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151.
We have previously shown that largemouth bass (Micropterus salmoides) has a remarkable ability to conjugate 4-hydroxy-2-nonenal (4HNE), a mutagenic and cytotoxic α,β-unsaturated aldehyde produced during the peroxidation of lipids. In addition, we have isolated a glutathione S-transferase cDNA (bass GSTA) that encodes a recombinant protein which is highly active in 4HNE conjugation and structurally similar to plaice (Pleuronectes platessa) GSTA. In the present study, HPLC-GST subunit analysis revealed the presence of at least two major GST isoforms in bass liver, with one peak constituting 80% of the total bass liver GST protein. Liquid chromatography mass spectrometry (LC–MS) and electrospray ionization analysis of the major bass GST subunit yielded a molecular weight of 26,396 kDa. Endo-proteinase Lys-C digestion and Edman degradation protein sequencing of this GST peak demonstrated that this protein was encoded by bass GSTA. Analysis of genomic DNA fragments isolated by nested PCR indicated the presence of a GST gene cluster in bass liver that contained GSTA, and was similar to a GST gene cluster characterized by Leaver et al., in plaice. Collectively, our data indicates the presence of a major GST in bass liver involved in the protection against oxidative stress. This GST is part of a gene cluster that may be conserved in certain freshwater and marine fish.  相似文献   
152.
Theoretical and Applied Climatology - We present preliminary analyses of the historical (1986–2005) climate simulations of a ten-member subset of the Coupled Model Inter-comparison Project...  相似文献   
153.
Marble-hosted ruby deposits represent the most important source of colored gemstones from Central and South East Asia. These deposits are located in the Himalayan mountain belt which developed during Tertiary collision of the Indian plate northward into the Eurasian plate. They are spatially related to granitoid intrusions and are contained in platform carbonates series that underwent high-grade metamorphism. All occurrences are located close to major tectonic features formed during Himalayan orogenesis, directly in suture zones in the Himalayas, or in shear zones that guided extrusion of the Indochina block after the collision in South East Asia. Ar–Ar dating of micas syngenetic with ruby and U–Pb dating of zircon included in ruby gives evidence that these deposits formed during Himalayan orogenesis, and the ages document the extensional tectonics that were active, from Afghanistan to Vietnam, between the Oligocene and the Pliocene.The petrography shows that ruby-bearing marbles formed in the amphibolite facies (T = 610 to 790 °C and P ~ 6 kbar). A fluid inclusion study defines the conditions of gem ruby formation during the retrograde metamorphic path (620 < T < 670 °C and 2.6 < P < 3.3 kbar) for the deposits of Jegdalek, Hunza and northern Vietnam.Whole rock analyses of non-ruby-bearing marbles indicate that they contain enough aluminum and chromiferous elements to produce all the ruby crystals that they contain. In addition, (C, O)-isotopic analyses of carbonates from the marbles lead to the conclusion that the marbles acted as a metamorphic closed fluid system that were not infiltrated by externally-derived fluids. The carbon isotopic composition of graphite in marbles reveals that it is of organic origin and that it exchanged C-isotopes with the carbonates during metamorphism. Moreover, the O-isotopic composition of ruby was buffered by metamorphic CO2 released during devolatilisation of marble and the H-isotopic composition of mica is consistent with a metamorphic origin for water in equilibrium with the micas. The (C, O, H)-isotopic compositions of minerals associated with marble-hosted ruby are all in agreement with the hypothesis, drawn from the unusual chemistry of CO2–H2S–COS–S8–AlO(OH)-bearing fluids contained in fluid inclusions, that gem ruby formed at P ~ 3 kbar and 620 < T < 670 °C, during thermal reduction of evaporite by organic matter, at high temperature-medium pressure metamorphism of platform carbonates during the Tertiary India–Asia collision. The carbonates were enriched in Al- and chromiferous-bearing detrital minerals, such as clay minerals that were deposited on the platform with the carbonates, and in organic matter. Ruby formed during the retrograde metamorphic path, mainly by destabilization of muscovite or spinel. The metamorphic fluid system was rich in CO2 released from devolatilisation of carbonates, and in fluorine, chlorine and boron released by molten salts (NaCl, KCl, CaSO4). Evaporites are key to explaining the formation of these deposits. Molten salts mobilized in situ Al and metal transition elements contained in marbles, leading to crystallization of ruby.  相似文献   
154.
The Na Son deposit is a small‐scale Pb–ZnPb–Zn–Ag deposit in northeast Vietnam and consists of biotite–chlorite schist, reddish altered rocks, quartz veins and syenite. The biotite–chlorite schist is intruded by syenite. Reddish altered rocks occur as an alteration halo between the biotite–allanite‐bearing quartz veins and the biotite–chlorite schist. Allanite occurs in the biotite–allanite‐bearing quartz veins and in the proximal reddish altered rocks. Rare earth element (REE) fluorocarbonate minerals occur along fractures or at rim of allanite crystals. The later horizontal aggregates of sulfide veins and veinlets cut the earlier reddish altered rocks. The earlier Pb–Zn veins consist of a large amount of galena and lesser amounts of sphalerite, pyrite and molybdenite. The later Cu veins cutting the Pb–Zn veins include chalcopyrite and lesser amounts of tetrahedrite and pyrite. The occurrences of two‐phase H2O–CO2 fluid inclusions in quartz from biotite–allanite‐bearing quartz veins and REE‐bearing fluorocarbonate minerals in allanite suggest the presence of CO2 and F in the hydrothermal fluid. The oxygen isotopic ratios of the reddish altered rocks, biotite–chlorite schist, and syenite range from +13.9 to +14.9 ‰, +11.5 to +13.3 ‰, and +10.1 to +11.6 ‰, respectively. Assuming an isotopic equilibrium between quartz (+14.6 to +15.8 ‰) and biotite (+8.6 ‰) in the biotite–allanite‐bearing quartz vein, formation temperature was estimated to be 400°C. At 400°C, δ18O values of the hydrothermal fluid in equilibrium with quartz and biotite range from +10.5 to +11.7 ‰. These δ18O values are consistent with fluid that is derived from metamorphism. Assuming an isotopic equilibrium between galena (+1.5 to +1.7 ‰) and chalcopyrite (+3.4 ‰), the formation temperature was estimated to be approximately 300°C. The formation temperature of the Na Son deposit decreased with the progress of mineralization. Based on the geological data, occurrence of REE‐bearing minerals and oxygen isotopic ratios, the REE mineralization is thought to result from interaction between biotite–chlorite schist and REE‐, CO2‐ and F‐bearing metamorphic fluid at 400°C under a rock‐dominant condition.  相似文献   
155.
