Suitability of Mn‐ and Fe‐Rich Reference Materials for Microanalytical Research          下载免费PDF全文

Dorothea S. Macholdt  Klaus Peter Jochum  Stephen A. Wilson  Laura M. Otter  Brigitte Stoll  Ulrike Weis  Meinrat O. Andreae 《Geostandards and Geoanalytical Research》2016,40(4):493-504

Manganese‐ and iron‐rich materials are of major geoscientific and economic interest, many of which contain microscopic features that provide valuable information. To obtain accurate results, a homogeneous microanalytical reference material for calibration is needed. Several researchers have used the Mn‐ and Fe‐rich RMs, JMn‐1, NOD‐A‐1, NOD‐P‐1 and FeMn‐1, for this purpose; therefore, they were tested in this study to determine their suitability for microanalysis. Their homogeneity was investigated by laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) with two different types of lasers (nano‐ and femtosecond), with spot and line scan analyses and with different operating parameters, such as spot size, pulse repetition rate and fluence. As the established manganese nodule RMs revealed inhomogeneities for picogram to microgram test portions, we also investigated the new synthetic Fe‐ and Mn‐rich RM, FeMnOx‐1. FeMnOx‐1 was found to be homogeneous for large (ø 40 μm: 2% RSD repeatability) and small (ø 8–10 μm: 10% RSD repeatability) spot sizes. This homogeneity is in the range of the homogeneous NIST SRM 610 and GSE‐1G reference glasses. Furthermore, FeMnOx‐1 revealed a large‐scale homogeneity within uncertainties of a few per cent, using test portions in the ng range, when measuring four individual mounts of this material.  相似文献   

Experimente zum Einfluß des Gesteinsglas-Chemismus auf die Zeolithbildung durch hydrothermale Umwandlung     

Ulrike Wirsching 《Contributions to Mineralogy and Petrology》1975,49(2):117-124

In the formation of zeolites by hydrothermal alteration volcanic glasses are the starting material in most cases. The experiments aimed at demonstrating in what way the chemistry of the volcanic glass influences:

1. the alteration rate of the volcanic glass to zeolites,
2. the kind of zeolites being formed and their formation conditions.

Three volcanic glasses were used, a basaltic, a phonolitic, and a rhyolitic one. The experimental conditions were as similar as possible to the natural alteration conditions. Solutions being used: H₂O dist (pH ～5.5), 0.01 n NaOH (pH ～10.5), and solutions of similar chemistry to the natural ones. The temperatures were 180 °, 200 °, 250 ° C. The experiments were carried out both in closed and in open systems. The experimental results show a difference in the alteration rate and in the zeolites being formed between the basaltic and the phonolitic glasses on the one hand and the rhyolitic one on the other. In case of the closed system the SiO₂-poor volcanic glasses react more rapidly than the SiO₂-rich one. The zeolites being formed are chabazite, phillipsite, analcime respectively mordenite, analcime. In case of the open system the influence of the chemistry of the volcanic glass on the alteration rate and the zeolite being formed is less significant. Which zeolite is formed at a given temperature depends on: the chemistry of the starting material, the chemistry of the reacting solution and wether there is a closed or an open system.  相似文献   

Single-domain chemical, thermochemical and thermal remanences in a basaltic rock     

Ulrike Draeger  Michel Prévot  Thierry Poidras  Janna Riisager † 《Geophysical Journal International》2006,166(1):12-32

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Water residence time as a driving force of zooplankton structure and succession     

Ulrike Obertegger  Giovanna Flaim  Maria Giovanna Braioni  Ruben Sommaruga  Flavio Corradini  Andrea Borsato 《Aquatic Sciences - Research Across Boundaries》2007,69(4):575-583

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Ar/Ar geochronology of Neogene phreatomagmatic volcanism in the western Pannonian Basin,Hungary     

Jan Wijbrans  Károly Németh  Ulrike Martin  Kadosa Balogh 《Journal of Volcanology and Geothermal Research》2007

Neogene alkaline basaltic volcanic fields in the western Pannonian Basin, Hungary, including the Bakony–Balaton Highland and the Little Hungarian Plain volcanic fields are the erosional remnants of clusters of small-volume, possibly monogenetic volcanoes. Moderately to strongly eroded maars, tuff rings, scoria cones, and associated lava flows span an age range of ca. 6 Myr as previously determined by the K/Ar method. High resolution ⁴⁰Ar/³⁹Ar plateau ages on 18 samples have been obtained to determine the age range for the western Pannonian Basin Neogene intracontinental volcanic province. The new ⁴⁰Ar/³⁹Ar age determinations confirm the previously obtained K/Ar ages in the sense that no systematic biases were found between the two data sets. However, our study also serves to illustrate the inherent advantages of the ⁴⁰Ar/³⁹Ar technique: greater analytical precision, and internal tests for reliability of the obtained results provide more stringent constraints on reconstructions of the magmatic evolution of the volcanic field. Periods of increased activity with multiple eruptions occurred at ca. 7.95 Ma, 4.10 Ma, 3.80 Ma and 3.00 Ma.  相似文献   

Nano‐Powdered Calcium Carbonate Reference Materials: Significant Progress for Microanalysis?     

