Measured and modeled effects of benthic algae on eutrophication in Indian River-Rehoboth Bay, Delaware     

Carl F. Cerco  Sybil P. Seitzinger 《Estuaries and Coasts》1997,20(1):231-248

A combination of field studies and mathematical modeling was used to examine the role of subtidal benthic algae in the eutrophication processes in two shallow estuarine systems. Field measurements indicated uptake by benthic algae retained ammonium and phosphate in the sediments when light at the sediment surface exceeded ≈150 μE m² s^?1. The measurements were used to calibrate a newly developed model of benthic algal activity. The benthic algal model was coupled with a hydrodynamic model, a eutrophication model, and a sediment diagenesis model. In the simulated ecosystem, benthic algae had a major influence in the intra-annual cycling of nitrogen and phosphorus. When nutrients were abundant in the water column (late winter and spring) they were transferred to the sediments through algal activity. Diagenesis released these nutrients to the water column in summer when nutrients were scarce. As a result of the nutrient transfer, annual primary production in the water column, in the presence of benthic algae, exceeded production in the absence of the algae.  相似文献   

Comparison of source rock geochemistry of selected rocks from the Schei Point group and Ringnes formation, Sverdrup basin, arctic Canada     

P. K. Mukhopadhyay  F. Goodarzi  M. A. Kruge  M. H. Alimi 《International Journal of Coal Geology》1997,34(3-4)

Organic-rich from the Schei Point group (middle to late Triassic in age) and the Ringnes formation (late Jurassic) from the Sverdrup basin of the Canadian arctic archipelago have been geochemically evaluated for source rock characterization. Most samples from the Schei Point group are organic-rich (> 2% TOC and are considered as immature to mature oil-prone source rocks [kerogen types I, I–II (IIA) and II (IIA)]. These kerogen types contain abundant AOM1, AOM2 and alginite (Tasmanales, Nostocopsis, Leiosphaeridia, acritarch and dinoflagellate) with variable amounts of vitrinite, inertinite and exinite. Samples from the Ringnes formation contain dominant vitrinite and inertinite with partially oxidized AOM2, alginite and exinite forming mostly immature to mature condensate- and gas-prone source rocks [kerogen type II–III (IIB), III and a few II (IIA)]. Schei Point samples contain higher bitumen extract, saturate hydrocarbons and saturate/ aromatic ratio than the Ringnes samples. Triterpane and sterane (dominant C₃₀) distribution patterns and stable carbon isotope of bitumen and kerogen suggest that the analyzed samples from the Schei Point group are at the onset of oil generation and contain a mixture of sapropelic (algal) and minor terrestrial humic organic matter. Sterane carbon number distributions in the Ringnes formation also suggest a mixed algal and terrestrial organic matter type. There are some variations in hopane carbon number distributions, but these are apparently a function of thermal maturity rather than significant genetic differences among samples. Pyrolysis-gas chromatography/mass spectrometry of the two samples with similar maturity shows that the Schei Point sample generates three times more pyrolyzate than the Ringnes sample. Both samples have a dominant aliphatic character, although the Ringnes sample contains phenol and an aromaticity that is higher than that of the Schei Point sample.  相似文献   

The origin and distribution of HAPs elements in relation to maceral composition of the A1 lignite bed (Paleocene, Calvert Bluff Formation, Wilcox Group), Calvert mine area, east-central Texas     

Sharon S. Crowley  Peter D. Warwick  Leslie F. Ruppert  James Pontolillo 《International Journal of Coal Geology》1997,34(3-4)

