Reconstruction of annual winter rainfall since A.D.1579 in central-eastern Spain based on calcite laminated sediment from Lake La Cruz     

Lidia Romero-Viana  Ramon Julià  Martin Schimmel  Antonio Camacho  Eduardo Vicente  M. Rosa Miracle 《Climatic change》2011,107(3-4):343-361

We present the first winter (December to March) rainfall reconstruction based in a novel proxy, the thickness of annual calcite laminations preserved in Lake La Cruz (central–eastern Spain). A previous calibration analysis between laminae thickness and the instrumental data series (1950 to present) indicated a highly significant correlation with winter rainfall. Therefore this study attempts the winter rainfall reconstruction since the onset of laminations (1579 a.d.) by means of the calibration function previously developed. The verification analysis between inferred annual values and earlier instrumental data (1859–1949) confirms the suitability of this novel proxy and the reliability of the series reconstructed. The reconstructed series show the fluctuating character of winter rainfall in the western Mediterranean area; interdecadal dry periods alternated with wetter periods following, in a board sense, the pattern recorded by documentary sources in other regions of the Iberian Peninsula. At present times regional winter rainfall anomalies are highly correlated with the phase of the North Atlantic Oscillation (NAO). However the time series analysis showed the dominance of nonstationary components at high frequencies of the climate signal over the last four centuries suggesting that the connection between winter rainfall and the NAO has not been stable over time and also other modes of variability, not only NAO, may have conditioned winter rainfall variability.  相似文献   

Sun–earth relationship inferred by tree growth rings in conifers from Severiano De Almeida,Southern Brazil     

A. Prestes  N.R. Rigozo  D.J.R. Nordemann  C.M. Wrasse  M.P. Souza Echer  E. Echer  M.B. da Rosa  P.H. Rampelotto 《Journal of Atmospheric and Solar》2011,73(11-12):1587-1593

This study of Sun–Earth relationships is based on tree growth rings analysis of araucarias (Araucaria angustifolia) collected at Severiano de Almeida (RS) Brazil. A chronology of 359 years was obtained, and the classical method of spectral analysis by iterative regression and wavelet method was applied to find periodicities and trends contained in the tree growth. The analysis of the dendrochronological series indicates representative periods of solar activity of 11 (Schwabe cycle), 22 (Hale cycle), and 80 (Gleissberg cycle) years. The result shows the possible influence of the solar activity on tree growth in the last 350 years. Periods of 2–7 years were also found and could represent a response of the trees to local climatic conditions. Good agreement between the time series of tree growth rings and the 11 year solar cycle was found during the maximum solar activity periods.  相似文献   

Patterns of rare earth and other trace elements in different size fractions of clays of Campanian–Maastrichtian deposits from the Portuguese western margin (Aveiro and Taveiro Formations)     

Rosa Marques  M. Isabel Prudêncio  M. Isabel Dias  Fernando Rocha 《Chemie der Erde / Geochemistry》2011,71(4):337-347

The Upper Cretaceous (Campanian–Maastrichtian) Taveiro and Aveiro Formations belong to the northern sector of the Lusitanian basin (Portuguese western margin). The Taveiro Formation was deposited in alluvial fans, including mud flow beds, lakes and sinuous rivers. The Aveiro Formation was deposited in a flat region with low hydrodynamics channels, with the formation of a barrier island-tidal system. The reconstruction of this sedimentary basin may be difficult due to its complex architecture. This work aims a methodology to be used in the reconstruction of Cretaceous sedimentary environments of the Lusitanian basin, through the establishment of geochemical patterns of different size fractions of those deposits. Chemical analysis was performed by instrumental neutron activation analysis (INAA), and the mineralogical composition obtained by X-ray diffractometry (XRD). The whole rock and different size fractions (? ≥ 125 μm, 63–125 μm, 20–63 μm, 2–20 μm and ? < 2 μm) of selected samples were studied aiming the rare earth elements (REE) and other trace elements distribution and its correlation with the grain size and mineralogy.The results obtained for the studied Cretaceous sediments showed that REE patterns and other trace elements distribution in the different size fractions may be used as a tool to differentiate deposits within and between sedimentary formations. Within the Taveiro Formation, REE are concentrated in the silt fractions (20–63 μm and 2–20 μm) of the Reveles deposit, and in the clay size fraction of S. Pedro deposit, which is richer in kaolinite. The 1st transition elements, particularly Zn, are correlated with the presence of smectite in the clay fraction of Reveles deposit. In the sand and silt size fractions (>2 μm) of samples from Taveiro Formation correlations were found between: Ga and 1st transition elements, and phyllosilicates; Cs and mica; and Rb and Ba, and K–feldspars.The Bustos deposit (Aveiro Formation) samples are very fine-grained and with a high proportion of the fine silt fraction where REE are concentrated, especially the heavy ones. Incorporation of MREE, Co and U in carbonates of the coarser fraction appears to occur. The abundances of the 1st transition elements, Ga and As, are correlated with phyllosilicates.Significant differences were found in the trace elements patterns of the various analysed size fractions of the Lusitanian basin of Cretaceous sediments, between and even within formations, which can be used as a methodological approach for a fine paleogeographic reconstruction.  相似文献   

