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91.
Quantifying the potential ash fall hazards from re-awakening volcanoes is a topic of great interest. While methods for calculating the probability of eruptions, and for numerical simulation of tephra dispersal and fallout exist, event records at most volcanoes that re-awaken sporadically on decadal to millennial cycles are inadequate to develop rigorous forecasts of occurrence, much less eruptive volume. Here we demonstrate a method by which eruption records from radiocarbon-dated sediment cores can be used to derive forecasting models for ash fall impacts on electrical infrastructure. Our method is illustrated by an example from the Taranaki region of New Zealand. Radiocarbon dates, expressed as years before present (B.P.), are used to define an age-depth model, classifying eruption ages (with associated errors) for a circa 1500–10 500 year B.P. record at Mt. Taranaki (New Zealand). In addition, data describing the youngest 1500 years of eruption activity is obtained from directly dated proximal deposits. Absence of trend and apparent independence in eruption intervals is consistent with a renewal model using a mix of Weibulls distributions, which was used to generate probabilistic forecasts of eruption recurrence. After establishing that interval length and tephra thickness were independent in the record, a thickness–volume relationship (from [Rhoades, D.A., Dowrick, D.J., Wilson, C.J.N., 2002. Volcanic hazard in New Zealand: Scaling and attenuation relations for tephra fall deposits from Taupo volcano. Nat. Hazards, 26:147–174]) was inverted to provide a frequency–volume relationship for eruptions. Monte Carlo simulation of the thickness–volume relationship was then used to produce probable ash fall thicknesses at any chosen site. Several critical electrical infrastructure sites in the Taranaki Region were analysed. This region, being the only gas and condensate-producing area in New Zealand, is of national economic importance, with activities in and around the area depending on uninterrupted power supplies. Forecasts of critical ash thicknesses (1 mm wet and 2 mm dry) that may cause short-circuiting, surges or power shutdowns in substations show that the annual probabilities of serious impact are between ~ 0.5% and 27% over a 50 year period. It was also found that while large eruptions with high ash plumes tend to affect “expected” areas in relation to prevailing winds, the direction impacts of small ash falls are far less predictable. In the Taranaki case study, areas out of normal downwind directions, but close to the volcano, have probabilities of impact for critical thicknesses of 1–2 mm of around half to 60% of those in downwind directions and therefore should not be overlooked in hazard analysis. Through this method we are able to definitively show that the potential ash fall hazard to electrical infrastructure in this area is low in comparison to other natural threats, and provide a quantitative measure for use in risk analysis and budget prioritisation for hazard mitigation measures.  相似文献   
92.
Eruption episodes, where a series of eruption events are generically related, can include the eruption of a wide spectrum of volcanic activity over decadal periods. This paper concentrates on the opening phases of an eruption episode which occurred approximately 1800 yrs BP from Mt Taranaki, New Zealand. These events spanned the eruption of differing bulk compositions and styles from two distinct vent locations; an andesitic sub-plinian eruption from the summit vent and a scoria cone-building eruption of basaltic magma from a satellite vent. Compositional profiles and zoning textures of plagioclase, amphibole and clinopyroxene phenocrysts from the opening andesitic event show evidence of magma mixing and subsequent crystallisation just prior to the initiation of the eruption episode. Titanomagnetite grain morphology and Ti variation suggest that the magma mixing event occurred within a few days to weeks before the eruption acting as a trigger for it. We present a magmatic model which is constrained by the petrological observations and eruptions of the episode. In this model magma differentiation at depth causes its rise and recharging of a mid-crustal magma storage area at 5–7 km. Although the recharging magma differed slightly in oxygen fugacity and temperature, it was compositionally and physically similar enough to the residing andesitic magma to allow efficient mixing. The petrological characteristics described here can be readily observed and enable identification of mixing events in other recent eruption episodes.  相似文献   
93.
