Hydration of rhyolitic glass during weathering as characterized by IR microspectroscopy   总被引：1，自引：0，他引：1  

Tadashi Yokoyama  Satoshi Okumura  Satoru Nakashima 《Geochimica et cosmochimica acta》2008,72(1):117-125

The mechanism and rate of hydration of rhyolitic glass during weathering were studied. Doubly polished thin sections of two rhyolites with different duration of weathering (Ohsawa lava: 26,000 yr, Awanomikoto lava: 52,000 yr) were prepared. Optical microscope observation showed that altered layers had developed along the glass surfaces. IR spectral line profile analysis was conducted on the glass sections from the surface to the interior for a length of 250 μm and the contents of molecular H₂O (H₂O_m), OH species (OH) and total water (H₂O_t) were determined. The diffusion profile of H₂O_m in Ohsawa lava extends beyond the layer observed by optical microscope. The content of H₂O_m in the hydrated region is much higher than that of OH species. Thus, the reaction from H₂O_m to OH appears to be little and H₂O_m is the dominant water species moving into the glass during weathering. Based on the concentration profiles, the diffusion coefficients of H₂O_m(D_H2Om) and H₂O_t(D_H2Ot) were determined to be 2.8 × 10⁻¹⁰ and 3.4 × 10⁻¹⁰ μm² s⁻¹ for Ohsawa lava, and 5.2 × 10⁻¹¹ and 4.1 × 10⁻¹¹ μm² s⁻¹ for Awanomikoto lava, respectively. The obtained D_H2Om during weathering are more than 2-3 orders of magnitude larger than the diffusion coefficient at ∼20 °C that is extrapolated from the diffusivity data for >400 °C. This might suggest that the mechanism of water transport is different at weathering conditions and >400 °C.  相似文献   

Direct correlation of radiolarian <Emphasis Type="Italic">Kilinora spiralis</Emphasis> Zone with the Late Jurassic ammonite faunal succession in the Kurisaka Formation,Kurosegawa Terrane,SW Japan     

Keisuke Ishida  Yasuyuki Tsujino  Takeshi Kozai  Tadashi Sato  Francis Hirsch 《中国科学D辑(英文版)》2009,52(12):1910-1923

The last appearance datum of the radiolarian Kilinora spiralis is recorded above the first appearance datum of the ammonite Ataxioceras (A.) kurisakense in the Todoro Section of the Kurisaka Formation, Southern Kurosegawa Terrane, Shikoku, SW Japan. The constraint by ammonite age prolongs the range of the Kilinora spiralis Zone, a remarkable Jurassic radiolarian zone in Japan-NW Pacific region, into the lower Kimmeridgian. The direct correlation of the Kilinora spiralis zone with the Late Jurassic ammonite faunal succession in the Kurisaka Formation will provide a clue to the still pending chronological difference between European and North American radiolarian zones.  相似文献   

Encystment and excystment of <Emphasis Type="Italic">Gyrodinium instriatum</Emphasis> Freudenthal et Lee     

Tomoyuki Shikata  Sou Nagasoe  Tadashi Matsubara  Yasuhiro Yamasaki  Yohei Shimasaki  Yuji Oshima  Takuji Uchida  Ian R. Jenkinson  Tsuneo Honjo 《Journal of Oceanography》2008,64(3):355-365

In the present study, we have investigated the conditions influencing encystment and excystment in the dinoflagellate Gyrodinium instriatum under laboratory conditions. We incubated G. instriatum in modified whole SWM-3 culture medium and in versions of modified SWM-3 from which NO₃ ⁻, PO₄ ³⁻, NO₃ ⁻ + PO₄ ³⁻, or Si had been omitted and observed encystment. Percentage encystment was high in the media without N and without P, while the percentage encystment in the medium lacking both N and P was highest. Moreover, to investigate N or P concentration which induced the encystment, Gyrodinium instriatum was also incubated in media with different concentrations of inorganic N and P; the concentrations of NO₂ ⁻ + NO₃ ⁻ and PO₄ ³⁻ were measured over time. The precursors of cysts appeared within 2 or 3 days of a decrease in NO₂ ⁻ + NO₃ ⁻ or PO₄ ³⁻ concentration to values lower than 1 μM or 0.2 μM, respectively. When cysts produced in the laboratory were incubated, we observed excystment after 8–37 days, without a mandatory period of darkness or low temperature. We incubated cysts collected from nature at different temperatures or in the dark or light and observed excystments. Natural cysts excysted at temperatures from 10 to 30°C, in both light and dark, but excystment was delayed at low temperatures. These studies indicate that G. instriatum encysts in low N or P concentration and excysts over a wide temperature range, regardless of light conditions, after short dormancy periods.  相似文献   

