases dramatically to values controlled by the low solubility of the cadmium-rich end member. This mechanism involves simultaneous dissolution-crystallization and is the same for both abiogenic and biogenic aragonites, the only difference being a result of the higher specific surface area of the biogenic starting material. Long-term uptake of cadmium by calcite occurs through a similar dissolution-crystallization mechanism, the final outcome being virtually the same, that is, surface precipitation of (Cd,Ca)CO₃ solid solutions. In this case, however, substrate and precipitate are isostructural and the process occurs by oriented overgrowth of thin lamellar crystallites, which spread to quickly cover the surface by a layer a few nanometers thick. This epitaxial layer armors the substrate from further dissolution, so that the process stops when only a small amount of cadmium has been removed from the fluid. As a result, the “sorption capacity” of calcite is considerably lower than that of aragonite. The study illustrates reaction pathways and “partial” equilibrium endpoints in surface-precipitation processes involving solid solutions.  相似文献   

Oxidative dissolution of pyritic sludge from the Aznalcóllar mine (SW Spain)     

C. Domnech  J. de Pablo  C. Ayora 《Chemical Geology》2002,190(1-4):339-353

As a result of the collapse of a mine tailing dam, a large extension of the Guadiamar valley was covered with a layer of pyritic sludge. Despite the removal of most of the sludge, a small amount remained in the soil, constituting a potential risk of water contamination. The kinetics of the sludge oxidation was studied by means of laboratory flow-through experiments at different pH and oxygen pressures. The sludge is composed mainly of pyrite (76%), together with quartz, gypsum, clays, and sulphides of zinc, copper, and lead. Trace elements, such as arsenic and cadmium, also constitute a potential source of pollution. The sludge is fine grained (median of 12 μm) and exhibits a large surface (BET area of 1.4±0.2 m² g⁻¹).

The dissolution rate law of sludge obtained is r=10^{−6.1(±0.3)} [O₂(aq)]^0.41(±0.04) a_H+^0.09(±0.06) g_sludge m⁻² s⁻¹ (22 °C, pH=2.5–4.7). The dissolution rate law of pyrite obtained is r=10^{−7.8(±0.3)} [O₂(aq)]^0.50(±0.04) a_H+^0.10(±0.08) mol m⁻² s⁻¹ (22 °C, pH=2.5–4.7). Under the same experimental conditions, sphalerite dissolved faster than pyrite but chalcopyrite dissolves at a rate similar to that of pyrite. No clear dependence on pH or oxygen pressure was observed. Only galena dissolution seemed to be promoted by proton activity. Arsenic and antimony were released consistently with sulphate, except at low pH conditions under which they were released faster, suggesting that additional sources other than pyrite such as arsenopyrite could be present in the sludge. Cobalt dissolved congruently with pyrite, but Tl and Cd seemed to be related to galena and sphalerite, respectively.

A mechanism for pyrite dissolution where the rate-limiting step is the surface oxidation of sulphide to sulphate after the adsorption of O₂ onto pyrite surface is proposed.  相似文献   

Segment-scale variations in the crustal structure of 150–300 kyr old fast spreading oceanic crust (East Pacific Rise,  8°15'N–10°5'N ) from wide-angle seismic refraction profiles     

J. Pablo Canales  Robert S. Detrick  Douglas R. Toomey  William S. D. Wilcock 《Geophysical Journal International》2003,152(3):766-794

  相似文献   

Strontium,SO42−/Cl− and Mg2+/Ca2+ ratios as tracers for the evolution of seawater into coastal aquifers: the example of Castell de Ferro aquifer (SE Spain)     

Pablo Pulido-Leboeuf  Antonio Pulido-Bosch  Maria Luisa Calvache  Ángela Vallejos  José Miguel Andreu 《Comptes Rendus Geoscience》2003,335(14):1039-1048

