Entropy production and coarse graining of the climate fields in a general circulation model     

Valerio Lucarini  Salvatore Pascale 《Climate Dynamics》2014,43(3-4):981-1000

We extend the analysis of the thermodynamics of the climate system by investigating the role played by processes taking place at various spatial and temporal scales through a procedure of coarse graining. We show that the coarser is the graining of the climatic fields, the lower is the resulting estimate of the material entropy production. In other terms, all the spatial and temporal scales of variability of the thermodynamic fields provide a positive contribution to the material entropy production. This may be interpreted also as that, at all scales, the temperature fields and the heating fields resulting from the convergence of turbulent fluxes have a negative correlation, while the opposite holds between the temperature fields and the radiative heating fields. Moreover, we obtain that the latter correlations are stronger, which confirms that radiation acts as primary driver for the climatic processes, while the material fluxes dampen the resulting fluctuations through dissipative processes. We also show, using specific coarse-graining procedures, how one can separate the various contributions to the material entropy production coming from the dissipation of kinetic energy, the vertical sensible and latent heat fluxes, and the large scale horizontal fluxes, without resorting to the full three-dimensional time dependent fields. We find that most of the entropy production is associated to irreversible exchanges occurring along the vertical direction, and that neglecting the horizontal and time variability of the fields has a relatively small impact on the estimate of the material entropy production. The approach presented here seems promising for testing climate models, for assessing the impact of changing their parametrizations and their resolution, as well as for investigating the atmosphere of exoplanets, because it allows for evaluating the error in the estimate of their thermodynamical properties due to the lack of high-resolution data. The findings on the impact of coarse graining on the thermodynamic fields on the estimate of the material entropy production deserve to be explored in a more general context, because they provide a way for understanding the relationship between forced fluctuations and dissipative processes in continuum systems.  相似文献   

Revisiting the Concentration Observations and Source Apportionment of Atmospheric Ammonia     

Yuepeng PAN  Mengna GU  Yuexin HE  Dianming WU  Chunyan LIU  Linlin SONG  Shili TIAN  Xuemei Lü  Yang SUN  Tao SONG  Wendell W. WALTERS  Xuejun LIU  Nicholas A. MARTIN  Qianqian ZHANG  Yunting FANG  Valerio FERRACCI  Yuesi WANG 《大气科学进展》2020,37(9):933-938

正While China’s Air Pollution Prevention and Control Action Plan on particulate matter since 2013 has reduced sulfate significantly, aerosol ammonium nitrate remains high in East China. As the high nitrate abundances are strongly linked with ammonia, reducing ammonia emissions is becoming increasingly important to improve the air quality of China. Although satellite data provide evidence of substantial increases in atmospheric ammonia concentrations over major agricultural regions, long-term surface observation of ammonia concentrations are sparse. In addition, there is still no consensus on  相似文献   

Erratum to “on the inclination distribution of the jovian irregular satellites”[Icarus 158 (2002) 434-449]     

Valerio Carruba  Joseph A. Burns  Philip D. Nicholson 《Icarus》2003,162(1):230-231

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Correlations between diffuse interstellar bands and atomic lines     

G. A. Galazutdinov  Giulio Manicò  Valerio Pirronello  Jacek Kre&#;owski 《Monthly notices of the Royal Astronomical Society》2004,355(1):169-177

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A GIS-based approach for gully erosion susceptibility modelling: a test in Sicily, Italy   总被引：4，自引：1，他引：3  

Christian Conoscenti  Valerio Agnesi  Silvia Angileri  Chiara Cappadonia  Edoardo Rotigliano  Michael Märker 《Environmental Earth Sciences》2013,70(3):1179-1195

