XMCD at Fe L<Subscript>2,3</Subscript> edges,Fe and S K edges on Fe<Subscript>7</Subscript>S<Subscript>8</Subscript>     

Isabelle Letard  Philippe Sainctavit  Catherine Deudon 《Physics and Chemistry of Minerals》2007,34(2):113-120

Pyrrhotite (Fe₇S₈) is a natural iron sulphide that can participate in rock magnetisation. Its electronic structure is not yet surely described. X-ray magnetic circular dichroism (XMCD) at Fe L_2,3 edges on Fe₇S₈, coupled with multiplet calculations, shows that iron is present only as Fe²⁺ in this magnetic iron sulphide. It reveals a strong magnetic orbital moment. XMCD at Fe and S K edges shows the quite strong polarization of both Fe and S in Fe₇S₈.  相似文献   

The junction of Fensch and Moselle rivers,France; mineralogy and composition of river materials     

Emmanuelle Montarges-Pelletier  Laurent Jeanneau  Pierre Faure  Isabelle Bihannic  Odile Barres  Bruno S. Lartiges 《Environmental Geology》2007,53(1):85-102

The Moselle river flows in the north-east of France, from Vosges Mountains to neighboring countries Luxembourg and Germany. One of its tributaries, the Fensch river, drains a highly industrialized watershed, strongly impacted by mining, smelting and surfacing activities. The objective of this work, part of a general research program on Moselle watershed (Zone Atelier Moselle) was to assess the impact of the polluted Fensch river on the global quality of the Moselle river. For that purpose, water, sediments and suspended particulate matter were sampled in both rivers, upstream and downstream the junction. Four main sampling campaigns were carried out, in winter during a flood event and in spring at low water level. On a first step, mineralogical analyses (XRD and FTIR) and chemical analyses (ICP-MS, ICP-AES), were performed on sediments, suspended particulate matters and filtered waters. Major and trace elements concentrations were obtained on two different granulometric fractions (0–2 mm and 0–50 μm) revealing the enrichment in heavy metals of fine particles. From one collecting campaign to another, seasonal variations could be evidenced on suspended matter composition even though major minerals (calcite, quartz and kaolinite) were always present. Furthermore, spatial variations were evidenced for Fensch and Moselle downstream sediments. Thus, very fine-grained sediments, poorly crystallized, displaying at the same time higher metal concentrations and higher organic matter content than in Fensch river material, were collected downstream, in a low hydrodynamic conditions zone, assumed as a preferential sedimentary zone or even as a placer. Strong correlations could be revealed between iron content and contaminant concentrations, confirming the origin of polluted material.  相似文献   

Characterizing flow zones in a fractured and karstified limestone aquifer through integrated interpretation of geophysical and hydraulic data     

Nathalie Van Meir  David Jaeggi  Martin Herfort  Simon Loew  Philippe A. Pezard  Gérard Lods 《Hydrogeology Journal》2007,15(2):225-240

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Garnet reequilibration and growth in the eclogite facies and geodynamical evolution near peak metamorphic conditions     

Hugues Raimbourg  Bruno Goffé  Laurent Jolivet 《Contributions to Mineralogy and Petrology》2007,153(1):1-28

Caledonian eclogite-facies metamorphism partially reworking Grenvillian granulite-facies anorthosite allows us to study the processes of garnet reequilibration at high pressure and to reconstruct the evolution of the unit near metamorphic peak conditions. Our results indicate that eclogite-facies metamorphism happened in two successive phases: first, inherited granulitic garnet was fractured and reequilibrated from their boundaries (crystal or fracture rims); then eclogite-facies minerals were crystallised in the fractures as overgrowths on inherited garnets. The reequilibration of inherited garnets is achieved through Fe²⁺Mg⁻¹ exchange, whereas eclogite-facies garnets crystallised during the subsequent phase are notably richer in Ca than un- and re-equilibrated granulitic garnet. Pseudosection construction shows that this lack in Ca reequilibration cannot be related to variations in thermodynamic conditions (a _H2O, reacting system composition) between the two phases. From the compilation of the available data, the reequilibration of granulitic garnet seems to be controlled by the inefficient intra- and inter-granular transport properties of Ca compared to Fe²⁺ and Mg. While these kinetic factors confine garnet reequilibration to Fe²⁺Mg⁻¹ exchange, the extent of reequilibration along this exchange vector is controlled by partitioning with adjacent omphacite. On the contrary to the diffusional reequilibration of granulitic garnet that lasted for several My according to our modelling of the diffusional relaxation, the strong compositional gradients between eclogite-facies and reequilibrated garnets, which are almost unaffected by diffusional reequilibration, provide evidence that rapid exhumation followed the crystallisation of eclogite-facies minerals. We propose that the movement reversal itself, from burial to exhumation, and associated deformation and fluid flow, triggered this crystallisation event. The resulting evolution near metamorphic peak conditions is therefore strongly asymmetrical: on the one hand, the prograde diffusional relaxation profiles indicate slow movement during the last stages of burial, whereas the unaffected retrograde overgrowth indicates fast exhumation rates.  相似文献   

