Constraints from high-pressure veins in eclogites on the composition of hydrous fluids in subduction zones   总被引：3，自引：0，他引：3  

Harry Becker  Klaus Peter Jochum  Richard W. Carlson 《Chemical Geology》1999,160(4):1207-308

Hydrous high-pressure veins formed during dehydration of eclogites in two paleo-subduction zones (Trescolmen locality in the Adula nappe, central Alps and Münchberg Gneiss Massif, Variscan fold belt, Germany) constrain the major and trace element composition of solutes in fluids liberated during dehydration of eclogites. Similar initial isotopic compositions of veins and host eclogites at the time of metamorphism indicate that the fluids were derived predominantly from the host rocks. Quartz, kyanite, paragonite, phengite, zoisite and omphacite are the dominant minerals in the veins. The major element compositions of the veins are in agreement with experimental evidence indicating that the composition of solutes in such fluids is dominated by SiO₂ and Al₂O₃. Relative to N-MORB, the veins show enrichments of Cs, Rb, Ba, Pb, and K, comparable or slightly lower abundances of Sr, U, and Th, and very low abundances of Nd, Sm, Zr, Nb, Ti and Y. The differential fractionation of highly incompatible elements such as K, U and Th in the veins, as well as the presence of hydrous minerals in the eclogites rule out partial melting as a cause for vein formation. These results confirm previous suggestions that fluids derived from subducted basalt may have low abundances of high field strength elements, rare earth elements and Y. Variable vein-eclogite enrichment factors of incompatible alkalis and to a lesser extent Pb appear to reflect mineralogical controls (phengite, epidote-group minerals) on partitioning of these elements during dehydration of eclogite in subduction zones. However, abundance variations of incompatible elements in minerals from eclogites suggest that the composition of fluids released from eclogites at temperatures <700°C may not reflect true equilibrium partitioning during dehydration. Simple models for the trace elements U and Th indicate the relative importance of the basaltic and sedimentary portions of subducted oceanic crust in producing the characteristic chemical signatures of these elements in convergent plate margin volcanism.  相似文献   

The nature of crystalline silica from the TAG submarine hydrothermal mound, 26°N Mid Atlantic Ridge     

Laurence Hopkinson  Stephen Roberts  Richard Herrington  Jamie Wilkinson 《Contributions to Mineralogy and Petrology》1999,137(4):342-350

Silica occurs in abundance in a variety of hydrothermal samples from the Trans-Atlantic Geotraverse (TAG) hydrothermal mound, 26°N Mid-Atlantic Ridge. The water content, trace element chemistry, and mineralogy of crystalline silica from 15 different samples have been examined by vibrational spectroscopy and probe microanalysis. The samples are from: shallow subsurface ferric iron oxyhydroxide silica deposits (n=4), a fragment of an active white smoker chimney (n=1), anhydrite bearing hydrothermal breccias (n=2), pyrite silica breccias (n=3), and silicified wall rock breccias (n=5). Length-fast chalcedony occurs in association with variable quantities of ferric iron oxyhydroxides in hydrothermal breccias from the mound flanks, within shallower subsurface chert samples, and within white smoker chimney walls. Samples from the anhydrite zone contain textures which are suggestive of an origin involving replacement of anhydrite. Samples taken from TAG 1 and 5 from below the anhydrite zone contain no chalcedony. Instead they contain subhedral quartz crystals which show oscillatory zoning in aluminium. Two types of crystalline silica namely, type A and type B quartz, are defined on the basis of the infrared spectra in the OH region from 3200 cm⁻¹ to 3600 cm⁻¹. The type A quartz occurs beneath the anhydrite zone at TAG 1 and 5. We propose a model that relates specific varieties of crystalline silica to different thermal and chemical environments within the mound interior. Length-fast chalcedony occurs in an outer low temperature envelope across the top and sides of the mound. The common association between length-fast chalcedony and ferric iron oxyhydroxides suggests that chalcedony crystallization is favoured where catalysis by ferric iron can occur. The apparent suppression of fibrous silica at the expense of single quartz crystals with increasing depth is attributed to differing growth rates and degrees of supersaturation of silica-bearing solutions with increasing temperature within the mound. The transition from type A to type B single crystal growth is interpreted to occur at temperatures approaching ˜360 °C due to decreasing solubility of aluminium in quartz, so that aluminium is rendered unavailable for type A valence compensation. Received: 10 September 1998 / Accepted: 6 July 1999  相似文献   

