Sediment–water interactions of natural oestrogens under estuarine conditions     

J. C. Bowman  J. L. Zhou  J. W. Readman 《Marine Chemistry》2002,77(4)

The natural human female hormones oestrone and 17β-oestradiol have been implicated in the disruption of endocrine systems in some wildlife adjacent to sewage effluents. The sorption behaviour of these two compounds under estuarine conditions was studied by spiking either 2.55 μg of oestrone or 2.65 μg of 17β-oestradiol in kinetic experiments. In equilibrium experiments, 3 ng of oestrone or 3.2 ng of 17β-oestradiol was added in each of the centrifuge tubes. Sorption onto sediment particles was relatively slow, with sorption equilibrium being reached in about 70 and 170 h for oestrone and 17β-oestradiol, respectively. The effects of a variety of environmental parameters on sorption were studied including salinity, sediment concentration (SC), the presence of a third phase, particle size and, also, surfactant concentrations. Results show that although salinity did not induce any statistically significant effect on the sorption of 17β-oestradiol, it did statistically enhance the sorption of oestrone, and a salting constant of 0.3 l mol⁻¹ was derived. The partition coefficient for both compounds decreased with increasing sediment concentration, a phenomenon that has been widely reported and attributed to the presence of colloids (which could enhance dissolved concentrations). In this paper, the true partition coefficients for sediment particles (K_p^true) and colloidal particles (K_c^true) have been calculated, and a K_p^true value of 141 and 102 ml g⁻¹ was obtained for oestrone and 17β-oestradiol, respectively. In addition, K_c^true values for oestrone (222×10² ml g⁻¹) and 17β-oestradiol (135×10² ml g⁻¹) were two orders of magnitude higher than their respective K_p^true values, suggesting that the colloidal particles are significantly stronger sorbents for natural oestrogens than sediment particles. Particles of different sizes were found to have different partition coefficients due to the strong relationships between partition coefficients for the two compounds and particulate organic carbon (POC) contents and specific surface areas (SSAs). The presence of a surfactant was shown to reduce the partition coefficients for the two compounds, although its concentrations being used were higher than those normally found in the natural environment.  相似文献   

Sedimentology of a subtidal,tide-dominated sand body in the Yellow Sea,southwest Korea     

George DeVries Klein  Y.A. Park  J.H. Chang  C.S. Kim 《Marine Geology》1982,50(3):221-240

Odanam Satoe, a subtidal, tide-dominated sand body in the Yellow Sea, Korea, is linear in plan and asymmetrical in cross-section. It consists of fine- to medium-grained, well-sorted subangular sand. Bedforms consist of high-amplitude (1–2 m) sandwaves on the lower flanks of the gentler-sloping bar surface, and medium-amplitude (0.5-1 m) sandwaves on the sand body trough adjoining the steeper face, the bar crest and shallower parts of the gently sloping bar surface. Bedforms are absent on the relatively steeper bar surface, which is characterized by 2° slopes. Bedform orientation on the gentler slope is oblique by 30° to the bar crest, parallel to the sand-body crest on the crest itself, and opposite to the steeper sand-body face in the trough below the steeper slope of the bar.Bottom current velocity data show that tidal currents are semi-rotary with a flood time—velocity asymmetry over the gentler slope, and ebb time—velocity asymmetry over the steeper slope during most of the tidal cycle. Tidal-current flow parallels bar elongation over the steeper slope, whereas over the gentler slope, tidal-current flow is directed at 30° to the bar crest and changes to normal to the crest one hour prior to low tide. Bedform orientation mapped with side-scan sonar shows agreement with these flow directions.Sand dispersal around the sand body is controlled by time—velocity asymmetry and partial rotary flow directions of tidal currents. This circulation causes not only a trapezoidal mode of grain dispersal, but also westerly migration of the sand body documented from comparative bathymetric surveys in 1964 and 1980.  相似文献   

On a model to propagate surface waves — A second order approach     

J.Chambel Leito  J.L.M. Fernandes 《Coastal Engineering》1992,18(3-4)

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Seasonal and diurnal variations in atmospheric pressure     

V. V. Ivanov 《Izvestiya Atmospheric and Oceanic Physics》2007,43(3):323-337

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Importance of spawning location and timing to successful transport to nursery areas: a simulation study of Gulf of Alaska walleye pollock   总被引：2，自引：0，他引：2  

Hinckley  Sarah; Hermann  Albert J.; Mier  Kathy L.; Megrey  Bernard A. 《ICES Journal of Marine Science》2001,58(5):1042-1052

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Breaking wave impact on vertical and sloping coastal structures     

M. S. Kirkgz 《Ocean Engineering》1995,22(1)

The results of laboratory experiments on the maximum and bottom impact pressures from waves breaking directly on vertical and sloping faced coastal structures are presented. Direct wave breaking on a wall is classified as early, late, and perfect breaking. Although the present study is aimed at dealing with the type of impact resulting from the perfect breaking, to some extent the occurrence of early and late breaking are unavoidable. The wave impact pressures, therefore, have a random nature of variation from impact-to-impact under the same conditions. The maximum and bottom impact pressures on walls are treated statistically. The effects of the wall angle and foreshore slope on these two quantities are examined. The results show that for practical applications, the still-water level can be taken as the acting place for the maximum impact pressure on the wall. Simultaneous impact pressure distribution below and above still-water level may be approximated as parabolic and linear, respectively. Finally, using a wall deflection criterion, a water depth region in front of the wall is defined, where the breaking wave forces may reach a critical level.  相似文献   

