An experimental study on impact-induced alterations of planetary organic simulants          下载免费PDF全文

Yasuhito Sekine  Kenya Kodama  Takamichi Kobayashi  Seiji Obata  Yu Chang  Nanako O. Ogawa  Yoshinori Takano  Naohiko Ohkouchi  Koichiro Saiki  Toshimori Sekine 《Meteoritics & planetary science》2018,53(6):1267-1282

The present study systematically investigates shock-induced alteration of organic simulants of planetary bodies (OSPBs) as a function of peak shock pressure and temperature by impact experiments. Our results show that the composition and structure of OSPBs are unchanged upon impacts at peak pressures ≤~5 GPa and temperatures ≤~350 °C. On the other hand, these are dramatically changed upon impacts at >7–8 GPa and > ~400 °C, through loss of hydrogen-related bonds and concurrent carbonization, regardless of the initial compositions of OSPBs. Compared with previous results on static heating of organic matter, we suggest that shock-induced alteration cannot be distinguished from static heating only by Raman and infrared spectroscopy. Our experimental results would provide a proxy indicator for assessing degree of shock-induced alteration of organic matter contained in carbonaceous chondrites. We suggest that a remote-sensing signature of the 3.3–3.6 μm absorption due to hydrogen-related bonds on the surface of small bodies would be a promising indicator for the presence of less-thermally-altered (i.e., <350 °C) organic matter there, which will be a target for landing to collect primordial samples in sample-return spacecraft missions, such as Hayabusa2 and OSIRIS-REx.  相似文献   

Regeneration dynamics of iron and nutrients from bay sediment into bottom water of Funka Bay,Japan     

Nanako Hioki  Kenshi Kuma  Yuichiroh Morita  Daichi Miura  Atsushi Ooki  Seiji Tanaka  Hiroji Onishi  Tetsuya Takatsu  Naoto Kobayashi  Yoshihiko Kamei 《Journal of Oceanography》2015,71(6):703-714

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The stability functions in the bulk similarity formulation for the unstable boundary layer     

Michiaki Sugita  Wilfried Brutsaert 《Boundary-Layer Meteorology》1992,61(1-2):65-80

An update is presented for the functionC in the heat transfer equation and for the functionB _w in the momentum transfer equation of the bulk similarity approach for the atmospheric boundary layer (ABL). Motives for this update are recent developments in the formulation of Monin-Obukhov functions for the surface layer, and the availability of the new data set of FIFE-89, the 1989 phase of the First ISLSCP Field Experiment, which took place over the same hilly prairie terrain in north-eastern Kansas as the 1987 phase, i.e., FIFE-87. Functional forms developed in earlier studies are considered. In addition, a new form is derived based on a simple dual structure of the ABL. The functions are calibrated with the data set obtained during FIFE-87; the results are then verified with the independent data set acquired during FIFE-89.Formerly at Cornell University.  相似文献   

Two-stage model of incorporation of seamount and oceanic blocks into sedimentary melange: Geochemical and biostratigraphic constraints in Jurassic Chichibu accretionary complex, Shikoku, Japan   总被引：1，自引：0，他引：1  

Seiji  Matsuda Yujiro  Ogawa† 《Island Arc》1993,2(1):7-14

Abstract The significance of timing and formation of mélange in accretionary prisms, particularly concerning basaltic and related rocks and pelagic sediments, is exemplified in the Sawadani area of the Jurassic Chichibu accretionary complex in Shikoku, southwest Japan. Major and trace element geochemistry of the basaltic and related rocks indicates that all are of a hot-spot origin which produced a seamount. Most of the rocks have a trend of differentiation from an alkalic parental magma. The time relationship between the blocks and matrices of the mélange deduced from radiolarian fossil evidence and macro- to microscopic characteristics of contacts between different lithologies indicates two stages of mixing of materials in the seafloor. The first mixing occurred on the flank of the seamount in the pelagic environments in the Late Permian, and the second occurred on the trench floor or in the accretionary prism after the Early Jurassic. These two stages show respectively the geological phenomena of a seamount within the Izanagi-Kula plate and its incorporation into the Asian continental margin.  相似文献   

An experimental study on Fischer‐Tropsch catalysis: Implications for impact phenomena and nebular chemistry     

Yasuhito SEKINE  Seiji SUGITA  Takafumi SHIDO  Takashi YAMAMOTO  Yasuhiro IWASAWA  Toshihiko KADONO  Takafumi MATSUI 《Meteoritics & planetary science》2006,41(5):715-729

