The Stubenberg meteorite—An LL6 chondrite fragmental breccia recovered soon after precise prediction of the strewn field          下载免费PDF全文

Addi Bischoff  Jean‐Alix Barrat  Kerstin Bauer  Christoph Burkhardt  Henner Busemann  Samuel Ebert  Michael Gonsior  Janina Hakenmüller  Jakub Haloda  Dennis Harries  Dieter Heinlein  Harald Hiesinger  Rupert Hochleitner  Viktor Hoffmann  Melanie Kaliwoda  Matthias Laubenstein  Colin Maden  Matthias M. M. Meier  Andreas Morlok  Andreas Pack  Alexander Ruf  Philippe Schmitt‐Kopplin  Maria Schönbächler  Robert C. J. Steele  Pavel Spurný  Karl Wimmer 《Meteoritics & planetary science》2017,52(8):1683-1703

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Carbon dioxide and methane in the Arctic atmosphere     

T. J. Conway  L. P. Steele 《Journal of Atmospheric Chemistry》1989,9(1-3):81-99

Fifty flask air samples were taken during April 1986 from a NOAA WP-3D Orion aircraft which flew missions across a broad region of the Arctic as part of the second Arctic Gas and Aerosol Sampling Program (AGASP II). The samples were subsequently analyzed for both carbon dioxide (CO₂) and methane (CH₄). The samples were taken in well-defined layers of Arctic haze, in the background troposphere where no haze was detected, and from near the surface to the lower stratosphere. Vertical profiles were specifically measured in the vicinity of Barrow, Alaska to enable comparisons with routine surface measurements made at the NOAA/GMCC observatory. Elevated levels of both methane and carbon dioxide were found in haze layers. For samples taken in the background troposphere we found negative vertical gradients (lower concentrations aloft) for both gases. For the entire data set (including samples collected in the haze layers) we found a strong positive correlation between the methane and carbon dioxide concentrations, with a linear regression slope of 17.5 ppb CH₄/ppm CO₂, a standard error of 0.6, and a correlation coefficient (r²) of 0.95. This correlation between the two gases seen in the aircraft samples was corroborated by in situ surface measurements of these gases made at the Barrow observatory during March and April 1986. We also find a similar relationship between methane and carbon dioxide measured concurrenty for a short period in the moderately polluted urban atmosphere of Boulder, Colorado. We suggest that the strong correlation between methane and carbon dioxide concentrations reflects a common source region for both, with subsequent long-range transport of the polluted air to the Arctic.  相似文献   

Experimentally determined dissolution kinetics of Na-rich borosilicate glass at far from equilibrium conditions: Implications for Transition State Theory     

Jonathan P. Icenhower  B. Peter McGrail  Eric M. Pierce  David K. Shuh  Jackie L. Steele 《Geochimica et cosmochimica acta》2008,72(12):2767-2788

