Antarctic Ice‐Core Water (USGS49) – A New Isotopic Reference Material for δ2H and δ18O Measurements of Water          下载免费PDF全文

Jennifer M. Lorenz  Haiping Qi  Tyler B. Coplen 《Geostandards and Geoanalytical Research》2017,41(1):63-68

As a result of the scarcity of isotopic reference waters for daily use, a new secondary isotopic reference material for international distribution has been prepared from ice‐core water from the Amundsen–Scott South Pole Station. This isotopic reference material, designated as USGS49, was filtered, homogenised, loaded into glass ampoules, sealed with a torch, autoclaved to eliminate biological activity and measured by dual‐inlet isotope‐ratio mass spectrometry. The δ²H and δ¹⁸O values of USGS49 are ?394.7 ± 0.4 and ?50.55 ± 0.04 mUr (where mUr = 0.001 = ‰), respectively, relative to VSMOW, on scales normalised such that the δ²H and δ¹⁸O values of SLAP reference water are, respectively, ?428 and ?55.5 mUr. Each uncertainty is an estimated expanded uncertainty (U = 2u_c) about the reference value that provides an interval that has about a 95% probability of encompassing the true value. This isotopic reference material is intended as one of two isotopic reference waters for daily normalisation of stable hydrogen and oxygen isotopic analysis of water with an isotope‐ratio mass spectrometer or a laser absorption spectrometer. It is available by the case of 144 glass ampoules or as a set of sixteen glass ampoules containing 5 ml of water in each ampoule.  相似文献   

A novel nuclear forensic tool involving deposit type normalized rare earth element signatures   总被引：1，自引：0，他引：1       下载免费PDF全文

Tyler L. Spano  Antonio Simonetti  Thomas Wheeler  Grace Carpenter  Devonee Freet  Enrica Balboni  Corinne Dorais  Peter C. Burns 《地学学报》2017,29(5):294-305

Identifying the provenance of uranium‐rich materials is a critical objective of nuclear forensic analysis. Rare earth element (REE) distributions within uranium ores are well‐established forensic indicators, but quantifying and correlating trace element signatures for U ores to known deposits has thus far involved intricate statistical analyses. This study reports average chondrite normalized (CN)‐REE signatures for important U deposit types worldwide, which are then employed to evaluate U ore paragenesis using a simple linear regression analysis. This technique provides a straightforward method that can aid in determining the deposit type of U ores based on their REE abundances, and combined with other forensic indicators (e.g. radiogenic isotope signatures) can provide essential provenance information for nuclear materials.  相似文献   

Thermodynamics and civilization: from ancient rivers to fossil fuel energy servants     

Tyler Volk 《Climatic change》2009,95(3-4):433-438

Civilization can be at least partially determined by climatic constraints upon net primary productivity and heat dissipation from the human body (Kleidon 2009). I discuss how these “metabolic” limitations were historically overcome: first, because large rivers in dry regions provided water to ancient civilizations; second, because fossil fuel energy servants working externally to muscle-limited bodies have produced economic well-being in a number of world areas.  相似文献   

Reconstruction of the hydrothermal history of the Cu–Ag vein-type mineralisation at Dikulushi, Kundelungu foreland, Katanga, D.R. Congo     

Stijn Dewaele  Philippe Muchez  Wouter Heijlen  Amanda Boutwood  Terry Lemmon  Roger Tyler 《Journal of Geochemical Exploration》2006,89(1-3):376

The Kundelungu foreland, north of the Lufilian arc in the Democratic Republic of Congo, contains a number of various vein-type and stratiform copper mineralisations. The geodynamic context and metallogenesis of these mineral occurrences remain enigmatic. Currently, the vein-type Cu–Ag ore deposit at Dikulushi is the most significant deposit in the region. Mineralisation at Dikulushi comprises two major styles: 1) a polysulphide assemblage (Zn–Pb–Fe–Cu–As) within brecciated rocks along an anticlinal closure; and 2) a vein-hosted Cu–Ag assemblage. Petrographic and fluid inclusion studies indicate that the early Zn–Pb–Fe–Cu–As assemblage formed from a high-salinity Ca–Na–Cl fluid of modest temperature (135–172 °C). The later, economically more significant vein-related Cu–Ag mineralisation formed from intermediate salinity, lower temperature (46–82 °C) Na–Cl fluids. Weathering of the sulphide minerals resulted in a supergene enrichment with the formation of secondary Cu-minerals.  相似文献   

