Paleoenvironmental records of water level and climatic changes from the middle to late Holocene at a Lake Erie coastal wetland, Ontario, Canada   总被引：2，自引：0，他引：2  

Sarah A. Finkelstein  Anthony M. Davis 《Quaternary Research》2006,65(1):33-43

Pollen and diatom assemblages, and peat stratigraphies, from a coastal wetland on the northern shore of Lake Erie were used to analyze water level and climatic changes since the middle Holocene and their effects on wetland plant communities. Peat deposition began 4700 cal yr B.P. during the Nipissing II transgression, which was driven by isostatic rebound. At that time, a diatom-rich wild rice marsh existed at the site. Water level dropped at the end of the Nipissing rise at least 2 m within 200 yr, leading to the development of shallower-water plant communities and an environment too dry for most diatoms to persist. The sharp decline in water level was probably driven primarily by outlet incision, but climate likely played some role. The paleoecological records provide evidence for post-Nipissing century-scale transgressions occurring around 2300, 1160, 700 and 450 cal yr B.P. The chronology for these transgressions correlates with other studies from the region and implies climatic forcing. Peat inception in shallow sloughs across part of the study area around 700 cal yr B.P. coincides with the Little Ice Age. These records, considered alongside others from the region, suggest that the Little Ice Age may have resulted in a wetter climate across the eastern Great Lakes region.  相似文献   

Geochemistry of silicic magmas in the Macolod Corridor, SW Luzon, Philippines: evidence of distinct, mantle-derived, crustal sources for silicic magmas     

Thomas A. Vogel  Timothy P. Flood  Lina C. Patino  Melissa S. Wilmot  Raymond Patrick R. Maximo  Carmencita B. Arpa  Carlo A. Arcilla  James A. Stimac 《Contributions to Mineralogy and Petrology》2006,151(3):267-281

Silicic volcanic deposits (>65 wt% SiO₂), which occur as domes, lavas and pyroclastic deposits, are relatively abundant in the Macolod Corridor, SW Luzon, Philippines. At Makiling stratovolcano, silicic domes occur along the margins of the volcano and are chemically similar to the silicic lavas that comprise part of the volcano. Pyroclastic flows are associated with the Laguna de Bay Caldera and these are chemically distinct from the domes and lavas at Makiling stratovolcano. As a whole, samples from the Laguna de Bay Caldera contain lower concentrations of MgO and higher concentrations of Fe₂O_3(t) than the samples from domes and lavas. The Laguna de Bay samples are more enriched in incompatible trace elements. The silicic rocks from the domes, Makiling Volcano and Laguna de Bay Caldera all contain high alkalis and high K₂O/Na₂O ratios. Melting experiments of primitive basalts and andesites demonstrate that it is difficult to produce high K₂O/Na₂O silicic magmas by fractional crystallization or partial melting of a low K₂O/Na₂O source. However, recent melting experiments (Sisson et al., Contrib Mineral Petrol 148:635–661, 2005) demonstrate that extreme fractional crystallization or partial melting of K-rich basalts can produce these silicic magmas. Our model for the generation of the silicic magmas in the Macolod Corridor requires partial melting of mantle-derived, evolved, moderate to K-rich, crystallized calc-alkaline magmas that ponded and crystallized in the mid-crust. Major and trace element variations, along with oxygen isotopes and ages of the deposits, are consistent with this model. Electronic Supplementary Material Supplementary material is available for this article at  相似文献   

Ultra-rapid landscape response and sediment yield following glacier retreat, Icy Bay, southern Alaska     

Andrew Meigs  William C. Krugh  Kelsay Davis  Greg Bank 《Geomorphology》2006,78(3-4):207-221

The páramo is a neotropical alpine ecosystem that covers more than 75,000 km² of the northern Andes of Colombia, Ecuador, Venezuela, and Peru. It provides important environmental services: more than 10 million people in the Andean highlands benefit from the water supply and regulation function, which is attributed to the volcanic soils that underlie the ecosystem. The soils are also major carbon sinks of global significance. Severe land use changes and soil degradation threaten both the hydrology and carbon sink function. Nevertheless, soil genesis and properties in the páramo is rather poorly understood, nor are their ecological functions well documented. The impact of the geomorphology of the páramo on soil genesis was studied in the rio Paute basin, south Ecuador. Two toposequences were described and analysed. In each toposequence, four pedons were selected representing summit, backslope, undrained plain situation, and valley bottom positions in the landscape. The soils are classified as Hydric Andosols in the World Reference Base for Soil Resources and Epiaquands or Hydrudands in Soil Taxonomy. They are very acidic and have a high organic matter content, high P deficiency, and Al toxicity. Their water content ranges from 2.64 g g^− 1 at saturation, down to 1.24 g g^− 1 at wilting point, resulting in a large water storage capacity. Two major soil forming processes are identified: (1) volcanic ash deposition and (2) accumulation of organic carbon. Volcanic ash deposits may vary in depth as a result of regional geomorphological factors such as parent material, orientation, slope, and altitude. Organic carbon accumulation is an interaction of both waterlogging, which depends on the position in the landscape, and the formation of organometallic complexes with Al and Fe released during volcanic ash breakdown. Despite the high variability in parent material and topography, the soil is characterised by a notable homogeneity in physico-chemical properties. Statistical analysis reveals that only topographic location has a slight but significant influence on soil pH as well as the organic matter content, saturated conductivity and water retention at high pressure. Finally, the exceptional properties of these soils provide useful insights to improve classification of the Andosols reference group of the FAO World reference Base for Soil Resources.  相似文献   