Phytate as a novel phosphorus-specific paleo-indicator in aquatic sediments   总被引:1,自引:0,他引:1  
A reliable geochemical paleo-indicator for phosphorus remains elusive, despite the importance of understanding historical changes in the nutrient status of aquatic ecosystems. We assessed the potential of phytate (salts of myo-inositol hexakisphosphate) as a novel phosphorus-specific paleo-indicator by measuring its concentrations in dated sediments from an embayment in Helsinki, Finland, with a known 200-year history of trophic changes. Phytate was extracted in a solution containing sodium hydroxide and EDTA and detected by solution 31P NMR spectroscopy with spectral deconvolution. Concentrations varied markedly with sediment depth and paralleled previously determined changes in diatom assemblages and geochemical indicators linked to trophic status. In contrast, total sediment phosphorus did not reflect phosphorus inputs to the embayment, presumably due to the mobilization of inorganic phosphate under anoxic conditions during periods of high pollutant loading. Importantly, phytate appeared to be stable in these brackish sediments, in contrast to other organic and inorganic phosphates which declined abruptly with depth. We therefore conclude that phytate represents a potentially important indicator of historical changes in phosphorus inputs to water bodies, although additional studies are required to confirm its stability under conditions likely to be encountered in lakes and coastal ecosystems.  相似文献   
94.
Acquiring detailed eruption frequency datasets for a volcano system is essential for realistic eruption forecasts. However, accurate datasets are inherently difficult to compile, even if one or more well-dated eruption records are available. A single record typically under-represents the eruption frequency, while combining two or more records may result in an overrepresentation. Although glass compositions have proven to be successful in tephrochronological studies of dominantly rhyolitic tephras; microlitic growth and thin glass shards inhibit their application to andesitic tephras. A method consisting of a combination of two techniques for correlating syn-eruptive deposits is demonstrated on data from the typical andesitic stratovolcano of Mt. Taranaki, New Zealand. Firstly, tentative matches are identified using the radiocarbon age and associated error of each event. Secondly, the compositions of titanomagnetite micro-phenocrysts are used as an independent check, and shown to be a useful correlation tool where age data is available. Using two lake-core records containing tephra layers in an overlapping time-frame, the radiocarbon age-correlation procedure suggested 31 tephra matches. Geochemistry data were available for 15 of these pairs. In three of these cases, the titanomagnetite compositions did not match. Hence, these “paired” tephras were from compositionally distinct magmas and therefore likely represent separate events. An additional three matches were reassigned within the temporal uncertainty limits of the dating procedure, based on better geochemical pairing. The final combined dataset suggests that there have been at least 138 separate ash fall-producing eruptions between 96 and 10 150 years B.P. from Taranaki. Using the combined dataset the mixture of Weibulls renewal model forecasts a probability of 0.52 for an eruption occurring in the next 50 years at this volcano. The present annual eruption probability is estimated at 1.6%. This likelihood is almost double that obtained when relying on a single stratigraphic record.  相似文献   
95.
The northern uplands of Vietnam are witness to rapidly developing commodity markets for a range of forest and agricultural products. Since the early 1990s the cultivation of black cardamom (Amomum aromaticum) has become a source of cash income for a growing number of ethnic minority households in these uplands. Drawing on ethnographic fieldwork, and utilizing a commodity chain and livelihoods approach, this article investigates the contemporary dynamics surrounding the cultivation, harvesting and trade of dried cardamom fruit from Hmong cultivators in Lao Cai province to consumers elsewhere in Vietnam and beyond to China and the global market. We analyse the spatial and social structures of these commodity chains, drawing attention to a range of mechanisms of access. We find that these mechanisms are reliant upon specific ethnic relations as well as different forms of capital that together sustain economic advantages for particular actors. While focusing on the ethnic minority cultivators active in these commodity chains, we also call for more nuanced understandings of how the trade in forest products fits within local agricultural systems and household livelihood decision making processes in the Vietnam uplands.  相似文献   
96.
