CO₂ solubility in dacitic melts equilibrated with H₂O-CO₂ fluids: Implications for modeling the solubility of CO₂ in silicic melts     

Harald Behrens  Susanne Ohlhorst  Michel Champenois 《Geochimica et cosmochimica acta》2004,68(22):4687-4703

The solubility of CO₂ in dacitic melts equilibrated with H₂O-CO₂ fluids was experimentally investigated at 1250°C and 100 to 500 MPa. CO₂ is dissolved in dacitic glasses as molecular CO₂ and carbonate. The quantification of total CO₂ in the glasses by mid-infrared (MIR) spectroscopy is difficult because the weak carbonate bands at 1430 and 1530 cm⁻¹ can not be reliably separated from background features in the spectra. Furthermore, the ratio of CO_2,mol/carbonate in the quenched glasses strongly decreases with increasing water content. Due to the difficulties in quantifying CO₂ species concentrations from the MIR spectra we have measured total CO₂ contents of dacitic glasses by secondary ion mass spectrometry (SIMS).At all pressures, the dependence of CO₂ solubility in dacitic melts on x^fluid_CO2,total shows a strong positive deviation from linearity with almost constant CO₂ solubility at x_CO2fluid > 0.8 (maximum CO₂ solubility of 795 ± 41, 1376 ± 73 and 2949 ± 166 ppm at 100, 200 and 500 MPa, respectively), indicating that dissolved water strongly enhances the solubility of CO₂. A similar nonlinear variation of CO₂ solubility with x_CO2fluid has been observed for rhyolitic melts in which carbon dioxide is incorporated exclusively as molecular CO₂ (Tamic et al., 2001). We infer that water species in the melt do not only stabilize carbonate groups as has been suggested earlier but also CO₂ molecules.A thermodynamic model describing the dependence of the CO₂ solubility in hydrous rhyolitic and dacitic melts on T, P, f_CO2 and the mol fraction of water in the melt (x_water) has been developed. An exponential variation of the equilibrium constant K₁ with x_water is proposed to account for the nonlinear dependence of x_CO2,totalmelt on x_CO2fluid. The model reproduces the CO₂ solubility data for dacitic melts within ±14% relative and the data for rhyolitic melts within 10% relative in the pressure range 100-500 MPa (except for six outliers at low x_CO2fluid). Data obtained for rhyolitic melts at 75 MPa and 850°C show a stronger deviation from the model, suggesting a change in the solubility behavior of CO₂ at low pressures (a Henrian behavior of the CO₂ solubility is observed at low pressure and low H₂O concentrations in the melt). We recommend to use our model only in the pressure range 100-500 MPa and in the x_CO2fluid range 0.1-0.95. The thermodynamic modeling indicates that the partial molar volume of total CO₂ is much lower in rhyolitic melts (31.7 cm³/mol) than in dacitic melts (46.6 cm³/mol). The dissolution enthalpy for CO₂ in hydrous rhyolitic melts was found to be negligible. This result suggests that temperature is of minor importance for CO₂ solubility in silicic melts.  相似文献   

Field and petrological evidence for a Late Palaeozoic (Upper Carboniferous–Permian) age of the Erfaulet orthogneiss (Gran Paradiso,western Alps)     

Benjamin Le Bayon  Michel Ballèvre 《Comptes Rendus Geoscience》2004,336(12):1079-1089

In the Gran Paradiso massif (western Alps), the boundary between the Erfaulet orthogneiss and the overlying metasediments (Money Complex) is interpreted as a Late Palaeozoic intrusive contact. Major arguments in favour of this hypothesis are: (i) the obliquity of the sedimentary layering with respect to the contact; (ii) the presence of aplitic dykes within the Money Complex; (iii) the lack of a mylonitic zone; and (iv) rare relics of an early generation of garnet in the Money metasediments, interpreted as evidence of the contact metamorphism of the Erfaulet granite. To cite this article: B. Le Bayon, M. Ballèvre, C. R. Geoscience 336 (2004).  相似文献   

Caractéristiques et signification d'un niveau coquillier majeur à brachiopodes,marqueur événementiel dans l'évolution dévonienne de la Saoura (Sahara du Nord-Ouest,Algérie)     

Abdelkader Ouali Mehadji  Serge Elmi  Patrick Rachebœuf  Larbi Mekahli 《Comptes Rendus Geoscience》2004,336(14):1283-1292

In the Saoura, the brachiopod shell beds, so-called niveau coralligène, correspond to a major shell deposit dated to the Late Emsian. Brachiopods and crinoids dominate the benthic assemblage that contains also corals, bryozoans, trilobites, goniatites, and orthocones. This major level has a large geographic distribution and it is characterized by a wide brachiopod diversity due to time-averaging, taphonomic feedback and alternate bottom conditions changing from soft to shelly and firm. This kind of brachiopod association is linked to a transgressive onlap system. At regional extent, we can correlate this major shell bed to similar shell deposits from the Ahnet-Mouydir, Tindouf, and Zemmour areas. It indicates an important transgressive event underlined by change in the sedimentation from detritic deposits to carbonate sediments. To cite this article: A. Ouali Mehadji et al., C. R. Geoscience 336 (2004).  相似文献   

Atlantic sources of the Arctic Ocean surface and halocline waters   总被引：8，自引：0，他引：8  

Bert Rudels  E. Peter Jones  Ursula Schauer  Patrick Eriksson 《Polar research》2004,23(2):181-208

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Using commercial finite element packages for the study of earth deformations, sea levels and the state of stress   总被引：5，自引：0，他引：5  

