An approach to characterisation of multi-scale pore geometry and correlation with moisture storage and transport coefficients in cement-stabilised soils     

Matthew R. Hall  Sacha J. Mooney  Craig Sturrock  Paolo Matelloni  Sean P. Rigby 《Acta Geotechnica》2013,8(1):67-79

An experimental approach to the characterisation of the complex, multi-scale pore geometry in cement-stabilised soils is presented, in which the pore size distribution inclusively spans at least six orders of magnitude from ~3 nm up to >3 mm. These most likely result from the combined effects of granular inter-particle packing, clay/cement clothing and bridging effects, cement hydration and clay/cement pozzolanic reactions, and alteration of larger pore geometries as a result of solid mass mobilisation and transport following capillary wetting/drying regimes. Experimental data are presented and were obtained through a combination of X-ray computed tomography, mercury intrusion porosimetry and N₂ physisorption supported by ‘wet mode’ environmental scanning electron microscopy. Data strongly suggest that macropore/capillary pore size distribution, mean pore size, sorptivity and transport coefficients are a function of particle size distribution (when compaction energy is constant). Mesopore size distribution, which dominates hygric sorption/desorption behaviour, occurs within the clay/cement matrix and also appears to be strongly influenced by the particle size distribution of the granular phase. All other factors being equal, manipulation of granular particle size distribution can be used to engineer the hygric (vapour) and capillary (liquid) potentials and also the fluid transport coefficients of these materials.  相似文献   

Palaeoenvironmental response to the ∼74 ka Toba ash-fall in the Jurreru and Middle Son valleys in southern and north-central India     

Sacha Claire Jones 《Quaternary Research》2010,73(2):336-104

Distal deposits of rhyolitic volcanic ash from the ∼74 ka “supervolcanic” eruption of Toba, in northern Sumatra, are preserved in numerous river valleys across peninsular India. The Toba eruption is hypothesized to have resulted in climate change and the devastation of ecosystems and hominin populations. This study reports the results of the analysis of sediments and stratigraphical sequences from sites in the Jurreru and Middle Son valleys in southern and north-central India. The aim of the study is to determine the extent of palaeoenvironmental change in both valleys as a result of the ash-fall. Inferences based on evidence from the Jurreru valley are more detailed, where pre- and post-Toba palaeoenvironmental changes are divided into seven phases. The results indicate that ash-fall deposits in both valleys underwent several phases of reworking that possibly lasted for several years, indicating that ash was mobile in the landscape for a considerable period of time prior to burial. This could have enhanced and lengthened the detrimental effects of the ash on vegetation and water sources, as well as animal and hominin populations.  相似文献   

Evidence for Non-Conservative Behaviour of Chlorine in Humid Tropical Environments     

Jerome Viers  Bernard Dupre  Jean-Jacques Braun  Remi Freydier  Sacha Greenberg  Jules Ndam Ngoupayou  Lus Sigha Nkamdjou 《Aquatic Geochemistry》2001,7(2):127-154

The knowledge of the biogeochemical cycle of chlorine (Cl)is important since this element is used as a tracer of geochemical and hydrological processes in oceanic or continental environments. More specifically, Cl can be used to correct surface water composition from atmospheric contribution in order to calculate precise chemical weathering rates in watersheds. Beyond the problem of potential Cl sources in a given watershed, which is directly related to the lithology, vegetation, and industrial activities, the Cl normalization is based on the assumption that this element behaves conservatively during surface processes (e.g., chemical weathering, adsorption/desorption processes).The purpose of the present study is to forecast the geochemical behavior of Cl in a forested ecosystem located under humid tropical environment.For this reason, we have analyzed the Cl (and also Ca and Na) concentrations ofsurface waters (rainwater, groundwater, river water) over a two-year period in the Nsimi–Zoetele watershed (Cameroon).The Cl mass balance for the watershed appears to be equilibrated over the studied period (1995–1996) but Cl behavior in Mengong River draining the watershed suggests a non-conservative behavior. Indeed, Cl concentrationsin the Mengong River are low during dry seasons and high during wet seasons, which is the reverse tendency to what is usually observed taking into account dilution and evaporation processes. As Cl concentrations in the Mengong River are lower than those measured in all the feeding reservoirs, Cl should be adsorbed onto the soils of the watershed. However, as the Cl mass balance is equilibrated over the whole-year, Cl should be adsorbed and releasedat a seasonal scale. The results we obtained for this small watershed were not generalized for a larger studied basin (i.e., Nyong River basin). Even if these results should be followed by further investigations, this study suggests that Cl normalization should be used with caution to avoid under- or over-estimation of chemical weathering rates.  相似文献