The strontium content and the SO₄^2?/Cl^? and Mg²⁺/Ca²⁺ ratios were used as natural tracers of the residence time of seawater intrusion into the Castell de Ferro aquifer. Analysis of these parameters indicated the existence of two principal flowpaths in the aquifer. The first flows through the eastern part of the aquifer, through the karstified Castell de Ferro massif; it accommodates a larger and more rapid flow, so that the residence time is shorter, leading to lower SO₄²⁺/Cl^? ratios, lower Sr²⁺ content and higher Mg²⁺/Ca²⁺ ratios. The second flowpath is in the western sector, and flows exclusively through alluvial deposits; the flow here is slower, particularly that flowing towards the sea. Thus the residence time of the water here will be longer and there is scant flushing of the intruded seawater; this is manifested in the high Sr²⁺ content, high SO₄²⁺/Cl^? and low Mg²⁺/Ca²⁺ ratios. To cite this article: P. Pulido-Leboeuf et al., C. R. Geoscience 335 (2003).  相似文献   

Volunteered geographic information systems: Technological design patterns     

Jos Pablo Gmez‐Barrn  Miguel ngel Manso‐Callejo  Ramn Alcarria 《Transactions in GIS》2019,23(5):976-1007

Volunteered geographic information (VGI) has been studied extensively within various contexts, however, generally focusing on isolated aspects of data. Therefore, we still need to advance the structured knowledge of the mechanisms that affect and support its creation. This article aims to contribute to the integrated study of VGI systems (VGIS) in order to enhance design processes that lead to a more systematic and efficient VGI management. We define VGIS, their main components, and general architectures. Then, we use the service blueprinting technique to conduct the case study of several systems, identifying system actions to find the processes and technologies forming the different functional components of VGIS: elements of the technological infrastructure that implement diverse processes to facilitate participation and data management. Integrated in the data collection component, we also propose a typology of crowdsourcing tasks that—coupled with the functional components—establishes a foundation for VGIS research and design. We characterize these components, arguing that they are necessary in the development of VGIS, however, there is still a need for a more detailed study of the flow of processes and subprocesses and how they work under the criteria of different types of projects to continue facilitating their design.  相似文献   

Does hillslope trenching enhance groundwater recharge and baseflow in the Peruvian Andes?          下载免费PDF全文

Lauren D. Somers  Jeffrey M. McKenzie  Samuel C. Zipper  Bryan G. Mark  Pablo Lagos  Michel Baraer 《水文研究》2018,32(3):318-331

As Andean glaciers rapidly retreat due to climate change, the balance of groundwater and glacial meltwater contributions to stream discharge in tropical, proglacial watersheds will change, potentially increasing vulnerability of water resources. The Shullcas River Watershed, near Huancayo, Peru, is fed only partly by the rapidly receding Huaytapallana glaciers (<20% of dry season flow). To potentially increase recharge and therefore increase groundwater derived baseflow, the government and not‐for‐profit organizations have installed trenches along large swaths of hillslope in the Shullcas Watershed. Our study focuses on a nonglacierized subcatchment of the Shullcas River Watershed and has 2 objectives: (a) create a model of the Shullcas groundwater system and assess the controls on stream discharge and (b) investigate the impact of the infiltration trenches on recharge and baseflow. We first collected hydrologic data from the field including a year‐long hydrograph (2015–2016), meteorological data (2011–2016), and infiltration measurements. We use a recharge model to evaluate the impact of trenched hillslopes on infiltration and runoff processes. Finally, we use a 3‐dimensional groundwater model, calibrated to the measured dry season baseflow, to determine the impact of trenching on the catchment. Simulations show that trenched hillslopes receive approximately 3.5% more recharge, relative to precipitation, compared with unaltered hillslopes. The groundwater model indicates that because the groundwater flow system is fast and shallow, incorporating trenched hillslopes (~2% of study subcatchment area) only slightly increases baseflow in the dry season. Furthermore, the location of trenching is an important consideration: Trenching higher in the catchment (further from the river) and in flatter terrain provides more baseflow during the dry season. The results of this study may have important implications for Andean landscape management and water resources.  相似文献   

Observation of the Radio Radiation Flux of the Sun and Flares at a Wavelength of 5 cm     

Tlatov  A. G.  Bogod  V. M.  Pons  O.  Rodriges  M.  Estrada  R.  Pablo  S. 《Geomagnetism and Aeronomy》2020,60(8):1087-1092

Geomagnetism and Aeronomy - The results of long-term mesoscale observations in the microwave range are reviewed. The rationale for the resumption of observations at the Havana Radio Astronomy...  相似文献