G.S. Henderson and D.R. Baker (eds): Synchrotron Radiation: Earth,Environmental and Material Sciences Applications. (Short Course Series Volume 30)     

Ian M. Steele 《Mineralium Deposita》2003,38(4):516-516

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Hydrogeochemical exploration for Mississippi valley-type deposits, Arkansas, U.S.A.     

Kenneth F. Steele  T.F. Dilday III 《Journal of Geochemical Exploration》1985,23(1):71-79

Three areas located in northern Arkansas, U.S.A., representing differing host rock and mineralization, were selected to investigate the usefulness of hydrogeochemical exploration for Mississippi Valley-type Pb-Zn mineralization. Despite the geologic differences among the areas, there were no great differences in groundwater chemistry and threshold values. Anomalous Pb concentrations, and also anomalous Zn concentrations to a lesser extent, are useful in detecting the Pb-Zn mineralized areas; however, specific deposits could not be located. Because of the low threshold values (about 20 μg/1) for Pb and Zn, spring water must be utilized in order to avoid plumbing contamination.  相似文献   

Tropospheric methane in the mid-latitudes of the Southern Hemisphere     

P. J. Fraser  M. A. K. Khalil  R. A. Rasmussen  L. P. Steele 《Journal of Atmospheric Chemistry》1984,1(2):125-135

Results of more than 800 new measurements of methane (CH₄) concentrations in the Southern Hemisphere troposphere (34–41° S, 130–150° E) are reported. These were obtained between September 1980 and March 1983 from the surface at Cape Grim, Tasmania, through the middle (3.5–5.5 km) to the upper troposphere (7–10 km). The concentration of CH₄ increased throughout the entire troposphere over the measurement period, adding further support to the view that CH₄ concentrations are currently increasing on a global scale. For data averaged vertically through the troposphere the rate of increase found was 20 ppbv/yr or 1.3%/yr at December 1981. In the surface CH₄ data a seasonal cycle with a peak to peak amplitude of approximately 28 ppbv is seen, with the minimum concentration occurring in March and the maximum in September–October. A cycle with the same phase as that seen at the surface, but with a significantly decreased amplitude, is apparent in the mid troposphere but no cycle is detected in the upper tropospheric data. The phase and amplitude of the cycle are qualitatively in agreement with the concept that the major sink for methane is oxidation by hydroxyl radicals. Also presented is evidence of a positive vertical gradient in methane, with a suggestion that the magnitude of this gradient has changed over the period of measurements.  相似文献   

The global distribution of methane in the troposphere   总被引：6，自引：0，他引：6  

L. P. Steele  P. J. Fraser  R. A. Rasmussen  M. A. K. Khalil  T. J. Conway  A. J. Crawford  R. H. Gammon  K. A. Masarie  K. W. Thoning 《Journal of Atmospheric Chemistry》1987,5(2):125-171

Methane has been measured in air samples collected at approximately weekly intervals at 23 globally distributed sites in the NOAA/GMCC cooperative flask sampling network. Sites range in latitude from 90° S to 76° N, and at most of these we report 2 years of data beginning in early 1983. All measurements have been made by gas chromatography with a flame ionization detector at the NOAA/GMCC laboratory in Boulder, Colorado. All air samples have been referenced to a single secondary standard of methane-in-air, ensuring a high degree of internal consistency in the data. The precision of measurements is estimated from replicate determinations on each sample as 0.2%. The latitudinal distribution of methane and the seasonal variation of this distribution in the marine boundary layer has been defined in great detail, including a remarkable uniformity in background levels of methane in the Southern Hemisphere. We report for the first time the observation of a complete seasonal cycle of methane at the South Pole. A significant vertical gradient is observed between a sea level and a high altitude site in Hawaii. Globally averaged background concentrations in the marine boundary layer have been calculated for the 2 year-period May 1983–April 1985 inclusive, from which we find an average increase of 12.8 ppb per year, or 0.78% per year when referenced to the globally averaged concentration (1625 ppb) at the mid-point of this period. We present evidence that there has been a slowing down in the methane growth rate.Presented at the Conference on the Scientific Application of Baseline Observations of Atmospheric Composition (SABOAC), Aspendale, Australia, 7–9 November 1984.  相似文献   