Klaus Peter Jochum  Dieter Garbe‐Schnberg  Marina Veter  Brigitte Stoll  Ulrike Weis  Michael Weber  Federico Lugli  Anna Jentzen  Ralf Schiebel  Jasper A. Wassenburg  Dorrit E. Jacob  Gerald H. Haug 《Geostandards and Geoanalytical Research》2019,43(4):595-609

Homogeneity, mass fractions of about forty trace elements and Sr isotope composition of Ca carbonate reference materials (RMs) between original and nano‐powdered pellets are compared. Our results using nanosecond and femtosecond LA‐(MC)‐ICP‐MS show that the nano‐pellets of the RMs MACS‐3NP, JCp‐1NP and JCt‐1NP are about a factor of 2–3 more homogeneous than the original samples MACS‐3, JCp‐1 and JCt‐1, and are therefore much more suitable for microanalytical purposes. With the exception of Si, the mass fractions of the synthetic RM MACS‐3 agree with its fine‐grained analogue MACS‐3NP. Very small, but significant, differences between original and nano‐pellets are observed in the RMs JCp‐1 and JCt‐1 for some trace elements with very low contents, indicating the need for re‐certification. Strontium mass fractions in the analysed RMs are high (1500–7000 mg kg^?1), and their isotope compositions determined by LA‐MC‐ICP‐MS in the original and the nano‐pellets agree within uncertainty limits.  相似文献   

First lacustrine varve chronologies from Mexico: impact of droughts,ENSO and human activity since AD 1840 as recorded in maar sediments from Valle de Santiago   总被引：1，自引：0，他引：1  

Ulrike Kienel  Sabine Wulf Bowen  Roger Byrne  Jungjae Park  Harald Böhnel  Peter Dulski  James F. Luhr  Lee Siebert  Gerald H. Haug  Jörg F. W. Negendank 《Journal of Paleolimnology》2009,42(4):587-609

We present varve chronologies for sediments from two maar lakes in the Valle de Santiago region (Central Mexico): Hoya La Alberca (AD 1852–1973) and Hoya Rincón de Parangueo (AD 1839–1943). These are the first varve chronologies for Mexican lakes. The varved sections were anchored with tephras from Colima (1913) and Paricutín (1943/1944) and ²¹⁰Pb ages. We compare the sequences using the thickness of seasonal laminae and element counts (Al, Si, S, Cl, K, Ti, Mn, Fe, and Sr) determined by micro X-ray fluorescence spectrometry. The formation of the varve sublaminae is attributed to the strongly seasonal climate regime. Limited rainfall and high evaporation rates in winter and spring induce precipitation of carbonates (high Ca, Sr) enriched in ¹³C and ¹⁸O, whereas rainfall in summer increases organic and clastic input (plagioclase, quartz) with high counts of lithogenic elements (K, Al, Ti, and Si). Eolian input of Ti occurs also in the dry season. Moving correlations (5-yr windows) of the Ca and Ti counts show similar development in both sequences until the 1930s. Positive correlations indicate mixing of allochthonous Ti and autochthonous Ca, while negative correlations indicate their separation in sublaminae. Negative excursions in the correlations correspond with historic and reconstructed droughts, El Niño events, and positive SST anomalies. Based on our data, droughts (3–7 year duration) were severe and centred around the following years: the early 1850s, 1865, 1880, 1895, 1905, 1915 and the late 1920s with continuation into the 1930s. The latter dry period brought both lake systems into a critical state making them susceptible to further drying. Groundwater overexploitation due to the expansion of irrigation agriculture in the region after 1940 induced the transition from calcite to aragonite precipitation in Alberca and halite infiltration in Rincón. The proxy data indicate a faster response to increased evaporation for Rincón, the lake with the larger maar dimensions, solar radiation receipt and higher conductivity, whereas the smaller, steeper Alberca maar responded rapidly to increased precipitation.  相似文献   

Quantitative relationship between water-depth and sub-fossil ostracod assemblages in Lake Donggi Cona,Qinghai Province,China     

Steffen Mischke  Ulrich Bößneck  Bernhard Diekmann  Ulrike Herzschuh  Huijun Jin  Annette Kramer  Bernd Wünnemann  Chengjun Zhang 《Journal of Paleolimnology》2010,43(3):589-608

