Effects of mechanical and chemical processes on the degradation of plastic beach debris on the island of Kauai, Hawaii   总被引：3，自引：0，他引：3  

David A Cooper  Patricia L Corcoran 《Marine pollution bulletin》2010,60(5):650-654

Plastic debris is accumulating on the beaches of Kauai at an alarming rate, averaging 484 pieces/day in one locality. Particles sampled were analyzed to determine the effects of mechanical and chemical processes on the breakdown of polymers in a subtropical setting. Scanning electron microscopy (SEM) indicates that plastic surfaces contain fractures, horizontal notches, flakes, pits, grooves, and vermiculate textures. The mechanically produced textures provide ideal loci for chemical weathering to occur which further weakens the polymer surface leading to embrittlement. Fourier transform infrared spectroscopy (FTIR) results show that some particles have highly oxidized surfaces as indicated by intense peaks in the lower wavenumber region of the spectra. Our textural analyses suggest that polyethylene has the potential to degrade more readily than polypropylene. Further evaluation of plastic degradation in the natural environment may lead to a shift away from the production and use of plastic materials with longer residence times.  相似文献   

Antifouling biocides in discarded marine paint particles     

Rachel Parks  Patricia E. Frickers  James W. Readman 《Marine pollution bulletin》2010,60(8):1226-1230

Antifouling paint fragments collected from marinas and leisure boat maintenance facilities and in the vicinity of abandoned boats have been chemically characterised. High concentrations of Cu (23-380 mg g⁻¹) and Zn (14-160 mg g⁻¹) in the samples (n = 14) are consistent with the use of these metals in the principal biocidal and non-biocidal pigments in contemporary antifouling formulations. Up to about 2% and 7% of the respective metals were solvent-extractable, suggesting that organo-forms of Cu and Zn (e.g. pyrithiones) were also present. Of the organic biocides, dichlofluanid was present in most samples and at concentrations up to about 20 mg g⁻¹. Chlorothalonil and Irgarol 1051® were only detected in one and four cases, respectively, and Sea Nine 211® was not detected in any sample. Results are discussed in terms of UK legislation regarding biocide usage and the likely effects and fate of discarded paint particles in coastal environments where boats are repaired or moored.  相似文献   

Surface dynamic deformation estimates from local seismicity: the Itoiz reservoir,Spain     

Miguel A. Santoyo  Patricia Martínez-Garzón  Antonio García-Jerez  Francisco Luzón 《Journal of Seismology》2016,20(3):1021-1039

We analyze the ground motion time histories due to the local seismicity near the Itoiz reservoir to estimate the near-source, surface 3D displacement gradients and dynamic deformations. The seismic data were obtained by a semipermanent broadband and accelerometric network located on surface and at underground sites. The dynamic deformation field was calculated by two different methodologies: first, by the seismo-geodetic method using the data from a three-station microarray located close to the dam, and second, by single station estimates of the displacement gradients. The dynamic deformations obtained from both methods were compared and analyzed in the context of the local free-field effects. The shallow 1D velocity structure was estimated from the seismic data by modeling the body wave travel times. Time histories obtained from both methods result quite similar in the time window of body wave arrivals. The strain misfits between methods vary from 1.4 to 35.0 % and rotational misfits vary from 2.5 to 36.0 %. Amplitudes of displacement gradients vary in the range of 10^?8 to 10^?7 strains. From these results, a new scaling analysis by numerical modeling is proposed in order to estimate the peak dynamic deformations for different magnitudes, up to the expected maximum M _w in the region (M5.5). Peak dynamic deformations due to local M _w5.5 earthquakes would reach amplitudes of 10^?5 strain and 10^?3 radians at the Itoiz dam. The single station method shows to be an adequate option for the analysis of local seismicity, where few three-component stations are available. The results obtained here could help to extend the applicability of these methodologies to other sites of engineering interest.  相似文献   

The Landscape of Diversity in U.S. Higher Education Geography     

Joy K. Adams  Patricia Solís  Jean McKendry 《The Professional geographer》2013,65(2):183-194

Palynological analyses were completed for the A and B horizons of a forested Mollic Hapludalf to determine type, amount, and distribution of pollen and spores within the soil solum. Hypotheses regarding the origin of pollen and the mechanisms of its movement within soil bodies are also advanced. Pollen downwash within the mineral soil seems to be very slow and confined to the uppermost porous and most homogenized part of the solum. The predominance of non-arboreal pollen at depth was believed to be a result of deposition with the loess parent material. High arboreal pollen frequencies in the upper horizons coupled with increases in non-arboreal types at depth indicate gradual ongoing mixing from the present vegetation into the soil.  相似文献   

Divergent Perspectives on Water Security: Bridging the Policy Debate     

Patricia A. Gober  Graham E. Strickert  Douglas A. Clark  Kwok P. Chun  Diana Payton  Kristin Bruce 《The Professional geographer》2013,65(1):62-71

Environmental policy discussion is replete with references to water security, food security, ecosystem health, community resilience, sustainable development, and sustainable urbanism. These terms are, by their very nature, ambiguous and difficult to define; they allow room, however, for a variety of actors to conceptualize water, food, ecological, economic, and urban problems in ways that allow them to move forward on contentious issues. This article focuses on the idea of water security and asks how it is conceptualized and used for regional policy debate in western Canada. We asked fifty-eight water stakeholders from the Saskatchewan River Basin to define water security, identify major barriers to security, and prioritize water problems. Responses showed there are myriad ways to think about water security, ranging from narrow conceptualizations, such as reliability, quality, and quantity, to broader sustainability perspectives about the nature of resource development and its social and economic consequences. The human dimensions of water security (governance, land use, and competing demands) were assigned higher priority than its biophysical aspects (flooding, droughts, and climate change). Framing water security to emphasize the human capacity to manage uncertain and rapid biophysical and societal change offers the opportunity to unite actors who otherwise would be separated by core environmental values, definitions of water security, provincial context (Alberta vs. Saskatchewan), and occupation.  相似文献   