The origin and distribution of twelve potentially Hazardous Air Pollutants (HAPs; As, Be, Cd, Cr, Co, Hg, Mn, Ni, Pb, Sb, Se, and U) identified in the 1990 Clean Air Act Amendments were examined in relation to the maceral composition of the A1 bed (Paleocene, Calvert Bluff Formation, Wilcox Group) of the Calvert mine in east-central Texas. The 3.2 m-thick A1 bed was divided into nine incremental channel samples (7 lignite samples and 2 shaley coal samples) on the basis of megascopic characteristics. Results indicate that As, Cd, Cr, Ni, Pb, Sb, and U are strongly correlated with ash yield and are enriched in the shaley coal samples. We infer that these elements are associated with inorganic constituents in the coal bed and may be derived from a penecontemporaneous stream channel located several kilometers southeast of the mining block. Of the HAPs elements studied, Mn and Hg are the most poorly correlated to ash yield. We infer an organic association for Mn; Hg may be associated with pyrite. The rest of the trace elements (Be, Co, and Se) are weakly correlated with ash yield. Further analytical work is necessary to determine the mode of occurrence for these elements. Overall, concentrations of the HAPs elements are generally similar to or less than those reported in previous studies of lignites of the Wilcox Group, east-central region, Texas. Petrographic analysis indicates the following ranges in composition for the seven lignite samples: liptinites (5–8%), huminites (88–95%), and inertinites (trace amounts to 7%). Samples from the middle portion of the A1 bed contain abundant crypto-eugelinite compared to the rest of the samples; this relationship suggests that the degradation of plant material was an important process during the development of the peat mire. With the exception of Hg and Mn, relatively low levels of the HAPs elements studied are found in the samples containing abundant crypto-eugelinite. We infer that the peat-forming environment for this portion of the coal bed was very wet with minimal detrital input. Relatively high concentrations of crypto-humotelinite were found in samples from the top and base of the coal bed. The presence of abundant crypto-humotefinite in this part of the coal bed suggests the accumulation of wood-rich peat under conditions conducive to a high degree of tissue preservation in the peat mire. Although several of the trace elements (Be, Co, Ni, and Sb) exhibit enrichment in these samples, they are not necessarily chemically associated with humotelinite. We infer that these elements, with the exception of Be, are possibly associated with deposition of the roof and floor rock of the coal bed; however, further analytical work would be necessary to confirm this hypothesis. Beryllium may have an organic origin.  相似文献   

Geochemistry of an island-arc plutonic suite: Wadi Dabr intrusive complex, Eastern Desert, Egypt     

Fawzy F. Abu El-Ela 《Journal of African Earth Sciences》1997,24(4):473-496

The Wadi Dabr intrusive complex, west of Mersa-Alam, Eastern Desert, Egypt ranges in composition from gabbro to diorite, quartz diorite and tonalite. The gabbroic rocks include pyroxene-horn blend e gabbro, hornblende gabbro, quartz-hornblende gabbro, metagabbro and amphibolite. Mineral chemistry data for the gabbroic rocks indicate that the composition of clinopyroxenes ranges from diopside to augite and the corresponding magma is equivalent to a volcanic-arc basalt. Plagioclase cores range from An₇₅ to An₃₄ for the gabbroic varieties, except for the metagabbro which has An _11–18. The brown amphiboles are primary phases and classified as calcic amphiboles, which range from tschermakitic hornblende to magnesiohornblende. Green hornblende and actinolite are secondary phases. Hornblende barometry and hornblende-plagioclase themometry for the gabbroic rocks estimate crystallisation conditions of 2–5 kb and 885–716°C.The intrusive rocks cover an extensive silica range (47.86–72.54 wt%) and do not exhibit simple straight-line variation on Harker diagrams for many elements (e.g. TiO₂, Al₂O₃, FeO^*, MgP, CaO, P₂O₅, Cr, Ni, V, Sr, Zr and Y). Most of these elements exhibit two geochemical trends suggesting two magma sources.The gabbroic rocks are relatively enriched in large ion lithophile elements (K, Rb, Sr and Ba) and depleted in high field strength elements (Nb, Zr, Ti and Y) which suggest subduction-related magma. Rare earth element (REE) data demonstrate that the gabbroic rocks have a slight enrichment of light REE [(La/Yb)_N=2.67−3.91] and depletion of heavy REE ((Tb/Yb)_N=1.42−1.47], which suggest the parent magma was of relatively primitive mantle source.The diorites and tonalites are clearly calc-alkaline and have negative anomalies of Nb, Zr, and Y which also suggest subduction-related magma. They are related to continental trondhjemites in terms of Rb---Sr, K---Na---Ca, and to volcanic-arc granites in terms of Rb---and Nb---Y.The Wadi Dabr intrusive complex is analogous to intrusions emplaced in immature ensimatic island-arcs and represents a mixture of mantle (gabbroic rocks) and crustal fusion products (diorites and tonalites) modified by fractional processes.  相似文献   

Redetermination of the transformation enthalpies of the xanthoconite–proustite, pyrostilpnite–pyrargyrite and trechmannite–smithite phase transitions     

