TritonX-100－5-Br-PADAP光度法测定铜和镍   总被引：2，自引：0，他引：2  

萨木嘎  刘颖  嘎日迪 《岩矿测试》1999,18(4):5

研究了非离子型表面活性剂Ｔｒｉｔｏｎ Ｘ－ １００ 存在下,用５ － Ｂｒ － ＰＡＤＡＰ 光度法测定铜、镍的方法。结果表明：在ｐＨ９ ．０ 的硼砂缓冲介质中,５ － Ｂｒ － ＰＡＤＡＰ 与铜和镍生成紫红色络合物,λＣｕｍ ａｘ ＝ ５７５ ｎｍ ,εＣｕ ＝ １ ．０４ ×１０５ Ｌ·ｍｏｌ－ １·ｃｍ － １ ;λＮｉｍ ａｘ ＝ ５７５ ｎｍ ,εＮｉ ＝ １ ．１４ ×１０５ Ｌ·ｍｏｌ－ １·ｃｍ － １ 。铜和镍的质量浓度分别在０ ～５６０ μｇ／ Ｌ和０ ～４４０ μｇ／ Ｌ符合比尔定律。加入六偏磷酸钠后,由于偏磷酸镍的形成,镍不再与５ － Ｂｒ － ＰＡＤＡＰ 显色,可通过铜及铜镍总量的测定,计算出镍的含量。用该方法实测了钢样中铜和镍的含量,结果与推荐值相符,对铜和镍５ 次测定的ＲＳＤ均小于５ ％ 。  相似文献   

单轴压缩下大理岩的Q值与频率关系的研究          下载免费PDF全文

马丽云  赵建华 《地球物理学报》1990,33(6):689-693

实验采用单轴压缩循环加载方式,在地震频段内测量了莱阳大理岩的品质因数Q值.在频率为0.1-10 Hz范围内,Q值随频率变化是非线性的,而且在5 Hz附近出现峰值.用正弦波和用三角波两种方式加载所获得的Q值与频率关系很相似,并且三角波加载所测得的Q值普遍高于用正弦波加载测得的Q值.疲劳试验结果表明,正弦波循环加载大大降低了岩石的强度,三角波则对岩石强度降低较少.  相似文献   

Crustal deformation and tectonic levels of Nujiang Gorge since the Miocene     

LIU ZhiCheng  JI JianQing  SA Xiao  CHEN YaPeng  ZHONG DaLai 《中国科学:地球科学(英文版)》2018,(1)

Crustal deformation shows different patterns at different depths due to changes in the physical properties of rock.Tectonic levels can be defined based on the geometry and deformation mechanisms of crustal deformation patterns. Nujiang Gorge, with a high riverbed drop, great erosion depth, and strong deformation, has rock exposures at different tectonic levels and thus provides an ideal lab for deformation study. This paper takes the Nujiang Gorge from Chawalong to Fugong as the object to identify structural deformation patterns at different depths through field study and deformation analysis. At depth, the primary form of deformation is flow deformation, as shown on the outcrops at Maji. Ductile shear deformation can be found in many outcrops within the study region, e.g., the Gaoligong dextral shear zone and Puladi-Songta sinistral shear zone that lie to the south and north of Maji, respectively. Further to the north of Puladi, the dominated deformation pattern is similar fold and dense sub-vertical foliation. In addition, brittle faults, as evidence of shallow deformation, can be seen overprinting on the deeper deformation features all over the region. Based on those observations, this paper identifies four tectonic levels from depth to the surface: flow deformation, ductile shear deformation, similar fold, and brittle fault deformation, all of which result from the NEE-SWW compressive stress field. Further evidence from studies on the region′s thermal evolution and regional tectonics suggests that the development of different tectonic levels is closely linked to the discrepant uplift or denudation since the Miocene(~21 Ma).  相似文献   

2000-2013年浑善达克沙地植被净初级生产力变化研究     

元志辉  池勇峰  雷军  包刚  包玉海  萨楚拉  咏梅 《冰川冻土》2017,39(1):185-199

利用卫星遥感资料和地面气象观测资料,基于CASA模型及其他数理方法估算了浑善达克沙地2000-2013年生长季（4-10月）植被净初级生产力（NPP）,并对其时空变化特征进行了分析,讨论了气候因子和人类活动对植被净初级生产力的影响。结果表明： 14年间,研究区生长季的植被净初级生产力呈波动中增加趋势,多年平均NPP为239.8 gC·m^-2·a^-1。整个研究区表现为高NPP值（大于150 gC·m^-2·a^-1）的植被面积在增加,低NPP值（小于150 gC·m^-2·a^-1）的植被面积在减少。在空间分布上,研究区的北部、中部和南部边缘区域的植被NPP增加趋势较明显,而东部和西部部分区域未发生明显的趋势性变化。总体而言,研究区植被净初级生产力变化趋势与降水量的关系更密切,其相关系数达到0.86,是驱动植被NPP年际波动的最直接因素。而与温度呈负相关,相关系数为-0.42。综合考虑气候因素和人类活动对沙地NPP的影响发现,温度降低、种饲料面积、年末牲畜存栏头数和羊的数量的减少是NPP值提高的关键因素。  相似文献   

