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61.
Semi-arid riparian woodlands face threats from increasing extractive water demand and climate change in dryland landscapes worldwide. Improved landscape-scale understanding of riparian woodland water use (evapotranspiration, ET) and its sensitivity to climate variables is needed to strategically manage water resources, as well as to create successful ecosystem conservation and restoration plans for potential climate futures. In this work, we assess the spatial and temporal variability of Cottonwood (Populus fremontii)-Willow (Salix gooddingii) riparian gallery woodland ET and its relationships to vegetation structure and climate variables for 80 km of the San Pedro River corridor in southeastern Arizona, USA, between 2014 and 2019. We use a novel combination of publicly available remote sensing, climate and hydrological datasets: cloud-based Landsat thermal remote sensing data products for ET (Google Earth Engine EEFlux), Landsat multispectral imagery and field data-based calibrations to vegetation structure (leaf-area index, LAI), and open-source climate and hydrological data. We show that at landscape scales, daily ET rates (6–10 mm day−1) and growing season ET totals (400–1,400 mm) matched rates of published field data, and modelled reach-scale average LAI (0.80–1.70) matched lower ranges of published field data. Over 6 years, the spatial variability of total growing season ET (CV = 0.18) exceeded that of temporal variability (CV = 0.10), indicating the importance of reach-scale vegetation and hydrological conditions for controlling ET dynamics. Responses of ET to climate differed between perennial and intermittent-flow stream reaches. At perennial-flow reaches, ET correlated significantly with temperature, whilst at intermittent-flow sites ET correlated significantly with rainfall and stream discharge. Amongst reaches studied in detail, we found positive but differing logarithmic relationships between LAI and ET. By documenting patterns of high spatial variability of ET at basin scales, these results underscore the importance of accurately accounting for differences in woodland vegetation structure and hydrological conditions for assessing water-use requirements. Results also suggest that the climate sensitivity of ET may be used as a remote indicator of subsurface water resources relative to vegetation demand, and an indicator for informing conservation management priorities.  相似文献   
62.
In this study, we investigated Fe and Li isotope fractionation between mineral separates of olivine pheno- and xenocrysts (including one clinopyroxyene phenocryst) and their basaltic hosts. Samples were collected from the Canary Islands (Teneriffa, La Palma) and some German volcanic regions (Vogelsberg, Westerwald and Hegau). All investigated bulk samples fall in a tight range of Li and Fe isotope compositions (δ56Fewr = 0.06–0.17‰ and δ7Lima = 2.5–5.2‰, assuming δ7Li of the olivine-free matrix is virtually identical to that of the bulk sample for mass balance reasons). In contrast, olivine phenocrysts display highly variable, but generally light Fe and mostly light Li isotope compositions compared to their respective olivine-free basaltic matrix, which was considered to represent the melt (with δ56Feol = ? 0.24 to 0.14‰ and δ7Liol = ? 10.5 to + 6.5‰, respectively). Single olivine crystals from one sample display even a larger range of δ56Feol between ? 0.7 and + 0.1‰. One single clinopyroxene phenocryst displays the lightest Li isotope composition (δ7Licpx = ? 17.7‰), but no Fe isotope fractionation relative to melt. The olivine phenocrysts show variable Mg# and Ni (correlated in most cases) that range between 0.89 and 0.74 and between 300 and 3000 μg/g, respectively. These olivines likely grew by fractional crystallization in an evolving magma. One sample from the Vogelsberg volcano contained olivine xenocrysts (Mg# > 0.89 and Ni > 3000 μg/g), in addition to olivine phenocrysts. This sample displays the highest Li- and the second highest Fe-isotope fractionation between olivine and melt (Δ7Liol-melt = ? 13; Δ56Feol-melt = ? 0.29).Our data, i.e. the variable olivine- at constant whole rock and matrix isotope compositions, strongly indicate disequilibrium, i.e. kinetic Fe and Li isotope fractionation between olivine and melt (for Li also between cpx and melt) during fractional crystallization. Δ7Liol-melt is correlated with the Li partitioning between olivine and melt (i.e. with Liol/Limelt), indicating Li isotope fractionation due to preferential (faster) diffusion of 6Li into olivine during fractional crystallization. Olivine with low Δ7Liol-melt, also have low Δ56Feol-melt, indicating that Fe isotope fractionation is also driven by diffusion of isotopically light Fe into olivine, potentially, as Fe–Mg inter-diffusion. The lowest Δ56Feol-melt (? 0.40) was observed in a sample from Westerwald (Germany) with abundant magnetite, indicating relatively oxidizing conditions during magma differentiation. This may have enhanced equilibrium Fe isotope fractionation between olivine and melt or fine dispersed magnetite in the basalt matrix may have shifted its Fe isotope composition towards higher δ56Fe. The decoupling of Li- and Fe isotope fractionation in cpx is likely due to faster diffusion of Li relative to Fe in cpx, implying that the large investigated cpx phenocryst resided in the magma for only a short period of time which was sufficient for Li- but not for Fe diffusion. The absence of any equilibrium Fe isotope fractionation between the investigated cpx phenocryst and its basaltic host may be related to the similar Fe3 +/Fe2 + of cpx and melt. In contrast to cpx, the generally light Fe isotope composition of all investigated olivine separates implies the existence of equilibrium- (in addition to diffusion-driven) isotope fractionation between olivine and melt, on the order of 0.1‰.  相似文献   
63.