Mobility of aqueous contaminants at abandoned mining sites: insights from case studies in Sardinia with implications for remediation   总被引：1，自引：0，他引：1  

Rosa Cidu 《Environmental Earth Sciences》2011,64(2):503-512

Public awareness of environmental health issues has increased significantly in recent years, creating the need for detailed scientific studies that can identify potential environmental problems. This paper reports the results of hydrogeochemical surveys carried out in Sardinia, an Italian region with a long mining history. When mining operations in Sardinia ceased, actions for limiting the potential adverse effects of mine closure on the water system were not undertaken. Drainages from flooded mines and seeps from mining residues left on the ground are the main mining-related sources of contamination in Sardinia. Due to the proximity of mining sites to water resources and land that is within reach of animals and humans, the major risks to human health are associated with the direct discharge of contaminated waters into the streams and soils located down-gradient of the abandoned mines. Results of hydrogeochemical surveys carried out under different seasonal conditions showed that the dispersion of toxic and harmful elements (As, Cd, Ni, Pb, Sb and Zn) increases during the rainy season, especially under high runoff conditions. These results should help regional and national authorities to address present environmental regulations, particularly those regarding the quality of water resources. Furthermore, the results might be useful elsewhere for planning remediation actions at abandoned mining sites. Lessons learned by past mining in Sardinia indicate that correct disposal and management of mining residues should be mandatory from the beginning of exploitation and processing at each active mine. This would allow reduction of the environmental risks as well as the cost of remediation.  相似文献   

Metal binding by humic acids in recent sediments from the SW Iberian coastal area     

J.M. De la Rosa  M. SantosM.F. Araújo 《Estuarine, Coastal and Shelf Science》2011

The concentrations of Cu, Zn, Cr, Ni, Pb, As, Mn and Co were determined by Inductively Coupled Plasma–Mass Spectrometry both in recent sediments from different locations of the Huelva littoral (SW Iberian Peninsula) and in their humic acid (HA) fractions in order to evaluate distribution and binding capacity of those trace elements to HAs. In addition, elemental composition (C, N, S) and δ¹³C values were determined to appraise the sources of organic matter in the area. This study involved the comparison of selected samples taken from different environments including the estuary of the Guadiana River, the main fluvial system of the region, the Tinto and Odiel estuary system and the proximal shelf. Significant positive correlations were found among Cu, Zn, As and Pb in bulk sediments, suggesting a common origin of all of those elements: the mining activities and pyrite deposits located hinterland. On the other hand, results for Cr, Co and Ni pointed to the basic rocks from the low basin of the Guadiana River as their main source. Elemental (C, N) and isotopic (δ¹³C) composition of sediments indicated a significant contribution of autochthonous plankton in coastal shelf sediments, whereas estuarine and riverine sediments showed a major contribution of terrestrial biomass. Geochemical values for their corresponding HAs suggested a greater terrestrial contribution in the sedimentary OM of the coastal shelf sediments than in bulk sediments, which evidenced the influence of coastal currents and sediment fluxes. Humic acids sequester considerable amounts of Cu and Zn contributing to reduce the bioavailability of these contaminants.  相似文献   

Weathering of ordinary chondrites from the Atacama Desert,Chile, by Mössbauer spectroscopy and synchrotron radiation X‐ray diffraction     

Pablo Munayco  Jimmy Munayco  Roberto R. de Avillez  Millarca Valenzuela  Pierre Rochette  Jérôme Gattacceca  Rosa B. Scorzelli 《Meteoritics & planetary science》2013,48(3):457-473

