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91.
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海洋沉积物有机质碳氮稳定同位素(δ13C、δ15N)广泛用于有机质来源示踪、古生产力和古海洋环境重建。日本海沉积物δ13C和δ15N值一个显著特征是在末次冰盛期(LGM)同步负偏,但是对这一现象产生的原因以及他们的演化过程的认识仍然存在明显不足。在本研究中,我们详细调查了37 ka以来日本海中部LV53-23-1岩心沉积物δ13C和δ15N演化历史。结果显示,沉积物δ13C和δ15N分别介于-26.3‰至-22.5‰和1.6‰至6.1‰,低值出现在LGM(26.5~17 ka)暗色层状泥发育时期,指示较强的陆源输入贡献。在Heinrich冰阶1时期(17~14.5 ka),δ13C和δ15N快速正偏,表明日本海海洋环境发生了明显的转换,对应于对马海峡淹没及对马暖流入侵。14.5 ka之后,沉积物δ15N值恢复到5‰,与开阔大洋海水硝酸盐的δ15N值近似。我们采用二端员混合模型粗略地估算了有机质来源的相对贡献。LGM时期陆源有机质贡献介于65%至80%,14.5 ka以后海源有机质贡献介于60%至80%。除了增加的陆源有机质贡献以外,LGM时期沉积物δ15N亏损还涉及如下过程:(1)较高的含Fe沙尘供给提高日本海表层海洋生物固氮效率;(2)缺氧环境盛行减弱成岩作用对沉积物δ15N影响。37 ka以来,日本海沉积物δ13C和δ15N变化与有机质来源、营养盐的供给、表层生产力和沉积物氧化还原条件相关,实际受海平面和全球气候制约。  相似文献   
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The Late Paleozoic–Early Mesozoic Mongol-Okhotsk Ocean extended between the Siberian and Amur–North China continents.The timing and modalities of the oceanic closure are widely discussed.It is largely accepted that the ocean closed in a scissor-like manner from southwest to northeast(in modern coordinates),though the timing of this process remains uncertain.Recent studies have shown that both western(West Transbaikalia)and eastern(Dzhagda)parts of the ocean closed almost simultaneously at the Early–Middle Jurassic boundary.However,little information on the key central part of the oceanic suture zone is available.We performed U-Pb(LA-ICP-MS)dating of detrital zircon from wellcharacterized stratigraphic sections of the central part of the Mongol-Okhotsk suture zone.These include the initial marine and final continental sequences of the East Transbaikalia Basin,deposited on the northern Argun-Idemeg terrane basement.We provide new stratigraphic ages for the marine and continental deposits.This revised chronostratigraphy allows assigning an age of~165–155 Ma,to the collisionrelated flexure of the northern Argun-Idemeg terrane and the development of a peripheral foreland basin.This collisional process took place 5 to10 million years later than in the western and eastern parts of the ocean.We demonstrate that the northern Argun-Idemeg terrane was the last block to collide with the Siberian continent,challenging the widely supported scissor-like model of closure of the MongolOkhotsk Ocean.Different segments of the ocean closed independently,depending on the initial shape of the paleo continental margins.  相似文献   
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Forward dissolution rates of Na-Montmorillonite (Wyoming) SWy-2 smectite (Ca0.06Na0.56)[Al3.08Fe(III)0.38Mg0.54] [Si7.93 Al0.07]O20(OH)4 were measured at 25 °C in a mixed-flow reactor equipped with interior dialysis compartment (6-8 kDa membrane) as a function of pH (1-12), dissolved carbonate (0.5-10 mM), phosphate (10−5 to 0.03 M), and nine organic ligands (acetate, oxalate, citrate, EDTA, alginate, glucuronic acid, 3,4-dihydroxybenzoic acid, gluconate, and glucosamine) in the concentration range from 10−5 to 0.03 M. In organic-free solutions, the Si-based rates decrease with increasing pH at 1 ? pH ? 8 with a slope close to −0.2. At 9 ? pH ? 12, the Si-based rates increase with a slope of ∼0.3. In contrast, non-stoichiometric Mg release weakly depends on pH at 1 ? pH ? 12 and decreases with increasing pH. The empirical expression describing Si-release rates [R, mol/cm2/s] obtained in the present study at 25 °C, I = 0.01 M is given by
  相似文献   
95.