Mixing and differentiation in the Oruanui rhyolitic magma, Taupo, New Zealand: evidence from volatiles and trace elements in melt inclusions     

Yang Liu  Alfred T. Anderson  Colin J. N. Wilson  Andrew M. Davis  Ian M. Steele 《Contributions to Mineralogy and Petrology》2006,151(1):71-87

Large pyroclastic rhyolites are snapshots of evolving magma bodies, and preserved in their eruptive pyroclasts is a record of evolution up to the time of eruption. Here we focus on the conditions and processes in the Oruanui magma that erupted at 26.5 ka from Taupo Volcano, New Zealand. The 530 km³ (void-free) of material erupted in the Oruanui event is comparable in size to the Bishop Tuff in California, but differs in that rhyolitic pumice and glass compositions, although variable, did not change systematically with eruption order. We measured the concentrations of H₂O, CO₂ and major and trace elements in zoned phenocrysts and melt inclusions from individual pumice clasts covering the range from early to late erupted units. We also used cathodoluminescence imaging to infer growth histories of quartz phenocrysts. For quartz-hosted inclusions, we studied both fully enclosed melt inclusions and reentrants (connecting to host melt through a small opening). The textures and compositions of inclusions and phenocrysts reflect complex pre-eruptive processes of incomplete assimilation/partial melting, crystallization differentiation, magma mixing and gas saturation. ‘Restitic’ quartz occurs in seven of eight pumice clasts studied. Variations in dissolved H₂O and CO₂ in quartz-hosted melt inclusions reflect gas saturation in the Oruanui magma and crystallization depths of ∼3.5–7 km. Based on variations of dissolved H₂O and CO₂ in reentrants, the amount of exsolved gas at the beginning of eruption increased with depth, corresponding to decreasing density with depth. Pre-eruptive mixing of magma with varying gas content implies variations in magma bulk density that would have driven convective mixing. Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users.  相似文献   

Editorial     

Raymond Michels  Laurence Mansuy  Marcel Elie  Pierre Faure  Vincent Huault  Luis Martinez  Jacques Pironon 《Organic Geochemistry》2002,33(12)

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KARSTIC: a sensitivity method for carbonate aquifers in karst terrain   总被引：5，自引：2，他引：5  

A. Davis  A. Long  M. Wireman 《Environmental Geology》2002,42(1):65-72

. Groundwater in karstic aquifers can be dangerously sensitive to contamination. Many cities in the western USA rely on karstic carbonate aquifers for municipal water supplies. For example, Rapid City, South Dakota, pumps more than half of its drinking water from wells in the Madison Limestone. This work examined the sensitivity of karstic aquifers to surface contamination in mountainous terrain. Where karstic carbonate aquifers are exposed at their outcrop areas, they are particularly susceptible to the introduction of contamination through diffuse recharge or through point recharge at swallow holes along streams. Residential developments in mountainous regions of the western USA are encroaching on the recharge areas of karstic aquifers. Many of these residential developments are served by onsite wastewater disposal systems such as septic tanks and drain fields, with the attendant danger of introduction of pathogens from malfunctioning treatment systems above fractured limestone which offers little filtering. Where streams disappear into karstic aquifers at swallow holes, microbial contaminants such as Giardia or Cryptosporidium are a concern, as well as potential spills, leaks, or accidents along roads near these streams. The KARSTIC method developed and modified in this work puts greater emphasis on karst features than previous sensitivity procedures such as the US Environmental Protection Agency's DRASTIC method. The modified method gives increased attention to highly sensitive areas of karstic carbonate aquifers by weighting the synergistic effects of fracturing, karst development, and swallow holes of recharging streams. In a field application, hydrogeologic maps of a watershed in the Black Hills, USA, were digitized into a geographic information system. The resulting sensitivity map and report can be used by planners, managers, and the public as a screening tool for assessing groundwater sensitivity in regions which include karstic aquifers.  相似文献   

Elemental and isotopic fractionation of Type B calcium-, aluminum-rich inclusions: experiments, theoretical considerations, and constraints on their thermal evolution     