Gradient field of undersea sound speed structure extracted from the GNSS-A oceanography     

Yokota  Yusuke  Ishikawa  Tadashi  Watanabe  Shun-ichi 《Marine Geophysical Researches》2019,40(4):493-504

Marine Geophysical Research - After the twenty-first century, the Global Navigation Satellite System-Acoustic ranging (GNSS-A) technique detected geodetic events such as co- and postseismic effects...  相似文献   

Exploring the 7:4 mean motion resonance—II: Scattering evolutionary paths and resonance sticking     

Patryk Sofia Lykawka  Tadashi Mukai 《Planetary and Space Science》2006,54(1):87-100

In our preliminary study, we have investigated basic properties and dynamical evolution of classical TNOs around the 7:4 mean motion resonance with Neptune (a∼43.7 AU), motivated by observational evidences that apparently present irregular features near this resonance (see [Lykawka and Mukai, 2005a. Exploring the 7:4 mean motion resonance—I. Dynamical evolution of classical trans-Neptunian objects (TNOs). Space Planet. Sci. 53, 1175-1187]; hereafter “Paper I”). In this paper, we aim to explore the dynamical long-term evolution in the scattered disk (but not its early formation) based on the computer simulations performed in Paper I together with extra computations. Specifically, we integrated the orbital motion of test particles (totalizing a bit more than 10,000) placed around the 7:4 mean motion resonance under the effect of the four giant planets for the age of the Solar System. In order to investigate chaotic diffusion, we also conducted a special simulation with on-line computation of proper elements following tracks in phase space over 4-5 Gyr. We found that: (1) A few percent (1-2%) of the test particles survived in the scattered disk with direct influence of other Neptunian mean motion resonances, indicating that resonance sticking is an extremely common phenomenon and that it helps to enhance scattered objects longevity. (2) In the same region, the so-called extended scattered TNOs are able to form via very long resonance trapping under certain conditions. Namely, if the body spends more than about 80% of its dynamical lifetime trapped in mean motion resonance(s) and there is the action of a k+1 or (k+2)/2 mean motion resonance (e.g., external mean motion resonances with Neptune described as (j+k)/j with j=1 and 2, respectively). According to this hypothetical mechanism, 5-15% of current scattered TNOs would possess thus probably constituting a significant part of the extended scattered disk. (3) Moreover, considering hot orbital initial conditions, it is likely that the trans-Neptunian belt (or Edgeworth-Kuiper belt) has been providing members to the scattered disk, so that scattered TNOs observed today would consist of primordial scattered bodies mixed with TNOs that came from unstable regions of the trans-Neptunian belt in the past.Considering the three points together, our results demonstrated that the scattered disk has been evolving continuously since early times until present.  相似文献   

Hydration-dehydration interactions between glycine and anhydrous salts: Implications for a chemical evolution of life     

Norio Kitadai  Tadashi Yokoyama 《Geochimica et cosmochimica acta》2011,75(21):6285-6299

Polymerizations of organic monomers including amino acids, nucleotides and monosaccharides are essential processes for chemical evolution of life. Since these reactions proceed with “dehydration” reactions, they are possibly promoted if combined with thermodynamically favorable “hydration” reactions of minerals and salts. To test the possibility, we conducted heating experiments of the simplest amino acid “glycine (Gly)” mixed with four simple anhydrous salts (MgSO₄, SrCl₂, BaCl₂ and Li₂SO₄) at 140 °C up to 20 days. Gly polymerization was strongly promoted by mixing with the salts in the order of MgSO₄ > SrCl₂ > BaCl₂ > Li₂SO₄. Up to 6-mer of Gly polymers were synthesized in the Gly-MgSO₄ mixture, and a total yield of Gly polymers attained about 7% of the initial amount of Gly by the 20 days heating. The total yield was about 200 times larger than that from the heating of Gly alone. XRD measurements of the Gly-MgSO₄ mixture revealed the generation of MgSO₄ monohydrate during Gly polymerization. These observations indicate that Gly polymerization was promoted by the salt hydrations through the hydration-dehydration interactions. Based on the observations, we tried to find a relationship between thermodynamic characteristics of the interactions and the promotion effects of each salt on Gly polymerization. It was found that the salts having lower hydration Δ_rG⁰ (easier to hydrate) promote Gly polymerization more strongly. The relationship was used to estimate promotion effects of simple oxide minerals on Gly polymerization. The estimations were consistent with previous observations about the effects of these minerals on Gly polymerization. The fact suggests that the hydration-dehydration interactions between amino acids and minerals are an important mechanism for amino acids’ polymerizations on minerals.  相似文献   