Some terrestrial areas have climatic and geomorphologic features that favor the preservation, and therefore, accumulation of meteorites. The Atacama Desert in Chile is among the most important of such areas, known as DCA. This desert is the driest on Earth, one of the most arid, uninhabitable localities with semiarid, arid, and hyper‐arid conditions. The meteorites studied here were collected from within the DCA of San Juan and Pampa de Mejillones, located, respectively, in the Central Depression and the Coastal Range of the Atacama Desert. ⁵⁷Fe Mössbauer spectroscopy was used for quantitative analysis of the degree of weathering of the meteorites, through the determination of the proportions of the various Fe‐bearing phases and in particular the amount of oxidized iron in terrestrial alteration products. The abundance of ferric ions in weathered chondrites can be related to specific precursor compositions and to the level of terrestrial weathering. The aim of the study was the identification, quantification, and differentiation of the weathering products in the ordinary chondrites found in the San Juan and the Pampa de Mejillones areas of the Atacama Desert. The ⁵⁷Fe Mössbauer spectroscopy study was complemented by synchrotron radiation X‐ray diffraction and magnetic susceptibility measurements. The results allow a clear differentiation of the rate of weathering in meteorite samples collected from the San Juan versus the Pampa de Mejillones areas of the Atacama Desert.  相似文献   

Volcanic soil formation in Calabria (southern Italy): The Cecita Lake geosol in the late Quaternary geomorphological evolution of the Sila uplands     

Fabio Scarciglia  Rosanna De Rosa  Giuseppe Vecchio  Carmine Apollaro  Gaetano Robustelli  Filippo Terrasi 《Journal of Volcanology and Geothermal Research》2008

This paper focuses on the main morphological, physical, chemical and mineralogical features of an andic-like soil, widely outcropping in the Sila upland plateau of Calabria (southern Italy), and its potential role in tephrostratigraphy. A multidisciplinary and multiscale approach allowed identification of this soil as a “masked” distal archive of volcanic products, developed on granite rocks and sediments with a coeval pyroclastic input during pedogenesis. The study demonstrates that the contribution of volcanic parent materials can be successfully hypothesized and assessed even in the absence, limited extent or poor preservation of primary eruptive products. The soil has an Andisol-like appearance, despite laboratory data that do not match the entire suite of diagnostic criteria for the Andisol taxonomic order. Geomorphological, stratigraphic and pedologic results, coupled with tephrostratigraphic and radiometric data, concur to suggest a Late Pleistocene(?) to Holocene age of the Andisol-like soil. In particular, the rhyolitic chemical composition of small-sized glass fragments (identified by SEM–EDS analyses) indicates soil genesis contributed by volcanic ash, probably sourced from Aeolian Arc explosive activity spanning the last 30 ka. Accordingly, the evidence of limited relict clay illuviation and the specific type of pedogenesis allowing the development of andic properties (in turn related to the neoformation of clay minerals from the weathering of volcanic glass) are consistent with a climatic shift from a seasonally-contrasted to a constantly humid pedoenvironment. This change can be ascribed to the Lateglacial(?) or Early–Middle Holocene to Late Holocene transition. Calibrated AMS ¹⁴C dates performed on charcoal fragments sampled from three representative soil profiles, provide Late Holocene ages (3136 ± 19, 343 ± 16 and 92 ± 24 yr BP), in accord with archaeological finds. On the basis of the consistent stratigraphic position, lateral continuity and wide extent, the soil can be considered a good pedostratigraphic marker in the Sila highlands and is informally defined as the “Cecita Lake geosol”. It supplies valuable time constraints for the underlying (occasionally overlying) deposits and/or soils. Moreover, it allows regional-scale morphostratigraphic correlations and detailed reconstruction of Late Pleistocene–Holocene geomorphic events in Calabria, a very suitable region for distal tephra deposition in the central Mediterranean peri-volcanic area. The effects of high-energy volcanic eruptions are interfingered with or superimposed by other geomorphic processes and climatic or anthropogenic signals.  相似文献   

The influence of variable topography on the depositional behaviour of pyroclastic density currents: The examples of the Upper Pollara eruption (Salina Island,southern Italy)     

Roberto Sulpizio  Rosanna De Rosa  Paola Donato 《Journal of Volcanology and Geothermal Research》2008

Stratigraphic reconstruction of the Upper Pollara eruption has allowed for the inference of eruptive mechanisms and the distillation of a sedimentological model for pyroclastic density currents (PDCs) moving across variable topography. The pre-eruptive topography in the study area was characterised by a tuff ring-like morphology, with both inward and outward dipping slopes. Highly viscous, moderately porphyritic, dacitic to rhyolitic magmas fed the eruption, which was characterised by a Vulcanian eruptive style. The stratigraphic succession was divided into five eruption units (EUs), which result from different phases of the eruption separated by stases. Sustained columns occurred only during EU1, while PDC generation dominates EU2–5. Lithofacies analysis of the PDC deposits indicates the prevalence of massive coarse-grained deposits on the inner slopes of the Pollara crater, which are interpreted as the deposits of a flow-boundary zone dominated by granular flow or fluid escape regimes. Dune-bedded, massive to stratified lithofacies dominate the outer slopes of the Pollara crater, and are interpreted as the deposits of PDCs with flow-boundary zones in which traction played a major role. Thin, massive PDC deposits are exposed on the sub-horizontal Malfa terrace, and are interpreted as representative of flow-boundary zones dominated by a granular flow regime. The occurrence of stacked deposits indicates that most of the PDCs were characterised by unsteady pulsatory behaviour, with development of trains of pulses during their transport. The downcurrent lithofacies transitions observed for the Upper Pollara deposits have finally been compared with other similar lithofacies associations which have been described for short-lived PDCs at tuff rings, in order to discuss the influence of pre-eruptive topography on lithofacies association.  相似文献   