Pollution studies in the Clyde Sea area     

J.H. Steele  A.D. McIntyre  R. Johnston  I.G. Baxter  G. Topping  H.D. Dooley 《Marine pollution bulletin》1973,4(10):153-157

The Firth of Clyde on the west coast of Scotland is a major seaway and vacation area, it supports important commercial fisheries and receives domestic, industrial and agricultural wastes from a catchment area with a population of well over 2 million. The Department of Agriculture and Fisheries for Scotland has a continuing investigation of the area to keep track of the increasing threat of pollution, particularly to the fishing industry.  相似文献   

Saturn's satellites: Nuar-infrared spectrophotometry (0.6–2.5 μm) of the leading and trailing sides and compositional implications     

Roger N. Clark  Robert H. Brown  Pamela D. Owensby  Alex Steele 《Icarus》1984,58(2):265-281

Near-infrared spectra, 0.65–2.5 μm, are presented for Tethys, Dione, Rhea, Iapetus, and Hyperion. Water ice absorptions at 2.0, 1.5, and 1.25 μm are seen in the spectra of all five objects (except the 1.25-μm band was not detected in spectra of Hyperion) and the weak 1.04-μm ice absorption is detected on the leading and trailing sides of Rhea, and the trailing side of Dione. Upper limits to the 1.04-μm ice band depth are <0.3% for the leading side of Dione; <0.7% for the leading side of Iapetus, and the trailing side of Tethys; <1% on the trailing side of Iapetus; and <5% on the leading side of Tethys. The leading-trailing side ice band depth differences on Saturn's satellites are similar to those for the Galilean satellites, indicating possible surface modification by magnetospheric charged particle bombardment. Limits are determined for the amount of particulates, trapped gases, and amonium hydroxide on the surface. The surfaces of Saturn's satellites (except the dark side of Iapetus) are nearly pure water ice, with probably less than about 1 wt% particulate minerals. The ice could be clathrates with as much as a few weight percent trapped gases. The upper limit of amonium hydroxide depends on the spectral data precision and varies from ～ 1 wt% NH₃ for the leading side of Rhea to ～ 10 wt% NH₃ for Dione.  相似文献   

Fertile and barren AlCr-spinel harzburgites from the upper mantle: Ion and electron probe analyses of trace elements in olivine and orthopyroxene: Relation to lherzolites     

R.L. Hervig  J.V. Smith  I.M. Steele  J.B. Dawson 《Earth and Planetary Science Letters》1980,50(1):41-58

Ion and electron microprobe analyses of twenty-one CrAl-spinel harzburgite xenoliths from southern African kimberlites show two chemical groups. Orthopyroxenes from “fertile” harzburgites have higher CaO (mean of 11, 0.95 wt.%), Al₂O₃ (3.05 wt.%), Cr₂O₃ (0.85 wt.%) and Li (0.8 ppmw) than those from “barren” harzburgites (mean of 10, CaO 0.24 wt.%, Al₂O₃ 1.10 wt.%, Cr₂O₃ 0.35 wt.%, Li 0.3 ppmw). Olivines from all harzburgites have similar chemistry except that mean values of Li and Na are higher for barren than fertile harzburgites (Li 0.9 vs. 0.4 ppmw; Na₂O 16 vs. 7 ppmw). Orthopyroxenes from fertile harzburgites are chemically distinct from those in garne lherzolites from southern Africa and spinel lherzolites from southwest U.S.A., but orthopyroxenes from barren harzburgites are indistinguishable from those in many coarse garnet lherzolites.Chromium, Ca, Ni, Na and Li in coexisting olivines and orthopyroxenes from the above rock types show complex patterns, which for Ca, Cr and Ni can be related to pressure and temperature. Temperatures from an empirically calibrated thermometer based on Ni-Mg exchange between olivine and orthopyroxene, measured modes of harzburgites (fertile, mean of 10: ol 68, opx 31, spinel-silicate intergrowth <0.5; barren, mean of 8: ol 76, opx 23, spinel and spinel-silicate intergrowth 1), and high-pressure experimental studies suggest (a) that harzburgites are residues of partial melting, (b) that barren harzburgites were melted to a greater extent at a higher temperature (though probably at a similar depth) than fertile harzburgites, and (c) that incomplete reequilibration during retrograde metamorphism has led to development of complex inter- and intragranular textures, probably in the range ～700–900°C.  相似文献   

