Subsea-floor replacement in volcanic-hosted massive sulfide deposits   总被引：1，自引：0，他引：1  

Mark G. Doyle  Rodney L. Allen   《Ore Geology Reviews》2003,23(3-4):183-222

Recent research on volcanic-hosted massive sulfide (VMS) deposits indicates that syngenetic subsea-floor replacement ores form an important component of many deposits. In the context of VMS deposits, subsea-floor replacement can be defined as the syn-volcanic formation of sulfide minerals within pre-existing volcanic or sedimentary deposits by infiltration and precipitation in open spaces (fractures, inter- and intra-granular porosity) as well as replacement of solid materials.There are five criteria for distinguishing subsea-floor replacement in massive sulfide deposits: (1) mineralized intervals are enclosed within rapidly emplaced volcanic or sedimentary facies (lavas, intrusions, subaqueous mass-flow deposits, pyroclastic fallout); (2) relics of the host facies occur within the mineral deposit; (3) replacement fronts occur between the mineral deposit and the host lithofacies; (4) the mineral deposit is discordant to bedding; and (5) strong hydrothermal alteration continues into the hanging wall without an abrupt break in intensity. Criteria 1–3 are diagnostic of replacement, whereas criteria 4 and 5 may suggest replacement but are not alone diagnostic. Because clastic sulfide ores contain accessory rock fragments collected by the parent sediment gravity flow(s) during transport, criteria 2 can only be applied to massive, semi-massive, disseminated or vein style deposits, and not clastic ores.The spectrum of VMS deposit types includes deposits that have accumulated largely subsea-floor, and others in which sedimentation and volcanism were synchronous with hydrothermal activity, and precipitation of sulfides occurred at and below the sea floor over the life of the hydrothermal system. Deposits that formed largely subsea-floor are mainly hosted by syn-eruptive or post-eruptive volcaniclastic facies (gravity flow deposits, water-settled fall, autoclastic breccia). However, some subsea-floor replacement VMS deposits are hosted by lavas and syn-volcanic intrusions (sills, domes, cryptodomes). Burial of sea-floor massive sulfide by lavas or sediment gravity flow deposits can interrupt sea-floor mineralization and promote subsea-floor replacement and zone-refining.The distance below the sea floor at which infiltration and replacement took place is rarely well constrained, with published estimates ranging from less than 1 to more than 500 m, but mainly in the range 10–200 m. The upper few tens to hundreds of metres in the volcano-sedimentary pile are the favoured position for replacement, as clastic facies are wet, porous and poorly consolidated in this zone, and at greater depths become progressively more compacted, dewatered, altered, and less amenable to large scale infiltration and replacement by hydrothermal fluids. Furthermore, sustained mixing between the upwelling hydrothermal fluid and cold seawater is regarded as a major cause of sulfide precipitation in VMS systems, and this mixing process generally becomes less effective with increasing depth in the volcanic pile.The relative importance of subsea-floor replacement in VMS systems is related principally to four factors: the permeability and porosity patterns of host lithofacies, sedimentation rate, the relative ease of replacement of host lithofacies (especially glassy materials) and early formed alteration minerals during hydrothermal attack, and physiochemical characteristics of the hydrothermal fluid.  相似文献   

The Value of Improved ENSO Prediction to U.S. Agriculture     

Andrew R. Solow  Richard F. Adams  Kelly J. Bryant  David M. Legler  James J. O'Brien  Bruce A. McCarl  William Nayda  Rodney Weiher 《Climatic change》1998,39(1):47-60

The economic value of long-range weather prediction is measured by the increase in social welfare arising from the use of the prediction in economic decisionmaking. This paper describes a study of the economic value of ENSO prediction to U.S. agriculture. The interdisciplinary study involved the analysis of data and models from meteorology, plant science, and economics under a framework based on Bayesian decision analysis. The estimated annual value of perfect ENSO prediction to U.S. agriculture is $323 million.  相似文献   

Manganiferous schists and their origin,Hidaka Mountains,Hokkaido, Japan     

Rodney H. Grapes  Seiji Hashimoto 《Contributions to Mineralogy and Petrology》1978,68(1):23-35