Abstract— Fischer‐Tropsch catalysis, by which CO and H₂ are converted to CH₄ on the surface of transition metals, has been considered to be one of the most important chemical reactions in many planetary processes, such as the formation of the solar and circumplanetary nebulae, the expansion of vapor clouds induced by cometary impacts, and the atmospheric re‐entry of vapor condensate due to asteroidal impacts. However, few quantitative experimental studies have been conducted for the catalytic reaction under conditions relevant to these planetary processes. In this study, we conduct Fischer‐Tropsch catalytic experiments at low pressures (1.3 times 10^?4 bar ≤ P ≤ 5.3 times 10^?1 bar) over a wide range of H₂/CO ratios (0.25–1000) using pure iron, pure nickel, and iron‐nickel alloys. We analyze what gas species are produced and measure the CH₄ formation rate. Our results indicate that the CH₄ formation rate for iron catalysts strongly depends on both pressure and the H₂/CO ratio, and that nickel is a more efficient catalyst at lower pressures and lower H₂/CO ratios. This difference in catalytic properties between iron and nickel may come from the reaction steps concerning disproportionation of CO, hydrogenation of surface carbon, and the poisoning of the catalyst. These results suggest that nickel is important in the atmospheric re‐entry of impact condensate, while iron is efficient in circumplanetary subnebulae. Our results also indicate that previous numerical models of iron catalysis based on experimental data at 1 bar considerably overestimate CH₄ formation efficiency at lower pressures, such as the solar nebula and the atmospheric re‐entry of impact condensate.  相似文献   

Thermohaline staircases in the Warm-Core Ring off Cape Erimo,Hokkaido and their fluxes due to salt finger     

Hideo Miyake  Seiji Sasaki  Hidekazu Yamaguchi  Kiyoshi Masuda  Gen Anma  Yoshihiko Kamei 《Journal of Oceanography》1995,51(1):99-109

Thermohaline staircases off Cape Erimo, Hokkaido are described and their physical properties are compared with those in other seas. The mean fluxes for heat and salt across the interface induced by salt finger were estimated as 105 cal cm^–2d^–1, and 0.03 g cm^–2d^–1, respectively. These values were in the same order as those in Caribbean Sea. The effective eddy diffusivities were also in the same order as the Caribbean ones. This suggests that the double-diffusive convection plays on important role on the water mass conversions occurring in the interfrontal zone between the Oyashio and the Kuroshio Waters.  相似文献   

Determination of dissolved nucleic acids in seawater by the fluorescence dye, ethidium bromide     

Seiji Sakano  Akiyoshi Kamatani 《Marine Chemistry》1992,37(3-4)

A new method for the determination of dissolved double-stranded deoxyribonucleic acid (DNA) and ribonucleic acid (RNA) in seawater was developed, evaluated and used to study the fates of these nucleic acids in marine ecosystems. These nucleic acids, which were pre-concentrated on a hydroxyapatite column, were determined fluorometrically by the use of ethidium bromide dye, which binds specifically to the double-stranded polynucleotide. No dissolved organic matter coexisting in the pre-concentrated sample solution interfered in the analysis of DNA and RNA. Column recoveries of DNA and RNA in a sample volume of up to 11 were 93% and 97%, respectively, and 90% of both at 51. The detection limits of DNA and RNA concentrated from a 51 sample by this fluorometric method were 0.6 and 1.1 μg l⁻¹, respectively. The concentration of dissolved nucleic acids in the waters from Tokyo Bay and Sagami Bay showed great variation in space and time. DNA ranged from 1 to 32 μg l⁻¹, and RNA from below the detection limit to 34 μg l⁻¹. The total amount of phosphorus in nucleic acids was an important fraction (12.9 ± 8.2%) of the dissolved organic phosphorus (DOP) and showed a good correlation with DOP.  相似文献   

Monitoring and simulation of water, heat, and CO2 fluxes in terrestrial ecosystems based on the APEIS-FLUX system     

WATANABE Masataka  WANG Qinxue  HAYASHI Seiji  MURAKAMI ShogoLIU Jiyuan  OUYANG Zhu  LI Yan  LI Yingnian  WANG Kelin 《地理学报》2005,15(2):131-141

The Integrated Environmental Monitoring (IEM) project, part of the Asia-Pacific Environmental Innovation Strategy (APEIS) project, developed an integrated environmental monitoring system that can be used to detect, monitor, and assess environmental disasters, degradation, and their impacts in the Asia-Pacific region. The system primarily employs data from the moderate resolution imaging spectrometer (MODIS) sensor on the Earth Observation System- (EOS-) Terra/Aqua satellite, as well as those from ground observations at five sites in different ecological systems in China. From the preliminary data analysis on both annual and daily variations of water, heat and CO2 fluxes, we can confirm that this system basically has been working well. The results show that both latent flux and CO2 flux are much greater in the crop field than those in the grassland and the saline desert, whereas the sensible heat flux shows the opposite trend. Different data products from MODIS have very different correspondence, e.g. MODIS-derived land surface temperature has a close correlation with measured ones, but LAI and NPP are quite different from ground measurements, which suggests that the algorithms used to process MODIS data need to be revised by using the local dataset. We are now using the APEIS-FLUX data to develop an integrated model, which can simulate the regional water, heat, and carbon fluxes. Finally, we are expected to use this model to develop more precise high-order MODIS products in Asia-Pacific region.  相似文献   