Spatial characterization of land surface energy fluxes and uncertainty estimation at the Salar de Atacama,Northern Chile     

Stephanie K. Kampf  Scott W. Tyler 《Advances in water resources》2006

We use Advanced Spaceborne Thermal Emission and Reflection radiometer (ASTER) data to estimate spatial energy flux and evaporation distributions at the Salar de Atacama, a playa in Northern Chile. Our approach incorporates ASTER surface kinetic temperature, emissivity, and reflectance data, ground-based meteorological measurements, and empirical parameters. Energy flux distributions are estimated using either spatially constant or spatially distributed values of model parameters, with spatially distributed parameters assigned separately to each land cover category in an image classification. We test the sensitivity of energy budget calculations to state variable and parameter values by conducting Monte Carlo simulations for regions with ground energy budget measurements. Results show that assigning spatially distributed model parameters via land cover classifications yields significant improvements to ground and sensible heat flux predictions. Latent heat fluxes cannot, however, be predicted with sufficient accuracy to allow estimation of area-integrated evaporative moisture loss at this low-evaporation playa.  相似文献   

Evaporation and land surface energy budget at the Salar de Atacama, Northern Chile   总被引：3，自引：0，他引：3  

Stephanie K. Kampf  Scott W. Tyler  Cristin A. Ortiz  Jos F. Muoz  Paula L. Adkins 《Journal of Hydrology》2005,310(1-4):236-252

Playa systems are driven by evaporation processes, yet the mechanisms by which evaporation occurs through playa salt crusts are still poorly understood. In this study we examine playa evaporation as it relates to land surface energy fluxes, salt crust characteristics, groundwater and climate at the Salar de Atacama, a 3000 km² playa in northern Chile containing a uniquely broad range of salt crust types. Land surface energy budget measurements were taken at eight representative sites on this playa during winter (August 2001) and summer (January 2002) seasons. Measured values of net all-wave radiation were highest at vegetated and rough halite crust sites and lowest over smooth, highly reflective salt crusts. Over most of the Salar de Atacama, net radiation was dissipated by means of soil and sensible heat fluxes. Dry salt crusts tended to heat and cool very quickly, whereas soil heating and cooling occurred more gradually at wetter vegetated sites. Sensible heating was strongly linked to wind patterns, with highest sensible heat fluxes occurring on summer days with strong afternoon winds. Very little energy available at the land surface was used to evaporate water. Eddy covariance measurements could only constrain evaporation rates to within 0.1 mm d⁻¹, and some measured evaporation rates were less than this margin of uncertainty. Evaporation rates ranged from 0.1 to 1.1 mm d⁻¹ in smooth salt crusts around the margin of the salar and from 0.4 to 2.8 mm d⁻¹ in vegetated areas. No evaporation was detected from the rugged halite salt crust that covers the interior of the salar, though the depth to groundwater is less than 1 m in this area. These crusts therefore represent a previously unrecorded end member condition in which the salt crusts form a practically impermeable barrier to evaporation.  相似文献   

Concerning the derivation of the KS-transformation     

Otto Volk 《Celestial Mechanics and Dynamical Astronomy》1973,8(2):297-305

The Kustaanheimo-Stiefel (KS) transformation is shown to follow naturally from the general solution of the two-body motion if half-arguments are introduced. Application to collision orbits and to the exact triangular solutions of Lagrange (vide E. Stiefel and G. Scheifele: 1971,Linear and Regular Celestial Mechanics, Springer, Berlin-Heidelberg-New York, p. 23–35).Notations x Position vector (x, y, z) - r=|x| Distance from the origin - 1/2h Energy constant or Kepler motion - c Angular momentum vector of Kepler motion - t physical time ()^·=d/dt () - new independent variable ()=d/d () Note by editor: This is the well-known Three-dimensional regularization, published in 1965 by P. Kustaanheimo and E. Stiefel, Perturbation Theory of Kepler Motion Based on Spinor Regularization,J. reine angewandte Mathematik 218, 204. The present article was written during Professor Volk's stay at the Zurich Technische Hochschule in 1972, when he also celebrated his 80th birthday.  相似文献   

The microwave opacity of Saturn's rings at wavelengths of 3.6 and 13 cm from Voyager 1 radio occultation     

