Uranium(6+) sorption on montmorillonite: Experimental and surface complexation modeling study     

Roberto T. Pabalan  David R. Turner 《Aquatic Geochemistry》1997,2(3):203-226

Sorption interactions with montmorillonite and other clay minerals in soils, sediments, and rocks are potentially important mechanisms for attenuating the mobility of U(6+) and other radionuclides through the subsurface environment. Batch experiments were conducted (in equilibrium with atmospheric % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiiYdd9qrFfea0dXdf9vqai-hEir8Ve% ea0de9qq-hbrpepeea0db9q8as0-LqLs-Jirpepeea0-as0Fb9pgea% 0lrP0xe9Fve9Fve9qapdbaqaaeGacaGaaiaabeqaamaabaabcaGcba% acbiGaiWiG-bfadaWgaaWcbaacbaGaa43qaiaa+9eadaWgaaqaaiaa% +jdaaWqabaaaleqaaaaa!400D!\[P_{CO_2 } \])to determine the effects of varying pH (2 to 9), solid-mass to solution-volume ratio (M/V = 0.028 to 3.2 g/L), and solution concentration (2 × 10^?7 and 2 × 10^?6 M ²³³U) on U(6+) sorption on SAz-1 montmorillonite. The study focused on U(6+) surface complexation on hydroxylated edge sites as the sorption mechanism of interest because it is expected to be the predominant sorption mechanism at pHs typical of natural waters (pH ≈6 to ≈9). Thus, the experiments were conducted with a 0.1 M NaNO₃ matrix to suppress ion-exchange between U(6+) in solution and interlayer cations. The results show that U(6+) sorption on montmorillonite is a strong function of pH, reaching a maximum at near-neutral pH (≈6 to ≈6.5) and decreasing sharply towards more acidic or more alkaline conditions. A comparison of the pH-dependence of U(6+) sorption with that of U(6+) aqueous speciation indicates a close correspondence between U(6+) sorption and the predominance field of U(6+)-hydroxy complexes. At high pH, sorption is inhibited due to formation of aqueous U(6+)-carbonate complexes. At low pH, the low sorption values indicate that the 0.1 M NaNO₃ matrix was effective in suppressing ion-exchange between the uranyl (UO₂ ²⁺) species and interlayer cations in montmorillonite. At pH and carbonate concentrations typical of natural waters, sorption of U(6+) on montmorillonite can vary by four orders of magnitude and can become negligible at high pH. The experimental results were used to develop a thermodynamic model based on a surface complexation approach to permit predictions of U(6+) sorption at differing physicochemical conditions. A Diffuse-Layer model (DLM) assuming aluminol (>AlOH^?) and silanol (>SiOH^?) edge sites and two U(6+) surface complexation reactions per site effectively simulates the complex sorption behavior observed in the U(6+)-H₂O-CO₂-montmorillonite system at an ionic strength of 0.1 M and pH > 3.5. A comparison of model predictions with data from this study and from published literature shows good agreement and suggests that surface complexation models based on parameters derived from a limited set of data could be useful in extrapolating radionuclide sorption over a range of geochemical conditions. Such an approach could be used to support transport modeling by providing a better alternative to the use of constant K _d s in transport calculations.  相似文献   

The 1906 eruption of Vesuvius: from magmatic to phreatomagmatic activity through the flashing of a shallow depth hydrothermal system     

Antonella Bertagnini  Patrizia Landi  Roberto Santacroce  Alessandro Sbrana 《Bulletin of Volcanology》1991,53(7):517-532

