A laser-photolysis fragment-fluorescence (LPFF) method for the detection of gaseous nitric acid in ambient air     

Th. Papenbrock  F. Stuhl 《Journal of Atmospheric Chemistry》1990,10(4):451-469

The development and first tests of a novel method for the direct, sensitive, selective, and fast detection of gaseous nitric acid in air are described. The detection method is based on the laser-photolysis fragment-fluorescence (LPFF) method using 193 nm (ArF) laser light. The photolysis process yielding OH fluorescence has been thoroughly investigated. Up to now, the method has been found to be practically free of interferences. The mixing ratio for nitric acid is measured on-line with a detection limit of about 0.1 ppbv for an accumulation time of the signal of 10–15 min. A number of tests and field measurements were performed to demonstrate the feasibility and limits of the described detection method.  相似文献   

Book reviews     

Krings  Th.  Bora  Lakshmi N.  West  Robert C.  Rugg  Dean S.  Tietze  Wolf  Grotewold  Andreas  Hellen  J. A. 《GeoJournal》1990,22(3):381-384

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Platinum-group minerals in quaternary gold placers in the upper Chindwin area of northern Burma     

Dr. D. Hagen  Dr. Th. Weiser  Than Htay 《Mineralogy and Petrology》1990,42(1-4):265-286

In the Chindwin Basin in northern Burma, there is a system of five Pleistocene terraces in which gold placers with low concentrations of platinum-group minerals (PGM) occur. Samples were taken from four sites in the Chindwin Basin and one from near an ophiolite occurrence on the northeast side of the Chindwin Basin; they were studied under the microscope, with a scanning electron microscope, and an electron microprobe. The main minerals were Pt-Fe and Os-Ir-Ru alloys, usually in a ratio between 2 and 5. In most cases, the shape of the grains allowed a quick distinction between the two types. Sperrylite, laurite, irarsite, cooperite, tulameenite, and isomertieite occur infrequently as individual mineral grains and sometimes as inclusions in the alloy grains. Braggite, platarsite, hollingworthite, bowieite, keithconnite, cuproiridsite, malanite, stibiopalladinite, geversite, kashinite, several unnamed PGM, and Fe, Ni, and Cu sulfides were observed as inclusions, mainly in the Pt-Fe alloys and also to a lesser extent in the Os-Ir-Ru alloys. Lamellar and myrmekite-like intergrowths, oriented exsolution lamellae, and idiomorphic inclusions of sulfides in the alloys indicate a magmatic origin of the PGM. The origin of the PGM is assumed to be ophiolites in northern Burma. A continual decrease in mean grain size occurred during transport.

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Platingruppenminerale in quartären Goldseifen im oberen Chindwingebiet in Nord-Burma

Zusammenfassung Im Gebiet des Chindwin Basin in Nordburma ist ein System von fünf pleistozänen Terrassen ausgebildet, in denen Goldseifen mit geringen Anteilen an PGM auftreten.PGM-Konzentrate von vier Vorkommen des Chindwin Basin und eine weitere Probe aus der Nähe eines Ophiolithvorkommens im Nordosten des Chindwin Basin wurden mit optischer Mikroskopie, Rasterelektronenmikroskopie und Mikrosonde untersucht.Hauptmineralien sind Pt-Fe-Legierungen und Os-Ir-Ru-Legierungen in einem Verhältnis von 2: 1 bis 5: 1. Ihre Morphologie kugeliger oder plattiger, teilweise idiomorpher Körner erlaubt in den meisten Fällen eine rasche Identifizierung der beiden Typen. Sehr selten treten als Einzelminerale, aber auch als Einschlüsse in Legierungen, Sperrylith, Laurit, Irarsit, Cooperit, Tulameenit und Isomertieit auf. Braggit, Platarsit, Hollingworthit, Bowieit, Keithconnit, Cuproiridsit, Malanit, Stibiopalladinit, Geversit, Kaschinit, einige unbekannte PGM und Fe-, Ni- und Cu-Sulfide wurden nr als Einschlüsse, hauptsächlich in Pt-Fe-Legierungen, weniger in Os-Ir-Ru-Legierungen, beobachtet.Lamellare und myrmekitische Verwachsungen, orientierte Entmischungen und idiomorphe Einschlüsse von Sulfiden in Legierungen weisen auf eine magmatische Entstehung der PGM hin. Die Herkunft der PGM wird in Ophiolithen Nordburmas vermutet. Beim Transport hat eine kontinuierliche Abnahme der mittleren Korngrösse stattgefunden.