Frank M. Richter  Andrew M. Davis  Denton S. EbelAkihiko Hashimoto 《Geochimica et cosmochimica acta》2002,66(3):521-540

Experiments exposing Type B calcium-, aluminum-rich inclusion (CAI)-like melts at high temperatures to high vacuum or reducing hydrogen-rich gas mixtures were used to determine the rates and consequences of elemental and isotopic fractionation by evaporation. Silicon and magnesium were found to evaporate much faster than calcium and aluminum, and the resulting residual liquid trajectories in composition space are reproduced via a thermodynamic model for the saturation vapor pressure of the evaporating species. Isotopic fractionations associated with evaporation were measured for magnesium. The resulting relationship between fraction of magnesium lost and enrichment of the residue in the heavy isotopes of magnesium follows a Rayleigh fractionation curve with a fractionation factor that is close to, but not exactly, the theoretically expected value. The rate of evaporation is found to be a strong function of temperature, oxygen fugacity, and melt composition, which can be understood and modeled in terms of the dependence of the saturation vapor pressures on these variables. The relationship between evaporation rate, which we measure, and calculated saturation vapor involves empirical evaporation coefficients that we find to be significantly less than one (∼0.1). Analytical and numerical models are used to characterize how diffusion in both the melt and in the surrounding gas affects evaporation rates and the degree of chemical and isotopic fractionation. The experimental data and theoretical considerations are combined to give a parameterization of the rates and consequences of evaporation of Type B CAI-like liquids, which is then used to translate the measured isotopic fractionation of Type B CAIs into constraints on their thermal history. Cooling rates of the order of 10°C per hour are indicated.  相似文献   

Volatiles in glasses from Mauna Loa Volcano,Hawai'i: implications for magma degassing and contamination,and growth of Hawaiian volcanoes     

Michael G. Davis  Michael O. Garcia  Paul Wallace 《Contributions to Mineralogy and Petrology》2003,144(5):570-591

Glasses from Mauna Loa pillow basalts, recent subaerial vents, and inclusions in olivine were analyzed for S, Cl, F, and major elements by electron microprobe. Select submarine glasses were also analyzed for H₂O and CO₂ by infrared spectroscopy. The compositional variation of these tholeiitic glasses is dominantly controlled by crystal fractionation and they indicate quenching temperatures of 1,115-1,196 °C. Submarine rift zone glasses have higher volatile abundances (except F) than nearly all other submarine and subaerial glasses with the maximum concentrations increasing with water depth. The overwhelming dominance of degassed glasses on the submarine flanks of Mauna Loa implies that much of volcano's recent submarine growth involved subaerially erupted lava that reached great water depths (up to 3.1 km) via lava tubes. Anomalously high F and Cl in some submarine glasses and glass inclusions indicate contamination possibly by fumarolic deposits in ephemeral rift zone magma chambers. The relatively high CO₂ but variable H₂O/K₂O and S/K₂O in some submarine rift zone glasses indicates pre-eruptive mixing between degassed and undegassed magma within Mauna Loa's rift system. Volatile compositions for Mauna Loa magmas are similar to other active Hawaiian volcanoes in S and F, but are less Cl-rich than Ll'ihi glasses. However, Cl/K2O ratios are similar. Mauna Loa and Ll'ihi magmas have comparable, but lower H₂O than those from Kilauea. Thus, Kilauea's source may be more H₂O-rich. The dissimilar volatile distribution in glasses from active Hawaiian volcanoes is inconsistent with predictions for a simple, concentrically zoned plume model.  相似文献   

Chlorine-36 in groundwater of the United States: empirical data     

Stanley N. Davis  Stephen Moysey  DeWayne L. Cecil  Marek Zreda 《Hydrogeology Journal》2003,11(2):217-227

Natural production of the radionuclide chlorine-36 (³⁶Cl) has provided a valuable tracer for groundwater studies. The nuclear industry, especially the testing of thermonuclear weapons, has also produced large amounts of ³⁶Cl that can be detected in many samples of groundwater. In order to be most useful in hydrologic studies, the natural production prior to 1952 should be distinguished from more recent artificial sources. The object of this study was to reconstruct the probable preanthropogenic levels of ³⁶Cl in groundwater in the United States. Although significant local variations exist, they are superimposed on a broad regional pattern of ³⁶Cl/Cl ratios in the United States. Owing to the influence of atmospherically transported ocean salt, natural ratios of ³⁶Cl/total Cl are lowest near the coast and increase to a maximum in the central Rocky Mountains of the United States. Electronic Publication  相似文献   

Contens of Volume 59     

Henry F. Diaz  Jon K. Eischeid  Chris Duncan  Raymond S. Bradley 《Climatic change》2003,59(3):417-418

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