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41.
The degree of contamination in soils, sediments and dusts can be assessed based on knowledge of a variety of factors, such as industrialization, type of contaminants, deposition conditions, contamination-control techniques, along with the characteristics of the recipient environmental compartments, which include pathways for contamination transport, depth of infiltration, and degree of groundwater contamination. The impact of contaminants also depends on the quantity, mobility and speciation of contaminants/wastes as well as on the sensitivity of the recipient compartments. With sufficient knowledge of these factors, a number of conclusions can be drawn concerning the status of contamination in industrialized areas. This literature review aims to scrutinize some of the methods used to analyse the occurrence, speciation, mobility, bioavailability and likely the toxic effects of contaminants in the environment.  相似文献   
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We present new calculations of the evolving UV background out to the epoch of cosmological reionization and make predictions for the amount of GeV gamma-ray attenuation by electron–positron pair production. Our results are based on recent semi-analytic models of galaxy formation, which provide predictions of the dust-extinguished UV radiation field due to starlight, and empirical estimates of the contribution due to quasars. We account for the reprocessing of ionizing photons by the intergalactic medium. We test whether our models can reproduce estimates of the ionizing background at high redshift from flux decrement analysis and proximity effect measurements from quasar spectra, and identify a range of models that can satisfy these constraints. Pair production against soft diffuse photons leads to a spectral cut-off feature for gamma rays observed between 10 and 100 GeV. This cut-off varies with redshift and the assumed star formation and quasar evolution models. We find only negligible amounts of absorption for gamma rays observed below 10 GeV for any emission redshift. With observations of high-redshift sources in sufficient numbers by the Fermi Gamma-ray Space Telescope and new ground-based instruments, it should be possible to constrain the extragalactic background light in the UV and optical portion of the spectrum.  相似文献   
45.
We analysed simultaneous archival XMM–Newton and Rossi X-ray Timing Explorer observations of the X-ray binary and black hole candidate Swift J  1753.5−0127  . In a previous analysis of the same data, a soft thermal component was found in the X-ray spectrum, and the presence of an accretion disc extending close to the innermost stable circular orbit was proposed. This is in contrast with the standard picture in which the accretion disc is truncated at large radii in the low/hard state. We tested a number of spectral models and found that several of them fit the observed spectra without the need of a soft disc-like component. This result implies that the classical paradigm of a truncated accretion disc in the low/hard state cannot be ruled out by these data. We further discovered a broad iron emission line between 6 and 7 keV in these data. From fits to the line profile we found an inner disc radius that ranges between ∼6 and 16 gravitational radii, which can be in fact much larger, up to ∼250 gravitational radii, depending on the model used to fit the continuum and the line. We discuss the implications of these results in the context of a fully or partially truncated accretion disc.  相似文献   
46.
We present near-infrared spectroscopy of the recurrent nova RS Ophiuchi (RS Oph) obtained on several occasions after its latest outburst in 2006 February. The  1–5 μ  m spectra are dominated by the red giant, but the H  i , He  i and coronal lines present during the eruption are present in all our observations. From the fits of the computed infrared spectral energy distributions to the observed fluxes, we find   T eff= 4200 ± 200   K for the red giant. The first overtone CO bands at  2.3 μ  m, formed in the atmosphere of the red giant, are variable. The spectra clearly exhibit an infrared excess due to dust emission longward of  5 μ  m; we estimate an effective temperature for the emitting dust shell of 500 K, and find that the dust emission is also variable, being beyond the limit of detection in 2007. Most likely, the secondary star in RS Oph is intrinsically variable.  相似文献   
47.