Integrating Stalagmite, Vertebrate, and Pollen Sequences to Investigate Holocene Vegetation and Climate Change in the Southern Midwestern United States     

Rhawn F. Denniston  Luis A. Gonzalez  Holmes A. Semken  Jr.  Yemane Asmerom  Richard G. Baker  Heather Recelli-Snyder  Mark K. Reagan  E. Arthur Bettis  III 《Quaternary Research》1999,52(3):381

Speleothem carbon and oxygen isotopic records from Onondaga Cave, south-central Missouri, and Beckham Creek Cave, north-central Arkansas, are compared with the Cupola Pond and Oldfield Swamp pollen series from southeastern Missouri and the Rodgers Shelter and Modoc Shelter vertebrate biostratigraphic sequences from central Missouri and southwestern Illinois. Similar, and roughly contemporaneous, shifts between deciduous forest and steppe indicators throughout the Holocene are revealed in each database. These independent proxies record steppe conditions between approximately 9000 and 1500 cal yr B.P. A shift toward lighter speleothem carbon may reflect a change from warm and dry to cool and dry conditions between 4500 and 3000 yr B.P. The sensitive response of speleothem δ¹³C to changes in vegetation emphasizes their importance as paleoclimate records in an area containing few other millenial-scale climate proxies.  相似文献   

Paleoenvironmental and Human Behavioral Implications of the Boegoeberg 1 Late Pleistocene Hyena Den, Northern Cape Province, South Africa     

Richard G. Klein  Kathryn Cruz-Uribe  David Halkett  Tim Hart  John E. Parkington 《Quaternary Research》1999,52(3):393

Boegoeberg 1 (BOG1) is located on the Atlantic coast of South Africa, 850 km north of Cape Town. The site is a shallow rock shelter in the side of a sand-choked gully that was emptied by diamond miners. Abundant coprolites, chewed bones, and partially digested bones implicate hyenas as the bone accumulators. The location of the site, quantity of bones, and composition of the fauna imply it was a brown hyena nursery den. The abundance of Cape fur seal bones shows that the hyenas had ready access to the coast. Radiocarbon dates place the site before 37,000 ¹⁴C yr ago, while the large average size of the black-backed jackals and the presence of extralimital ungulates imply cool, moist conditions, probably during the early part of the last glaciation (isotope stage 4 or stage 3 before 37,000 ¹⁴C yr ago) or perhaps during one of the cooler phases (isotope substages 5d or 5b) within the last interglaciation. Comparisons of the BOG1 seal bones to those from regional Middle Stone Age (MSA) and Later Stone Age (LSA) archeological sites suggest (1) that hyena and human seal accumulations can be distinguished by a tendency for vertebrae to be much more common in a hyena accumulation and (2) that hyena and LSA accumulations can be distinguished by a tendency for hyena-accumulated seals to represent a much wider range of individual seal ages. Differences in the way hyenas and people dismember, transport, and consume seal carcasses probably explain the contrast in skeletal part representation, while differences in season of occupation explain the contrast in seal age representation. Like modern brown hyenas, the BOG1 hyenas probably occupied the coast year-round, while the LSA people focused their coastal visits on the August–October interval when nine-to-eleven-month-old seals were abundant. The MSA sample from Klasies River Mouth Cave 1 resembles BOG1 in seal age composition, suggesting that unlike LSA people, MSA people obtained seals more or less throughout the year.  相似文献   