A calibration data set of 51 surface sediment samples from Lake Donggi Cona on the northeastern Tibetan Plateau was investigated to study the relationship between sub-fossil ostracod assemblages and water depth. Samples were collected over a depth range from 0.6 to 80 m. A total of 16 ostracod species was identified from the lake with about half of the species restricted to the Tibetan Plateau and its adjacent mountain ranges and poorly known in terms of ecological preferences, and the other half displaying a mainly Holarctic distribution. Living macrophytes and macroalgae were recorded in Lake Donggi Cona down to a depth of about 30 m, and bivalve (Pisidium cf. zugmayeri) and gastropod (Gyraulus, Radix) shells were found down to depths of 43 and 48 m, respectively. The ostracod-water-depth relationship was assessed by multivariate statistical analysis and ostracod-based transfer functions for water depth were constructed. Weighted averaging partial least squares (WA-PLS) regression provided the best model with a coefficient of determination r ² of 0.91 between measured and ostracod-inferred water depth, a root mean square error of prediction of 8% and a maximum bias of 10.6% of the gradient length, as assessed by leave-one-out cross-validation. Our results show the potential of ostracods as palaeo-depth indicators in appropriate settings. However, transfer-function applications using fossil ostracod assemblages for palaeo-depth estimations require a thorough understanding of the palaeolimnological conditions of lakes and therefore detailed multi-proxy analysis to avoid misinterpretation of ostracod-based inferences.  相似文献   

Using variations in the stable carbon isotope composition of macrophyte remains to quantify nutrient dynamics in lakes     

Ulrike Herzschuh  Steffen Mischke  Hanno Meyer  Birgit Plessen  Chengjun Zhang 《Journal of Paleolimnology》2010,43(4):739-750

The apparent isotope enrichment factor ε_macrophyte of submerged plants (ε_{macrophyte–DIC} = δ¹³C_macrophyte − δ¹³C_DIC) is indicative of dissolved inorganic carbon (DIC) supply in neutral to alkaline waters and is related to variations in aquatic productivity (Papadimitriou et al. in Limnol Oceanogr 50:1084–1095, 2005). This paper aims to evaluate the usage of ε_macrophyte inferred from isotopic analyses of submerged plant fossils in addition to analyses of lake carbonate as a palaeolimnological proxy for former HCO₃ ⁻ concentrations. Stable carbon isotopic analysis of modern Potamogeton pectinatus leaves and its host water DIC from the Tibetan Plateau and Central Yakutia (Russia) yielded values between −23.3 and +0.4‰ and between +14.0 and +6.5‰, respectively. Values of ε _{Potamogeton–DIC} (range −15.4 to +1.1‰) from these lakes are significantly correlated with host water HCO₃ ⁻ concentration (range 78–2,200 mg/l) (r = −0.86; P < 0.001), thus allowing for the development of a transfer function. Palaeo-ε _{Potamogeton–ostracods} values from Luanhaizi Lake on the NE Tibetan Plateau, as inferred from the stable carbon isotope measurement of fossil Potamogeton pectinatus seeds (range −24 to +2.8‰) and ostracods (range −7.8 to +7.5%) range between −14.8 and 1.6‰. Phases of assumed disequilibrium between δ¹³C_DIC and δ¹³C_ostracods known to occur in charophyte swards (as indicated by the deposition of charophyte fossils) were excluded from the analysis of palaeo-ε. The application of the ε _{Potamogeton–DIC}-HCO₃ ⁻ transfer function yielded a median palaeo-HCO₃ ⁻ -concentration of 290 mg/l. Variations in the dissolved organic carbon supply compare well with aquatic plant productivity changes and lake level variability as inferred from a multiproxy study of the same record including analyses of plant macrofossils, ostracods, carbonate and organic content.  相似文献   

Late Pleistocene sediments and environmental change at Plaza Creek,Falkland Islands,South Atlantic     

Richard Clark  Ulrike Maria Huber  Peter Wilson 《第四纪科学杂志》1998,13(2):95-105

Late Pleistocene organic-rich sediments exposed in coastal bluffs near the head of Plaza Creek, East Falkland, have yielded conventional and AMS ¹⁴C dates of between 36 and 28 ka BP, and possess a pollen spectrum dominated by grasses, indicating a vegetation assemblage similar to that of the present day. Although some sample dates are anomalous and contamination by non-contemporaneous carbon cannot be ruled out entirely, the age estimates are consistent with evidence and dates from Antarctica, South America and the amphi-North Atlantic for climate shifts to interstadial conditions at around that time. The organic-rich units are developed in and enclosed by deposits attributed to processes of periglacial mass wasting. Grain-size characteristics suggest that these sediments may have been emplaced by solifluction, shallow translational landsliding and surface wash in at least five mass-wasting episodes. Some of the mass-wasting sediments might correlate with solifluction deposits above and below a podsolic soil dated to 26 ka BP at San Carlos, East Falkland, and with periods of cirque and valley glaciation identified in the uplands of the Falkland Islands. The similarity between late Pleistocene interstadial, Holocene and present-day pollen assemblages, and the lack of vegetation change within these periods, is characteristic of most cool temperate Southern Ocean islands, and may reflect the lack of sensitivity of the vegetation to climate change and/or a lack of climate variability for the time intervals covered. © 1998 John Wiley & Sons, Ltd.  相似文献