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31.
Phlogopite-bearing lithologies are the main constituent of the Phlogopite-Peridotite unit of the Finero sequence and the result of pervasive migration of metasomatizing melts/fluids. Conversely, the presence of phlogopite within the associated Finero Mafic Complex, a mafic-ultramafic pluton intruded into the metamorphic basement of the Adria plate, is mentioned in literature as rare. Recent detailed fieldwork has evidenced the presence of two distinct phlogopite-rich ultramafic lithologies within the Amphibole-Peridotite unit of the Finero Mafic Complex, where phlogopite is always associated with amphibole. Field and petrographic features of these occurrences, as well as major- and trace-element mineral chemistry, are here presented to i) place constraints on the nature of the parent melt from which they have been generated and ii) to address their relationship with the other lithologies of the Finero Complex. We find that these rocks were formed by late melt migrations along shear zones under high-T conditions. The geochemical affinity of these lithologies is different to the tholeiitic-transitional affinity reported in literature for the Finero Mafic Complex. The enrichment in LREE, Th, U and Sr of the associated amphibole possibly suggests that these phlogopite-bearing lithologies are genetically related to the metasomatic events that have affected the Finero mantle massif.  相似文献   
32.
Mean annual precipitation variability at decadal time scale over a southern Italy area (Calabria) was investigated to quantify the spatial and temporal patterns. A multivariate approach has been applied to analyse spatial?Ctemporal (1921?C2000) data of annual precipitation. A nested isotropic linear model of coregionalization was fitted to the experimental variograms including three basic structures: a nugget effect, an exponential model and a spherical model. The correlation structure between the decades was analysed by applying principal component analysis at each spatial scale, and specific factors at each characteristic scale were cokriged and mapped. Two components were identified: the first is mainly linked to local factors, which could be identified by the orographic characteristics of the region, while the long range component could be related to large-scale factors, like for example the processes of the global atmospheric circulation. In addition, in order to obtain a better insight into the pattern of relatively dry or wet zones, a standardized relative difference was calculated. The results showed that the annual precipitation decreased during the period 1921?C2000 and the spatial distribution changed with an increase of dry areas.  相似文献   
33.
We use present theoretical estimates for the density of long cosmic strings to predict the number of strong gravitational lensing events in astronomical imaging surveys as a function of the angular resolution and survey area. We show that angular resolution is the single most important factor, and that interesting limits on the dimensionless string tension   G μ/ c 2  can be obtained by existing and planned surveys. At the resolution of the Hubble Space Telescope ( HST ) (0.14 arcsec), it is sufficient to survey of the order of a few square degrees – well within reach of the current HST archive – to probe the regime   G μ/ c 2∼ 10−7  . If lensing by cosmic strings is not detected, such a survey would improve the limit on the string tension by a factor of two over that available from the cosmic microwave background. Future high resolution imaging surveys, covering a few hundred square degrees or more, either from space in the optical or from large-format radio telescopes on the ground, would be able to further lower this limit to   G μ/ c 2∼ 10−8  . These limits will not be improved significantly by increasing the solid angle of the survey.  相似文献   
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35.
First principles calculations have been used to investigate the condensation reactions of hydrated calcium bicarbonate monomers in a simulated aqueous environment. The reaction pathway for the calcium bicarbonate dimerization process has been computed at the density functional theory-PBE level with the COSMO dielectric continuum model to simulate the hydrated environment. The results indicate that calcium bicarbonate dimers form via an associative mechanism: the first step involves a sevenfold calcium bicarbonate intermediate followed by the loss of one water molecule from the first coordination shell of calcium. Both steps are characterised by a low energy barrier of approximately 2 kcal mol−1, suggesting that the dimerization process is not kinetically hindered in aqueous solution. However, the Gibbs free energies for the condensation reactions to form the calcium bicarbonate dimers and the species Ca(HCO3)2(H2O)4, Ca(HCO3)3(H2O)3 and Ca2(HCO3)(H2O)103+, computed using the PBE and mPW1B95 density functional theory levels for the gas-phase component and the UAHF-CPCM solvation model for the hydration contribution, are all positive, which indicates that the formation of these early calcium bicarbonate clusters is thermodynamically unfavourable in aqueous solutions. Our calculations therefore suggest that the oligomerization of calcium carbonate is not spontaneous in water, at the conditions considered in our simulations, i.e. T = 298 K and neutral pH, which indicates that the nucleation of calcium carbonate cannot occur through a homogeneous process when calcium-bicarbonate ion pairs are the major source of CaCO3 in the aqueous environment.  相似文献   
36.
ABSTRACT

Stream gauge-based information is the foundation for many hydrological applications in a river basin including the aquatic-habitat conservation. A simple two-parameter model for routing streamflow depth (alternatively, stream–stage) hydrographs and estimating corresponding discharge hydrographs in river channels is proposed using the multilinear approach, based on Nash-type discrete-cascade model. The applicability of this model is investigated by extending its framework to the realm of compound cross-section trapezoidal channels for both in-bank and overbank flows by using 20 flood events of the Tiber River in the Umbria region of Central Italy, and subsequently comparing the simulated results with the corresponding simulations of the HEC-RAS (Hydrologic Engineering Center – River Analysis System) hydrodynamic model and observed flow depth hydrographs. The field application, comparative study, and uncertainty and sensitivity analysis of the results demonstrate that the proposed multilinear discrete Nash-cascade stage-hydrograph (MDNS) routing model has the potential for routing floods in real-world rivers and canal irrigation systems, especially in operational mode.  相似文献   
37.