The April 1906 eruption of Vesuvius is the type-example of the final eruptions that close the short cycles of semi-persistent activity that characterized the volcano in the 1631–1944 period. The eruption had a marked explosive character that accompanied the emission of lava from several vents on the southern slopes of the volcano. The observed sequence of events was characterized by repeated fluctuations of the magma level within the conduit, by large lava fountains, by conduit partial collapses, and by the final explosive decapitation of the summit cone. Contemporary chronicles, although frequently contradictory, allow reconstruction of the eruption, which can be divided into four main phases: (1) lateral lava effusions; (2) lava fountains; (3) gas-pyroclasts column; (4) low dense clouds. Pyroclastic deposits of the Monte Somma ridge and northeastern slope can be related to observed and described events and mainly refer to the 2nd and 3rd phases. The increase in the degree of fragmentation of the juvenile component together with the marked increase of the lithic component and morphologic evidence emphasize the repeated occurrence of magmawater interaction. This was most spectacular in the 3rd phase of the eruption in which, after the decapitation of the cone, a high gas-pyroclasts eruption column was formed. Because of the nature of the lithic fragments (mainly hydrothermally altered and metasomatic rocks), the huge amount of steam, and the high lithic/juvenile ratio, it is unlikely that the largest part of the energy in play was related to the contact between magma and cold phreatic water. We suggest that most of the steam involved in this phase of the eruption came from flashing of the hydrothermal system connected to the very shallow feeding system of the volcano and formed as a consequence of repeated subsurface intrusions between 1872 and 1906. Juvenile products were ejected through the eruption, and represent (at least) two different magma bodies: the first (older) was erupted during the initial phase of the eruption and was exhausted at the beginning of the lava fountains phase, when fresh magma was involved in the eruption.  相似文献   

Detritus Rolling Down a Vertical Cliff of the Ligurian Sea (Italy): The Écological Role in Hard Bottom Communities     

Giorgio  Bavestrello  Riccardo  Cattaneo-Vietti  Roberto  Danovaro Mauro  Fabiano 《Marine Ecology》1991,12(4):281-292

Abstract. The detritus rolling down a vertical cliff was studied at Portofino Promontory (Ligurian Sea, Italy) at 16 m depth (January 1988- January 1989). The large amount of collected sediment is mainly due to the position of the traps; they collected not only the sedimenting material, but also the detritus rolling down along the cliff. The amount of sediment matter is 7 times greater in winter than in summer, showing a good correlation with rough seas and rain that cause a "mechanical cleaning" of animal and plant debris (Sérpulid tubes, shells, exuvias. leaves) along the cliff.
The Total Suspended Matter (TSM) in the water column shows maximum values in March and September. The organic fraction has an average concentration of 0.81 mg 1^-l. The phytoplanktonic biomass, measured as Chi a , shows an annual cycle with a peak in spring (1–2.7μg·l^-1). while in other periods of the year the value is about 0.3-0.5 μg·1^-1. A significant relationship was found between organic detritus in the collected sédiments and the Chi a in the water column. The great influence of the rocky wall detritus on the normal trend of the TSM in the coastal water column is pointed out.  相似文献   

Comparison Between the Energy Flow Networks of Two Habitats in the Venice Lagoon     

Simone Libralato  Roberto Pastres  Fabio Pranovi  Sa&#;a Raicevich  Angela Granzotto  Otello Giovanardi  Patrizia Torricelli 《Marine Ecology》2002,23(S1):228-236

Abstract. The energy flows of two habitats are quantified and compared by using a trophic network model. The habitats are representative of two typical subsystems of the Venice Lagoon: the seagrass meadows, which represent a mature stage in the ecological succession of lagoon environments, and the Tapes philippinarum fishing grounds, which are subjected to mechanical clam harvesting.
The results obtained for the 'seagrass habitat'are consistent with other field studies, confirming the'key-stone'role played by phanerogams in a lagoon environment. The results for the 'Tapes habitat'show that the energy flow from the sediment to the water column is extremely important. Indeed, the high T. philippinarum biomass cannot be supported solely by the primary production of the local phytoplankton. Instead, this biomass could be supported by a supply provided by the sediment resuspension caused by intensive clam fishing. These findings suggest the presence of a positive feedback between fishing effort and T. philippinarum standing crop.  相似文献   

A methodological approach to water quality assessment in an ungauged basin,Buenos Aires,Argentina     

Silvana Arreghini  Laura de Cabo  Rafael Seoane  Nicolás Tomazin  Roberto Serafini  Alicia Fabrizio de Iorio 《GeoJournal》2007,70(4):281-288