Manganiferous quartz-mica schists (4 m in stratigraphic thickness) overlie epidote amphibolite in the Chiroro River area, Hidaka Mountains, Hokkaido. The schist layers have a considerable range of A/F ratios and bulk oxidation ratios which vary from 21.5 to 100. Manganese contents are from 4 to 30 times higher than that of the average shale with 0.09% MnO. The schists are essentially quartz-white mica-biotite-Mn garnet-tourmaline-±epidote-magnetite assemblages. A highly oxidized layer (5–8 cm thick) 95 cm above the epidote amphibolite contact is characterized by viridine-piemontite-spessartine-Mn white mica-Mn tourmaline-Ti-Mn haematite indicative of both high initial manganese content and very high f _O2 conditions of recrystallization.Viridine contains up to 17 mol% Mn³⁺SiO₅ and coexists with piemontite with between 13.6 and 15.4 wt% Mn₂O₃. Mn-poor-Fe-rich (Ps₃₂) epidote occurs in the less oxidized schist enclosing the viridine-piemontite bearing seam. Garnets vary widely in composition with end member variations (mol%) of Spess_22.9–80.5; And_0.2–11.7; Alm_1.1–57.1; Pyr_2.0–12.2; Gross_7.0–49.0. The more manganiferous garnets occur in rocks with higher oxidation ratios while almandiferous varieties occur in schists with low oxidation ratios. Biotite ranges from green to red-brown varieties (increasing Ti and Fe) with Mg/ (Mg+Fe) ratios varying from 56 to 48. Ten to fifteen percent octahedral R²⁺ is replaced by Al indicating a trend towards eastonite-siderophyllite. The white micas deviate only slightly from dioctahedral stoichiometry but have up to 25% of octahedral sites occupied by Fe, Mg and to a lesser extent Mn and Ti as R²⁺ Si⁴⁺2Al³⁺ and in highly oxidized rocks as (Fe,Mn)³⁺Al³⁺. The white mica in the highly oxidized viridine-piemontite schist is pale pinkishorange, exhibits reverse pleochroism, and has between 0.30 and 0.43 wt% Mn₂O₃.There is a close comparison, both in terms of stratigraphic thickness and Fe-Mn variation, between the Chiroro schist sequence and many oceanic cores so that the bulk chemistry and mineralogy of the pelitic schists is largely an extension of the original Eh-pH conditions of hemipelagic sedimentation and post-depositional adjustments during diagenesis. The thin viridine-piemontite bearing schist is correlated with an oxidized, Fe-Mn rich layer commonly found in present day oceanic cores. The viridine presumably formed by reaction of original ferro-manganese microgranules and clay minerals. Halmrolytic alteration of the underlying metabasalt resulted in leaching of Mn and Fe (in particular) into the overlying sediments and the formation of concentrations of haematite — manganese oxide — Mn garnet along the schist-epidote amphibolite contact.Estimation of the P-T conditions of metamorphism from the phase relations and compositions in the epidote amphibolite associated with the manganiferous schist gives T °C = 530560 and a minimum P _fluid > 3 kb which corresponds to the epidote amphibolite facies of Barrovian-type terrains.This paper is dedicated to Professor Kenzo Yagi on the occasion of his retirement from the Chair of Mineralogy, Department of Geology and Mineralogy, Hokkaido University, Sapporo, Japan  相似文献   

The actinolite-hornblende series in metabasites and the so-called miscibility gap: A review     

Rodney H. Grapes  Colin M. Graham 《Lithos》1978,11(2):85-92

Variation of calcic amphibole chemistry with increasing grade of metamorphism in different metamorphic facies series is reviewed, and the nature of reactions generating hornblende in natural assemblages is discussed. Recent publications on the variation of calcic amphibole composition with metamorphic grade have provided a variety of conflicting evidence regarding the reality or otherwise of a miscibility gap within the calcic amphibole series. It is here concluded that, in most cases, composition gaps may be better ascribed to disequilibrium and kinetic factors, and to abrupt or discontinuous changes in the compositions of, or in the appearance or disappearance of, other phases involved in proposed reactions occurring at the actinolite-hornblende transition. The weight of current evidence does not support the existence of a miscibility gap.  相似文献   

Precise distance measurements in Iceland     

James L. Brander  Ronald G. Mason  Rodney W. Calvert   《Tectonophysics》1976,31(3-4)

Precise distance measurements made on four networks of permanent benchmarks situated on the active axes of Iceland during the four-year period 1968–1972 showed that a combination of left-lateral and extensional movement is occurring on the Reykjanes Peninsula in southwest Iceland at a rate of about 9 mm per year. Elsewhere in Iceland, the movements, if they exist, are too small to be detected. Measurements from a geothermal area in southwest Iceland showed also that large horizontal movements occur in the vicinity of producing geothermal wells.  相似文献   

Simulation of Water‐Table Aquifers Using Specified Saturated Thickness          下载免费PDF全文

Rodney A. Sheets  Mary C. Hill  Henk M. Haitjema  Alden M. Provost  John P. Masterson 《Ground water》2015,53(1):151-157