Exploring the Impact of Contextual Information on Student Performance and Interest in Open Humanitarian Mapping     

Patricia Solís  Patricia R. DeLucia 《The Professional geographer》2013,65(3):523-535

The opportunity to engage university students in authentic, open humanitarian mapping raises important questions about how to guide the quality and productivity of volunteer spatial contributions while providing a valuable learning experience. It presents the unique chance to pique new mappers’ interest, satisfaction, and confidence in spatial technologies in particular, and technology in general, as well as pique their interest in the people and places that are served by the humanitarian mapping projects. This article shares the findings of a study that explores the importance of sharing authentic contextual information about the purpose of the humanitarian mapping task. Two groups of beginner mappers were given mapping tasks, with only one group being provided details on the purpose. Comparisons were made on their respective performance and changes in affective response to a series of questions about technology, education, good citizenship, and empathy. Measures of the quantity and quality of spatial data produced; their respective levels of interest, satisfaction, and confidence in technology; and affective responses before and after mapping show the relative effects of contextual information. Results provide insights about the potential effectiveness of authentic instruction on the performance of mapping as well as the potential effect on mappers themselves. Key Words: citizenship, data quality, empathy, humanitarian mapping, volunteered geographic information.  相似文献   

The geospatial humanities: past,present and future     

Patricia Murrieta-Flores  Bruno Martins 《International journal of geographical information science》2013,27(12):2424-2429

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Effects of CO₂ on benthic biota: An in situ benthic chamber experiment in Storfjorden (Norway)     

Hiroshi Ishida  Lars G. Golmen  Julia West  Martin Krüger  Patricia Coombs  John Arthur Berge  Tastuo Fukuhara  Michimasa Magi  Jun Kita 《Marine pollution bulletin》2013

Carbon capture and storage (CCS) methods, either sub-seabed or in ocean depths, introduces risk of CO₂ leakage and subsequent interaction with the ecosystem. It is therefore important to obtain information on possible effects of CO₂. In situ CO₂ exposure experiments were carried out twice for 10 days during 2005 using a Benthic Chamber system at 400 m depth in Storfjorden, Norway. pCO₂ in the water above the sediment in the chambers was controlled at approximately 500, 5000 and 20,000 μatm, respectively. This article describes the experiment and the results from measured the biological responses within the chamber sediments. The results show effects of elevated CO₂ concentrations on biological processes such as increased nanobenthos density. Methane production and sulphate reduction was enhanced in the approximately 5000 μatm chamber.  相似文献   

Crustal structure and tectonic setting of the south central Andes from gravimetric analysis     

Cecilia Weidmann  Silvana Spagnotto  Orlando Álvarez  Marcos Sánchez  Federico Lince Klinger  Mario Giménez  Patricia Martínez 《Geofísica Internacional》2013,52(3):197-208

Based on terrestrial gravity data, in this paper we prepared a map of Bouguer anomalies, which was filtered to separate shallow and deep gravity sources. Based on a density model and gravimetric inversion techniques, the discontinuous crust-mantle boundary and the top of crystalline basement were modeled. Subsequently, the equivalent elastic thickness (Te) was evaluated, considering information from the crust-mantle discontinuity and topographic load, finding high Te values in the eastern Andean foothills and west of the Velasco range. These results are consistent with the positive isostatic and residual Bouguer anomaly values, which suggest the presence of high-density rocks in the mid-to upper crust. In addition, petrographic and geochemical analysis conducted in surface outcrops suggest a mantle origin.  相似文献   

Pesticides Removal by Filtration over Cactus Pear Leaves: A Cheap and Natural Method for Small‐Scale Water Purification in Semi‐Arid Regions     

Abraha Gebrekidan  Hannah Nicolai  Liese Vincken  Mekone Teferi  Tsehaye Asmelash  Tadesse Dejenie  Samuel Zerabruk  Kindeya Gebrehiwet  Hans Bauer  Josef Deckers  Patricia Luis  Luc De Meester  Bart van der Bruggen 《洁净——土壤、空气、水》2013,41(3):235-243

This study aims to examine the efficiency of Opuntia ficus‐indica for removing organochlorine pesticides from surface waters. Adsorption properties such as size, dose, and time of O. ficus‐indica for aldrin, dieldrin, and dichlorodiphenyltrichloroethane (DDT) were studied through stirring and column methods. Because of their high affinity and swelling characteristics, dried O. ficus‐indica was studied in stirring while fresh unpeeled O. ficus‐indica was applied in both stirring and column experiments and proved to be well‐suited to column application. Before removing pesticides, the column was flashed with distilled water eliminate the turbidity and smell from fresh unpeeled cactus. The removal of pesticides increased with an increasing adsorbent dose and decreased with adsorbent particle sizes. The optimum adsorbent dose is 10 g for dried and 15 g for fresh unpeeled O. ficus‐indica. The experimental results show that O. ficus‐indica possesses strong adsorption ability for aldrin, dieldrin, and DDT, and the adsorption isotherm data obeyed the Freundlich model. The results of our small‐scale experiments suggest a strong potential to develop local small‐scale water treatment units that can be used at the level of individual households or local communities, using a widely available adsorbent.  相似文献