The dissolution kinetics of five chemically complex and five chemically simple sodium silicate glass compositions (Na-Si±Al±B) were determined over a range of solution saturation values by varying the flow-through rates (1-100 mL/d) in a dynamic single-pass flow-through (SPFT) apparatus. The chemically complex borosilicate glasses are representative of prospective hosts for radioactive waste disposal and are characterized by relatively high molar Si/(Si + Al) and Na/(Al + B) ratios (>0.7 and >1.0, respectively). Analysis by X-ray absorption spectroscopy (XAS) indicates that the fraction of ^ivB to ⁱⁱⁱB (N₄) varies from 0.66 to 0.70. Despite large differences in bulk chemistry, values of δ²⁹Si peak shift determined by MAS-NMR varies only by about 7 ppm (δ²⁹Si = −94 to −87 ppm), indicating small differences in polymerization state for the glasses. Forward rates of reaction measured in dynamic experiments converge (average log₁₀ rate [40 °C, pH 9] = −1.87 ± 0.79 [g/(m² d)]) at high values of flow-rate (q) to sample surface area (S). Dissolution rates are independent of total Free Energy of Hydration (FEH) and this model appears to overestimate the impact of excess Na on chemical durability. For borosilicate glass compositions in which molar Na > Al + B, further addition of Na appears to stabilize the glass structure with respect to hydrolysis and dissolution. Compared to other borosilicate and aluminosilicate glasses, the glass specimens from this study dissolve at nearly the same rate (0-∼56×) as the more polymerized glasses, such as vitreous reedmergnerite (NaBSi₃O₈), albite, and silica. Dissolution of glass follows the order: boroaluminosilicate glass > vitreous reedmergnerite > vitreous albite > silica glass, which is roughly the same order of increasingly negative ²⁹Si chemical shifts. The chemical shift of ²⁹Si is a measure of the extent of bond overlap between Si and O and correlates with the forward rate of reaction. Thus, dissolution appears to be rate-limited by rupture of the Si-O bond, which is consistent with the tenants of Transition State Theory (TST). Therefore, dissolution at far from equilibrium conditions is dependent upon the speed of the rate-controlling elementary reaction and not on the sum of the free energies of hydration of the constituents of boroaluminosilicate glass.  相似文献   

Heterogeneous distribution of H2O in the Martian interior: Implications for the abundance of H2O in depleted and enriched mantle sources          下载免费PDF全文

Francis M. McCubbin  Jeremy W. Boyce  Poorna Srinivasan  Alison R. Santos  Stephen M. Elardo  Justin Filiberto  Andrew Steele  Charles K. Shearer 《Meteoritics & planetary science》2016,51(11):2036-2060

We conducted a petrologic study of apatite within 12 Martian meteorites, including 11 shergottites and one basaltic regolith breccia. These data were combined with previously published data to gain a better understanding of the abundance and distribution of volatiles in the Martian interior. Apatites in individual Martian meteorites span a wide range of compositions, indicating they did not form by equilibrium crystallization. In fact, the intrasample variation in apatite is best described by either fractional crystallization or crustal contamination with a Cl‐rich crustal component. We determined that most Martian meteorites investigated here have been affected by crustal contamination and hence cannot be used to estimate volatile abundances of the Martian mantle. Using the subset of samples that did not exhibit crustal contamination, we determined that the enriched shergottite source has 36–73 ppm H₂O and the depleted source has 14–23 ppm H₂O. This result is consistent with other observed geochemical differences between enriched and depleted shergottites and supports the idea that there are at least two geochemically distinct reservoirs in the Martian mantle. We also estimated the H₂O, Cl, and F content of the Martian crust using known crust‐mantle distributions for incompatible lithophile elements. We determined that the bulk Martian crust has ~1410 ppm H₂O, 450 ppm Cl, and 106 ppm F, and Cl and H₂O are preferentially distributed toward the Martian surface. The estimate of crustal H₂O results in a global equivalent surface layer (GEL) of ~229 m, which can account for at least some of the surface features on Mars attributed to flowing water and may be sufficient to support the past presence of a shallow sea on Mars' surface.  相似文献   

Erratum     

Richard Steele 《International journal of geographical information science》2013,27(6)

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Collapse risk of controlled rocking steel braced frames with different post‐tensioning and energy dissipation designs          下载免费PDF全文