The Albanian fold-and-thrust belt and the Peri-Adriatic Depression are well documented by means of seismic reflection profiles, GPS reference points, potential data, wells and outcrops. The continuous Oligocene to Plio-Quaternary sedimentary records help to constrain both the burial history of Mesozoic carbonate reservoirs, the timing of their deformation, and the coupled fluid flow and diagenetic scenarios.Since the mid-90s, the Albanian foothills were used as a natural laboratory to develop a new integrated methodology and work flow for the study of sub-thrust reservoir evolution, and to validate on real case studies the use of basin modelling tools as well as the application of new analytical methods for the study petroleum systems in tectonically complex areas.The integration of the interactions between petrographic and microtectonic studies, kinematic, thermal and fluid flow basin modelling, is described in detail. The fracturing of the reservoir intervals has a pre-folding origin in the Albanides and relates to the regional flexuring in the foreland. The first recorded cement has a meteoric origin, implying downward migration and the development of an earlier forebulge in the Ionian Basin. This fluid, which precipitates at a maximum depth of 1.5 km, is highly enriched in strontium, attesting for important fluid–rock interaction with the Triassic evaporites, located in diapirs. From this stage, the horizontal tectonic compression increases and the majority of the fluid migrated under high pressure, characterised by brecciated and crack-seal vein. The tectonic burial increased due to the overthrusting, that is pointed out by the increase of the precipitation temperature of the cements. Afterwards, up- or downward migration of SO42−, Ba2+ and Mg2+-rich fluids, which migrated probably along the décollement level, allows a precipitation in thermal disequilibrium. This period corresponds to the onset of the thrusting in the Ionian Zone. The last stage characterised the uplift of the Berati belt, developing a selective karstification due likely to the circulation of meteoric fluid.The main results of the fluid flow modelling show that the Upper Cretaceous–Paleocene carbonate reservoirs in the Ionian zone have been charged from the Tortonian onward, and that meteoric fluid migration should have intensely biodegraded the hydrocarbon in place. Concerning the migration paths, it has been demonstrated that the thrusts act principally as flow barriers in Albania, mainly due the occurrence of evaporites (non-permeable), except in the foreland, where they do not occur.  相似文献   
48.
An investigation of the metallurgical complex surroundings in Elbasani, Albania used background samples to rule out the level of contamination in the study area. Our results show that atmospheric dust particles and soils are of high concern while overbank sediments and actual river sediments are of lower concern. The heavy metals with concentrations of up to 5 times above the local background values are Zn, Cr, Ni, Cu, Fe and Co in soils; Fe, Cr, Co, Ni, Zn, Pb in dust particles; and, Cr and Zn in the actual river/stream sediments. Due to the small size of the dust particles and the atmospheric transportation mechanism primarily related to prevailing winds, the concern for the transport of dust particles is high, especially with respect to risks associated with inhalation. The people working and living in the vicinity of the metallurgical complex of Elbasani are at the highest risk of exposure. Concerns relating to soils are associated with the potential for translocation of the trace element particles into vegetation, in particular, within the upper part of the plants. Therefore, the consumption of the vegetables grown in the vicinity of the metallurgical site should be avoided. Special attention has been given to the Shkumbini river, where the long residence time of water and particulates may result in transitions of trace elements between dissolved and particulate phases downstream.  相似文献   
49.
The recent discoveries of deeply buried Cretaceous reservoir bodies in the Atlantic Ocean revealed that relationships between the distribution of spring carbonate deposits and faults are poorly understood. The well‐exposed Quaternary deposits at Obruktepe (Denizli Basin, Turkey) provide an opportunity to reconstruct the three‐dimensional sedimentary architecture of such a system. Integration of sedimentological, lithofacies and geochemical analyses reveals complexity in the lateral relationships between sedimentary environments, faults and geothermal spring carbonates. Five environmental systems are distinguished based on the lithofacies analysis: (i) vent; (ii) smooth slope; (iii) travertine‐terrace; (iv) tufa‐barrage; and (v) flood systems. Encrusting, baffling and settling sedimentary processes are reflected in data acquired at several scales, from lithofacies observations to the morphology and arrangement of geobodies, together with microfabrics and stable carbon and oxygen isotope data. Mean values of +4·9‰ δ13C and −8·74‰ δ18O Vienna PeeDee Belemnite reflect geothermal circulation of springwaters. The environmental distribution and lithofacies indicate a lateral continuum between travertine and tufa deposits within this hot spring system. This finding supports two depositional models in which water flow variation is the main control on both CaCO3 precipitation and the resulting formation of travertine and tufa. The proposed models address the factors responsible for the development of these complex mound‐shaped carbonate spring deposits, and how they are related to fluid circulation at depth and in association with faults.  相似文献   
50.
IR spectroscopy and photometry in the 0.8–2.4 and 3–14 mregions are reported for seven dates between March 21 1998 and July20 2000 UT. The shorter wavelength region displays a smooth continuum increasing to longerwavelengths that is indicative of the Wien tail of a Planck function. Only theHe I 1.0830 line is present early and it shows a P-Cygni profile which laterdisappears. The long wave spectra show a smooth continuum between 3 and 13m that was well fit by a gray body at 1000 K. A weak, unidentifiedemission feature appears between 8 and 10 m.  相似文献   
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