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51.
Proglacial lakes are effective sediment traps but their impact on the reliability of downstream sediment records to reconstruct glacier variability remains unclear. Here, we investigate the sedimentary signature of the recent recession of Steffen Glacier (Chilean Patagonia, 47°S) in downstream fjord sediments, with a focus on identifying the trapping (decreased downstream sediment yield) and filtering (removal of coarse particles) effectiveness of a growing intermediate proglacial lake. Four sediment cores were collected along a 14 km longitudinal transect in Steffen Fjord and the sediment physical and chemical properties were compared with aerial imagery at high temporal resolution. The caesium-137 (137Cs) chronology of the most distal core and sediment trap data suggest that sediment accumulation in the fjord remained relatively stable through time, despite the accelerating glacier recession and the growth of Steffen proglacial lake. This is in contrast with many studies that indicate a decrease in sediment yield during proglacial lake expansion. It implies that the increase in sediment export due to accelerating meltwater production may be balanced by the sediment trapping effect of the growing proglacial lake. The fjord sediments show a slight fining upward accompanied by a marked decrease in flood-induced grain-size peaks, most likely due to the increasing filtering and dampening effect of the expanding proglacial lake. Our findings show that the filtering effect of the proglacial lake reached a threshold in 1985, when the lake attained an area of 2.02 km2. The additional 5 km of glacier recession during the following 32 years did not have any significant impact on downstream sedimentation. This study confirms that proglacial lakes act as sediment traps but it indicates that (1) the trapping effect can be outpaced by accelerating glacier recession and (2) the filtering effect becomes stable once the lake attains a certain critical size. © 2020 John Wiley & Sons, Ltd.  相似文献   
52.
Water structure at hematite-water interfaces   总被引:1,自引:0,他引:1  
The atomic-level structure of water at mineral surfaces is an important controlling factor in interfacial reactions such as foreign ion incorporation, crystal growth and dissolution, and redox reactions. Molecular dynamics simulations with four different models based on interatomic potentials have been carried out to determine the atomic-level structure of three hematite-water interfaces. In addition, for each of the three surfaces, different terminations or protonation schemes were considered. The availability of surface X-ray scattering data for the surfaces considered here allowed for an extensive comparison with experimental data. Qualitatively, with the exception of one termination with one model, all models predict the correct arrangement of water molecules at the interface. Quantitatively, the agreement with experimental positions, distances, and layer occupancies is good to excellent, especially given the range of values reported in published experimental studies. Therefore, this study provides further evidence that interatomic potential models can be used to reliably predict the structure of mineral-water interfaces. In addition, molecular simulations are a valuable source of information to complement surface X-ray scattering experiments owing to their ability to directly determine the position of hydrogen atoms and to yield three-dimensional predicted structures at no added cost, as demonstrated in this work. Indeed, the molecular dynamics trajectories were analyzed to determine the surface structural controls on the interfacial water structure. Each of the three surface functional groups present at the surfaces considered in this work, namely, triply-coordinated oxo, doubly-coordinated hydroxo, and singly-coordinated aquo groups, was found to form similar hydrogen bond configurations with adsorbed water molecules at all surfaces. Oxo groups accept long-lasting and linear hydrogen bonds from adsorbed water molecules; hydroxo groups can form hydrogen bonds with other surface functional groups as well as with adsorbed water molecules; and aquo groups normally only donate hydrogen bonds to other surface groups or adsorbed water molecules. Additionally, the majority of adsorbed water molecules were found to adopt multiple configurations and orientations. This information was used to evaluate three-dimensional structural models of the interfaces, which were previously derived experimentally from one-dimensional electron density profiles and steric considerations.  相似文献   
53.
The main objective of this study is to develop a new photometric correction that is suitable for global Chang’ E-1 (CE-1) Interference Imaging Spectrometer (IIM) data. We considered two improvements in the accuracy of the photometric correction: (1) classifying the whole Moon’s surface into four classes (very bright rays, mature highlands, low FeO basalts, and high FeO basalts) based on the FeO contents; (2) decoupling the combined effects of the solar photometry and the detector responsivity along the cross-track. The results showed that our decoupling method could correct the non-uniformity of detector response but retain the cross-track photometry. Based on these in-flight calibrated data, spectrally continuous photometric functions of the four classes were obtained. By eliminating the contamination from highlands ejecta and low FeO basalts, the opposition surge of the high FeO maria was evident for the first time. The amplitude and width of the opposition surge presents wavelength dependence, which suggests that shadow hiding is the mechanism responsible for the opposition surge. A global lunar reflectance map whose boundaries between adjacent orbits are invisible was generated using the new four-type photometric functions. The quality of the global mosaic and the consistency of the reflectance spectra of the same area obtained in different orbits indicate the effectiveness of our photometric correction method. Although our method was specifically applied to the IIM data, the photometric correction method and the parameter values derived in this study is expected to be suitable for other optical instruments.  相似文献   
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55.
