Use of Groundwater Level Fluctuations near an Operating Water Supply Well to Estimate Aquifer Transmissivity     

Sergey Pozdniakov  Pavel Ivanov  Paul Davis  Nikolay Sizov 《Ground water》2021,59(1):49-58

We developed a method to estimate aquifer transmissivity from the hydraulic-head data associated with the normal cyclic operation of a water supply well thus avoiding the need for interrupting the water supply associated with a traditional aquifer test. The method is based on an analytical solution that relates the aquifer's transmissivity to the standard deviation of the hydraulic-head fluctuations in one or more observation wells that are due to the periodic pumping of the production well. We analyzed the resulting analytical solution and demonstrated that when the observation wells are located near the pumping well, the solution has a simple, Dupuit like form. Numerical analysis demonstrates that the analytical solution can also be used for a quasi-periodic pumping of the supply well. Simulation of cyclic pumping in a statistically heterogeneous medium confirms that the method is suitable for analyzing the transmissivity of weakly or moderately heterogeneous aquifers. If only one observation well is available, and the shift in the phase of hydraulic-head oscillations between the pumping well and the observation well is not identifiable. Prior knowledge of aquifer's hydraulic diffusivity is required to obtain the value of the aquifer transmissivity.  相似文献   

The Brazilian decimetric array and space weather     

Hanumant S. Sawant  Natchimuthuk Gopalswamy  Reinaldo R. Rosa  Robert A. Sych  Sergey A. Anfinogentov  Francisco C.R. Fernandes  José R. Cecatto  Joaquim E.R. Costa 《Journal of Atmospheric and Solar》2011,73(11-12):1300-1310

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Do organic ligands affect calcite dissolution rates?   总被引：1，自引：0，他引：1  

Eric H. Oelkers  Sergey V. Golubev  Oleg S. Pokrovsky  Pascale Bénézeth 《Geochimica et cosmochimica acta》2011,75(7):1799-5509

Steady state Iceland-spar calcite dissolution rates were measured at 25 °C in aqueous solutions containing 0.1 M NaCl and up to 0.05 M dissolved bicarbonate at pH from 7.9 to 9.1 in the presence of 13 distinct dissolved organic ligands in mixed-flow reactors. The organic ligands considered in this study include those most likely to be present in either (1) aquifers at the conditions pertinent to CO₂ sequestration or (2) soil/early diagenetic environments: acetate, phthalate, citrate, EDTA⁴⁻, succinate, d-glucosaminate, l-glutamate, d-gluconate, 2,4-dihydroxybenzoate, 3,4-dihydroxybenzoate, fumarate, malonate, and gallate. Results show that the presence of <0.05 mol/kg of these organic anions changes calcite dissolution rates by less than a factor of 2.5 with the exception of citrate and EDTA⁴⁻. The presence of 0.05 mol/kg citrate and EDTA⁴⁻ increases calcite dissolution rates by as much as a factor of 35 and 500, respectively, compared to rates in organic anion-free solutions. Further calcite dissolution experiments were performed in the presence of organic polymers similar to bacterial exudates, cell exopolysaccharides, and analogs of microbial cell envelopes: alginate, lichen extract, humic acid, pectin, and gum xanthan. In no case did the presence of <100 ppm of these organics change calcite dissolution rates by more than a factor of 2.5. Results obtained in this study suggest that the presence of aqueous organic anions negligibly affects calcite forward dissolution rates in most natural environments. Some effect on calcite reactivity may be observed, however, by the presence of organic anions if they change substantially the chemical affinity of the fluid with respect to calcite.  相似文献   

Geology, mineralization, stable isotope geochemistry, and fluid inclusion characteristics of the Novogodnee–Monto oxidized Au–(Cu) skarn and porphyry deposit, Polar Ural, Russia     

Serguei G. Soloviev  Sergey G. Kryazhev  Svetlana S. Dvurechenskaya 《Mineralium Deposita》2013,48(5):603-627