The Reconquista River is one of the most polluted rivers in Latin America. This paper aims at identifying the dynamics of water quality in an area with low or “background” concentrations of pollutants within the Reconquista River system in order to better define levels of pollution in the main system. In order to describe the dynamics of water quality in the background area, we propose a methodology based on flow estimation with the instantaneous unit hydrograph model and on measurements of physical and chemical water variables under different hydrological conditions. Because of high dissolved oxygen and low ammonium and o-phosphate concentrations, the Arroyo Durazno, a tributary stream of the Reconquista River, is defined as a background area. When a storm event begins, the concentration of nitrates and the electrical conductivity diminish. An increase in dissolved organic carbon suggests an important input of carbon from hillslope runoff. The proportion of fulvic and humic acids also increases. On the receding limb of the hydrograph, nitrate concentration was lower than during maximum flow and organic carbon concentration remained high. This behavior, known as the “flushing effect”, suggests that the soluble material accumulated in the drainage area during dry periods is transported to the stream by leaching or “lixiviation” and surface runoff, thus raising solute concentrations during the first few hours of the storm. Water quality changes rapidly, even in background areas, due to its dependence on the flow. The methodology followed in this paper can also be applied to other basins with similar characteristics. Due to the difficulty in defining baseline areas for surface waters, a knowledge of background water quality and its dynamics is essential for understanding pollution trends and anthropogenic impacts on rivers.  相似文献   

Photochemincal processes involving nitrite in surface water samples     

Claudio Minero  Serge Chiron  Gianpaolo Falletti  Valter Maurino  Ezio Pelizzetti  Roberto Ajassa  Maria Eugenia Carlotti  Davide Vione 《Aquatic Sciences - Research Across Boundaries》2007,69(1):71-85

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Origin and emplacement of ultramafic–mafic intrusions in the Erro-Tobbio mantle peridotite (Ligurian Alps, Italy)     

Giulio Borghini  Elisabetta Rampone  Laura Crispini  Roberto De Ferrari  Marguerite Godard 《Lithos》2007,94(1-4):210-229

The Erro-Tobbio peridotites (Voltri Massif, Ligurian Alps) represent subcontinental lithospheric mantle tectonically exhumed during Permo–Mesozoic extension of the Europe–Adria lithosphere. Previous studies have shown that exhumation started during Permian times, and occurred along kilometer-scale lithospheric shear zones which enhanced progressive deformation and recrystallization from spinel- to plagioclase-facies conditions. Ongoing field and petrologic investigations have revealed that the peridotites experienced, during uplift, a composite history of diffuse melt migration and multiple episodes of ultramafic–mafic intrusions. In this paper we present the results of field, structural and petrologic–geochemical investigations into a sector of the Erro-Tobbio peridotite unit that preserves well this multiple intrusion history. Melt impregnation in the peridotites is evidenced by significant plagioclase enrichment and crystallization of unstrained orthopyroxene replacing kinked mantle olivine and clinopyroxene; impregnating melts were thus opx-saturated. Melt–rock interaction caused chemical changes in mantle minerals (e.g. Al decrease and REE increase in cpx; Ti and Cr# enrichment in spinel). Nevertheless, clinopyroxenes still exhibit LREE depletion (Ce_N/Sm_N = 0.006–0.011), indicating a depleted signature for the percolating melts. Melt impregnation was thus related to diffuse porous flow migration of depleted MORB-type melt fractions that modified their compositions towards opx saturation by mantle–melt interaction during ascent. The impregnated peridotites are intruded by a hectometer-scale stratified cumulate body, mostly consisting of troctolites and plagioclase wehrlites, showing gradational, interfingered contacts with the host mantle rocks. Subsequent intrusion events are revealed by the occurrence of olivine gabbros as decameter-wide lenses, variably thick (centimeter- to meter-scale) dykes and thin dykelets, which crosscut both the peridotite foliation and the magmatic layering in the cumulates. Overall, major and trace element compositions of minerals in the intrusives indicate that they represent variably differentiated cumulus products crystallized from rather primitive N-MORB-type aggregated melts. Slightly more evolved compositions are shown by olivine gabbros, relative to the troctolites and plagioclase wehrlites of the cumulate body. Mineral chemistry features (e.g. the Fo–An correlation and high Na, Ti, Mg# in cpx) indicate that the studied intrusive rocks crystallized at moderate pressure conditions (3–5 kbar, i.e. 9–15 km depth). Our study thus points to a progressive transition from porous flow melt migration to emplacement of magmas in fractures, presumably related to progressive change of lithospheric mantle rheology during extension-related uplift and cooling.  相似文献   