Taylor C. Steele  Lydell D. A. Wiebe 《地震工程与结构动力学》2017,46(13):2063-2082

Controlled rocking steel braced frames (CRSBFs) are low‐damage self‐centring lateral force resisting systems. Previous studies have shown that designing the energy dissipation (ED) and post‐tensioning (PT) in CRSBFs using a response modification factor of R=8 can prevent collapse of structures during earthquakes beyond the design level. However, designers have unique control over the hysteretic behaviour of the system, even after the response modification factor is selected. Additionally, recent studies have suggested that CRSBFs could also be designed using R>8 while still satisfying performance limits. This paper examines how the response modification factor and the design of the ED and PT influence the collapse performance of CRSBFs with three and six storeys where collapse occurs because of over‐rotation of the base rocking joint. In addition, the influence of using an additional rocking joint above the base to mitigate higher‐mode forces is evaluated for a 12‐storey frame. A total of 18 different designs are considered for the three buildings using different ED and PT design parameters, including different response modification factors. A suite of 44 ground motions is scaled until at least 50% of the records cause collapse, and fragility curves are generated using the truncated incremental dynamic analysis curves. The results from two different assessment methodologies show that the parameters selected have a marked influence on the collapse performance of a CRSBF. Nevertheless, even CRSBFs designed using R>8 or without supplemental ED can have acceptably low probabilities of collapse, provided that the frame members are designed to remain elastic. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

The new 14C chronology for the Palaeolithic site of La Ferrassie,France: the disappearance of Neanderthals and the arrival of Homo sapiens in France     

S. Talamo  V. Aldeias  P. Goldberg  L. Chiotti  H. L. Dibble  G. Guérin  J.-J. Hublin  S. Madelaine  R. Maria  D. Sandgathe  T. E. Steele  A. Turq  S. J. P. Mcpherron 《第四纪科学杂志》2020,35(7):961-973

The grand abri at La Ferrassie (France) has been a key site for Palaeolithic research since the early part of the 20th century. It became the eponymous site for one variant of Middle Palaeolithic stone tools, and its sequence was used to define stages of the Aurignacian, an early phase of the Upper Palaeolithic. Several Neanderthal remains, including two relatively intact skeletons, make it one of the most important sites for the study of Neanderthal morphology and one of the more important data sets when discussing the Neanderthal treatment of the dead. However, the site has remained essentially undated. Our goal here is to provide a robust chronological framework of the La Ferrassie sequence to be used for broad regional models about human behaviour during the late Middle to Upper Palaeolithic periods. To achieve this goal, we used a combination of modern excavation methods, extensive geoarchaeological analyses, and radiocarbon dating. If we accept that Neanderthals were responsible for the Châtelperronian, then our results suggest an overlap of ca. 1600 years with the newly arrived Homo sapiens found elsewhere in France.  相似文献   

Creating a thinking space for the rising stars of Australian urban geography     

Dallas Rogers  Libby Porter  Wendy Steele  Donna Houston 《The Australian geographer》2019,50(2):141-143

The Institute of Australian Geographers Urban Study Group and Australian Geographer present the first essay in our Leading Insights/Thinking Space partnership. We discuss Dr Natalie Osborne's 2018 essay, flag Dr Marilu Melo's 2019 essay and talk about creating a thinking space for the rising stars of Australian urban geography.  相似文献   

The formation and aqueous alteration of CM2 chondrites and their relationship to CO3 chondrites: A fresh isotopic (O,Cd, Cr,Si, Te,Ti, and Zn) perspective from the Winchcombe CM2 fall     

R. C. Greenwood  R. Findlay  R. Martins  R. C. J. Steele  K. M. M. Shaw  E. Morton  P. S. Savage  M. E. Murphy  M. Rehkämper  I. A. Franchi  T. Elliott  M. D. Suttle  A. J. King  M. Anand  J. Malley  K. T. Howard  X. Zhao  D. Johnson  M.-C. Liu  K. A. McCain  N. R. Stephen 《Meteoritics & planetary science》2024,59(5):1170-1193