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With 8 Figures  相似文献   

Crustal observations beneath the southern North Sea and their tectonic and geological implications     

Richard H.B. Rijkers  Ed J.Th. Duin 《Tectonophysics》1994,240(1-4):215-224

In 1991, a deep seismic reflection line, MPNI-9101, was acquired in the southern North Sea from the Mesozoic Broad Fourteens Basin, across the West Netherlands Basin onto the London-Brabant Massif (LBM). The resultant section shows a strongly reflective lower crust beneath the area of Mesozoic basin development. This lower crustal reflectivity continues to be strong beneath the LBM. The travel time to the base of the reflective zone increases from approximately 11.0 s beneath the Mesozoic basins to 12.5 s beneath the LBM, suggesting a southward thickening of the crust (Rijkers et al., 1993). Based on these travel times and information from deep wells and refraction surveys. Moho depth is estimated to increase from about 31 km beneath the Mesozoic basins to about 38 km beneath the LBM. This difference in depth to the Moho can partly be explained by coaxial stretching of the crust beneath the Mesozoic basins. In comparison with the Mesozoic basins, the crust beneath the LBM was thickened during the Caledonian and Variscan orogenies.  相似文献   

Measurement of wind parameters and heat flux with the sensitron Doppler SODAR     

J. Keder  Th. Foken  W. Gerstmann  V. Schindler 《Boundary-Layer Meteorology》1989,46(1-2):195-204

The authors present the results of a comparison of wind parameters and heat flux inferred from Doppler SODAR (Sensitron/Sweden) with direct measurements using an acoustic anemometer (Kaijo-Denki, DAT 300) and a platinum wire thermometer. Rather important are the results of a calibration method for c _t ² from measurements of temperature standard deviation, and of an underestimation of the wind speed by Doppler SODAR. An operational means to calculate the flux of sensible heat on the basis of SODAR measurements is studied.  相似文献   

The influence of soil properties on the erodibility of Belgian loamy soils: A study based on rainfall simulation experiments     

Th. Verhaegen 《地球表面变化过程与地形》1984,9(6):499-507

Twenty soils from the Leuven region were tested in the laboratory with a rainfall simulator. Their texture varied from loam to loamy sand. On the basis of the results obtained, they were classified as a function of the runoff and splash erodibility. For every soil, several properties were determined and tentatively used to explain the classifications based on the runoff and splash erodibility. Significant negative correlations were found between silt content, aggregate stability, C_5–10 index, water content at saturation, and cohesion on the one side and erodibility on the other; a positive correlation was found between sand content and erodibility.  相似文献   

Field verification of a theoretical model to predict the dynamic response of a soft clay deposit     

V. R. Raju  Th. Neidhart  G. Huber 《Soil Dynamics and Earthquake Engineering》1995,14(1)

A 40-m thick clay deposit was subjected to sinusoidal excitations using a foundation block and an eccentric mass type vibrator. The response of the foundation block and the surrounding soil was measured using geophones inside the soil and on the surface. The phase shift between the excitation signal and the response signal, the accelerations of the foundation block and the particle velocities in the soil are compared with those obtained from a frequency-dependent numerical model based on the exact analytical solution for the boundary value problem of a rectangular foundation resting on a linear elastic halfspace.  相似文献   

Dynamic subsoil-coupling between rigid rectangular foundations     

Th. Triantafyllidis  B. Prange 《Soil Dynamics and Earthquake Engineering》1987,6(3)

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Magmatism and metamorphism in the Ladakh Himalayas (the Indus-Tsangpo suture zone)   总被引：1，自引：0，他引：1  

