Search for purines and pyrimidines in the Murchison meteorite     

W. van der Velden  Alan W. Schwartz 《Geochimica et cosmochimica acta》1977,41(7):961-968

A 1 g interior sample of the Murchison CII meteorite was examined for the presence of purines and pyrimidines by dual-column, ion-exclusion chromatography and ultraviolet spectroscopy. Xanthine, not previously reported in meteorites, was found to be the major purine liberated by extraction with formic acid, with a concentration corresponding to 2.3 μg/g of meteorite. Guanine (0.1 ppm) and hypoxanthine (0.04 ppm) were also tentatively identified. The presence of adenine could not be confirmed. No pyrimidines were detected at concentrations higher than the background level (0.01 ppm) in water, formic acid or strong acid extracts. Silylation of the water extract, however, resulted in the appearance of 4-hydroxypyrimidine, 4-hydroxy-2-methylpyrimidine and 4-hydroxy-6-methylpyrimidine. These compounds are-though to be formed during the silylation procedure from contaminants present in the reagent.  相似文献   

Seismogenic zone structure beneath the Nicoya Peninsula, Costa Rica, from three-dimensional local earthquake P- and S-wave tomography   总被引：3，自引：0，他引：3  

Heather R. DeShon  Susan Y. Schwartz  rew V. Newman  Victor González  Marino Protti  LeRoy M. Dorman  Timothy H. Dixon  Daniel E. Sampson  Ernst R. Flueh 《Geophysical Journal International》2006,164(1):109-124

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Geochemical characterisation and erosion stability of fine‐grained groyne field sediments of the Middle Elbe River     

Ren Schwartz 《洁净——土壤、空气、水》2006,34(3):223-233

Because of the significant reduction of flow velocity relative to the main current there is an accumulation of sediment material in the centre of the groyne fields over time (years to decades) up to a maximum of 1.5 m. Based on the element‐ and compound‐specific depth functions of this fine‐grained material with high organic matter content the sedimentation history of the Elbe River sediments concerning the environmentally relevant nutrients and pollutants can be reconstructed. It could be shown that the fresh sediments are less polluted than the deeper older ones. During the extreme flood of the river Elbe in August 2002 the critical erosion shear stress in the groyne fields was high enough to remobilise a considerable portion of the sediment depot. The hazard to the environment is high due to the fact that a significant part of the remobilised polluted sediments was distributed over the recent floodplain which is normally used as pasture. Thus these groyne field sediments represent a temporary danger for the water quality of the river Elbe. But the hazard of the solids sedimented in the recent floodplain of the river can be viewed as long‐lasting.  相似文献   

Large earthquake doublets and fault plane heterogeneity in the northern Solomon Islands subduction zone     

Zhengyu Xu  Susan Y. Schwartz 《Pure and Applied Geophysics》1993,140(2):365-390

In the Solomon Islands and New Britain subduction zones, the largest earthquakes commonly occur as pairs with small separation in time, space and magnitude. This doublet behavior has been attributed to a pattern of fault plane heterogeneity consisting of closely spaced asperities such that the failure of one asperity triggers slip in adjacent asperities. We analyzed body waves of the January 31, 1974,M _w =7.3, February 1, 1974,M _w =7.4, July 20, 1975 (1437)M _w =7.6 and July 20, 1975 (1945),M _w =7.3 doublet events using an iterative, multiple station inversion technique to determine the spatio-temporal distribution of seismic moment release associated with these events. Although the 1974 doublet has smaller body wave moments than the 1975 events, their source histories are more complicated, lasting over 40 seconds and consisting of several subevents located near the epicentral regions. The second 1975 event is well modeled by a simple point source initiating at a depth of 15 km and rupturing an approximate 20 km region about the epicenter. The source history of the first 1975 event reveals a westerly propagating rupture, extending about 50 km from its hypocenter at a depth of 25 km. The asperities of the 1975 events are of comparable size and do not overlap one another, consistent with the asperity triggering hypothesis. The relatively large source areas and small seismic moments of the 1974 doublet events indicate failure of weaker portions of the fault plane in their epicentral regions. Variations in the roughness of the bathymetry of the subducting plate, accompanying subduction of the Woodlark Rise, may be responsible for changes in the mechanical properties of the plate interface.To understand how variations in fault plane coupling and strength affect the interplate seismicity pattern, we relocated 85 underthrusting earthquakes in the northern Solomon Islands Are since 1964. Relatively few smaller magnitude underthrusting events overlap the Solomon Islands doublet asperity regions, where fault coupling and strength are inferred to be the greatest. However, these asperity regions have been the sites of several previous earthquakes withM _s 7.0. The source regions of the 1974 doublet events, which we infer to be mechanically weak, contain many smaller magnitude events but have not generated any otherM _s 7.0 earthquakes in the historic past. The central portion of the northern Solomon Islands Arc between the two largest doublet events in 1971 (studied in detail bySchwartz et al., 1989a) and 1975 contains the greatest number of smaller magnitude underthrusting earthquakes. The location of this small region sandwiched between two strongly coupled portions of the plate interface suggest that it may be the site of the next large northern Solomon Islands earthquake. However, this region has experienced no known earthquakes withM _s 7.0 and may represent a relatively aseismic portion of the subduction zone.  相似文献   