Mineralogy of the Ibitira eucrite and comparison with other eucrites and lunar samples     

I.M. Steele  J.V. Smith 《Earth and Planetary Science Letters》1976,33(1):67-78

Ibitira meteorite is interpreted as a strongly metamorphosed, unbrecciated, vesicular eucrite with a primary variolitic and secondary hornfelsic texture dominated by 60% pyroxene (bulk composition En₃₇Fs₄₈Wo₁₅ exsolved into lamellae several micrometers wide of augite En₃₂Fs₂₇Wo₄₁ and pigeonite En₄₀Fs₅₆Wo₄) and 30% plagioclase An₉₄ (mosaic extinction and variable structural state). Minor phases are 5% tridymite plates one-quarter occupied by plagioclase (An₉₄) inclusions; several percent intergrowths of ilmenite and Ti-chromite with trace kamacite Fe₉₉Co_0.5Ni_0.2 and narrow olivine (Fa₈₃) rims; one grain of low-Ti-chromite enclosed in tridymite; trace troilite with kamacite Fe₉₈Co_1.0Ni_0.9. Euhedral ilmenite, Ti-chromite, plagioclase and merrillite in vesicles indicate vapor deposition. These properties can be explained by a series of processes including at least the following: (1) igneous crystallization under pressure low enough to allow vesiculation, (2) prolonged metamorphism, perhaps associated with vapor deposition and reduction, to produce the coarse exsolution of the pyroxene and the coarse ilmenite-chromite intergrowths, (3) strong shock which affected the plagioclase and tridymite but not the pyroxene, (4) sufficient annealing to allow recrystallization of the plagioclase and tridymite, and partial conversion to the low structural state of the former.  相似文献   

Surface Reflectance Climate Data Records (CDRs) is a Reliable Landsat ETM+ Source to Study Chlorophyll Content in Pecan Orchards     

Yahia Othman  Caiti Steele  Rolston St. Hilaire 《Journal of the Indian Society of Remote Sensing》2018,46(2):211-218

We evaluated the relationships among three Landsat Enhanced Thematic Mapper (ETM+) datasets, top-of-atmosphere (TOA) reflectance, surface reflectance climate data records (surface reflectance-_CDR) and atmospherically corrected images using Fast Line-of-Sight atmospheric analysis of Spectral Hypercubes model (surface reflectance-_FLAASH) and their linkto pecan foliar chlorophyll content(chl-cont). Foliar chlorophyll content as determined with a SPAD meter, and remotely-sensed data were collected from two mature pecan orchards (one grown in a sandy loam and the other in clay loam soil) during the experimental period. Enhanced vegetation index derived from remotely sensed data was correlated to chl-cont. At both orchards, TOA reflectance was significantly lower than surface reflectance within the 550–2400 nm wavelength range. Reflectance from atmospherically corrected images (surface reflectance-_CDR and surface reflectance-_FLAASH) was similar in the shortwave infrared (SWIR: 1550–1750 and 2080–2350 nm) and statistically different in the visible (350–700 nm). Enhanced vegetation index derived from surface reflectance-_CDR and surface reflectance-_FLAASH had higher correlation with chl-cont than TOA. Accordingly, surface reflectance is an essential prerequisite for using Landsat ETM+  data and TOA reflectance could lead to miss-/or underestimate chl-cont in pecan orchards. Interestingly, the correlation comparisons (Williams t test) between surface reflectance-_CDR and chl-cont was statistically similar to the correlation between chl-cont and commercial atmospheric correction model. Overall, surface reflectance-_CDR, which is freely available from the earth explorer portal, is a reliable atmospherically corrected Landsat ETM+ image source to study foliar chlorophyll content in pecan orchards.  相似文献   

book review     

T.W. Steele 《Geostandards and Geoanalytical Research》1977,1(2):185-186

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