K. Honegger  V. Dietrich  W. Frank  A. Gansser  M. Thöni  V. Trommsdorff 《Earth and Planetary Science Letters》1982,60(2):253-292

Ladakh (India) provides a complete geological section through the northwestern part of the Himalayas from Kashmir to Tibet. Within this section the magmatic, metamorphic and geotectonic evolution of the northern Himalayan orogeny has been studied using petrographic, geochemical and isotope analytical techniques.The beginning of the Himalayan cycle was marked by large basaltic extrusions (Panjal Trap) of Permian to Lower Triassic age at the “northern” margin of the Gondwana continent (Indian Shield). These continental type tholeiitic basalts were followed by a more alkaline volcanism within the Triassic to Jurassic Lamayuru unit of the Gondwana continental margin.Lower Jurassic to Cretaceous oceanic crust and sediments (ophiolitic mélange s.s.) accompany the Triassic to Cretaceous flysch deposits within the Indus-Tsangpo suture zone, the major structural divide between the Indian Shield (High Himalaya) and the Tibetan Platform. So far, no relic of Paleozoic oceanic crust has been found.Subduction of the Tethyan oceanic crust during Upper Jurassic and Cretaceous time produced an island arc represented by tholeiitic and calc-alkaline volcanic rock series (Dras volcanics) and related intrusives accompanied by volcaniclastic flysch deposits towards the Tibetan continental margin.Subsequent to the subduction of oceanic crust, large volumes of calc-alkaline plutons (Trans-Himalayan or Kangdese plutons) intruded the Tibetan continental margin over a distance of 2000 km and partly the Dras island arc in the Ladakh region.The collision of the Indian Shield and Tibetan Platform started during the middle to upper Eocene and caused large-scale, still active intracrustal thrusting as well as the piling up of the Himalayan nappes. The tectonically highest of these nappes is built up of oceanic crust and huge slices of peridotitic oceanic mantle (Spongtang klippe).In the High Himalayas the tectonic activity was accompanied and outlasted by a Barrovian-type metamorphism that affected Triassic sediments of the Kashmir-Nun-Kun synclinorium up to kyanite/staurolite grade and the deeper-seated units up to sillimanite grade. Cooling ages of micas are around 20 m.y. (muscovite) and 13 m.y. (biotite). Towards the Indus-Tsangpo suture zone metamorphism decreases with no obvious discontinuity through greenschist, prehnite-pumpellyite to zeolite grade. Remnants of possibly an Eo-Himalayan blueschist metamorphism have been found within thrust zones accompanying ophiolitic mélange in the suture zone.  相似文献   

Very high CO2 cordierite from Norwegian Lapland: Mineralogy,petrology, and carbon isotopes     

Th. Armbruster  W. Schreyer  J. Hoefs 《Contributions to Mineralogy and Petrology》1982,81(4):262-267

The most CO₂-rich cordierite thus far encountered in nature with about 2.2 wt.% CO₂ and 0.3 wt.% H₂O occurs as large poikiloblasts in a strange non-foliated reaction rock that dissects well-foliated granulites being part of the classical Lapland granulite area described by Eskola. The cordierite is optically positive with the highest optic angle 2V _x (106°) and birefringence (– = 0.017) ever measured on natural cordierites, but it is also optically very heterogeneous due to secondary loss of CO₂ along fractures and zones paralleling the fluid-bearing channels. Based on the optical properties of the degassed Lapland cordierite and on literature data a ternary diagram is given, which shows the variations of this cordierite in 2V _x and birefringence as a function of channel-filling with both CO₂ and H₂O.Following Losert (1971) the cordierite coexists with calcite, a thus far unique mineral assemblage that is probably only stable at very high CO₂ pressures. In the present case, the of the cordierite (0.75) indicates, on the basis of literature data, a coexisting fluid with >0.95.The carbon isotope composition ¹³C of CO₂ in cordierite lies near –7, that of the calcite is slightly lighter than about –9. Thus, at least for the CO₂ in cordierite, a deep-seated origin may be possible.Based on the geologic occurrence it is speculated that the cordierite-bearing reaction rock could perhaps represent an annealed channel of late degassing in the granulitic lower crust.  相似文献