Around hundred landslides were triggered by the Kumamoto earthquakes in April 2016, causing fatalities and serious damage to properties in Minamiaso village, Kumamoto Prefecture, Japan. The landslides included many rapid and long-runout landslides which were responsible for much of the damage. To understand the mechanism of these earthquake-triggered landslides, we carried out field investigations with an unmanned aerial vehicle to obtain DSM and took samples from two major landslides (Takanodai landslide and Aso-ohashi landslide) to measure parameters of the initiation and the motion of landslides. A series of ring-shear tests and computer simulations were conducted using a measured Kumamoto earthquake acceleration record from KNet station KMM005, 10 km west of Aso-ohashi landslide. The research results supported our assumed mechanism of sliding-surface liquefaction for the rapid and long-runout motion of these landslides.  相似文献   
156.
An attempt is made in this study to search for a model which is capable of reproducing the reservoir storage components and runs' characteristics along with the mean, standard deviation, skewness and correlation coefficients of historical monthly streamflows. The model based upon the method of fragments and a scheme devised for annual values is found to yield satisfactory results and is, therefore, recommended for use.  相似文献   
157.
General expressions for the first four moments of the positive run-sum for independent sequences are derived and their computation scheme is indicated. The formulae for the moments of the truncated variable, which are needed in obtaining those of the positive run-sum, are then given for the case when the sequence under consideration follows one of the normal, log-normal, gamma or Rayleigh distributions.  相似文献   
158.
The objective of this study is to explore and compare the least square support vector machine (LSSVM) and multiclass alternating decision tree (MADT) techniques for the spatial prediction of landslides. The Luc Yen district in Yen Bai province (Vietnam) has been selected as a case study. LSSVM and MADT are effective machine learning techniques of classification applied in other fields but not in the field of landslide hazard assessment. For this, Landslide inventory map was first constructed with 95 landslide locations identified from aerial photos and verified from field investigations. These landslide locations were then divided randomly into two parts for training (70 % locations) and validation (30 % locations) processes. Secondly, landslide affecting factors such as slope, aspect, elevation, curvature, lithology, land use, distance to roads, distance to faults, distance to rivers, and rainfall were selected and applied for landslide susceptibility assessment. Subsequently, the LSSVM and MADT models were built to assess the landslide susceptibility in the study area using training dataset. Finally, receiver operating characteristic curve and statistical index-based evaluations techniques were employed to validate the predictive capability of these models. As a result, both the LSSVM and MADT models have high performance for spatial prediction of landslides in the study area. Out of these, the MADT model (AUC = 0.853) outperforms the LSSVM model (AUC = 0.803). From the landslide study of Luc Yen district in Yen Bai province (Vietnam), it can be conclude that the LSSVM and MADT models can be applied in other areas of world also for and spatial prediction. Landslide susceptibility maps obtained from this study may be helpful in planning, decision making for natural hazard management of the areas susceptible to landslide hazards.  相似文献   
159.
160.
While it remains the primary source of safe drinking and irrigation water in northwest Iran's Maku Plain, the region's groundwater is prone to fluoride contamination. Accordingly, modeling techniques to accurately predict groundwater fluoride concentration are required. The current paper advances several novel data mining algorithms including Lazy learners [instance-based K-nearest neighbors (IBK); locally weighted learning (LWL); and KStar], a tree-based algorithm (M5P), and a meta classifier algorithm [regression by discretization (RBD)] to predict groundwater fluoride concentration. Drawing on several groundwater quality variables (e.g., concentrations), measured in each of 143 samples collected between 2004 and 2008, several models predicting groundwater fluoride concentrations were developed. The full dataset was divided into two subsets: 70% for model training (calibration) and 30% for model evaluation (validation). Models were validated using several statistical evaluation criteria and three visual evaluation approaches (i.e., scatter plots, Taylor and Violin diagrams). Although Na+ and Ca2+ showed the greatest positive and negative correlations with fluoride (r = 0.59 and −0.39, respectively), they were insufficient to reliably predict fluoride levels; therefore, other water quality variables, including those weakly correlated with fluoride, should be considered as inputs for fluoride prediction. The IBK model outperformed other models in fluoride contamination prediction, followed by KStar, RBD, M5P, and LWL. The RBD and M5P models were the least accurate in terms of predicting peaks in fluoride concentration values. Results of the current study can be used to support practical and sustainable management of water and groundwater resources.  相似文献   
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