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The δ18O and δ17O values of olivine from Kenna are 7.6 and 3.0%, respectively, relative to SMOW. These values are typical of ureilites which form a unique group on a δ17O -δ18O graph. The ureilites are related to, but not directly derived from, the anhydrous phases of C2 and C3 meteorites. The 18O/16O fractionation between pyroxene and olivine is 0.60, indicating a temperature of last equilibration of 1000 ± 100°C.  相似文献   
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We invert differential SdS-SS traveltime residuals measured from stacked waveforms and finite-frequency sensitivity kernels for topography on the 410- and 660-km discontinuities. This approach yields higher resolution images of transition zone thickness than previous stacking methods, which simply average/smooth over topographic features. Apparent structure measured using simple stacking is highly dependent upon the bin size of each stack. By inverting for discontinuity topography with a variety of bin sizes, we can more accurately calculate the true structure. The inverted transition zone model is similar to simple stack models with an average thickness of 242 km, but the lateral variations in thickness are larger in amplitude and smaller in scale. Fast seismic velocities in 3-D mantle models such as SB4L18 correlate with areas of thicker transition zone. The elongated curvilinear regions of thickened transition zone that occur near subduction zones are narrow and high amplitude, which suggests relatively little lateral spreading and warming of subducted lithosphere within the transition zone. The anomalously thin transition zone regions are laterally narrow, and not broadly continuous. If these variations in transition zone thickness are interpreted as thermal in nature, then this model suggests significant temperature variations on small lateral scales.  相似文献   
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Relationships between sedimentary diatom assemblages and lakewater pH values from 36 lakes and experimentally acidified Lake 223, in the Experimental Lakes Area, were analyzed. The relationships were used to assign diatoms in the 36 lakes into pH preference groupings. Based on their regional distribution Cyclotella stelligera and Tabellaria flocculosa strain IIIp were categorized as pH indifferent, in comparison to other areas were they have been categorized as acidophilic. Two models were then applied to calculate transfer coefficients which were used to calculate diatom-inferred pH values for Lake 223. Index B and a multiple linear regression of the pH groupings yielded similar correlations (r2 0.82 and 0.84 respectively, p=0.0001). The multiple linear regression inferred a pH of 5.36 for acidified Lake 223 compared to a measured pH of 5.46.  相似文献   
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A new use for a 2-dimensional position sensitive diode (PSD) is described. A duolateral PSD was used with a microchannel plate image intensifier as a proof-of-concept photon counting (event driven) imager for astronomical imaging and photometry. This produced an imager capable of counting 25–30 kcps over the astronomical bands B, V & R, with an overall efficiency of ∼19%.  相似文献   
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We determined the chlorine isotope composition of 16 Martian meteorites using gas source mass spectrometry on bulk samples and in situ secondary ion microprobe analysis on apatite grains. Measured δ37Cl values range from ?3.8 to +8.6‰. The olivine‐phyric shergottites are the isotopically lightest samples, with δ37Cl mostly ranging from ?4 to ?2‰. Samples with evidence for a crustal component have positive δ37Cl values, with an extreme value of 8.6‰. Most of the basaltic shergottites have intermediate δ37Cl values of ?1 to 0‰, except for Shergotty, which is similar to the olivine‐phyric shergottites. We interpret these data as due to mixing of a two‐component system. The first component is the mantle value of ?4 to ?3‰. This most likely represents the original bulk Martian Cl isotope value. The other endmember is a 37Cl‐enriched crustal component. We speculate that preferential loss of 35Cl to space has resulted in a high δ37Cl value for the Martian surface, similar to what is seen in other volatile systems. The basaltic shergottites are a mixture of the other two endmembers. The low δ37Cl value of primitive Mars is different from Earth and most chondrites, both of which are close to 0‰. We are not aware of any parent‐body process that could lower the δ37Cl value of the Martian mantle to ?4 to ?3‰. Instead, we propose that this low δ37Cl value represents the primordial bulk composition of Mars inherited during accretion. The higher δ37Cl values seen in many chondrites are explained by later incorporation of 37Cl‐enriched HCl‐hydrate.  相似文献   
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We conducted a petrologic study of apatite within 12 Martian meteorites, including 11 shergottites and one basaltic regolith breccia. These data were combined with previously published data to gain a better understanding of the abundance and distribution of volatiles in the Martian interior. Apatites in individual Martian meteorites span a wide range of compositions, indicating they did not form by equilibrium crystallization. In fact, the intrasample variation in apatite is best described by either fractional crystallization or crustal contamination with a Cl‐rich crustal component. We determined that most Martian meteorites investigated here have been affected by crustal contamination and hence cannot be used to estimate volatile abundances of the Martian mantle. Using the subset of samples that did not exhibit crustal contamination, we determined that the enriched shergottite source has 36–73 ppm H2O and the depleted source has 14–23 ppm H2O. This result is consistent with other observed geochemical differences between enriched and depleted shergottites and supports the idea that there are at least two geochemically distinct reservoirs in the Martian mantle. We also estimated the H2O, Cl, and F content of the Martian crust using known crust‐mantle distributions for incompatible lithophile elements. We determined that the bulk Martian crust has ~1410 ppm H2O, 450 ppm Cl, and 106 ppm F, and Cl and H2O are preferentially distributed toward the Martian surface. The estimate of crustal H2O results in a global equivalent surface layer (GEL) of ~229 m, which can account for at least some of the surface features on Mars attributed to flowing water and may be sufficient to support the past presence of a shallow sea on Mars' surface.  相似文献   
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