Geodynamic evolution of a forearc rift in the southernmost Mariana Arc     

Julia M. Ribeiro  Robert J. Stern  Fernando Martinez  Osamu Ishizuka  Susan G. Merle  Katherine Kelley  Elizabeth Y. Anthony  Minghua Ren  Yasuhiko Ohara  Mark Reagan  Guillaume Girard  Sherman Bloomer 《Island Arc》2013,22(4):453-476

The southernmost Mariana forearc stretched to accommodate opening of the Mariana Trough backarc basin in late Neogene time, erupting basalts at 3.7–2.7 Ma that are now exposed in the Southeast Mariana Forearc Rift (SEMFR). Today, SEMFR is a broad zone of extension that formed on hydrated, forearc lithosphere and overlies the shallow subducting slab (slab depth ≤ 30–50 km). It comprises NW–SE trending subparallel deeps, 3–16 km wide, that can be traced ≥ ∼30 km from the trench almost to the backarc spreading center, the Malaguana‐Gadao Ridge (MGR). While forearcs are usually underlain by serpentinized harzburgites too cold to melt, SEMFR crust is mostly composed of Pliocene, low‐K basaltic to basaltic andesite lavas that are compositionally similar to arc lavas and backarc basin (BAB) lavas, and thus defines a forearc region that recently witnessed abundant igneous activity in the form of seafloor spreading. SEMFR igneous rocks have low Na₈, Ti₈, and Fe₈, consistent with extensive melting, at ∼23 ± 6.6 km depth and 1239 ± 40°C, by adiabatic decompression of depleted asthenospheric mantle metasomatized by slab‐derived fluids. Stretching of pre‐existing forearc lithosphere allowed BAB‐like mantle to flow along the SEMFR and melt, forming new oceanic crust. Melts interacted with pre‐existing forearc lithosphere during ascent. The SEMFR is no longer magmatically active and post‐magmatic tectonic activity dominates the rift.  相似文献   

Displacement and rectification of planetary fluids     

Melvin E. Stern  Colin Y. Shen 《地球物理与天体物理流体动力学》2013,107(1):81-118

Abstract

Laboratory experiments on the decay (spin-up) of fluid motion on the β-plane are compared with theory. Under weakly dissipative conditions, some particles conserve potential vorticity during the entire decay. We also study the rectified mean flow which is produced by the lateral Reynolds Stress when a low frequency force is applied to the planetary fluid. The possible connection of effects with oceanic phenomena is briefly discussed.  相似文献   

Lithospheric petrology of the eastern Arabian Plate: Constraints from Al-Ashkhara (Oman) xenoliths     

Sobhi Nasir  Robert J. Stern 《Lithos》2012

Mafic granulite and spinel lherzolite xenoliths from Cenozoic alkaline basalts near Al-Ashkhara, eastern Oman, have been selected for a systematic mineralogical, geochemical and Sr–Nd–Pb isotopic study. This is the only place in E Arabia where samples of both lower crust and upper mantle can be examined. Lower crustal xenoliths consist of two mineralogically and chemically distinct groups: gabbronorite (subequal abundances of ortho- and clino-pyroxene and plagioclase) and plagioclase pyroxenite (dominant pyroxene and subordinate plagioclase). Temperature estimates for lower crustal xenoliths using the two pyroxene geothermometer (T-Wells) yield 810–865 °C. The mineral assemblage (spinel–pyroxene–plagioclase) and Al content in pyroxene indicate that plagioclase-bearing xenoliths equilibrated at 5–8 kbar (13 and 30 km depth) in the lower crust. εNd and ⁸⁷Sr/⁸⁶Sr calculated at 700 Ma for Al-Ashkhara lower crustal xenoliths (+ 6.4 to + 6.6; ⁸⁷Sr/⁸⁶Sr = 0.7028 to 0.7039) are consistent with the interpretation that juvenile, mafic melts were added to the lower crust during Neoproterozoic time and that there was no discernible contribution from pre-Neoproterozoic crust. Upper mantle xenoliths consist of both dry and hydrous (phlogopite-bearing) lherzolites. These peridotites are more Fe-rich than expected for primitive mantle or melt residues and probably formed by pervasive circulation of melts that have refertilized pre-existing mantle peridotites. Mineral equilibration temperatures range from 990 to 1070 °C. Isotopic compositions calculated at 700 Ma are εNd = + 6.8 to + 7.8 and ⁸⁷Sr/⁸⁶Sr = 0.7016 to 0.7025, indicating depleted upper mantle. Pb isotopic compositions indicate that the metasomatism was relatively recent, perhaps related to Paleogene tectonics and basanite igneous activity. Nd model ages for the spinel peridotite xenoliths range between 0.59 and 0.65 Ga. The xenolith data suggest that eastern Arabian lower crust is of hotspot origin, in contrast to western Arabian lower crust, which mostly formed at a convergent plate margin. Geochemical and isotopic differences between lower crust and upper mantle indicate that these are unrelated, possibly because delamination replaced the E Arabian mantle root in Neoproterozoic time.  相似文献   