加拿大内陆水的保护     

Richard D. Robarts  Robert A. Halliday 《湖泊科学》1998,10(S1):13-24

Contrary to general international perception, Canada does not have an unlimited supply of freshwater. However, because Canada has a small population, it does have a generous water allocation on a per capita basis. Nor is Canada immune from water quality problems:its cold continental climate, urbanization and industrial activities all contribute to water quality concerns and deterioration. Generally, the authority to manage water in Canada is held by the country''s provincial governments. The Great Lakes basin is the world''s largest freshwater ecosystem and is located in Canada''s industrial heartland. Water issues, starting with phosphorus in the 1960''s, created international headlines. In the 1970''s toxics became the predominant issue and this led to the Great Lakes Water Quality Agreement which established the ecosystem approach to water quality management. This approach is now the standard approach to water quality management and has been successfully applied to a number of other lake and river ecosystems in Canada. While there have been improvements in the water quality of the Great Lakes much remains to be done on toxic elimination and the large contaminant stores in the sediments. Atmospheric deposition has become a significant source of chemicals from outside the basin The Canadian prairies, the agricultural heartland of Canada, is one major ecozone that has not been selected to have current and potential water quality problems examined by a federal government program. Both the quantity and quality of water in this region are potentially significant factors limiting economic diversification and sustainable development in this vast and ecologically disturbed region.  相似文献   

Using constrained inversion of gravity and magnetic field to produce a 3D litho‐prediction model          下载免费PDF全文

Omid Mahmoodi  Richard S. Smith  Bill Spicer 《Geophysical Prospecting》2017,65(6):1662-1679

Geologically constrained inversion of gravity and magnetic field data of the Victoria property (located in Sudbury, Canada) was undertaken in order to update the present three‐dimensional geological model. The initial and reference model was constructed based on geological information from over 950 drillholes to constrain the inversion. In addition, downhole density and magnetic susceptibility measured in six holes were statistically analysed to derive lower and upper bounds on the physical properties attributed to the lithological units in the reference model. Constrained inversion of the ground gravity and the airborne magnetic data collected at the Victoria property were performed using GRAV3D and MAG3D, respectively. A neural network was trained to predict lithological units from the physical properties measured in six holes. Then, the trained network was applied on the three‐dimensional distribution of physical properties derived from the inversion models to produce a three‐dimensional litho‐prediction model. Some of the features evident in the lithological model are remnants of the constraints, where the data did not demand a significant change in the model from the initial constraining model (e.g., the thin pair of diabase dykes). However, some important changes away from the initial model are evident; for example, a larger body was predicted for quartz diorite, which may be related to the prospective offset dykes; a new zone was predicted as sulfide, which may represent potential mineralisation; and a geophysical subcategory of metabasalt was identified with high magnetic susceptibility and high density. The litho‐prediction model agrees with the geological expectation for the three‐dimensional structure at Victoria and is consistent with the geophysical data, which results in a more holistic understanding of the subsurface lithology.  相似文献   

Simulating Stable Isotope Ratios in Plumes of Groundwater Pollutants with BIOSCREEN‐AT‐ISO          下载免费PDF全文

Patrick Höhener  Zhi M. Li  Maxime Julien  Pierrick Nun  Richard J. Robins  Gérald S. Remaud 《Ground water》2017,55(2):261-267

BIOSCREEN is a well‐known simple tool for evaluating the transport of dissolved contaminants in groundwater, ideal for rapid screening and teaching. This work extends the BIOSCREEN model for the calculation of stable isotope ratios in contaminants. A three‐dimensional exact solution of the reactive transport from a patch source, accounting for fractionation by first‐order decay and/or sorption, is used. The results match those from a previously published isotope model but are much simpler to obtain. Two different isotopes may be computed, and dual isotope plots can be viewed. The dual isotope assessment is a rapidly emerging new approach for identifying process mechanisms in aquifers. Furthermore, deviations of isotope ratios at specific reactive positions with respect to “bulk” ratios in the whole compound can be simulated. This model is named BIOSCREEN‐AT‐ISO and will be downloadable from the journal homepage.  相似文献   

Experimental study of deformable connection consisting of buckling‐restrained brace and rubber bearings to connect floor system to lateral force resisting system          下载免费PDF全文

Georgios Tsampras  Richard Sause  Robert B. Fleischman  Jose I. Restrepo 《地震工程与结构动力学》2017,46(8):1287-1305