The aim of this study is to analyze the susceptibility conditions to gully erosion phenomena in the Magazzolo River basin and to test a method that allows for driving the factors selection. The study area is one of the largest (225 km²) watershed of southern Sicily and it is mostly characterized by gentle slopes carved into clayey and evaporitic sediments, except for the northern sector where carbonatic rocks give rise to steep slopes. In order to obtain a quantitative evaluation of gully erosion susceptibility, statistical relationships between the spatial distributions of gullies affecting the area and a set of twelve environmental variables were analyzed. Stereoscopic analysis of aerial photographs dated 2000, and field surveys carried out in 2006, allowed us to map about a thousand landforms produced by linear water erosion processes, classifiable as ephemeral and permanent gullies. The linear density of the gullies, computed on each of the factors classes, was assumed as the function expressing the susceptibility level of the latter. A 40-m digital elevation model (DEM) prepared from 1:10,000-scale topographic maps was used to compute the values of nine topographic attributes (primary: slope, aspect, plan curvature, profile curvature, general curvature, tangential curvature; secondary: stream power index; topographic wetness index; LS-USLE factor); from available thematic maps and field checks three other physical attributes (lithology, soil texture, land use) were derived. For each of these variables, a 40-m grid layer was generated, reclassifying the topographic variables according to their standard deviation values. In order to evaluate the controlling role of the selected predictive variables, one-variable susceptibility models, based on the spatial relationships between each single factor and gullies, were produced and submitted to a validation procedure. The latter was carried out by evaluating the predictive performance of models trained on one half of the landform archive and tested on the other. Large differences of accuracy were verified by computing geometric indexes of the validation curves (prediction and success rate curves; ROC curves) drawn for each one-variable model; in particular, soil texture, general curvature and aspect demonstrated a weak or a null influence on the spatial distribution of gullies within the studied area, while, on the contrary, tangential curvature, stream power index and plan curvature showed high predictive skills. Hence, predictive models were produced on a multi-variable basis, by variously combining the one-variable models. The validation of the multi-variables models, which generally indicated quite satisfactory results, were used as a sensitivity analysis tool to evaluate differences in the prediction results produced by changing the set of combined physical attributes. The sensitivity analysis pointed out that by increasing the number of combined environmental variables, an improvement of the susceptibility assessment is produced; this is true with the exception of adding to the multi-variables models a variable, as slope aspect, not correlated to the target variable. The addition of this attribute produces effects on the validation curves that are not distinguishable from noise and, as a consequence, the slope aspect was excluded from the final multi-variables model used to draw the gully erosion susceptibility map of the Magazzolo River basin. In conclusion, the research showed that the validation of one-variable models can be used as a tool for selecting factors to be combined to prepare the best performing multi-variables gully erosion susceptibility model.  相似文献   

Retrieval and tentative indentification of the 3 μm spectral feature in Titan's haze     

Sang J. Kim  C.K. Sim  A. Bellucci  I.O. Song 《Planetary and Space Science》2011,59(8):699-704

Recently, an unidentified 3.3-3.4 μm feature found in the solar occultation spectra of the atmosphere of Titan observed by Cassini/VIMS was tentatively attributed to the C-H stretching mode of aliphatic hydrocarbon chains attached to large organic molecules, but without properly extracting the feature from adjacent influences of strong CH₄ and weak C₂H₆ absorptions (Bellucci et al., 2009). In this work, we retrieve the detailed spectral feature using a radiative transfer program including absorption and fluorescent emission of both molecules, as well as absorption and scattering by haze particles. The spectral features of the haze retrieved from the VIMS data at various altitudes are similar to each other, indicating relatively uniform spectral properties of the haze with altitude. However, slight deviations observed near 127 km and above 300 km suggest inhomogeneity at these altitudes. We find that the positions of the major spectral peaks occur at 3.33-3.37 μm, which are somewhat different from the typical 3.3 μm aromatic or 3.4 μm aliphatic C-H stretches usually seen in the spectra of dust particles of the interstellar medium and comets. The peaks, however, coincide with those of the solid state spectra of C₂H₆, CH₄, and CH₃CN; and a broad shoulder from 3.37 to 3.50 μm coincides with those of C₅H₁₂ and C₆H₁₂ as well as those of typical aliphatic C-H stretches. This result combined with high-altitude (∼1000 km) haze formation process recently reported by Waite et al. (2007) opens a new question on the chemical composition of the haze particles. We discuss the possibility that the 3 μm feature may be due to the solid state absorption bands of these molecules (or some other molecules) and we advocate additional laboratory measurements for the ices of hydrocarbon and nitrogen-bearing molecules present in Titan's atmosphere for the identification of this 3 μm feature.  相似文献   

AOST: Fourier spectrometer for studying mars and phobos     

O. I. Korablev  A. V. Grigor’ev  B. E. Moshkin  L. V. Zasova  F. Montmessin  A. B. Gvozdev  V. N. Shashkin  D. V. Patsaev  V. S. Makarov  S. V. Maksimenko  N. I. Ignatiev  A. A. Fedorova  G. Arnold  A. V. Shakun  A. I. Terentiev  A. V. Zharkov  B. S. Mayorov  Yu. V. Nikol’sky  I. V. Khatuntsev  G. Bellucci  M. Giuranna  R. O. Kuz’min  A. V. Rodin 《Solar System Research》2012,46(1):31-40

An AOST Fourier spectrometer of the Phobos-Soil project is intended for studying Mars and Phobos by means of measurements of IR radiation spectra of the Martian surface and atmosphere, the Phobos surface, and the spectrum of solar radiation passing through the Martian atmosphere on its limb. The main scientific problems to be solved with the spectrometer on Mars are measurements of methane content, search for minor constituents, and study of diurnal variations in the temperature and atmospheric aerosol. The spectrometer will also study the Martian and Phobos surface both remotely and after landing. The spectral range of the instrument is 2.5?C25 ??m, the best spectral resolution (without apodization) is 0.6 cm^?1, and the instantaneous field of view is 2.5°. The recording time of one spectrum is equal to 5 s in solar observations and 50 s in observations of Mars and Phobos. The instrument has self-thermal stabilization and two-axis pointing systems, as well as a built-in radiation source for flight calibration. The spectrometer mass is 4 kg, and power consumption is up to 13 W. Scientific problems, measurement modes, and, briefly, engineering implementation of the experiment are discussed in this work.  相似文献   