B. Meyer  F. Scholz 《Physics and Chemistry of Minerals》1997,24(1):50-52

 We report here refined values of the transformation enthalpy for xanthoconite to proustite (54.81 kJ/mol) and pyrostilpnite to pyrargyrite (40.32 kJ/mol). Additionally, the enthalpy for the transformation of trechmannite to smithite (5.82 kJ/mol) has been determined. The refinement was possible by taking into account a previously unknown dependence of electrochemical signals on the amount of substance undergoing the reduction process. Received December 21, 1995/Revised, accepted June 29, 1996  相似文献   

ELNES spectroscopy of mixed Si coordination minerals     

B. Poe  F. Seifert  T. Sharp  Z. Wu 《Physics and Chemistry of Minerals》1997,24(7):477-487

 Si K- and L-edge ELNES spectroscopy and multiple-scattering (MS) calculations are used to examine mixed Si coordination compounds varying in Si^VI:Si^IV ratio. As in previous studies, the edges are influenced mainly by silicon coordination (tetrahedral vs. octahedral), as supported by the MS calculations. We demonstrate two methods semi-quantitatively to extract the value of Si^VI/(Si^VI+Si^IV): (1) A linear relationship between the L_2,3-L₁ splitting and Si^VI/(Si^VI+Si^IV) is observed, (2) a fitting method based on the coaddition of reference tetrahedral and octahedral Si spectra is applied to both Si K- and L-edge ELNES spectra. Received: February 10, 1997 / Revised, accepted: May 23, 1997  相似文献   

Distribution of isomorphous cations within octahedral sheets in montmorillonite from Camp-Bertaux     

F. Muller  G. Besson  A. Manceau  V.-A. Drits 《Physics and Chemistry of Minerals》1997,24(3):159-166

 Ni-saturated montmorillonite from Camp-Bertaux heated at different temperatures has been studied by X-ray powder diffraction, X-ray absorption (EXAFS) and vibration IR spectroscopy. Analysis of the experimental data has shown that heating of samples at temperatures higher than 150° C was accompanied by migration of Ni cations into vacant cis-octahedra of 2:1 layers. In the octahedral sheet the Ni cation has two “heavy” (Fe) and four “light” (Al and Mg) nearest octahedral cations. A model for the octahedral cation distribution in Camp-Bertaux montmorillonite was proposed in which Fe and Mg octahedral cations are segregated in small clusters. Received July 7, 1996 / Revised, accepted August 23, 1996  相似文献   

中国汽车工业──改革开放后的重整与国际化   总被引：4，自引：0，他引：4  

薛凤旋  刘卫东 《地理研究》1997,16(3):1-11

大规模的重整和广泛的国际化是改革开放后中国汽车工业发展的两个主要特征。作者首先从企业组织结构、生产能力与品种结构、规模经济和空间分布等四个方面分析了近二十年来中国汽车工业重整的效果及所形成的行业特征;其次根据利用的外资和技术的来源以及涉及的技术形态分析了其国际化的程度及在世界汽车工业中的位置;最后总结了中国汽车工业面临的若干问题,并提出在散乱的格局和跨国公司竞争的双重压力下,中国汽车工业正处于成长的关键时期。  相似文献   

Application of discovery process models in estimating petroleum resources at the play level in China     

Zhuoheng Chen  Richard Sinding-Larsen  Xinhua Ma 《Natural Resources Research》1997,6(4):317-328

Discovery process modeling has gained wide acceptance in the Chinese exploration community. In recent years, a variety of discovery process models have been applied to the prediction of undiscovered petroleum resources at the play level in sedimentary basins in China. However, challenging problems have been encountered, particularly when one method alone has been applied to small plays in nonmarine sedimentary basins or in plays with an unusual order of discovery wells. This paper presents results gotten by using the lognormal discovery process model of the Geological Survey of Canada and the geoanchored method for three petroleum plays in basins with different geologic settings. Although the predicted shapes of the parentsize distributions which use these two models, were not always similar, the expected values of the total resources and the number of fields (pools) to be discovered are comparable. The combined use of two discovery process models in the same play compensates for the weaknesses in one method compared with the other and vice versa. Thus, more reliable estimates are the result.  相似文献   

Special issue on quantitative estimates of the geology of large regions and their application to mineralresource assessment     

Richard B. McCammon  W. David Menzie  Lawrence J. Drew  Janet S. Sachs 《Natural Resources Research》1997,6(3):155-155

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