Role of bedrock groundwater in the rainfall–runoff process in a small headwater catchment underlain by volcanic rock     

Sho Iwagami  Maki Tsujimura  Yuichi Onda  Jun Shimada  Tadashi Tanaka 《水文研究》2010,24(19):2771-2783

The role of bedrock groundwater in rainfall–runoff processes is poorly understood. Hydrometric, tracer and subsurface water potential observations were conducted to study the role of bedrock groundwater and subsurface flow in the rainfall–runoff process in a small headwater catchment in Shiranui, Kumamoto prefecture, south‐west Japan. The catchment bedrock consists of a strongly weathered, fractured andesite layer and a relatively fresh continuous layer. Major chemical constituents and stable isotopic ratios of δ¹⁸O and δD were analysed for spring water, rainwater, soil water and bedrock groundwater. Temporal and spatial variation in SiO₂ showed that stream flow under the base flow condition was maintained by bedrock groundwater. Time series of three components of the rainstorm hydrograph (rainwater, soil water and bedrock groundwater) separated by end member mixing analysis showed that each component fluctuated during rainstorm, and their patterns and magnitudes differed between events. During a typical mid‐magnitude storm event, a delayed secondary runoff peak with 1·0 l s⁻¹ was caused by increase in the bedrock groundwater component, whereas during a large rainstorm event the bedrock groundwater component increased to ≈ 2·5 l s⁻¹. This research shows that the contribution of bedrock groundwater and soil water depends strongly on the location of the groundwater table, i.e. whether or not it rises above the soil–bedrock interface. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Possible effects of secular resonances in Phobos and Triton     

Tadashi Yokoyama 《Planetary and Space Science》2002,50(1):63-77

Due to the tides, the orbits of Phobos and Triton are contracting. While their semi major axes are decreasing, several possibilities of secular resonances involving node, argument of the pericenter and mean motion of the Sun will take place. In the case of Mars, if the obliquity (ε), during the passage through some resonances, is not so small, very significant variations of the inclination will appear. In one case, capture is almost certain provided that ε?20°. For Triton there are also similar situations, but capture seems to be not possible, mainly because in S₁ state, Triton's orbit is sufficiently inclined (far) with respect to the Neptune's equator. Following Chyba et al. (Astron. Astrophys. 219 (1989) 123), a simplified equation that gives the evolution of the inclination versus the semi major axis, is derived. The time needed for Triton crash onto Neptune is longer than that one obtained by these authors, but the main difference is due to the new data used here. In general, even in the case of non-capture passages, some significant jumps in inclination and in eccentricities are possible.  相似文献   

Subglacial drainage system changes of the Gulkana Glacier,Alaska: discharge and sediment load observations and modelling     

Daisaku Kido  Kazuhisa A. Chikita  Kenta Hirayama 《水文研究》2007,21(3):399-410

Hydrological characteristics of englacial and subglacial drainage systems in Gulkana Glacier, Alaska, were examined by analysing temporal variations of discharge and sediment load in the proglacial Phelan Creek in 2001. From data plots on semi‐log paper, it appeared appropriate to separate both discharge and sediment load into fast and slow components. The two components were possibly produced by two different drainage systems: an englacial and subglacial, ‘channellized’ system in the ablation zone, and a subglacial, ‘distributed’ system in the accumulation zone. The data indicate the occurrence of an event during which part of the ‘distributed’ drainage system changed into the ‘channellized’ drainage system. The daily time‐series of discharge and sediment load were represented using a tank model. In the model, the drainage from an additional tank was added, supposing that a subglacial reservoir full of water and sediment collapsed slowly when the subglacial drainage system changed from distributed to channellized. The simulation with the collapsed tank gave much more reasonable results than those with no collapsed tank. The contribution of the collapsed tank to total sediment load is 24%, which is much larger than 9% to total discharge. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

An optical and near-infrared search for brown dwarfs in the Pleiades cluster     

Chie Nagashima †  Paul D. Dobbie  Takahiro Nagayama  Yasushi Nakajima  Tetsuya Nagata  Motohide Tamura  Tadashi Nakajima  Koji Sugitani  Hidehiko Nakaya  Simon T. Hodgkin  rew J. Pickles  Shuji Sato 《Monthly notices of the Royal Astronomical Society》2003,343(4):1263-1270

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