The influence of salinity and flocculation upon the acquisition of remanent magnetization in some artificial sediments     

M. J. van  Vreumingen 《Geophysical Journal International》1993,114(3):607-614

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Oxidation state and electronic configuration determination of copper in tetrahedrite group minerals by L-edge X-ray absorption spectroscopy     

R. A. D. Pattrick  G. van der Laan  D. J. Vaughan  C. M. B. Henderson 《Physics and Chemistry of Minerals》1993,20(6):395-401

L-edge X-ray absorption spectroscopy employing a synchrotron radiation source has been used to study the electronic structure and valency of Cu in the chemically and structurally complex tetrahedrite group of minerals. Mechanical mixtures of Cu²⁺O and Cu⁺FeS₂ were used to estimate the relative cross sections of Cu²⁺ and Cu⁺; the absorption of Cu²⁺ at 931 eV is 25 times greater than that of Cu⁺ at 945 eV. Using this calibration, Cu²⁺/Cu ratios were found to vary from 0.00 to 0.054 in the tetrahedrite samples studied; the highest proportion of Cu²⁺ occurs in synthetic tetrahedrites with a composition close to Cu₁₂Sb₄S₁₃. This study reveals the utility of the technique for determining the valence state of copper in complex minerals, allowing the crystal chemistry to be more fully characterised.  相似文献   

Hydrophobic and electrostatic parameters in bacterial adhesion   总被引：5，自引：0，他引：5  

Mark C. M. van Loosdrecht  Willem Norde  Johannes Lyklema  Alexander J. B. Zehnder 《Aquatic Sciences - Research Across Boundaries》1990,52(1):103-114

Recently it has been shown that the initial stages of bacterial adhesion to a model-surface of sulphated polystyrene can best be described using hydrophobic and electrostatic parameters. In the present study it is tested whether these parameters can generally be applied to predict bacterial adhesion by using (i) glass, as a model for hydrophilic and natural surfaces of silicates and oxides, (ii) polystyrene coated with proteins, as a model for a surface coated with an organic layer, and (iii) river Rhine sediment, as an example of a natural surface. Adhesion to glass was dominated by electrostatic interaction, whereas adhesion to polystyrene coated with various types of proteins depended on the surface characteristics of the bacteria and the type of protein. By relating Van der Waals interactions to hydrophobicity of the interacting species, the adhesion of bacteria to the various surfaces including the river Rhine sediments could be interpreted in terms of the DLVO-theory. It is therefore concluded that the conceptual principles of the DLVO-theory (interplay of Van der Waals and electrostatic interactions) are suitable to describe, at least qualitatively, the initial processes of bacterial adhesion to a wide range of surfaces.  相似文献   

Sediment yield in South Africa — A preliminary geographical analysis     

Kim Boucher  Alex van Breda Weaver Dr. 《GeoJournal》1991,23(1):7-17

The study examines the spatial relationships between sediment yield and 15 independent environmental variables in 54 catchments in South Africa. Rooseboom's (1978) data on the sediment yield from the catchments were standardized for a single time period. Bivariate regression analyses reveal no simple relationships. Multivariate regression analyses conducted for the whole and various sub-areas of South Africa indicate that latitude and longitude are the primary variables affecting spatial variations in sediment yield. This may be as a result of latitude and longitude being surrogate variables reflecting variation in other environmental variables (e. g. geology, vegetation). Within the sub-areas, 43.4% to 97.8% of the variation in sediment yield is explained by the combined variation in a number of different environmental variables. This study highlights a need for the collection and analysis of more sediment yield data, which would allow the analyses to be refined, to predict sediment yields from ungauged catchments in South Africa.  相似文献   

Remote sensing of substances in water     

Heinz van der Piepen Dr.  Roland Doerffer Dr. 《GeoJournal》1991,24(1):27-48

Remote sensing of water colour and its application to the mapping of pigments, suspended matter and other substances by means of airborne and spaceborne sensors is discussed. After an introduction to the physical process involved, the methods for a quantitative interpretation especially of CZCS data are indicated. Applications towards the monitoring of coastal pollution, of algae blooms and of dynamic processes are shown by means of selected examples. Multispectral scanner and imaging spectrometer technologies are discussed with special reference to NASA's Earth Observation System and ESA's Earth Observation Programme.  相似文献   

Chronostratigraphy and paleoclimatic meaning of cryogenic deformations in the Central European loess     

Brigitte van Vliet-Lanoë Dr. 《GeoJournal》1991,24(2):157-163

Cryoturbations in loess reflect cold and wet environments but not necessarily permafrost. Only flat bottomed cryoturbations are indicative of it. Outside the permafrost zone they occur during the wet period of the last glaciation: during the early Weichselian, the lower pleniglacial, the end of the middle pleniglacial and the late glacial. Their morphology ist related to the frost susceptibility of the superimposed layers, expressed in form of differential frost heaving, ruled by the drainage quality and the frost susceptibility gradient. Their diagenesis is discussed.  相似文献   