Response of littoral chironomid communities and organic matter to late glacial lake—level,vegetation and climate changes at Lago dell’Accesa (Tuscany,Italy)     

Laurent Millet  Boris Vannière  Valérie Verneaux  Michel Magny  Jean Robert Disnar  Fatima Laggoun-Défarge  Anne Véronique Walter-Simonnet  Gilles Bossuet  Elena Ortu  Jacques-Louis de Beaulieu 《Journal of Paleolimnology》2007,38(4):525-539

This study focuses on the response of lacustrine littoral chironomid communities to late glacial changes in limnological, environmental and climate conditions in the Mediterranean context. Late glacial chironomid (Diptera: Chironomidae) assemblages, organic petrography and geochemistry were analysed in a sediment core from the littoral zone of Lago dell’Accesa (Tuscany, Italy), where the lake-level fluctuations and the vegetation history have been previously reconstructed. Comparison of the chironomid stratigraphy to other proxies (pollen assemblages, organic petrography and geochemistry, lake-level) and regional climate reconstruction suggested the predominant influence of lake-level changes on the littoral chironomid fauna. The main lowering events that occurred during the Oldest and the Younger Dryas were followed by higher proportions of taxa typical of littoral habitats. A complementary study of organic matter suggested the indirect impact of lake-level on the chironomids through changes in humic status and habitat characteristics, such as the type of substrate and aquatic macrophyte development. Several chironomid taxa, such as Glyptotendipes, Microtendipes and Cricotopus type patens, were identified as possible indicators of low lake-level in the late glacial records. Nevertheless, this study suggested that parallel analyses of organic matter and chironomid assemblages may be needed to circumvent misinterpretation of littoral chironomid assemblage stratigraphy. There was a weak response of the chironomid assemblages to small lake-level lowerings that corresponded to the Older Dryas and Preboreal oscillations. A higher level of determination, e.g. to the species group level, may be necessary to increase the sensibility of the indicators to lake-level changes.  相似文献   

An archaeomagnetic investigation of a Roman amphorae workshop in Albinia (Italy)     

Mimi J. Hill  Philippe Lanos  Annick Chauvin  Daniele Vitali  Fanette Laubenheimer 《Geophysical Journal International》2007,169(2):471-782

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A simplified approach for vulnerability assessment in moderate-to-low seismic hazard regions: application to Grenoble (France)   总被引：3，自引：2，他引：3  

Philippe Guéguen  Clotaire Michel  Laele LeCorre 《Bulletin of Earthquake Engineering》2007,5(3):467-490

Due to the moderate seismic risks in France, the building vulnerability assessment methods developed for high seismic risk countries could not easily be used here because of their cost and the low-risk perception among the public and officials. A light vulnerability assessment method is proposed and tested in Grenoble (France), based on classes and scores provided in the GNDT method but simplified in terms of visual screening and number of structural parameters used. Compared to the RiskUE method, the damage obtained by our approach shows that 90% of buildings have residuals smaller than 0.2, i.e. one grade of the EMS98 damage scale. A large scale survey is devised and conducted among the inhabitants of Grenoble in order to collect the main structural parameters. By comparing the results from the survey to the historical urbanization of Grenoble and to expert surveys performed in two urban districts, the information useful for the light method of vulnerability assessment can be rapidly collected by non-experts reducing substantially the estimate cost. The average damage is then computed using the GNDT formula considering the probable intensities which could be observed in Grenoble (VII and VIII). The average damage reaches 0.4 in the oldest part of Grenoble mainly made of masonry buildings and 0.2 in reinforced concrete suburbs where reinforced concrete predominates. The results are a relative vulnerability assessment that provides useful initial information for the urban zones of Grenoble where the vulnerability is higher. This method can be used to classify the seismic vulnerability in wide seismic-prone regions to a fair degree of accuracy and at low cost.  相似文献   

Inversion of interference hydraulic pumping tests in both homogeneous and fractal dual media     

Frederick Delay  Anne Kaczmaryk  Philippe Ackerer 《Advances in water resources》2007

This work proposes a complete method for automatic inversion of data from hydraulic interference pumping tests based on both homogeneous and fractal dual-medium approaches. The aim is to seek a new alternative concept able to interpret field data, identify macroscopic hydraulic parameters and therefore enhance the understanding of flow in porous fractured reservoirs. Because of its much contrasted sensitivities to parameters, the dual-medium approach yields an ill-posed inverse problem that requires a specific optimization procedure including the calculation of analytical sensitivities and their possible re-scaling. Once these constraints are fulfilled, the inversion proves accurate, provides unambiguous and reliable results. In the fractal context inverting several drawdown curves from different locations at the same time reveals more accurate. Finally, hydraulic parameters drawn from inversion should be taken into account to improve in various situations the conditioning of up-scaled flow in fractured rocks.  相似文献   