Background

Reactive oxygen species (ROS) are vital regulators of many cellular functions in the body. The intracellular ROS concentration is highly regulated by a balance between pro-oxidants and anti-oxidants. A chronic excess of pro-oxidants leads to elevated ROS concentrations and inflammation, possibly initiating or enhancing disease onset. Mineral-induced generation of ROS, the role of minerals in upregulating cellular ROS, and their role in the development of several occupational diseases are now widely recognized. However, there is no standard protocol to determine changes in ROS production in cells after exposure to mineral dust or earth materials in general. In this study, a new method for determining the degree of cellular toxicity (i.e., cytotoxicity) of particles is described that will help bridge the gap in knowledge.

Results

By measuring the production of ROS and the viability of cells, an inflammatory stress response (ISR) indicator is defined. This approach normalizes the ROS upregulation with respect to the number of viable cells at the time of measurement. We conducted experiments on a series of minerals and soils that represent materials that are inert (i.e., glass beads, anatase, and a soil with low trace element content), moderately reactive (i.e., soil with high trace element content), and highly reactive (i.e., pyrite). Inert materials generated the lowest ISR, averaging 350% compared to the control. Acid washed pyrite produced the highest ISR (1,100 fold higher than the control). The measurements conducted as a function of time showed a complex response. Most materials showed an increase in ISR with particle loading.