The 2002–03 Mt Etna flank eruption began on 26 October 2002 and finished on 28 January 2003, after three months of continuous explosive activity and discontinuous lava flow output. The eruption involved the opening of eruptive fissures on the NE and S flanks of the volcano, with lava flow output and fire fountaining until 5 November. After this date, the eruption continued exclusively on the S flank, with continuous explosive activity and lava flows active between 13 November and 28 January 2003. Multi-disciplinary data collected during the eruption (petrology, analyses of ash components, gas geochemistry, field surveys, thermal mapping and structural surveys) allowed us to analyse the dynamics of the eruption. The eruption was triggered either by (i) accumulation and eventual ascent of magma from depth or (ii) depressurisation of the edifice due to spreading of the eastern flank of the volcano. The extraordinary explosivity makes the 2002–03 eruption a unique event in the last 300 years, comparable only with La Montagnola 1763 and the 2001 Lower Vents eruptions. A notable feature of the eruption was also the simultaneous effusion of lavas with different composition and emplacement features. Magma erupted from the NE fissure represented the partially degassed magma fraction normally residing within the central conduits and the shallow plumbing system. The magma that erupted from the S fissure was the relatively undegassed, volatile-rich, buoyant fraction which drained the deep feeding system, bypassing the central conduits. This is typical of most Etnean eccentric eruptions. We believe that there is a high probability that Mount Etna has entered a new eruptive phase, with magma being supplied to a deep reservoir independent from the central conduit, that could periodically produce sufficient overpressure to propagate a dyke to the surface and generate further flank eruptions.Editorial responsibility: J. Donnelly-Nolan  相似文献   
38.
Gravitational time delays, observed in strong lens systems where the variable background source is multiply imaged by a massive galaxy in the foreground, provide direct measurements of cosmological distance that are very complementary to other cosmographic probes. The success of the technique depends on the availability and size of a suitable sample of lensed quasars or supernovae, precise measurements of the time delays, accurate modeling of the gravitational potential of the main deflector, and our ability to characterize the distribution of mass along the line of sight to the source. We review the progress made during the last 15 years, during which the first competitive cosmological inferences with time delays were made, and look ahead to the potential of significantly larger lens samples in the near future.  相似文献   
39.
Research in aquatic ecology requires adequate sampling designs if the underlying processes that govern population and community dynamics are to be understood. Adequate sampling design is particularly important for organisms inhabiting environments such as mangroves. Thus, collecting quantitative ecological data remains a major challenge. Here, we analysed the structural and temporal dynamics of a tidal cycle and mangrove fish assemblages at 15 sites along the Brazilian central coast. Specifically, we used two non-extractive sampling techniques, which included stationary underwater visual census (s-UVC) and stationary underwater wide-camera census (s-UWC). Our results showed that by reducing potential observer effects, the s-UWC protocol maximized fish counts, yielding more accurate and precise estimates. In contrast, although the s-UVC technique was a useful approach, this technique did not yield precise density and richness estimates. Furthermore, the negative effect associated with the presence of an observer (i.e., diver) was a significant constraint to the observer-based technique. Furthermore, the methods were more similar for the high tide samples and more divergent for the flood tide and ebb tide samples. These pronounced divergences among tidal periods allowed the application of a temporal mixed-sampling protocol (i.e., unbalanced temporal samples) based on s-UWC without the loss of statistical power. Methodological gains also were felt with a reduction in the costs associated with the presence of a trained observer in water and overcoming of constraints positively related to depth limitations. Overall, the s-UWC protocol adequately captures species using different stages of the tide to enter the mangroves.  相似文献   
40.
The experience gained with the current generation of X-ray telescopes like Chandra and XMM-Newton has shown that low energy “soft” protons can pose a severe threat to the possibility to exploit scientific data, reducing the available exposure times by up to 50% and introducing a poorly reproducible background component. These soft protons are present in orbits outside the radiation belts and enter the mirrors, being concentrated towards the focal plane instruments, losing energy along their path and finally depositing their remaining energy in the detectors. Their contribution to the residual background will be even higher for ATHENA with respect to previous missions, given the much higher collecting area of the mirrors, even if the instruments will likely suffer no significant radiation damage from this particles flux. As a consequence this soft proton flux shall be damped with the use of a magnetic diverter to avoid excess background loading on the WFI or X-IFU instruments. We present here a first complete evaluation of this background component for the two focal plane instruments of the ATHENA mission in absence of a magnetic diverter, and derive the requirements for such device to reduce the soft protons induced background below the level required to enable the mission science. We estimate the soft proton flux expected in L2 for the interplanetary component and for the component generated locally by acceleration processes in the magnetotail. We produce a proton response matrix for each of the two instruments of ATHENA focal plane, exploiting two independent Monte Carlo simulations to estimate the optics concentration efficiency, and Geant4 simulations to evaluate the energy loss inside the radiation filters and deposited in the detector. With this modular approach we derive the expected fluxes and spectra for the soft protons component of the background. Finally, we calculate the specifics of a magnetic diverter able to reduce such flux below the required level for both X-IFU and WFI.  相似文献   
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