This paper presents experimental and numerical studies of a full‐scale deformable connection used to connect the floor system of the flexible gravity load resisting system to the stiff lateral force resisting system (LFRS) of an earthquake‐resistant building. The purpose of the deformable connection is to limit the earthquake‐induced horizontal inertia force transferred from the floor system to the LFRS and, thereby, to reduce the horizontal floor accelerations and the forces in the LFRS. The deformable connection that was studied consists of a buckling‐restrained brace (BRB) and steel‐reinforced laminated low‐damping rubber bearings (RB). The test results show that the force–deformation responses of the connection are stable, and the dynamic force responses are larger than the quasi‐static force responses. The BRB+RB force–deformation response depends mainly on the BRB response. A detailed discussion of the BRB experimental force–deformation response is presented. The experimental results show that the maximum plastic deformation range controls the isotropic hardening of the BRB. The hardened BRB force–deformation responses are used to calculate the overstrength adjustment factors. Details and limitations of a validated, accurate model for the connection force–deformation response are presented. Numerical simulation results for a 12‐story reinforced concrete wall building with deformable connections show the effects of including the RB in the deformable connection and the effect of modeling the BRB isotropic hardening on the building seismic response. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Sediment and nutrient storage in a beaver engineered wetland          下载免费PDF全文

Alan Puttock  Hugh A. Graham  Donna Carless  Richard E. Brazier 《地球表面变化过程与地形》2018,43(11):2358-2370

Beavers, primarily through the building of dams, can deliver significant geomorphic modifications and result in changes to nutrient and sediment fluxes. Research is required to understand the implications and possible benefits of widespread beaver reintroduction across Europe. This study surveyed sediment depth, extent and carbon/nitrogen content in a sequence of beaver pond and dam structures in South West England, where a pair of Eurasian beavers (Castor fiber) were introduced to a controlled 1.8 ha site in 2011. Results showed that the 13 beaver ponds subsequently created hold a total of 101.53 ± 16.24 t of sediment, equating to a normalised average of 71.40 ± 39.65 kg m². The ponds also hold 15.90 ± 2.50 t of carbon and 0.91 ± 0.15 t of nitrogen within the accumulated pond sediment. The size of beaver pond appeared to be the main control over sediment storage, with larger ponds holding a greater mass of sediment per unit area. Furthermore, position within the site appeared to play a role with the upper‐middle ponds, nearest to the intensively‐farmed headwaters of the catchment, holding a greater amount of sediment. Carbon and nitrogen concentrations in ponds showed no clear trends, but were significantly higher than in stream bed sediment upstream of the site. We estimate that >70% of sediment in the ponds is sourced from the intensively managed grassland catchment upstream, with the remainder from in situ redistribution by beaver activity. While further research is required into the long‐term storage and nutrient cycling within beaver ponds, results indicate that beaver ponds may help to mitigate the negative off‐site impacts of accelerated soil erosion and diffuse pollution from agriculturally dominated landscapes such as the intensively managed grassland in this study. © 2018 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.  相似文献   

Effects of rainfall,overland flow and their interactions on peatland interrill erosion processes          下载免费PDF全文

Changjia Li  Joseph Holden  Richard Grayson 《地球表面变化过程与地形》2018,43(7):1451-1464

Interrill erosion processes on gentle slopes are affected by mechanisms of raindrop impact, overland flow and their interaction. However, limited experimental work has been conducted to understand how important each of the mechanisms are and how they interact, in particular for peat soil. Laboratory simulation experiments were conducted on peat blocks under two slopes (2.5° and 7.5°) and three treatments: Rainfall, where rainfall with an intensity of 12 mm h^?1 was simulated; Inflow, where upslope overland flow at a rate of 12 mm h^?1 was applied; and Rainfall + Inflow which combined both Rainfall and Inflow. Overland flow, sediment loss and overland flow velocity data were collected and splash cups were used to measure the mass of sediment detached by raindrops. Raindrop impact was found to reduce overland flow by 10 to 13%, due to increased infiltration, and reduce erosion by 47% on average for both slope gradients. Raindrop impact also reduced flow velocity (80–92%) and increased roughness (72–78%). The interaction between rainfall and flow was found to significantly reduce sediment concentrations (73–85%). Slope gradient had only a minor effect on overland flow and sediment yield. Significantly higher flow velocities and sediment yields were observed under the Rainfall + Inflow treatment compared to the Rainfall treatment. On average, upslope inflow was found to increase erosion by 36%. These results indicate that overland flow and erosion processes on peat hillslopes are affected by upslope inflow. There was no significant relationship between interrill erosion and overland flow, whereas stream power had a strong relationship with erosion. These findings help improve our understanding of the importance of interrill erosion processes on peat. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献