Purines,pyrimidines and organic carbon in lake sediments — A comparison of sediments from lakes of varying degrees of eutrophication     

W. Van Der Velden  Alan W. Schwartz 《Chemical Geology》1976,18(4):273-284

Sediment cores from the Great Lakes of North America and the Bodensee (Lake Constance) were analysed for purine and pyrimidine contents and total organic carbon. Lakes subject to recent cultural eutrophication showed steep increases in both organic carbon and purine and pyrimidine concentrations in the recently deposited sediments. Analytical results for Lake Huron (oligotrophic) and for a highly eutrophic area of the Bodensee (Gnadensee) appeared remarkably similar, in that only gradual, linear increases were observed in the total organic carbon curves. The curves for total purines and pyrimidines were also less steep for these cores as compared to the others studied. A possible explanation is that both areas represent lakes with no serious, recent changes in productivity. Uracil was found to decrease in concentration faster than any other purine or pyrimidine in the first few centimeters of all cores, supporting previous suggestions of more rapid turnover of this pyrimidine in sediments.  相似文献   

Automated calibration applied to watershed‐scale flow simulations     

Zhongbo Yu  Franklin W. Schwartz 《水文研究》1999,13(2):191-209

Complexity in simulating the hydrological response in large watersheds over long times has prompted a significant need for procedures for automatic calibration. Such a procedure is implemented in the basin‐scale hydrological model (BSHM), a physically based distributed parameter watershed model. BSHM simulates the most important basin‐scale hydrological processes, such as overland flow, groundwater flow and stream–aquifer interaction in watersheds. Here, the emphasis is on estimating the groundwater parameters with water levels in wells and groundwater baseflows selected as the calibration targets. The best set of parameters is selected from within plausible ranges of parameters by adjusting the values of hydraulic conductivity, storativity, groundwater recharge and stream bed permeability. The baseflow is determined from stream flow hydrographs by using an empirical scheme validated using a chemical approach to hydrograph separation. Field studies determined that the specific conductance for components of the composite hydrograph were sufficiently unique to make the chemical approach feasible. The method was applied to the Big Darby Creek Watershed, Ohio. The parameter set selected for the groundwater system provides a good fit with the estimated baseflow and observed water well data. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

Relationships between physical‐geochemical soil properties and erodibility of streambanks among different physiographic provinces of Tennessee,USA          下载免费PDF全文

Badal Mahalder  John S. Schwartz  Angelica M. Palomino  Jon Zirkle 《地球表面变化过程与地形》2018,43(2):401-416

Erosion of cohesive soils in fluvial environments is dependent on physical, geochemical and biological properties, which govern inter‐particle attraction forces and control detachment rates from stream beds and banks. Most erosion rate models are based on the excess shear stress equation where the soil erodibility coefficient (k_d) is multiplied by the difference between the boundary hydraulic shear stress (τ_b) and the soil critical shear stress (τ_c). Both k_d and τ_c are a function of soil properties and must be obtained through in situ field or laboratory testing. Many studies have generated predictive relationships for k_d and τ_c derived from various soil properties. These studies typically were conducted in watersheds within a single physiographic region with a common surficial geology and/or investigated a limited number of soil properties, particularly geochemical properties. With widely reported differences in relationships between τ_c and soil properties, this study investigated differences in predictive relationships for τ_c among different physiographic provinces in Tennessee, USA. Erodibility parameters were determined in the field using a mini‐jet test device. Among these provinces, statistically four unique clusters were identified from a dataset of 128 observations and these data clusters were used to develop predictive models for τ_c to identify dominant properties governing erosion. In these clusters, 16 significant physical and geochemical soil properties were identified for τ_c prediction. Among these soil properties, water content and passing #200 sieve (percentage soil less than 75 μm) were the dominant controlling parameters to predict τ_c in addition to clay percentage (< 2 μm), bulk density, and soil pore water chemistry. This study suggests that unique relationships exist for physiographic provinces that are likely due to soil physical‐geochemical processes associated with surficial geology that determine minerology of the cohesive soil. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Status and outlook of hiking trails in the central part of the Low Tatra Mountains in Slovakia between 1980–1981 and 2013–2014     

HRN?IAROVá Tatiana  KENDERESSY Pavol  ?PULEROVá Jana  VLACHOVI?OVá Miriam  PISCOVá Veronika  DOBROVODSKá Marta 《山地科学学报》2018,15(8):1615-1632