Simulating groundwater flow in a water‐table (unconfined) aquifer can be difficult because the saturated thickness available for flow depends on model‐calculated hydraulic heads. It is often possible to realize substantial time savings and still obtain accurate head and flow solutions by specifying an approximate saturated thickness a priori, thus linearizing this aspect of the model. This specified‐thickness approximation often relies on the use of the “confined” option in numerical models, which has led to confusion and criticism of the method. This article reviews the theoretical basis for the specified‐thickness approximation, derives an error analysis for relatively ideal problems, and illustrates the utility of the approximation with a complex test problem. In the transient version of our complex test problem, the specified‐thickness approximation produced maximum errors in computed drawdown of about 4% of initial aquifer saturated thickness even when maximum drawdowns were nearly 20% of initial saturated thickness. In the final steady‐state version, the approximation produced maximum errors in computed drawdown of about 20% of initial aquifer saturated thickness (mean errors of about 5%) when maximum drawdowns were about 35% of initial saturated thickness. In early phases of model development, such as during initial model calibration efforts, the specified‐thickness approximation can be a very effective tool to facilitate convergence. The reduced execution time and increased stability obtained through the approximation can be especially useful when many model runs are required, such as during inverse model calibration, sensitivity and uncertainty analyses, multimodel analysis, and development of optimal resource management scenarios.  相似文献   

Seasonal and interannual variation of the phytoplankton and copepod dynamics in Liverpool Bay     

Naomi Greenwood  Rodney M. Forster  Veronique Créach  Suzanne J. Painting  Anna Dennis  Stewart J. Cutchey  Tiago Silva  David B. Sivyer  Tim Jickells 《Ocean Dynamics》2012,62(2):307-320

The seasonal and interannual variability in the phytoplankton community in Liverpool Bay between 2003 and 2009 has been examined using results from high frequency, in situ measurements combined with discrete samples collected at one location in the bay. The spring phytoplankton bloom (up to 29.4 mg chlorophyll m⁻³) is an annual feature at the study site and its timing may vary by up to 50 days between years. The variability in the underwater light climate and turbulent mixing are identified as key factors controlling the timing of phytoplankton blooms. Modelled average annual gross and net production are estimated to be 223 and 56 g C m⁻² year⁻¹, respectively. Light microscope counts showed that the phytoplankton community is dominated by diatoms, with dinoflagellates appearing annually for short periods of time between July and October. The zooplankton community at the study site is dominated by copepods and use of a fine mesh (80 μm) resulted in higher abundances of copepods determined (up to 2.5 × 10⁶ ind. m⁻²) than has previously reported for this location. There is a strong seasonal cycle in copepod biomass and copepods greater than 270 μm contribute less than 10% of the total biomass. Seasonal trends in copepod biomass lag those in the phytoplankton community with a delay of 3 to 4 months between the maximum phytoplankton biomass and the maximum copepod biomass. Grazing by copepods exceeds net primary production at the site and indicates that an additional advective supply of carbon is required to support the copepod community.  相似文献   

Unusual Emissions at Various Energies Prior to the Impulsive Phase of the Large Solar Flare and Coronal Mass Ejection of 4 November 2003     

Pierre Kaufmann  Gordon D. Holman  Yang Su  C. Guillermo Gimenez de?Castro  Emilia Correia  Luis O. T. Fernandes  Rodney V. de Souza  Adolfo Marun  Pablo Pereyra 《Solar physics》2012,279(2):465-475

The GOES X28 flare of 4 November 2003 was the largest ever recorded in its class. It produced the first evidence for two spectrally separated emission components, one at microwaves and the other in the THz range of frequencies. We analyzed the pre-flare phase of this large flare, twenty?minutes before the onset of the major impulsive burst. This period is characterized by unusual activity in X-rays, sub-THz frequencies, H??, and microwaves. The CME onset occurred before the onset of the large burst by about 6?min. It was preceded by pulsations of 3??C?5?s periods at sub-THz frequencies together with X-ray and microwave enhancements. The sub-THz pulsations faded out as impulsive bursts were detected at 100??C?300?keV and 7?GHz, close to the time of the first H?? brightening and the CME onset. The activities detected prior to and at the CME onset were located nearly 2?arcmin south of the following large flare, suggesting they were separate events. This unusual activity brings new clues to understanding the complex energy buildup mechanisms prior to the CME onset, occurring at a distinct location and well before the major flare that exploded afterwards.  相似文献   

The emerging field of medical geology in brief: some examples     

Brenda J. Buck  Sandra C. Londono  Brett T. McLaurin  Rodney Metcalf  Hassina Mouri  Olle Selinus  Refilwe Shelembe 《Environmental Earth Sciences》2016,75(6):449

  相似文献