Io’s sublimation-driven atmosphere is modeled using the direct simulation Monte Carlo (DSMC) method. These rarefied gas dynamics simulations improve upon earlier models by using a three-dimensional domain encompassing the entire planet computed in parallel. The effects of plasma heating, planetary rotation, inhomogeneous surface frost, molecular residence time of SO2 on the exposed (non-volatile) rocky surface, and surface temperature distribution are investigated. Circumplanetary flow is predicted to develop from the warm dayside toward the cooler nightside. Io’s rotation leads to a highly asymmetric frost surface temperature distribution (due to the frost’s high thermal inertia) which results in circumplanetary flow that is not axi-symmetric about the subsolar point. The non-equilibrium thermal structure of the atmosphere, specifically vibrational and rotational temperatures, is also examined. Plasma heating is found to significantly inflate the atmosphere on both the dayside and nightside. The plasma energy flux causes high temperatures at high altitudes but plasma energy depletion through the dense gas column above the warmest frost permits gas temperatures cooler than the surface at low altitudes. A frost map (Douté, S., Schmitt, B., Lopes-Gautier, R., Carlson, R., Soderblom, L., Shirley, J., and the Galileo NIMS Team [2001]. Icarus 149, 107-132) is used to control the sublimated flux of SO2 which can result in inhomogeneous column densities that vary by nearly a factor of four for the same surface temperature. A short residence time for SO2 molecules on the “rock” component is found to smooth lateral atmospheric inhomogeneities caused by variations in the surface frost distribution, creating an atmosphere that looks nearly identical to one with uniform frost coverage. A longer residence time is found to agree better with mid-infrared observations (Spencer, J.R., Lellouch, E., Richter, M.J., López-Valverde, M.A., Jessup, K.L, Greathouse, T.K., Flaud, J. [2005]. Icarus 176, 283-304) and reproduce the observed anti-jovian/sub-jovian column density asymmetry. The computed peak dayside column density for Io assuming a surface frost temperature of 115 K agrees with those suggested by Lyman-α observations (Feaga, L.M., McGrath, M., Feldman, P.D. [2009]. Icarus 201, 570-584). On the other hand, the peak dayside column density at 120 K is a factor of five larger and is higher than the upper range of observations (Jessup, K.L., Spencer, J.R., Ballester, G.E., Howell, R.R., Roesler, F., Vigel, M., Yelle, R. [2004]. Icarus 169, 197-215; Spencer et al., 2005).  相似文献   
96.
The formation of Zr I and Zr II lines in stellar atmospheres under non-LTE conditions has been considered for the first time. A model zirconium atom has been composed using 148 Zr I levels, 772 Zr II levels, and the ground Zr III state. Non-LTE calculations have been performed for model atmospheres with T eff = 5500 and 6000 K, log g = 2.0 and 4.0, [M/H] = −3, −2, −1, 0. In the entire investigated range of parameters, the Zr I levels are shown to be underpopulated relative to their LTE populations in the line formation region. In contrast, the excited Zr II levels are overpopulated, while the ground state and lower excited levels of Zr II retain their LTE populations. Since the non-LTE effects cause the Zr I and Zr II spectral lines being investigated to weaken, the non-LTE corrections to the abundance derived from Zr I and Zr II lines are positive. For Zr II lines, they increase with decreasing metallicity and surface gravity up to 0.34 dex for the model with T eff = 5500, log g = 2.0, and [M/H] = −2. The non-LTE effects depend weakly on temperature. The non-LTE corrections for Zr I lines reach 0.33 dex for solar-metallicity models. Zr I and Zr II lines in the solar spectrum have been analyzed. The non-LTE zirconium abundances derived from lines in the two ionization stages are shown to agree between themselves within the error limits, while the LTE abundance difference is 0.28 dex. The zirconium abundance in the solar atmosphere (averaged over Zr I and Zr II lines) is log ɛZr,⊙ = 2.63 ± 0.07.  相似文献   
97.
Patterns in the spatial or temporal distribution of genotypes may be indicative of natural selection. Previous work on the woolly mammoth melanocortin-1 receptor (Mc1r) gene identified three polymorphic positions that suggest Pleistocene populations may have harboured both light- and dark-haired mammoths (Rompler et al., 2006, 313: 62). Here, we extend this work and present the first population-level analysis of a functional gene in an extinct species. We genotyped the Mc1r gene in 47 woolly mammoth samples excavated from sites across the central portion of the woolly mammoths’ former range to examine the extent of variation of this polymorphism through time and across space. Only one individual was found to be heterozygous, indicating that the frequency of the ‘light’ mutant allele was very low. We conclude that light-coloured woolly mammoths would have been very rare, and may even have been non-existent if the ‘light’ mutant allele was strongly selected against in its homozygotic form. With the increasing availability of large-scale sequencing technologies, population-level datasets capable of identifying local adaptation will become increasingly attainable.  相似文献   
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