Generation of a double Kelvin wave resulting from the reflection of the Rossby wave by the jump layer     

V. L. Dorofeyev  L. I. Sukhikh 《Physical Oceanography》1994,5(2):83-95

This paper considers the evolution of a spatially-localized divergent Rossby wave field near the depth jump. If the jump magnitude is comparable to the depth, Rossby waves are fully reflected and a double Kelvin wave is then generated. The Rossby waves and the double Kelvin wave are described by the first- and zero-approximation fields of the asymptotic expansion, respectively. Over the characteristic Rossby wave period, the level elevation produced by the double Kelvin wave spreads over an extensive area, theraby making up for the change in the total fluid mass of the Rossby waves.Translated by Vladimir A. Puchkin.  相似文献   

Vertical habitat partitioning by large calanoid copepods in the oceanic subarctic Pacific during Spring   总被引：1，自引：0，他引：1  

David L. Mackas  Hugh Sefton  Charles B. Miller  Anne Raich 《Progress in Oceanography》1993,32(1-4)

The copepods Neocalanus plumchrus, N. flemingeri, N. cristatus, and Eucalanus bungii dominate the net zooplankton throughout the subarctic Pacific Ocean. All four species have an extensive seasonal ontogenetic vertical migration, completing most or all of their feeding and somatic growth in spring and early summer. We used stratified tows with MOCNESS and BIONESS instrumented net systems to resolve their upper ocean vertical distributions in May and June of 1984, 1987 and 1988. In each year the feeding copepodite stages of all four species were concentrated above the permanent halocline (roughly from 0 to 150m). However, the four species showed strong vertical species zonation and segregation within this layer. We consistently found a near-surface pair (N. plumchrus and N. flemingeri) and a subsurface pair (N. cristatus and E. bungii). The boundary between these groups shifts vertically, but was sharply defined and was very often coincident with a weak and transient thermocline marking the base of the layer actively mixed by surface wind and wave energy. Diel vertical migration was very limited during our sampling periods.The data suggest that the vertical distribution patterns of the copepods could be set by responses to the local intensity of turbulent mixing in the watercolumn. N. plumchrus and N. flemingeri occupied a stratum characterized by strong turbulence. N. cristatus and E. bungii occupied a stratum that was a local minimum in turbulence profiles. The depth of the boundary between the species pairs was deeper when winds and surface energy inputs were strong. The vertical partition pattern may also be determined by a difference in feeding strategy between the species pairs. N. plumchrus and N. flemingeri may feed on the enhanced protozoan population of the mixed layer, while N. cristatus and E. bungii feed on particle aggregates settling from above.  相似文献   

Harpacticoida taxocen diversity in the silty-sandy littoral zone of Kandalaksha Bay of the White Sea     

E. S. Chertoprud  M. V. Chertoprud  D. V. Kondar  P. N. Kornev  A. A. Udalov 《Oceanology》2006,46(4):492-500

The fauna composition, ecological groups, and life forms of Harpacticoids of soft littoral grounds from 15 sites off the Karelian coast in Kandalaksha Bay of the White Sea were studied. Six types of harpacticoid taxocens with different sets of dominating species are described. On silty sands with clear signs of desalination, the Stenchelia palustris taxocen is common; medium-grained sands are characterized by the Heterolaophonte minuta, Paraleptastacus kliei — Huntemannia jadensis, and Amphiascoides nanus — Scottopsyllus minor taxocens; while on coarse sands, the Ameira parvula and Ameira scotti — Mesochra lilljeborgi taxocens have developed. The diversity of the taxocens is partly explained by the differences in the grain-size composition and salinity at different sites. In addition, groups of various taxocens dwelling on the same type of the sediments were found in different minor bights of the coastline.  相似文献   

The impact of mesoscale eddies on plankton dynamics in the upper ocean     

C. L. Smith  K. J. Richards  M. J. R. Fasham 《Deep Sea Research Part I: Oceanographic Research Papers》1996,43(11-12)

A coupled QuasiGeostrophic mixed-layer ECOsystem model (QGECO) is used to investigate the impact of the underlying mesoscale eddy field on the spatial and temporal scales of biological production and on overall rates of primary productivity. The model exhibits temporal trends in the biological and physical fields similar to those observed in the North Atlantic; i.e. the mixed layer shallows in spring causing a rapid increase in phytoplankton concentrations and a corresponding decline in nutrient levels. Heterogeneity is produced in the mixed layer through Ekman pumping velocities resulting from the interaction of windstress and surface currents. This variability impacts on biological production in two ways. Firstly, spatial variations in the depth of the mixed layer affect the photosynthetically active radiation (PAR) availability and hence production rates, and secondly, eddy enhanced exchange between the surface water and those at depth bring additional nutrients into the euphotic zone. These processes result in significant spatial and temporal heterogeneity in the ecosystem distributions.Investigation of the spatial heterogeneity of the biological system finds variability to be significantly greater than that of the mixed layer. The relationship between the eddy field and the ecosystem is investigated. The structure and correlation of the biogeochernical fields change with time. The biological fields are found to have a shorter horizontal scale, but whiter spectrum than the underlying eddy field.Overwinter conditions are found to have a profound effect on the variability, size and timing of the following spring bloom event. Variations in the nitrate levels are primarily responsible for the variability in the biological system in the first year. In subsequent years the variation in the overwintering population is found to be dominant.  相似文献