G.Leonard Tyler  Essam A. Marouf  Richard A. Simpson  Howard A. Zebker  Von R. Eshleman 《Icarus》1983,54(2):160-188

Radio occultation observations of Saturn's rings with Voyager 1 provided independent measurements of complex (amplitude and phase) microwave extinction and near-forward scattering cross section of the rings at wavelengths (λ) of 3.6 and 13 cm. The ring opening was 5.9°. The normal microwave opacities, τ[3.6] and τ[13], provide a measure of the total cross-sectional area of particles larger than about 1 and 4 cm radius, respectively. Ring C exhibits gently undulating (～ 1000 km) structure of normal opacity τ[3.6] ? 0.25 except for several narrow imbedded ringlets of less than about 100 km width and τ[3.6] ～ 0.5 to 1.0. The normalized differential opacity Δτ/τ[3.6], where Δτ = τ[3.6] ? τ[13], is about 0.3 over most of ring C, indicating a substantial fraction of centimeter-size particles. Some narrow imbedded ringlets show marked increases in Δτ/τ[3.6] near their edges, implying an enhancement in the relative population of centimeter-size and smaller particles at those locations. In the Cassini division, several sharply defined gaps separate regions of opacity τ ～ 0.08 and τ ～ 0.25; the opacity in the Cassini Division appears to be nearly independent of λ. The boundary features at the outer edges of ring C and the Cassini Division are remarkably similar in width and opacity profile, suggesting a similar dynamical control. Ring A appears to be nearly homogeneous over much of its width with 0.6 < τ[3.6] < 0.8 but with considerable thickening, to τ[3.6] ～ 1.0, near its inner boundary with the Cassini division. Normalized differential opacity decreases from ～0.3 at the inner and outer edges of ring A to Δτ/τ[3.6] ～ 0 at a point about one-third of the distance from the inner edge to the outer. The inner one-fourth of ring B has τ[3.6] ～ 1.0, except very near the boundary with ring C, where it is greater. The outer three-fourths of ring B has $\text{τ[3.6] ? 1.2}$. The differential opacity for the inner one-fourth of ring B is Δτ/τ[3.6] ～ 0.15. There are no gaps in ring B exceeding about 2 km in width. Ring F was observed at 3.6 cm as a single ringlet of radial width $\text{? 2}\text{km}$, but was not detected in 13 cm data.  相似文献   

Probable PSD behaviour in the Rossville-type diabase of Pennsylvania     

Karen Wagner Volk 《Geophysical Journal International》1977,49(3):685-693

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The analysis of oil trapped during secondary migration   总被引：1，自引：0，他引：1  

Simon C. George  Manzur Ahmed  Keyu Liu  Herbert Volk 《Organic Geochemistry》2004,35(11-12):1489

During secondary migration, there is an opportunity for oil to be trapped as fluid inclusions (FIs) within framework grains such as quartz and within diagenetic cements that have a crystalline structure. Oil saturation on migration pathways remains relatively low, so typically fewer oil inclusions get trapped compared with samples from an oil column. Geochemical analysis of the much smaller amounts of inclusion oil present in samples from interpreted oil migration pathways has been attempted for two samples from the Champagny-1 and Delamere-1 wells in the Vulcan Sub-Basin, northern offshore Australia. A combination of petrographic analysis, bulk geochemical inclusion analysis and log evaluation confirmed that both samples were from oil migration pathways. Despite the small number of oil inclusions, reliable geochemical data were acquired from both samples that were significantly above the levels detected for the system and outside-rinse blanks. The FI oil trapped on the interpreted oil migration pathway in Champagny-1 was generated from clay-rich marine source rock with little terrigenous organic matter input. It was generated at peak oil window maturity and correlates best with oils derived from the Late Jurassic Lower Vulcan Formation. In contrast, the Delamere-1 FI oil contains evidence of greater input of terrigenous organic matter and was generated at early oil window maturity. This FI oil also contains a signature of a biodegraded component, which could have been generated either from the Middle Jurassic Plover Formation, or from an older source rock. These data indicate that it is feasible to geochemically map migration pathways across prospects or basins, and to analyse palaeo-oil compositions in oil zones where the few inclusions get trapped. This also suggests that the few oil inclusions that sometimes occur in Proterozoic or Archaean rocks may be analysable in the future, which would provide relatively pristine and robust data on the composition and diversity of Earth’s early biosphere.  相似文献