Book Reviews     

Roberto Andorno 《Pure and Applied Geophysics》2006,163(1):243-258

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Effects of column axial force – bending moment interaction on inelastic seismic response of steel frames     

Marina Como  Mario De Stefano  Roberto Ramasco 《地震工程与结构动力学》2003,32(12):1833-1852

It is well known that axial force – bending moment interaction (N–M interaction) affects to a large extent the cyclic inelastic behaviour of structural elements, especially columns in framed structures, with reduction in bending capacity and loss of available ductility. A few studies have also shown that significant inelastic axial shortening affects the response of column elements subjected to medium–high levels of axial loads and cyclic bending. This paper is primarily aimed at evaluating the effects of column N–M interaction on the inelastic seismic response of steel frames. By considering the contemporaneous action of vertical loads, due to gravity, and of horizontal seismic excitation, it is shown that the progressive axial shortening of adjacent columns may differ substantially, thus inducing significant relative settlements at the ends of the connecting beams and, then, remarkable amplifications in beam plastic rotations. An evaluation of additional beam plastic rotations induced by column N–M interaction is carried out for real structures by investigating the inelastic response of steel frames designed according to European standards under horizontal and vertical earthquake excitations. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

The influence of the geological and geomorphological settings on shallow landslides. An example in a temperate climate environment: the June 19, 1996 event in northwestern Tuscany (Italy)   总被引：2，自引：0，他引：2  

Giacomo D''Amato Avanzi  Roberto Giannecchini  Alberto Puccinelli 《Engineering Geology》2004,73(3-4):215-228

On June 19, 1996, an extremely heavy rainstorm hit a restricted area in the Apuan Alps (northwestern Tuscany, Italy). Its max intensity concentrated over an area of about 150 km² astride the Apuan chain, where 474 mm was recorded in about 12 h (21% of the mean annual precipitation, with an intensity up to 158 mm/h). The storm caused floods and hundreds of landslides and debris flows, which produced huge damage (hundreds of millions of Euros), partially destroyed villages and killed 14 people. This paper reports the results obtained from a detailed field survey and aerial view interpretation. In the most severely involved area, 647 main landslides were investigated, mapped and related to the geologic, geomorphic and vegetational factors of the source areas. This was in order to define the influence of these factors and contribute to an evaluation of the landslide hazard in the study area. An assessment was also made of the total area and volume of material mobilised by landsliding. The study area, about 46 km² wide, includes three typically mountainous basins, characterised by narrow, deep cut valleys and steep slopes, where many rock types outcrop. Most of the landslides were shallow and linear, referable to complex, earth and debris translational slide, which quickly developed into flow (soil slip–debris flow). Usually, they involved colluvium and started in hollows underlain by metamorphic rock (metasandstone and phyllite), often dipping downslope. Therefore, bedrock lithology and impermeability appeared to be important factors in the localisation of the landslide phenomena. The investigation of the geomorphic and land use features in the source areas also frequently highlighted a rectilinear profile of the slope, a high slope gradient (31–45°) and dense chestnut wood cover. In the area, about 985,000 m² (2.1% of 46 km²) was affected by landsliding and about 700,000 m² of this area was covered by chestnut forest. The landslides removed about 7000 trees. The volume of mobilised material was about 1,360,000 m³; about 220,000 m³ remained on the slopes, while the rest poured into the streams. In addition, about 945,000 m³ was mobilised by the torrential erosion in the riverbeds.  相似文献