Patrick Wu 《Geophysical Journal International》2004,158(2):401-408

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Instability of a periodic system of faults     

Michel Campillo  Cristian Dascalu  Ioan R. Ionescu 《Geophysical Journal International》2004,159(1):212-222

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Characterizing the properties of dissolved organic matter isolated by XAD and C-18 solid phase extraction and ultrafiltration   总被引：1，自引：0，他引：1  

Sara B. Schwede-Thomas  Yu-Ping Chin  Karl J. Dria  Patrick Hatcher  Edith Kaiser  Barbara Sulzberger 《Aquatic Sciences - Research Across Boundaries》2005,67(1):61-71

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Seismic signature of a phreatic explosion: hydrofracturing damage at Karthala volcano, Grande Comore Island, Indian Ocean     

Cécile Savin  Jean-Robert Grasso  Patrick Bachelery 《Bulletin of Volcanology》2005,67(8):717-731

Karthala volcano is a basaltic shield volcano with an active hydrothermal system that forms the southern two-thirds of the Grande Comore Island, off the east coat of Africa, northwest of Madagascar. Since the start of volcano monitoring by the local volcano observatory in 1988, the July 11th, 1991 phreatic eruption was the first volcanic event seismically recorded on this volcano, and a rare example of a monitored basaltic shield. From 1991 to 1995 the VT locations, 0.5<M_l<4.3, show a crack shaped pattern (3 km long, 1 km wide) within the summit caldera extending at depth from –2 km to +2 km relative to sea level. This N-S elongated pattern coincides with the direction of the regional maximum horizontal stress as deduced from regional focal mechanism solutions. This brittle signature of the damage associated with the 1991 phreatic eruption is a typical pattern of the seismicity induced by controlled fluid injections such as those applied at geothermal fields, in oil and gas recovery, or for stress measurements. It suggests the 1991 phreatic eruption was driven by hydraulic fracturing induced by forced fluid flow. We propose that the extremely high LP and VT seismicity rates, relative to other effusive volcanoes, during the climax of the 1991 phreatic explosion, are due to the activation of the whole hydrothermal system, as roughly sized by the distribution of VT hypocenters. The seismicity rate in 1995 was still higher than the pre-eruption seismicity rate, and disagrees with the time pattern of thermo-elastic stress readjustment induced by single magma intrusions at basaltic volcanoes. We propose that it corresponds to the still ongoing relaxation of pressure heterogeneity within the hydrothermal system as suggested by the few LP events that still occurred in 1995.Editorial responsibility: H Shinohara  相似文献   

Migrating pingos in the permafrost region of the Tibetan Plateau, China and their hazard along the Golmud–Lhasa railway     

Zhenhan Wu  Patrick J. Barosh  Daogong Hu  Zhonghai Wu  Ye Peisheng  Liu Qisheng  Zhou Chunjing 《Engineering Geology》2005,79(3-4):267-287

Most pingos in the permafrost region of the high northern Tibetan Plateau form along active fault zones and many change position annually along the zones and thus appear to migrate. The fault zones conduct geothermal heat, which thins permafrost, and control cool to hot springs in the region. They maintain ground-water circulation through broken rock in an open system to supply water for pingo growth during the winter in overlying fluvial and lacustrian deposits. Springs remain after the pingos thaw in the summer. Fault movement, earthquakes and man's activities cause the water pathways supplying pingos to shift and consequently the pingos migrate.

The hazard posed to the new Golmud–Lhasa railway across the plateau by migrating pingos is restricted to active fault zones, but is serious, as these zones are common and generate large earthquakes. Pingos have damaged the highway and the oil pipeline adjacent to the railway since 2001. One caused tilting and breaking of a bridge pier and destroyed a highway bridge across the Chumaerhe fault. Another has already caused minor damage to a new railway bridge. Furthermore, the construction of a bridge pier in the North Wuli fault zone in July–August 2003 created a conduit for a new spring, which created a pingo during the following winter. Measures taken to drain the ground-water via a tunnel worked well and prevented damage before the railway tracks were laid. However, pier vibrations from subsequent train motion disrupted the drain and led to new springs, which may induce further pingo growth beneath the bridge.

The migrating pingos result from active fault movement promoting artesian ground-water circulation and changing water pathways under the seasonal temperature variations in the permafrost region. They pose a serious hazard to railway construction, which, in turn can further disturb the ground-water conduits and affect pingo migration.  相似文献   

Fabric studies within the Cascade Lake shear zone, Sierra Nevada, California   总被引：1，自引：0，他引：1  

Basil Tikoff  Matthew R. Davis  Christian Teyssier  Michel de St. Blanquat  Guillaume Habert  Sven Morgan   《Tectonophysics》2005,400(1-4):209-226

The Cascade Lake shear zone occurs on the eastern margin of the Tuolumne Intrusive Suite, Sierra Nevada Batholith, California. Foliation in the zone is NNW trending and subvertical, and lineation is moderately south plunging. Deformation is syn-tectonic with emplacement of the Cathedral Peak granodiorite. A deformation gradient exists toward the NE margin of this pluton, with higher strains and lower temperatures of deformation found near the contact. We compare fabric data collected very densely in this shear zone using several techniques: field fabrics, 3D orientation of K-feldspar megacrysts, and AMS (anisotropy of magnetic susceptibility) analysis. In general, the results from the three different methods are in agreement. Deformation in this shear zone is part of a larger pattern of deformation within the Cathedral Peak granodiorite, as recorded by AMS analysis, and dextral shearing associated within the last stage of plutonism within the Sierra Nevada magmatic arc.  相似文献