Conclusions

The amount of cellularly generated ROS and cell viability combined provide a better understanding of particle-induced oxidative stress. The results indicate that some earth materials may solicit an initial burst of ROS, followed by a second phase in which cell viability decreases and ROS production increases, leading to a high ISR value. Hence, measurements conducted over a range of particle loading combined with multiple data measurements up to 24 hours can provide new insights in the possible effect of exposure to earth materials on human health.  相似文献   
64.
A GIS-based model framework, designed as a raster module for the Open Source software GRASS, was developed for simulating the mobilization and motion of debris flows triggered by rainfall. Designed for study areas up to few square kilometres, the tool combines deterministic and empirical model components for infiltration and surface runoff, detachment and sediment transport, slope stability, debris flow mobilization, and travel distance and deposition. The model framework was applied to selected study areas along the international road from Mendoza (Argentina) to Central Chile. The input parameters were investigated at the local scale. The model was run for a number of rainfall scenarios and evaluated using field observations and historical archives in combination with meteorological data. The sensitivity of the model to a set of key parameters was tested. The major scope of the paper is to highlight the capabilities of the model—and of this type of models in general—as well as its limitations and possible solutions.  相似文献   
65.
66.
The FORS Deep Field project is a multi-colour, multi-object spectroscopical investigation of a ∼ 7′ × ′' region near the south galactic pole based mostly on observations carried out with the FORS instruments attached to the VLT telescopes. It includes the QSO Q 0103-260 (z = 3.36). The goal of this study is to improve our understanding of the formation and evolution of galaxies in the young Universe. In this contribution, the photometric observations are presented. In particular, a combined B and I selected UBgRIJKs photometric catalog of 8753 objects in the FDF is presented and its content is briefly described. The formal 50% completeness limits for point sources, derived from the coadded images, are 25.64, 27.69, 26.86, 26.68, 26.37, 23.60 and 21.57in U, B, g, R, I, J and Ks, respectively. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   
67.
The distribution of barium and other elements related to biological productivity has been studied in two Palaeocene sections from the Middle East. In the bathyal Ben Gurion section, Israel, Ba* (= Ba/Al2O3× 15%) concentrations are low, in the range 0.04% to 0.3% in the lower Palaeocene, and very high, 1% to 2%, throughout most of the upper Palaeocene. In the neritic Gebel Aweina section in Egypt Ba* values are low, < 0.1%, throughout the entire Palaeocene. The Ba* enrichments at Ben Gurion and their correlations with increases in P2O5 and opaline silica, and local and global δ13C maxima, indicate that upwelling and high productivity were important in this region during the late Palaeocene. The absence of Ba* enrichments in the shallower Gebel Aweina section probably reflects the strong depth dependence of biobarium deposition. In the uppermost Palaeocene, at the level where the global benthic extinction event is registered, Ba* concentrations in the Ben Gurion section increase to anomalous 6%. which suggests that upwelling and possibly wind strengths intensified during this event. The results speak against deep-water formation in this region since downwelling and not upwelling is required.  相似文献   
68.
69.
In preparation of activities planned for the realization of the Global Geodetic Observing System (GGOS), a group of German scientists has carried out a study under the acronym GGOS-D which closely resembles the ideas behind the GGOS initiative. The objective of the GGOS-D project was the investigation of the methodological and information-technological realization of a global geodetic-geophysical observing system and especially the integration and combination of the space geodetic observations. In the course of this project, highly consistent time series of GPS, VLBI, and SLR results were generated based on common state-of-the-art standards for modeling and parameterization. These series were then combined to consistently and accurately compute a Terrestrial Reference Frame (TRF). This TRF was subsequently used as the basis to produce time series of station coordinates, Earth orientation, and troposphere parameters. In this publication, we present results of processing algorithms and strategies for the integration of the space-geodetic observations which had been developed in the project GGOS-D serving as a prototype or a small and limited version of the data handling and processing part of a global geodetic observing system. From a comparison of the GGOS-D terrestrial reference frame results and the ITRF2005, the accuracy of the datum parameters is about 5?C7?mm for the positions and 1.0?C1.5?mm/year for the rates. The residuals of the station positions are about 3?mm and between 0.5 and 1.0?mm/year for the station velocities. Applying the GGOS-D TRF, the offset of the polar motion time series from GPS and VLBI is reduced to 50 ??as (equivalent to 1.5?mm at the Earth??s surface). With respect to troposphere parameter time series, the offset of the estimates of total zenith delays from co-located VLBI and GPS observations for most stations in this study is smaller than 1.5?mm. The combined polar motion components show a significantly better WRMS agreement with the IERS 05C04 series (96.0/96.0???as) than VLBI (109.0/100.7???as) or GPS (98.0/99.5???as) alone. The time series of the estimated parameters have not yet been combined and exploited to the extent that would be possible. However, the results presented here demonstrate that the experiences made by the GGOS-D project are very valuable for similar developments on an international level as part of the GGOS development.  相似文献   
70.
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