Gas phase reactions of alkyl nitrates with hydroxyl radicals under tropospheric conditions in comparison with photolysis     

K. H. Becker  K. Wirtz 《Journal of Atmospheric Chemistry》1989,9(4):419-433

Rate constants for the reaction of OH radicals with some branched alkyl nitrates have been measured applying a competitive technique. Methyl nitrite photolysis in synthetic air was used as OH radical source at 295±2 K and 1000 mbar total pressure. Using a rate constant of 2.53×10^-12 cm³ s^-1 for the reaction of OH radicals with n-butane as reference, the following rate constants were obtained (units: 10^-12 cm³ s^-1): isopropyl nitrate, 0.59±0.22; isobutyl nitrate, 1.63±0.20; 3-methyl-2-butyl nitrate, 1.95±0.15; 2-methyl-1-butyl nitrate, 2.50±0.15; 3-methyl-1-butyl nitrate, 2.55±0.35. These values have been combined with the literature data to recalculate the substituent factors F(X) for the different nitrate groups which can be used to predict OH rate constants for organic nitrates for which experimental data are not available.Preliminary measurements of the photolysis frequency of isopropyl nitrate have shown that for this nitrate as a model substance, OH reactions and direct photolysis are of equal importance under tropospheric conditions.  相似文献   

Multiple Forward Scattering of Surface Waves: Comparison With an Exact Solution and Born Single-Scattering Methods   总被引：2，自引：0，他引：2  

Wolfgang Friederich  Erhard Wielandt  Stefan Stange 《Geophysical Journal International》1993,112(2):264-275

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Significance of the remotely sensed thermal infrared measurements obtained over a citrus orchard   总被引：1，自引：0，他引：1  

J.A. Sobrino  V. Caselles  F. Becker 《ISPRS Journal of Photogrammetry and Remote Sensing》1990,44(6)

In this work we have developed a theoretical model that helps the interpretation of the remotely sensed thermal infrared measurements carried out over citrus orchards. A detailed analysis of the different factors which take part in the definition of the effective emissivity and temperature (observation height, viewing angle, type of soil, dimensions and separation between orange trees) is made. The model was validated under vertical observation in a citrus orchard during seven nights. In this situation we have determined that the model performs to an accuracy of about 1%.  相似文献   

How does landfill leachate affect the chemical processes in a lake system downgradient from a landfill site?     

Thomas Striebel  Wolfgang Schäfer  Stefan Peiffer 《Aquatic Sciences - Research Across Boundaries》1991,53(4):346-366

A field study on the geochemical properties of a chemically-stressed limnic environment was performed in Lake Silbersee, which receives leachate water of high inorganic loading from an upgradient landfill site. The highly concentrated sulfate ion in groundwater, when entering the pore water system of the lake, gives rise to an intensive microbial sulfate reduction. A diagenetic approach was used to explain the existence of a marine-like aqueous system within a geologically slightly acidic aquifer, consisting of a well-buffered lake water and an alkalinity producing, excess sulphide containing sediment pore water system.  相似文献   

Book reviews     

Yukio Fujinawa  A. V. Koloskov  Gerardo G. Tango  Lech Stefaníak  Douglas R. Schmitt  Kei Katsumata  Vernon F. Cormier  Wladislaw Lyatsky  Krzysztof Haman  P. Vincent  Konrad Bajer  Henryk Piwkowski 《Pure and Applied Geophysics》1991,136(2-3):343-367

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Samarium-neodymium data on two late Proterozoic ophiolites of Saudi Arabia and implications for crustal and mantle evolution     

Stefan Claesson  John S. Pallister  Mitsunobu Tatsumoto 《Contributions to Mineralogy and Petrology》1984,85(3):244-252

Whole-rock and mineral samples from the Jabal al Wask and Jabal Ess ophiolites, northwestern Saudi Arabia, yield Sm-Nd isochron ages of 743+24 Ma and 782±38 Ma, respectively. These formation ages, which provide maximum limits for possible obduction ages, are in broad but not precise agreement with the previously known geologic history of the Arabian Shield. They indicate that the ophiolitic rocks are roughly coeval with nearby volcanic and plutonic rocks, supporting a back-arc origin for the two ophiolites. We suggest that the Jabal al Wask and Jabal Ess ophiolites were parts of the same northeast-southwest trending ophiolite belt, now offset along the Najd fault system. Initial _Nd values range from +6.6 to+ 7.6, indicating derivation from a mantle source that has been LIL-depleted for at least 2 Ga. Reported _Nd values from the Arabian Shield that are lower than this suggest the presence of older, reworked continental crust.  相似文献   