The Novogodnee–Monto oxidized Au–(Cu) skarn and porphyry deposit is situated in the large metallogenic belt of magnetite skarn and Cu–Au porphyry deposits formed along the Devonian–Carboniferous Urals orogen. The deposit area incorporates nearly contemporaneous Middle–Late Devonian to Late Devonian–Early Carboniferous calc-alkaline (gabbro to diorite) and potassic (monzogabbro, monzodiorite- to monzonite-porphyry, also lamprophyres) intrusive suites. The deposit is represented by magnetite skarn overprinted by amphibole–chlorite–epidote–quartz–albite and then sericite–quartz–carbonate assemblages bearing Au-sulfide mineralization. This mineralization includes early high-fineness (900–990?‰) native Au associated mostly with cobaltite as well as with chalcopyrite and Co-pyrite, intermediate-stage native Au (fineness 830–860?‰) associated mostly with galena, and late native Au (760–830?‰) associated with Te minerals. Fluid inclusion and stable isotope data indicate an involvement of magmatic–hydrothermal high-salinity (>20 wt.% NaCl-equiv.) chloride fluids. The potassic igneous suite may have directly sourced fluids, metals, and/or sulfur. The abundance of Au mineralization is consistent with the oxidized character of the system, and its association with Co-sulfides suggests elevated sulfur fugacity.  相似文献   

Stability and equation of state of post-aragonite BaCO3     

Joshua P. Townsend  Yun-Yuan Chang  Xiaoting Lou  Miguel Merino  Scott J. Kirklin  Jeff W. Doak  Ahmed Issa  Chris Wolverton  Sergey N. Tkachev  Przemyslaw Dera  Steven D. Jacobsen 《Physics and Chemistry of Minerals》2013,40(5):447-453

At ambient conditions, witherite is the stable form of BaCO₃ and has the aragonite structure with space group Pmcn. Above ~10 GPa, BaCO₃ adopts a post-aragonite structure with space group Pmmn. High-pressure and high-temperature synchrotron X-ray diffraction experiments were used to study the stability and equation of state of post-aragonite BaCO₃, which remained stable to the highest experimental P–T conditions of 150 GPa and 2,000 K. We obtained a bulk modulus K ₀ = 88(2) GPa with $K'$  = 4.8(3) and V ₀ = 128.1(5) ų using a third-order Birch-Murnaghan fit to the 300 K experimental data. We also carried out density functional theory (DFT) calculations of enthalpy (H) of two structures of BaCO₃ relative to the enthalpy of the post-aragonite phase. In agreement with previous studies and the current experiments, the calculations show aragonite to post-aragonite phase transitions at ~8 GPa. We also tested a potential high-pressure post–post-aragonite structure (space group C222 ₁ ) featuring four-fold coordination of oxygen around carbon. In agreement with previous DFT studies, ΔH between the C222 ₁ structure and post-aragonite (Pmmn) decreases with pressure, but the Pmmn structure remains energetically favorable to pressures greater than 200 GPa. We conclude that post–post-aragonite phase transformations of carbonates do not follow systematic trends observed for post-aragonite transitions governed solely by the ionic radii of their metal cations.  相似文献   

Bayesian updating via bootstrap filtering combined with data-driven polynomial chaos expansions: methodology and application to history matching for carbon dioxide storage in geological formations     

Sergey Oladyshkin  Holger Class  Wolfgang Nowak 《Computational Geosciences》2013,17(4):671-687

Model calibration and history matching are important techniques to adapt simulation tools to real-world systems. When prediction uncertainty needs to be quantified, one has to use the respective statistical counterparts, e.g., Bayesian updating of model parameters and data assimilation. For complex and large-scale systems, however, even single forward deterministic simulations may require parallel high-performance computing. This often makes accurate brute-force and nonlinear statistical approaches infeasible. We propose an advanced framework for parameter inference or history matching based on the arbitrary polynomial chaos expansion (aPC) and strict Bayesian principles. Our framework consists of two main steps. In step 1, the original model is projected onto a mathematically optimal response surface via the aPC technique. The resulting response surface can be viewed as a reduced (surrogate) model. It captures the model’s dependence on all parameters relevant for history matching at high-order accuracy. Step 2 consists of matching the reduced model from step 1 to observation data via bootstrap filtering. Bootstrap filtering is a fully nonlinear and Bayesian statistical approach to the inverse problem in history matching. It allows to quantify post-calibration parameter and prediction uncertainty and is more accurate than ensemble Kalman filtering or linearized methods. Through this combination, we obtain a statistical method for history matching that is accurate, yet has a computational speed that is more than sufficient to be developed towards real-time application. We motivate and demonstrate our method on the problem of CO₂ storage in geological formations, using a low-parametric homogeneous 3D benchmark problem. In a synthetic case study, we update the parameters of a CO₂/brine multiphase model on monitored pressure data during CO₂ injection.  相似文献   