Indisputable geochronology of Icelandic volcanism may contribute to improving the use of volcanic proxies for paleoenvironmental studies. Accurate and reliable ages may also provide some useful constraints in studying the possible relationship between volcanism and deglaciation in Iceland. Given the difficulty of dating accurately young and low potassic volcanic samples from Iceland, the relationship between deglaciation and increasing levels of volcanism has been shown only for the last deglaciation. The purpose of this study is to evaluate the potential of the unspiked K–Ar dating method for dating Quaternary Icelandic volcanic rocks, because we consider that reliable K–Ar ages of interglacial and sub-glacial volcanic products may generate useful data sets for paleoclimatic reconstructions, so enabling the link between glaciation and volcanic activity to be better established. Given the ages and precisions obtained, this study demonstrates that the unspiked K–Ar method is a promising tool for reconstructing the recent volcanic activity in Iceland during glacial and interglacial intervals.  相似文献   
56.
57.
The tropical Indian Ocean climate variability is investigated using an artificial neural network analysis called self-organizing map (SOM) for both observational data and coupled model outputs. The SOM successfully captures the dipole sea surface temperature anomaly (SSTA) pattern associated with the Indian Ocean Dipole (IOD) and basin-wide warming/cooling associated with ENSO. The dipole SSTA pattern appears only in boreal summer and fall, whereas the basin-wide warming/cooling appears mostly in boreal winter and spring owing to the phase-locking nature of these phenomena. Their occurrence also undergoes significant decadal variation. Composite diagrams constructed for nodes in the SOM array based on the simulated SSTA reveal interesting features. For the nodes with the basin-wide warming, a strong positive SSTA in the eastern equatorial Pacific, a negative Southern Oscillation, and a negative precipitation anomaly in East Africa are found. The nodes with the positive IOD are associated with a weak positive SSTA in the central equatorial Pacific or positive SSTA in the eastern equatorial Pacific, a positive (negative) sea level pressure anomaly in the eastern (western) tropical Indian Ocean, and a positive precipitation anomaly over East Africa. The warming in the central equatorial Pacific appears to correspond to El Niño Modoki discussed recently. These results suggest usefulness of SOM in studying large-scale ocean–atmosphere coupled phenomena.  相似文献   
58.
In many earth sciences applications, the geological objects or structures to be reproduced are curvilinear, e.g., sand channels in a clastic reservoir. Their modeling requires multiple-point statistics involving jointly three or more points at a time, much beyond the traditional two-point variogram statistics. Actual data from the field being modeled, particularly if it is subsurface, are rarely enough to allow inference of such multiple-point statistics. The approach proposed in this paper consists of borrowing the required multiple-point statistics from training images depicting the expected patterns of geological heterogeneities. Several training images can be used, reflecting different scales of variability and styles of heterogeneities. The multiple-point statistics inferred from these training image(s) are exported to the geostatistical numerical model where they are anchored to the actual data, both hard and soft, in a sequential simulation mode. The algorithm and code developed are tested for the simulation of a fluvial hydrocarbon reservoir with meandering channels. The methodology proposed appears to be simple (multiple-point statistics are scanned directly from training images), general (any type of random geometry can be considered), and fast enough to handle large 3D simulation grids.  相似文献   
59.
Geochemistry of Adakites from the Philippines: Constraints on Their Origins   总被引:1,自引:0,他引:1  
Abstract. We have identified in the Philippine Archipelago 230 samples of Late Miocene to Quaternary intermediate and evolved magmatic rocks or glasses, the compositions of which plot within the adakitic field defined by Defant and Drum-mond (1990) using Sr/Y ratios versus Y contents. These rocks belong to four different subductions, along the Manila Trench (Batan, Northern Luzon, Central Luzon), the Negros and Sulu Trenches (Negros and Western Mindano), the Cotobato Trench (Southern Mindanao) and the Philippine Trench (Eastern Mindanao). Lavas from Central Mindanao overlie the deep remnants of the Molucca Sea Plate, and were emplaced in a post-collision setting.
All these samples show a significant depletion in Y and HREE with respect to their "normal" calc-alkaline equivalents, suggesting that garnet was either a residual phase during partial melting or a fractionating mineral during differentiation or assimilation coupled with fractional crystallisation (AFC). However, only 19 samples out of our set (i.e., 8 %) display very high Sr/Y ratios (100–250). Our preferred model for the genesis of these "typical adakites" is ca. 20 % partial melting of subducted altered oceanic metabasalts converted to eclogite. This melting process could have been triggered by water from the underlying serpentinites. Most of the samples, termed "intermediate adakites", display major and trace element chemical features intermediate between those of the former group and those of normal calc-alkaline lavas. We show that magma mixing between slab-derived adakitic magmas and mafic mantle-derived melts accounts for most of the trends linking typical and intermediate adakites, although an additional contribution of mantle is required in some cases.  相似文献   
60.
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