The Cloud Ice Mountain Experiment (CIME) 1998: experiment overview and modelling of the microphysical processes during the seeding by isentropic gas expansion     

Wolfram Wobrock  Andrea I. Flossmann  Marie Monier  Jean-Marc Pichon  Laurent Cortez  Jean-Franois Fournol  Alfons Schwarzenbck  Stephan Mertes  Jost Heintzenberg  Paolo Laj  Giordano Orsi  Loretta Ricci  Sandro Fuzzi  Harry Ten Brink  Piet Jongejan  Ren Otjes 《Atmospheric Research》2001,58(4):7907

The second field campaign of the Cloud Ice Mountain Experiment (CIME) project took place in February 1998 on the mountain Puy de Dôme in the centre of France. The content of residual aerosol particles, of H₂O₂ and NH₃ in cloud droplets was evaluated by evaporating the drops larger than 5 μm in a Counterflow Virtual Impactor (CVI) and by measuring the residual particle concentration and the released gas content. The same trace species were studied behind a round jet impactor for the complementary interstitial aerosol particles smaller than 5 μm diameter. In a second step of experiments, the ambient supercooled cloud was converted to a mixed phase cloud by seeding the cloud with ice particles by the gas release from pressurised gas bottles. A comparison between the physical and chemical characteristics of liquid drops and ice particles allows a study of the fate of the trace constituents during the presence of ice crystals in the cloud.In the present paper, an overview is given of the CIME 98 experiment and the instrumentation deployed. The meteorological situation during the experiment was analysed with the help of a cloud scale model. The microphysics processes and the behaviour of the scavenged aerosol particles before and during seeding are analysed with the detailed microphysical model ExMix. The simulation results agreed well with the observations and confirmed the assumption that the Bergeron–Findeisen process was dominating during seeding and was influencing the partitioning of aerosol particles between drops and ice crystals. The results of the CIME 98 experiment give an insight on microphysical changes, redistribution of aerosol particles and cloud chemistry during the Bergeron–Findeisen process when acting also in natural clouds.  相似文献   

Adaptation of prestack migration to multi-offset ground-penetrating radar (GPR) data     

Donatienne Leparoux  Dominique Gibert  Philippe Côte 《Geophysical Prospecting》2001,49(3):374-386

In adapting the prestack migration technique used in seismic imaging to the inversion of ground‐penetrating radar (GPR) from time‐ to depth‐sections, we show that the theoretical integral formulation of the inversion can be applied to electromagnetic problems, albeit with three assumptions. The first two assumptions concern the electromagnetic characteristics of the medium, primarily that the medium must be perfectly resistive and non‐dispersive, and the third concerns the antennae radiation pattern, which is taken to be 2D. The application of this adaptation of the inversion method is confirmed by migrating actual GPR measurements acquired on the test site of the Laboratoire Central des Ponts et Chaussées. The results show good agreement with the geometry of the structures in the medium and confirm that the possible departure from the assumption of a purely resistive medium has no visible effect on the information concerning the geometry of scattering and reflecting structures. The field experiments also show that prestack migration processing is sufficiently robust with regard to the assumption of a non‐dispersive medium. The assumption of a 2D antennae radiation pattern, however, produces artefacts that could be significant for laterally heterogeneous media. Nevertheless, where the medium is not highly laterally heterogeneous, the migration gives a clear image of the scattering potential due to the geometry of structural contrasts in the medium; the scatterers are well focused from diffraction hyperbolae and well localized. Spatial geometry has limited dimensional accuracy and positions are located with a maximum error equal to the minimum wavelength of the signal bandpass. Objects smaller than one wavelength can nevertheless be detected and well focused if their dielectric contrasts are sufficiently high, as in the case of iron or water in gneiss gravels. Furthermore, the suitability of multi‐offset protocols to estimate the electromagnetic propagating velocity and to decrease the non‐coherent noise level of measurements is confirmed. Our velocity estimation is based on the semblance calculation of multi‐offset migrated images, and we confirmed the relevance of this quantification method using numerical data. The signal‐to‐noise ratio is improved by summing multi‐offset results after the addition of random noise on measurements. Thus the adaptation of prestack migration to multi‐offset radar measurements significantly improves the resolution of the scattering potential of the medium. Limitations associated with the methods used here suggest that 3D algorithms should be applied to strongly laterally heterogeneous media and further studies concerning the waveform inversion are necessary to obtain information about the electric nature of the medium.  相似文献