Determination of mercury biogeochemical fluxes in the remote Mackenzie River Basin,northwest Canada,using speciation of sulfur and organic carbon     

Jesse Carrie  Gary A. Stern  Hamed Sanei  Robie W. Macdonald  Feiyue Wang 《Applied Geochemistry》2012

The Mackenzie River Basin (MRB) in NW Canada is one of the least human-impacted large watersheds in the world. The western and eastern sub-basins of the MRB are also marked by contrasting geology, geomorphology, hydrology, and biology. These remarkable differences in a remote river basin provide a unique opportunity to probe the biogeochemical processes governing the sources, transport, and bioavailability of Hg at the terrestrial-marine interface and ultimately in the Arctic Ocean. Based on a large dataset of the concentration and speciation of Hg, S and organic matter in surface sediments across the MRB, a source-apportioned budget was constructed for Hg in the MRB. The results indicate that the Hg flux in the basin originates primarily from the weathering of sulfide minerals in the western mountainous sub-basin (∼78% of the total), followed by the erosion of coal deposits along the mainstream of the Mackenzie River (∼10%), with the remainder split between atmospheric inputs and organic matter-bound Hg (6% and 5%, respectively). Although the Hg flux from the eastern peatland sub-basin only accounts for ∼10% of the total riverine Hg flux, Hg in this region correlates strongly with labile organic matter, and will likely have a much stronger influence on local biota.  相似文献   

How predictable is the northern hemisphere summer upper-tropospheric circulation?   总被引：1，自引：0，他引：1  

June-Yi Lee  Bin Wang  Q. Ding  K.-J. Ha  J.-B. Ahn  A. Kumar  B. Stern  O. Alves 《Climate Dynamics》2011,37(5-6):1189-1203

The retrospective forecast skill of three coupled climate models (NCEP CFS, GFDL CM2.1, and CAWCR POAMA 1.5) and their multi-model ensemble (MME) is evaluated, focusing on the Northern Hemisphere (NH) summer upper-tropospheric circulation along with surface temperature and precipitation for the 25-year period of 1981–2005. The seasonal prediction skill for the NH 200-hPa geopotential height basically comes from the coupled models’ ability in predicting the first two empirical orthogonal function (EOF) modes of interannual variability, because the models cannot replicate the residual higher modes. The first two leading EOF modes of the summer 200-hPa circulation account for about 84% (35.4%) of the total variability over the NH tropics (extratropics) and offer a hint of realizable potential predictability. The MME is able to predict both spatial and temporal characteristics of the first EOF mode (EOF1) even at a 5-month lead (January initial condition) with a pattern correlation coefficient (PCC) skill of 0.96 and a temporal correlation coefficient (TCC) skill of 0.62. This long-lead predictability of the EOF1 comes mainly from the prolonged impacts of El Niño-Southern Oscillation (ENSO) as the EOF1 tends to occur during the summer after the mature phase of ENSO. The second EOF mode (EOF2), on the other hand, is related to the developing ENSO and also the interdecadal variability of the sea surface temperature over the North Pacific and North Atlantic Ocean. The MME also captures the EOF2 at a 5-month lead with a PCC skill of 0.87 and a TCC skill of 0.67, but these skills are mainly obtained from the zonally symmetric component of the EOF2, not the prominent wavelike structure, the so-called circumglobal teleconnection (CGT) pattern. In both observation and the 1-month lead MME prediction, the first two leading modes are accompanied by significant rainfall and surface air temperature anomalies in the continental regions of the NH extratropics. The MME’s success in predicting the EOF1 (EOF2) is likely to lead to a better prediction of JJA precipitation anomalies over East Asia and the North Pacific (central and southern Europe and western North America).  相似文献   

Lunar atmospheric H₂ detections by the LAMP UV spectrograph on the Lunar Reconnaissance Orbiter     

S. Alan Stern  Jason C. Cook  Jean -Yves Chaufray  Paul D. Feldman  G. Randall Gladstone  Kurt D. Retherford 《Icarus》2013

We report on the detection of H₂ as seen in our analysis of twilight observations of the lunar atmosphere observed by the LAMP instrument aboard NASA’s Lunar Reconnaissance Orbiter. Using a large amount of data collected on the lunar atmosphere between September 2009 and March 2013, we have detected and identified, the presence of H₂ in the native lunar atmosphere, for the first time. We derive a surface density for H₂ of 1.2 ± 0.4 × 10³ cm⁻³ at 120 K. This is about 10 times smaller than originally predicted, and several times smaller than previous upper limits from the Apollo era data.  相似文献