Reconstruction of hydrocarbons accumulation in sediments affected by the oil refinery industry: the case of Tehuantepec Gulf (Mexico)     

Ana Carolina Ruiz-Fernández  Mario Sprovieri  Mauro Frignani  Joan Albert Sanchez-Cabeza  Maria Luisa Feo  Luca Giorgio Bellucci  Libia Hascibe Pérez-Bernal  Michel Preda  María Luisa Machain-Castillo 《Environmental Earth Sciences》2012,67(3):727-742

The Isthmus of Tehuantepec corresponds to the shortest distance (~200?km) between the Gulf of Mexico and the Pacific Ocean in Southern Mexico, and the main economical activity of this region is oil extraction and refining. Polycyclic aromatic hydrocarbons (PAHs) and total petroleum hydrocarbons (TPHs) were determined in a ²¹⁰Pb dated sediment core collected from the continental shelf of Tehuantepec Gulf, in the vicinity of the oil refinery of Salina Cruz, Oaxaca, the main oil refining facility of the country. The sediments were mostly of coarse nature and hence PAHs and TPHs concentrations throughout the core (61?C404???g?g^?1 and 29?C154?mg?kg^?1, respectively) were below international quality benchmarks. Depth profiles of both PAHs and TPHs concentrations showed increasing trends since the early 1900s but the higher values were found from the 1950s to present. PAH congener ratios showed that these contaminants had both petrogenic and pyrolitic sources, although the former has been predominant since the 1970s. The Salina Cruz refinery started operations in 1978 but the oil industry activities in the Tehuantepec Isthmus go back to the beginning of the twentieth century with the operation of Minatitlan refinery in the Gulf of Mexico, and the Gulf of Tehuantepec being the main conduit for oil distribution in the Pacific coast. The observed changes in contaminant distributions described well the oil industry development in the area.  相似文献   

Mitochondrial DNA and microsatellites reveal significant divergence in the beachflea Orchestia montagui (Talitridae: Amphipoda)     

Laura Pavesi  Alan Deidun  Elvira De Matthaeis  Ralph Tiedemann  Valerio Ketmaier 《Aquatic Sciences - Research Across Boundaries》2012,74(3):587-596

Talitrids are semiterrestrial crustacean amphipods inhabiting sandy and rocky beaches; they generally show limited active dispersal over long distances. In this study we assessed levels of population genetic structure and variability in the talitrid amphipod Orchestia montagui, a species strictly associated to stranded decaying heaps of the seagrass Posidonia oceanica. The study is based on six populations (153 individuals) and covers five basins of the Mediterranean Sea (Tyrrhenian, Ionian, Adriatic, Western and Eastern basins). Samples were screened for polymorphisms at a fragment of the mitochondrial DNA (mtDNA) coding for the cytochrome oxidase subunit I gene (COI; 571 base pairs) and at eight microsatellite loci. MtDNA revealed a relatively homogeneous haplogroup, which clustered together the populations from the Western, Tyrrhenian and Eastern basins, but not the populations from the Adriatic and Ionian ones; microsatellites detected two clusters, one including the Adriatic and Ionian populations, the second grouping all the others. We found a weak geographic pattern in the genetic structuring of the species, with a lack of isolation by distance at either class of markers. Results are discussed in terms of probability of passive dispersal over long distances through heaps of seagrass.  相似文献   

Statistical correlation of earthquake and ambient noise spectral ratios     

Giovanna Cultrera  Valerio De Rubeis  Nikos Theodoulidis  Héloïse Cadet  Pierre-Yves Bard 《Bulletin of Earthquake Engineering》2014,12(4):1493-1514

The Horizontal-to-Vertical Spectral Ratio from earthquake (HVSR) and from ambient noise (HVN) recordings realistically indicate the fundamental frequency of soil response but, for the majority of the worldwide examined sites, they do not provide reliable amplification curves as calculated by the earthquake standard Spectral Ratio (SSR). Given the fact that HVSR and especially HVN can be easily obtained, it is challenging to search for a meaningful correlation with SSR amplification functions for the entire frequency band and to use the results for the SSR estimate at a further site where only noise measurements are available. To this aim we used recordings from 75 sites worldwide and we applied a multivariate statistical approach (canonical correlation analysis) to investigate and quantify any correlation among spectral ratios. The canonical correlation between SSR and HVN is then used to estimate the expected SSR at each site by a weighted average of the SSR values measured at the other sites; the weights are properly set to account more for sites with similar behaviour in terms of the canonical correlation results between HVN and SSR. This procedure, repeated for all sites in turn, constitutes the basis of a cross validation. The comparison between the inferred and the original SSR highlights the improvements of site response estimation with respect to the use of ambient noise techniques. The goodness and limitations of the reconstruction procedure are explained by specific geological settings.  相似文献