AbstractThe characteristics and distribution of clay minerals and their effects on reservoir quality in the Huagang sandstones in the Xihu Sag, East China Sea Basin were studied by using X-ray diffraction, casting thin-sections, scanning electron microscopy, electron microprobe analysis, fluid inclusion analysis, constant-rate mercury injection and nuclear magnetic resonance. Clay minerals consist of kaolinite, chlorite, illite and illite–smectite mixed layer (I/S); kaolinite forms from dissolved feldspars, chlorite occurs as clay coatings that are transformed from clay precursors owing to the flocculation of suspended detrital clays or the crystallisation of pore fluids, and illite forms from the illitisation of detrital smectite, authigenic kaolinite and K-feldspars. Clay distribution is controlled by sedimentary environments, burial history and lithologies. Typical reservoirs in the western sub-sag are thin and developed in braided river facies at relatively shallow burial depths with clays dominated by kaolinite. However, typical reservoirs in the central inversion tectonic zone are thicker and developed in a braided delta front facies at deeper burial depths with clays mainly consisting of chlorite, illite and I/S. High-quality reservoirs are characterised by coarse granularity, high quartz content and low clay content with widespread development of chlorite coatings that inhibit quartz cements at low temperatures. At higher temperatures, the high-quality reservoirs develop more pores providing growth space for quartz cements and result in the coexistence of chlorite coatings and quartz cements. The high-quality reservoirs are controlled by their lithological characteristics rather than chlorite coatings. Illite and I/S clays create severe damage to reservoirs by reducing the size and connectivity of pore-throats. 相似文献
In this paper, we study theoretically and experimentally the coherent control of non-resonant two-photon transition in a molecular system (Perylene dissolved in chloroform solution) by shaping the femtosecond pulses with simple phase patterns (cosinusoidal and π phase step-function shape). The control efficiency of the two-photon transition probability is correlated with both the laser field and the molecular absorption bandwidth. Our results demonstrate that, the two-photon transition probability in a molecular system can be reduced but not completely eliminated by manipulating the laser field, and the control efficiency is minimal when the molecular absorption bandwidth is larger than twice the laser spectral bandwidth. 相似文献
The late-Paleozoic mafic volcanic rocks occurring in the surrounding areas of the Gonghe basin are distributed in the A’nyêmaqên ophiolite zone, Zongwulong tectonic zone and Kuhai-Saishitang volcanic zone. The mafic volcanics in the A’nyêmaqên zone formed an ancient ridge-centered hotspot around the Majixueshan OIB, the Kuhai-Saishitang mafic rocks consist of E-MORB and continental rift basalts and the Zongwulong volcanic rocks are enriched N-MORB. The regionally low Nb/U and Ce/Pb ratios reflect the influence of the OIB material on the mafic magma source. From geochemistry, spatial distribution and tectonic relationship of the mafic rocks, an ancient triple-junction centered at the Majixueshan can be inferred. The existence of the Kuhai-Saishitang aulacogen may have provided a tectonic channel for the Majixueshan OIB materials metasomatizing the magma source for the Zongwulong rocks. The formation of the triple-junction and the rifting of the Zongwulong zone have separated the orogens and massifs in the region.
Estuaries are elementary geochemical fronts where river water and seawater mix. Within this mixing zone, iron and other non-conservative
elements can undergo complex reactions to form new solid phases. In order to understand authigenic iron oxide formation in
the Yangtze River Estuary, two onsite water-mixing sets of experiments were conducted, one by mixing variable amounts of unfiltered
Yangtze River water with filtered East China Sea water of different salinity (set 1), the other by mixing variable amounts
of filtered Yangtze River water with filtered East China Sea water of different salinity (set 2). In set 2, the minerals newly
formed in the course of mixing were investigated by means of a scanning electron microscope fitted with an energy-dispersive
X-ray analytical system. It was found that ferrihydrite and lepidocrocite were formed in these mixing experiments, coexisting
in nearly equal amounts. These iron oxides appear as aggregated particles with a large grain-size range of several microns
to more than 100 μm. The electrolytic properties of seawater played an important role in the formation of these authigenic
iron oxides. Kaolinite and organic aggregates were also found in the experimentally mixed pre-filtered waters. Amounts of
newly formed suspended matter (set 2) were one to three orders of magnitude lower than those of total suspended matter (TSM)
(set 1). This implies that newly formed minerals represent only a very small proportion of TSM in the estuarine mixing zone
of the Yangtze River. 相似文献