As part of an integrated consortium study, we have undertaken O, Cd, Cr, Si, Te, Ti, and Zn whole rock isotopic measurements of the Winchcombe CM2 meteorite. δ⁶⁶Zn values determined for two Winchcombe aliquots are +0.29 ± 0.05‰ (2SD) and +0.45 ± 0.05‰ (2SD). The difference between these analyses likely reflects sample heterogeneity. Zn isotope compositions for Winchcombe show excellent agreement with published CM2 data. δ¹¹⁴Cd for a single Winchcombe aliquot is +0.29 ± 0.04‰ (2SD), which is close to a previous result for Murchison. δ¹³⁰Te values for three aliquots gave indistinguishable results, with a mean value of +0.62 ± 0.01‰ (2SD) and are essentially identical to published values for CM2s. ε⁵³Cr and ε⁵⁴Cr for Winchcombe are 0.319 ± 0.029 (2SE) and 0.775 ± 0.067 (2SE), respectively. Based on its Cr isotopic composition, Winchcombe plots close to other CM2 chondrites. ε⁵⁰Ti and ε⁴⁶Ti values for Winchcombe are 3.21 ± 0.09 (2SE) and 0.46 ± 0.08 (2SE), respectively, and are in line with recently published data for CM2s. The δ³⁰Si composition of Winchcombe is −0.50 ± 0.06‰ (2SD, n = 11) and is essentially indistinguishable from measurements obtained on other CM2 chondrites. In conformity with petrographic observations, oxygen isotope analyses of both bulk and micromilled fractions from Winchcombe clearly demonstrate that its parent body experienced extensive aqueous alteration. The style of alteration exhibited by Winchcombe is consistent with relatively closed system processes. Analysis of different fractions within Winchcombe broadly support the view that, while different lithologies within an individual CM2 meteorite can be highly variable, each meteorite is characterized by a predominant alteration type. Mixing of different lithologies within a regolith environment to form cataclastic matrix is supported by oxygen isotope analysis of micromilled fractions from Winchcombe. Previously unpublished bulk oxygen isotope data for 12 CM2 chondrites, when combined with published data, define a well-constrained regression line with a slope of 0.77. Winchcombe analyses define a more limited linear trend at the isotopically heavy, more aqueously altered, end of the slope 0.77 CM2 array. The CM2 slope 0.77 array intersects the oxygen isotope field of CO3 falls, indicating that the unaltered precursor material to the CMs was essentially identical in oxygen isotope composition to the CO3 falls. Our data are consistent with earlier suggestions that the main differences between the CO3s and CM2s reflect differing amounts of water ice that co-accreted into their respective parent bodies, being high in the case of CM2s and low in the case of CO3s. The small difference in Si isotope compositions between the CM and CO meteorites can be explained by different proportions of matrix versus refractory silicates. CMs and COs may also be indistinguishable with respect to Ti and Cr isotopes; however, further analysis is required to test this possibility. The close relationship between CO3 and CM2 chondrites revealed by our data supports the emerging view that the snow line within protoplanetary disks marks an important zone of planetesimal accretion.  相似文献   

Hydrogeochemical exploration for barite, Ouachita Mountains, U.S.A.     

Kenneth F. Steele  George H. Wagner 《Journal of Geochemical Exploration》1983,19(1-3)

Approximately 100 springs were sampled as part of a general geochemical survey in a 130 by 140 km multi-mineralized area of the Ouachita Mountains. The study area was subdivided into Area I and Area II based on differences in lithology and mineralization. Area I is composed primarily of the Paleozoic Stanley Shale and the Arkansas Novaculite Formation, and has considerable manganese (often present as psilomelane) and barite mineralization. The barite occurs primarily as replacement deposits in shale in Area I. Area II is composed of Paleozoic and Cretaceous sedimentary rocks, and Quaternary alluvium. Mercury, antimony, strontium and barite mineralization is present. The barite mineralization occurs as cement in the Cretaceous sandstone and gravel in this area.The widely prevalent barite cement in Area II is reflected by higher median and upper range values of barium concentration and also higher median and threshold % BaSO₄ saturation values. The presence of barite as cement in the sediments of Area II tends to mask the detection of the barite deposits in this area. Approximately 83% of the sites within 1.7 km of known barite mineralization in Area I were characterized by anomalous barium concentration, and 67% within 3.4 km. Anomalous % BaSO₄ saturation values and Ba/Sr ratios produced success rates generally similar to those of anomalous barium concentrations. Anomalous strontium concentrations did not prove effective in detecting barite mineralization.  相似文献