We report on the iron Kα line properties of a sample of Seyfert galaxies observed with the XMM‐Newton EPIC pn instrument. Using a systematic and uniform analysis, we find that complexity at iron‐K is extremely common in the XMM‐Newton spectra. Once appropriate soft X‐ray absorption, narrow 6.4 keV emission and associated Compton reflection are accounted for, ∼75% of the sample show an improvement when a further component is introduced. The typical properties of the broad emission are both qualitatively and quantitatively consistent with previous results from ASCA. The complexity is in general very well described by relativistic accretion disk models. In most cases the characteristic emission radius is constrained to be within ∼50R g, where strong gravitational effects become important. We find in about 1/3 of the sample the accretion disk interpretation is strongly favoured over competing models. In a few objects no broad line is apparent. We find evidence for emission within 6R g in only two cases, both of which exhibit highly complex absorption. Evidence for black hole spin based on the X‐ray spectra therefore remains tentative. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
97.
Abstract— Previous Raman investigations on experimentally shocked ingle‐crystal olivine indicated that the olivine Raman bands seemingly shift to a higher wave number with increasing shock pressure. If this effect could be confirmed, Raman analysis of natural shock‐metamorphosed minerals could potentially provide an important shock barometric tool. We carried out a Raman spectroscopic study on olivine in a series of natural dunite samples experimentally shocked to pressures between 5 and 59 GPa. In addition, we analyzed olivine grains in a sample of the Cold Bokkeveld C1 meteorite. We studied samples of several dunites with olivine of 90.64–92.00 mole% Fo to determine Raman effects in the region from 200 to 900 cm?1. Several olivine grains per sample/shock pressure stage were analyzed. Raman analysis, however, showed little or no shift with increasing shock pressure. The shifts to higher or lower frequencies observed were not specific for a given pressure stage, with some grains within a sample showing more shift than others. This finding is unrelated to the crystallographic orientation of analyzed grains and cannot be related systematically to the different degrees of optically determined shock metamorphism of the analyzed grains. We identified an increase in full width at half maximum (FWHM) for the 824 cm?1 band with increased shock pressure in the shocked Åheim samples above 45 GPa and, to a lesser extent, for the 856 cm?1 band. Evaluation of band broadening of olivine in the Cold Bokkeveld meteorite showed FWHM values that were much greater (9–20 cm?1) than those of olivine in the shocked dunite samples (7–12 cm?1). We concluded that these differences in FWHM are due to differences in chemical composition between the meteoritic and the experimentally shocked olivine. Therefore, using Raman spectroscopy to detect small shifts in wave numbers to higher frequencies with increased shock pressure does not yield consistent effects for polycrystalline dunite. An extra band at 650 cm?1 was identified in the Raman spectra of the unshocked Mooihoek dunite and the Åheim dunite samples shocked to 5, 29.3, and 59 GPa, as well as another at 696 cm?1 in all the spectra of the 59 GPa Åheim sample. The cause of these extra bands is not known. Comparison of these results with Raman spectra of olivine from the Cold Bokkeveld C1 meteorite did not allow us to determine shock pressures for the meteoritic olivine.  相似文献   
98.
99.
Abstract— Iodine-xenon analyses of chondrules from the Bjurböle L4 and Parnallee LL3.6 meteorites have been made using a continuous wave laser microprobe and the resonance ionisation mass spectrometer RELAX. The excess 129Xe content released from the Bjurböle chondrule is lower than previous stepped-heating studies have found, suggesting that the technique does not completely degas the samples. Nonetheless, clear isochrons were produced, and data for initial 129Xe/130Xe are consistent with earlier work. A correlation is evident in each chondrule between 131Xe* and 128Xe* perhaps indicating a common host-phase for their parent nuclides, a condition possibly fulfilled by a Te- and I-bearing sulfide. The I-Xe system of a Parnallee macrochondrule exhibits no excess 129Xe, possibly as a result of thermal alteration or deformation before accumulation of the meteorite. A cristobalite-bearing chondrule depleted in 16O yields an I-Xe age of 4.5 ± 0.5 Ma after the mean Bjurböle age.  相似文献   
100.
Citation information is discussed as a means for ranking the research and publication visibility of eleven graduate programs in geography. It is suggested that the ranks produced by this objective method correspond better to the peer-based ranks of the 1982 NRC survey of graduate programs than those derived from publication counts. Citation information also provides a means of evaluating the differences between programs' inter- and intradisciplinary visibility.  相似文献   
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