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Moore  M. H.  Hudson  R. L.  Ferrante  R. F. 《Earth, Moon, and Planets》2003,92(1-4):291-306
Near the inner edge of the Edgeworth-Kuiper Belt (EKB) are Pluto and Charon, which are known to have N2- and H2O-dominated surface ices, respectively. Such non-polar and polar ices, and perhaps mixtures of them, also may be present on other trans-Neptunian objects. Pluto, Charon, and all EKB objects reside in a weak, but constant UV-photon and energetic ion radiation environment that drives chemical reactions in their surface ices. Effects of photon and ion processing include changes in ice composition, volatility, spectra, and albedo, and these have been studied in a number of laboratories. This paper focuses on ice processing by ion irradiation and is aimed at understanding the volatiles, ions, and residues that may exist on outer solar system objects. We summarize radiation chemical products of N2-rich and H2O-rich ices containing CO or CH4, including possible volatiles such as alcohols, acids, and bases. Less-volatile products that could accumulate on EKB objects are observed to form in the laboratory from acid-base reactions, reactions promoted by warming, or reactions due to radiation processing of a relatively pure ice (e.g., CO → C3O2). New IR spectra are reported for the 1–5 mu;m region, along with band strengths for the stronger features of carbon suboxide, carbonic acid, the ammonium and cyanate ions, polyoxymethylene, and ethylene glycol. These six materials are possible contributors to EKB surfaces, and will be of interest to observers and future missions.  相似文献   
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We present the results of the preliminary study of the comet Hale-Bopp spectrum obtained April 17, 1997 by K. Churyumov and F. Mussayev with the help of the 1-meter Zeiss reflector and the echelle spectrometer (spectral resolutionλ/Δ λ ≈ 50000), CCD and the long slit, oriented along the radius-vector(“Sun-comet direction”). Energy distributions for three selected regions including the C3, C2 (0-0) and CN(Δ ν = 0) molecules emissions of the comet Hale-Bopp spectrum were built. The rotational lines of the CN(Δ ν = 0) band were identified. The nature of the high emission peak near λ 4020 Å in the C3 band is discussed. The presence of the cometary continuum of the nonsolar origin is assumed.  相似文献   
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 The mean state of the tropical atmosphere is important as the nature of the coupling between the ocean and the atmosphere depends nonlinearly on the basic state of the coupled system. The simulation of the annual cycle of the tropical surface wind stress by 17 atmospheric general circulation models (AGCMs) is examined and intercompared. The models considered were part of the Atmospheric Model Intercomparison Project (AMIP) and were integrated with observed sea surface temperature (SST) for the decade 1979–1988. Several measures have been devised to intercompare the performance of the 17 models on global tropical as well as regional scales. Within the limits of observational uncertainties, the models under examination simulate realistic tropical area-averaged zonal and meridional annual mean stresses. This is a noteworthy improvement over older generation low resolution models which were noted for their simulation of surface stresses considerably weaker than the observations. The models also simulate realistic magnitudes of the spatial distribution of the annual mean surface stress field and are seen to reproduce realistically its observed spatial pattern. Similar features are observed in the simulations of the annual variance field. The models perform well over almost all the tropical regions apart from a few. Of these, the simulations over Somali are interesting. Over this region, the models are seen to underestimate the annual mean zonal and meridional stresses. There is also wide variance between the different models in simulating these quantities. Large model-to-model variations were also seen in the simulations of the annual mean meridional stress field over equatorial Indian Ocean, south central Pacific, north east Pacific and equatorial eastern Pacific oceans. It is shown that the systematic errors in simulating the surface winds are related to the systematic errors in simulating the Inter-Tropical Convergence Zone (ITCZ) in its location and intensity. Weaker than observed annual mean southwesterlies simulated by most models over Somali is due to weaker than observed southwesterlies during the Northern Hemisphere summer. This is related to the weaker than observed land precipitation simulated by most models during the Northern Hemisphere summer. The diversity in simulation of the surface wind over Somali and equatorial Indian ocean is related to the diversity of AGCMs in simulating the precipitation zones in these regions. Received: 2 August 1996 / Accepted: 7 February 1997  相似文献   
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In urban environments, one major concern with deep excavations in soft clay is the potentially large ground deformations in and around the excavation. Excessive movements can damage adjacent buildings and utilities. There are many uncertainties associated with the calculation of the ultimate or serviceability performance of a braced excavation system. These include the variabilities of the loadings, geotechnical soil properties, and engineering and geometrical properties of the wall. A risk‐based approach to serviceability performance failure is necessary to incorporate systematically the uncertainties associated with the various design parameters. This paper demonstrates the use of an integrated neural network–reliability method to assess the risk of serviceability failure through the calculation of the reliability index. By first performing a series of parametric studies using the finite element method and then approximating the non‐linear limit state surface (the boundary separating the safe and ‘failure’ domains) through a neural network model, the reliability index can be determined with the aid of a spreadsheet. Two illustrative examples are presented to show how the serviceability performance for braced excavation problems can be assessed using the reliability index. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
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