Manganiferous schists and their origin,Hidaka Mountains,Hokkaido, Japan     

Rodney H. Grapes  Seiji Hashimoto 《Contributions to Mineralogy and Petrology》1978,68(1):23-35

Manganiferous quartz-mica schists (4 m in stratigraphic thickness) overlie epidote amphibolite in the Chiroro River area, Hidaka Mountains, Hokkaido. The schist layers have a considerable range of A/F ratios and bulk oxidation ratios which vary from 21.5 to 100. Manganese contents are from 4 to 30 times higher than that of the average shale with 0.09% MnO. The schists are essentially quartz-white mica-biotite-Mn garnet-tourmaline-±epidote-magnetite assemblages. A highly oxidized layer (5–8 cm thick) 95 cm above the epidote amphibolite contact is characterized by viridine-piemontite-spessartine-Mn white mica-Mn tourmaline-Ti-Mn haematite indicative of both high initial manganese content and very high f _O2 conditions of recrystallization.Viridine contains up to 17 mol% Mn³⁺SiO₅ and coexists with piemontite with between 13.6 and 15.4 wt% Mn₂O₃. Mn-poor-Fe-rich (Ps₃₂) epidote occurs in the less oxidized schist enclosing the viridine-piemontite bearing seam. Garnets vary widely in composition with end member variations (mol%) of Spess_22.9–80.5; And_0.2–11.7; Alm_1.1–57.1; Pyr_2.0–12.2; Gross_7.0–49.0. The more manganiferous garnets occur in rocks with higher oxidation ratios while almandiferous varieties occur in schists with low oxidation ratios. Biotite ranges from green to red-brown varieties (increasing Ti and Fe) with Mg/ (Mg+Fe) ratios varying from 56 to 48. Ten to fifteen percent octahedral R²⁺ is replaced by Al indicating a trend towards eastonite-siderophyllite. The white micas deviate only slightly from dioctahedral stoichiometry but have up to 25% of octahedral sites occupied by Fe, Mg and to a lesser extent Mn and Ti as R²⁺ Si⁴⁺2Al³⁺ and in highly oxidized rocks as (Fe,Mn)³⁺Al³⁺. The white mica in the highly oxidized viridine-piemontite schist is pale pinkishorange, exhibits reverse pleochroism, and has between 0.30 and 0.43 wt% Mn₂O₃.There is a close comparison, both in terms of stratigraphic thickness and Fe-Mn variation, between the Chiroro schist sequence and many oceanic cores so that the bulk chemistry and mineralogy of the pelitic schists is largely an extension of the original Eh-pH conditions of hemipelagic sedimentation and post-depositional adjustments during diagenesis. The thin viridine-piemontite bearing schist is correlated with an oxidized, Fe-Mn rich layer commonly found in present day oceanic cores. The viridine presumably formed by reaction of original ferro-manganese microgranules and clay minerals. Halmrolytic alteration of the underlying metabasalt resulted in leaching of Mn and Fe (in particular) into the overlying sediments and the formation of concentrations of haematite — manganese oxide — Mn garnet along the schist-epidote amphibolite contact.Estimation of the P-T conditions of metamorphism from the phase relations and compositions in the epidote amphibolite associated with the manganiferous schist gives T °C = 530560 and a minimum P _fluid > 3 kb which corresponds to the epidote amphibolite facies of Barrovian-type terrains.This paper is dedicated to Professor Kenzo Yagi on the occasion of his retirement from the Chair of Mineralogy, Department of Geology and Mineralogy, Hokkaido University, Sapporo, Japan  相似文献   

The extent of the unstable Monin-Obukhov layer for temperature and humidity above complex hilly grassland     

Wilfried Brutsaert  Michiaki Sugita 《Boundary-Layer Meteorology》1990,51(4):383-400

Potential temperature, specific humidity and wind profiles measured by radiosondes under unstable but windy conditions during FIFE in northeastern Kansas were analyzed within the framework of Monin-Obukhov similarity. Around 86% of these profiles were found to have a height range over which the similarity, formulated in terms of the Businger-Dyer functions, is valid and for which the resulting surface fluxes are in good agreement with independent measurements at ground stations. When scaled with the surface roughness z ₀ = 1.05 m and the displacement height d ₀ = 26.9 m, for the potential temperature this height range was 45 (±31) (z – d ₀ )/z ₀ 104 (±54) and the comparison of the profile-derived surface fluxes with the independent measurements gave a correlation coefficient of r = 0.96. For the specific humidity these values are 42 (±29) (z – d ₀ )/z ₀ 96 (±38) and r = 0.94. In terms of the height of the bottom of the inversion H _i , in the morning hours the upper limit of (z – d ₀ ) in the Monin-Obukhov layer is approximately 0.3H _i , whereas for a fully developed ABL it is closer to 0.1H _i . Probably, as a result of the short sampling times and perhaps also of the small gradients under the windy conditions, the exact height range of validity was difficult to establish from a mere inspection of these profiles.  相似文献