New Approach to Study Extended Evolution of Supergranular Flows and Their Advection of Magnetic Elements     

Lisle  Jason  De Rosa  Marc  Toomre  Juri 《Solar physics》2000,197(1):21-30

Using velocity and magnetogram data extracted from the full-disk field of view of MDI during the 1999 Dynamics Program, we have studied the dynamics of small-scale magnetic elements (3–7 Mm in size) over time periods as long as six days while they are readily visible on the solar disk. By exploiting concurrent time series of magnetograms and Doppler images, we have compared the motion of magnetic flux elements with the supergranular velocity field inferred from the correlation tracking of mesogranular motions. Using this new method (which combines the results from correlation tracking of mesogranules with detailed analysis of simultaneous magnetograms), it is now possible to correlate the motions of the velocity field and magnetic flux for long periods of time and at high temporal resolution. This technique can be utilized to examine the long-term evolution of supergranulation and associated magnetic fields, for it can be applied to data that span far longer time durations than has been possible previously. As tests of its efficacy, we are able to use this method to verify many results of earlier investigations. We confirm that magnetic elements travel at approximately 350 m s ^–1 throughout the duration of their lifetime as they are transported by supergranular outflows. We also find that the positions of the magnetic flux elements coincide with the supergranular network boundaries and adjust as the supergranular network itself evolves over the six days of this data set. Thus we conclude that this new method permits us to study the extended evolution of the supergranular flow field and its advection of magnetic elements. Since small-scale magnetic elements are strongly advected by turbulent convection, their dynamics can give important insight into the properties of the subsurface convection.  相似文献   

Hercynian subduction-related processes within the metamorphic continental crust in Calabria (southern Italy)     

Fabrizio Tursi  Richard Spiess  Vincenzo Festa  Rosa Anna Fregola 《Journal of Metamorphic Geology》2020,38(7):771-793

Linking the deformation history of mylonitized continental rocks to the progress of devolatilization reactions that trigger reaction softening is critical for the understanding of crustal scale processes. We have analysed the field geometries and microstructures of deformed rocks within the southern Hercynian belt in Calabria, as well as modelled the pressure–temperature–deformation (P–T–d) trajectory of a main ductile shear zone that tectonically coupled the deeper crustal Mammola Paragneiss Unit with the upper crustal Stilo–Pazzano Phyllite Unit. P–T modelling of the mylonitic Mammola Paragneiss Unit was performed through calculation of phase equilibrium diagrams with the software thermocalc in the MnNCKFMASHTO model system. The prograde P–T–d trajectory is based on the zoning profiles of garnet porphyroblasts and their mineral inclusions, primarily barroisite and epidote. P–T modelling shows that peak metamorphic conditions of ~0.9 GPa and 585°C were reached during a D_n-1 under-thrusting event. The following exhumation during the D_n mylonitic event, and contact metamorphism during D_n+1 and D_n+2 folding events, have also been modelled because they are essential to restore the previous tectono-metamorphic history. The exhumation trajectory was modelled down to 0.3 GPa with temperatures of 440–460°C, under fluid-deficient conditions, as well as the final late Carboniferous contact metamorphism up to T_max of 680–720°C. The prograde path shows clear evidence for thermal buffering during garnet growth at the expense of chlorite, with a heating-dominated stage after chlorite breakdown. Subsequently, a rheological change associated with epidote breakdown (i.e. reaction softening) occurred, highlighted by a net steepening of the P/T trajectory towards the pressure peak. On the basis of the barroisite inclusions within garnet porphyroblasts as well as the ‘hairpin’ shape of the reconstructed P–T–d path (before contact metamorphism), we infer that the unusual low T/P gradient for the Hercynian crust exposed in the Mammola Paragneiss Unit records its involvement in the Palaeotethys–Gondwana subduction beneath Laurussia during D_n-1 under-thrusting. We present a new palaeotectonic interpretation along the southern Hercynian belt in Calabria during the Upper Mississippian–Lower Pennsylvanian, that is consistent with previous geochronology studies.  相似文献