Measurements of Powder Snow Avalanches- Laboratory -     

Stefan Keller 《Surveys in Geophysics》1995,16(5-6):661-670

Laboratory simulation of powder snow avalanches serves for the validation of numerical models and as a tool in its own right for consulting and research purposes. Two-phase gravity currents are simulated in water with quartz powder or glass spheres as the particle phase. Particle-phase velocity profiles and particle-phase volume fraction profiles are measured with an ultrasonic device. The experimental setup and the current state of the measurement technique are described and preliminary results are presented.  相似文献   

Geochemical Indicators of Intrinsic Bioremediation   总被引：19，自引：0，他引：19  

Robert C. Borden  Carlos A. Gomez  Mark T. Becker 《Ground water》1995,33(2):180-189

A detailed field investigation has been completed at a gasoline-contaminated aquifer near Rocky Point, NC, to examine possible indicators of intrinsic bioremediation and identify factors that may significantly influence the rate and extent of bioremediation. The dissolved plume of benzene, toluene, ethylbenzene, and xylene (BTEX) in ground water is naturally degrading. Toluene and o-xylene are most rapidly degraded followed by m-, p-xylene, and benzene. Ethylbenzene appears to degrade very slowly under anaerobic conditions present in the center of the plume. The rate and extent of biodegradation appears to be strongly influenced by the type and quantity of electron acceptors present in the aquifer. At the upgradient edge of the plume, nitrate, ferric iron, and oxygen are used as terminal electron acceptors during hydrocarbon biodegradation. The equivalent of 40 to 50 mg/I of hydrocarbon is degraded based on the increase in dissolved CO₂ relative to background ground water. Immediately downgradient of the source area, sulfate and iron are the dominant electron acceptors. Toluene and o-xylene are rapidly removed in this region. Once the available oxygen, nitrate, and sulfate are consumed, biodegradation is limited and appears to be controlled by mixing and aerobic biodegradation at the plume fringes.  相似文献   

A komatiite component in Apollo 16 highland breccias: implications for the nickel-cobalt systematics and bulk composition of the moon     

A.E. Ringwood  Stefan Seifert  Heinrich Wnke 《Earth and Planetary Science Letters》1987,81(2-3)

The lunar crust at the Apollo 16 landing site contains substantial amounts of a “primitive component” in which the ferromagnesian group of elements is concentrated. The composition of this component can be retrieved via an analysis of mixing relationships displayed by lunar breccias. It is found to be a komatiite which is compositionally similar to terrestrial komatiites both in major and minor elements. The komatiite component of the lunar crust is believed to have formed by extensive degrees of melting of the lunar interior at depths greater than were involved in the formation of the lunar magma ocean which was parental to the crust. After formation of the anorthositic crust, it was invaded by extensive flows and intrusions of komatiite magma from these deeper source regions. The komatiites became intimately mixed with the anorthosite by intensive meteoroid impacts about 4.5 b.y. ago, thereby accounting for the observed mixing relationships displayed by the crust. The compositional similarity between lunar and terrestrial komatiites strongly implies a corresponding similarity between the compositions of their source regions in the lunar interior and the Earth's upper mantle. The composition of the lunar interior can be modelled more specifically by combining the komatiite composition with its liquidus olivine composition (as determined experimentally) in proportions chosen so as to produce a cosmochemically acceptable range of Mg/Si ratios for the bulk Moon. Except for higher FeO and lower Na₂O, the range of compositions thereby obtained for the bulk moon is very similar to the composition of the Earth's upper mantle.The effects of meteoritic contamination on the abundances of cobalt and nickel in lunar highland breccias were subtracted on the assumption that the contaminating projectiles were chondritic. The cobalt and nickel residuals thereby obtained were found to correlate strongly with the (Mg + Fe) content of the breccias, demonstrating that the Co and Ni are associated with the ferromagnesian component of the breccias and are genuinely indigenous to the Moon. The lunar highland Co and Ni residuals also display striking Ni/Co versus Ni correlations which follow a similar trend to those displayed by terrestrial basalts, picrites and komatiites. The lunar trends provide further decisive evidence of the indigenous nature of the Co and Ni residuals and suggest the operation of extensive fractionation controlled by olivine-liquid equilibria in producing the primitive component of the lunar breccias. Indigenous nickel abundances at the Apollo 14, 15 and 17 sites are much lower than at the Apollo 16 site, although rocks from all sites follow the same Ni/Co versus Ni trends. It is suggested that the primitive component at the Apollo 14, 15 and 17 sites was generally of basaltic composition, in contrast to the komatiitic nature of the Apollo 16 primitive component.  相似文献   

The non-linear seismic response of AGR core graphite brick slices—correlation of experimental and analytical results     

Khalid Ahmed  Stefan Stojko 《地震工程与结构动力学》1987,15(2):159-188

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