This study presents a methodology for assessment of the condition of hiking trails (HTs) and their impact zones in the central part of the Low Tatra mountain range, based on comparison of two complex data sets gathered in 33 years apart. The first field investigation was performed in 1980 and 1981, and the second in 2013 and 2014. The main goal was to perform a landscape typology in order to assess the susceptibility of landscape complexes to occurrence of anthropogenic and natural destruction processes and to assess the condition and prospects of HTs and their impacts on the adjacent alpine environment. Landscape complexes were characterised by selected abiotic, biotic and technical parameters of HTs and their impact zones. Due to the high variability of these parameters over the length of the HTs, we had to decide on how to map them. This was done using a square grid with 100 m-sized cells. For each cell with HT, the parameters were assigned the typical value within that cell. In total, 26.3 km of HT were studied, stretching over 266 grid cells. On comparison of the two data sets, it was seen that, 64% (171 grid cells) display a generally positive condition, with 54% (143 grid cells) even exhibiting significant improvement or continuously positive state of their condition. 36% (95 grid cells) were in bad condition, including 3% (9 grid cells) whose state had deteriorated, and 2% (6 grid cells) whose state had significantly deteriorated, in the time between the two assessments.  相似文献   

RHESSI Data Analysis Software: Rationale and Methods     

Schwartz  R.A.  Csillaghy  A.  Tolbert  A.K.  Hurford  G.J.  Mc Tiernan  J.  Zarro  D. 《Solar physics》2002,210(1-2):165-191

The Reuven Ramaty High-Energy Solar Spectroscopic Imager (RHESSI) performs imaging spectroscopy of the Sun with high spatial and spectral resolution from 3 keV to 17 MeV using indirect Fourier-transform techniques. We review the rationale behind the RHESSI data analysis software, and explain the underlying structure of the software tools. Our goal was to make the large data set available within weeks after the RHESSI launch, and to make it possible for any member of the scientific community to analyze it easily. This paper describes the requirements for the software and explores our decisions to use the SolarSoftWare and Interactive Data Language programming packages, to support both Windows and Unix platforms, and to use object-oriented programming. We also describe how the data are rapidly disseminated and how ancillary data sets are used to enhance the RHESSI science. Finally, we give a schematic overview of some of the data flow through the high-level analysis tools. More information on the data and analysis procedures can be found at the RHESSI Data Center website, http://hesperia.gsfc.nasa.gov/rhessidatacenter. Supplementary material to this paper is available in electronic form at http://dx.doi.org/10.1023/A:1022444531435  相似文献   

Hydrochemical models of the sulphidic tailings dumps at Matchless (Namibia) and Selebi-Phikwe (Botswana)     

M. O. Schwartz  A. Schippers  L. Hahn 《Environmental Geology》2006,49(4):504-510

The sulphidic tailings dumps at Matchless (Namibia) and Selebi-Phikwe (Botswana) are located in a similar semiarid environment but have a contrasting mineralogical composition. The Matchless tailings are pyrite-rich, whereas the Selebi-Phikwe tailings are dominated by pyrrhotite. Hydrochemical models are established with computer codes for water-balance, sulphide oxidation rate and hydrochemical equilibrium calculations. The data input is based on detailed mineralogical, chemical and kinetic investigations carried out on the core of boreholes drilled in 2000 and 2003. The oxidation of pyrrhotite proceeds at a much faster rate than the oxidation of pyrite. The PYROX code, which is used for kinetic calculations, can take these differences into account by applying different oxide-coating diffusion coefficients (D₂) for pyrrhotite and pyrite. Humidity-cell testing is widely used to predict the post-mining composition of drainage water in humid climates. However, the semiarid conditions at Matchless and Selebi-Phikwe only allow a minimal water flux within the dump. Under such conditions, humidity-cell testing is likely to overestimate the seepage-water pH. This is suggested by the hydrochemical equilibrium calculations for the post-mining period at Selebi-Phikwe, which predict a seepage-water pH about one unit lower than the pH at the end of the 26-weeks humidity-cell testing period. The acidity of the seepage water can be reduced by about half a pH unit, if an oxygen barrier below the evaporation zone is installed. A clay layer 0.5 m thick covered by >1.5 m tailings represents the optimal design for a wet barrier. All three computer codes used for water-balance calculations (HELP3, UNSAT-H and HYDRUS-1D), predict >85% average water saturation for such a layer, which diminishes the diffusion of oxygen into the pile and production of SO₄⁻² and H⁺. The alternative design for a dry barrier consists of a vegetated silt layer 1 m thick on top of the tailings. This barrier does not significantly influence the diffusion of oxygen although it reduces the net infiltration to ≤11 mm/year.  相似文献