Marble mylonites in the Bancroft shear zone, Ontario, Canada: microstructures and deformation mechanisms     

van der Pluijm Ben A. 《Journal of Structural Geology》1991,13(10)

Mylonitization of medium-grade marbles in the Bancroft shear zone, Ontario, Canada, is characterized by decreasing grain-size of both calcite and graphite, and a variety of textures. Calcite grain-sizes vary from several millimeters in the protolith, to 50–200 μm in mylonite, to <30 μm in ultramylonite. Corresponding calcite grain shapes are equant in the protolith, elongate in protomylonite (first-developed dimensional preferred orientation), equant in coarse mylonite, elongate in fine mylonite (second-developed dimensional preferred orientation) and generally equant in ultramylonite, which suggests that external energy (applied stress) that tends to elongate grains competed with internal energy sources (e.g. distortional strain) that favor equant shapes. Graphite grain-size changes from several millimeters to centimeters in the protolith to submicroscopic in ultramylonite. In the mylonitic stages, graphite is present as dark bands, while in the ultramylonitic stage it is preserved as a fine coating on calcite grains.Based on textural evidence, twinning (exponential creep; regime I), dynamic recrystallization (power law creep; regime II) and possibly grain boundary sliding superplasticity (regime III) are considered the dominant deformation mechanisms with increasing intensity of mylonitization; their activity is largely controlled by calcite grain-size. Calcite grain-size reduction occurred predominantly by the process of rotation recrystallization during the early stages of mylonitization, as indicated by the occurrence of core and mantle or mortar structures, and by the grain-size of subgrains and recrystallized grains. Grain elongation in S-C structures indicates the activity of migration recrystallization; these structures are not the result of flattening of originally equant grains. Differential stress estimates in coarse mylonites and ultramylonites, based on recrystallized grain-size, are 2–5 and 14–38 MPa, respectively. Initial grain-size reduction of graphite occurred by progressive separation along basal planes, analogous to mica fish formation in quartzo-feldspathic mylonites.Calcite-graphite thermometry on mylonitic and ultramylonitic samples shows that the metamorphic conditions during mylonitization were 475 ± 50°C, which, combined with a differential stress value of 26 MPa, gives a strain rate of 1.2 x 10⁻¹⁰s⁻¹ based on constitutive equations; corresponding displacement rates are <38 mmyr⁻¹.  相似文献   

The first and the second e of the extreme value distribution,EV1     

M. A. J. van Montfort  A. Otten 《Stochastic Environmental Research and Risk Assessment (SERRA)》1991,5(1):69-76

In the peak over threshold model resulting in the Extreme-value distribution, type I, (EV1) the firste of the distribution function is based on the Poisson number of exceedances, and the seconde arises from the Exponentially distributed magnitudes.This paper, on the one hand, generalises the Poisson model to the (positive and negative) Binomial distribution, and, on the other hand, the Exponential distribution is generalised to the Generalised Pareto distribution. Lack of fit with respect to the Poisson and Exponential distribution is measured by statistics derived from those which would be locally most powerful if the estimates of the location and scale parameter were equal to the true parameter values. Ways of combining both statistics are discussed.  相似文献   

Verschmutzungen durch alkylierte Phenole in der Deutschen Bucht     

Dr. Norbert Theobald  Dr. Gerhard Dahlmann  Stephan Dick 《Ocean Dynamics》1991,44(5-6):345-360

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Long-range weather forecasts through numerical and empirical methods     

H. M. van den Dool 《Dynamics of Atmospheres and Oceans》1994,20(3)

There has been much improvement in numerical weather prediction since L.F. Richardson (1922, Weather Prediction by Numerical Process, Cambridge University Press, Cambridge, p. 236) wrote his famous book. NWP has primarily been successful in improving day-by-day forecasts starting from an observed detailed Initial Condition (IC) out to about a week. The purpose of this paper is to discuss first the state of the art in long-range NWP by presenting results of a new large numerical experiment (named DERF90; from Dynamical Extended Range Forecasting in 1990 out to 90 days) conducted at the National Meteorological Center (NMC) during the summer and autumn of 1990 (Section 2). One hundred and twenty eight 90-day global forecasts were made from successive daily initial conditions (IC), thus giving us ample opportunity to assess skill of forecasts at lead times beyond 1 week.We then move on to define the notion of a limit of predictability (LOP), and following a procedure by Lorenz (1982), give a numerical estimate of the LOP using the DERF90 data set. We then produce a list of reasons, as to why this estimate (LOP = 18 days) should not be taken too literally. In particular, we argue that the LOP varies as a function of the flow itself, and it would be (much) larger if we had, as we will ultimately, a coupled ocean-atmosphere model for making long-lead forecasts. Last, but not least, we present results of empirical forecasts that point to modest but significant skill well beyond the traditional LOP (a few weeks).A specific recent example of empirical forecasting is discussed. Through Canonical Correlation Analysis (CCA), experimental forecasts are being made for the United States surface temperatures at lead times of several seasons. While modest, the skill is significant in that it defies the existence or a 3-week LOP, and so demonstrates the potential for model improvements.  相似文献