Carboniferous–Permian volcanic evolution in Central Europe—U/Pb ages of volcanic rocks in Saxony (Germany) and northern Bohemia (Czech Republic)     

Uwe Hoffmann  Christoph Breitkreuz  Karel Breiter  Sergey Sergeev  Klaus Stanek  Marion Tichomirowa 《International Journal of Earth Sciences》2013,102(1):73-99

Nine SHRIMP U/Pb ages on zircon and two Pb/Pb single zircon ages have been determined from Late Paleozoic volcanic rocks from Saxony and northern Bohemia. Samples came from the Teplice-Altenberg Volcanic Complex, the Meissen Volcanic Complex, the Chemnitz Basin, the Döhlen Basin, the Brandov-Olbernhau Basin, and the North Saxon Volcanic Complex. The Teplice-Altenberg Volcanic Complex is subdivided into an early Namurian phase (Mikulov Ignimbrite, 326.8 ± 4.3 Ma), thus older than assumed by previous studies, and a late caldera-forming phase (Teplice Ignimbrite, 308.8 ± 4.9 Ma). The age of the latter, however, is not well constrained due to a large population of inherited zircon and possible hydrothermal overprint. The Leutewitz Ignimbrite, product of an early explosive volcanic episode of the Meissen Volcanic Complex yielded an age of 302.9 ± 2.5 Ma (Stephanian A). Volcanic rocks intercalated in the Brandov-Olbernhau Basin (BOB, 302 ± 2.8 Ma), Chemnitz Basin (CB, 296.6 ± 3.0 Ma), Döhlen Basin (DB, 296 ± 3.0 Ma), and the North Saxon Volcanic Complex (NSVC, c. 300–290 Ma) yielded well-constrained Stephanian to Sakmarian ages. The largest Late Paleozoic ignimbrite-forming eruption in Central Europe, the Rochlitz Ignimbrite, has a well-defined middle Asselian age of 294.4 ± 1.8 Ma. Ages of palingenic zircon revealed that the Namurian-Westphalian magmatism assimilated larger amounts of crystalline basement that formed during previous Paleozoic geodynamic phases. The Precambrian inherited ages support the chronostratigraphic structure assumed for the Saxo-Thuringian Zone of the Variscan Orogen. The present results help to improve the chronostratigraphic allocation of the Late Paleozoic volcanic zones in Central Europe. At the same time, the radiometric ages have implications for the interbasinal correlation and for the geodynamic evolution of the Variscan Orogeny.  相似文献   

Effects of placer mining on suspended sediment budget: case study of north of Russia’s Kamchatka Peninsula     

Sergey R. Chalov 《水文科学杂志》2013,58(5):1081-1094

Abstract

Placer mines are located in river valleys, along river benches, or along the pathways of ancient channels. Open-pit mining alters the stream hydrology and enhances sediment transport. The present study focuses on sediment transport in the area of the platinum placer mining located at the north of Russia’s Kamchatka Peninsula (Seynav-Galmoenan placer deposits). Based on hydrological field investigations, a conceptual model was derived to assess anthropogenic effects on the total sediment budget of rivers. The model illustrates key processes controlling sediment dynamics in the Vyvenka River basin. Field work included water-discharge and sediment-load measurements, assessment of annual channel change in rivers in mining site areas, and evaluation of the relative importance of sediment sources and transport processes. In this study, we estimated total sediment delivery from opencast placer mining of 60 t year^-1; the annual mass wasting rate ranges from 2 to 5.5 kg m^-2 year^-1, which is three orders of magnitude higher than from non-mined streams. Mass wasting dominates surface erosion on the hillslopes and produces significant wastewater effluents; however, erosion of the artificially stratified channel reaches is the primary contributor to the annual sediment yield of the mined rivers (21.4%).