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81.
82.
Samples from nine Central Vietnam coastal lagoons, together with three soils and sediments collected in two freshwater reservoirs of the Thua Thien-Hué province, were analysed for polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). Total concentrations are low, from 192 to 2912 pg g−1 and depth profiles in Tam Giang-Cau Hai (TG-CH) sediment cores show only minor changes over time in PCDD/F input and composition. Octachloro dibenzo-p-dioxin (OCDD) is the prevailing congener (approximately 90%), indicating combustion as the main PCDD/F source to these coastal systems, whereas natural formation might be partly responsible for the presence at depth. 2,3,7,8-Tetrachloro dibenzo-p-dioxin (TCDD), largely sprayed together with Agent Orange over the study areas during the war (1961–1971), is absent or very low. This result supports the hypothesis of strong degradation soon after spraying. Multivariate statistical analyses account for the presence of local, short-range sources as observed in the northern part of the TG-CH lagoon.  相似文献   
83.
F. Altieri  L. Zasova  G. Bellucci  B. Gondet 《Icarus》2009,204(2):499-511
We present a method to derive the 2D maps of the O2 (a1Δg) airglow emission at 1.27 μm from the OMEGA/MEx nadir observations. The OMEGA imaging capabilities allow monitoring the 2D distribution, daily and seasonal variation of the O2 emission intensities with a detection limit of 4 MR. The highest values, of the order of ∼31 MR, are found on the south pole for 11 h < LT < 13 h, during the early spring (186° < Ls < 192°) of martian year (MY) 27, according to the Mars Year numbering scheme of Clancy et al. [Clancy, R.T., Wolff, M.J., Christensen, P.R., 2003. Mars aerosol studies with the MGS TES emission phase function observations: Optical depths, particle sizes, and ice cloud types versus latitude and solar longitude. J. Geophys. Res. 108. doi: 10.1029/2003JE002058]. In the polar regions the day-by-day variability, associated with polar vortex turbulences, is obtained of the order of 30-50% as predicted by the model [Lefévre, F., Lebonnois, S., Montmessin, F., Forget, F., 2004. Three-dimensional modeling of ozone on Mars. J. Geophys. Res. 109, E07004. doi: 10.1029/2004JE002268] and found by SPICAM [Perrier, S., Bertaux, J.-L., Lebonnois, S., Korablev, O., Fedorova, A., 2006. Global distribution of total ozone on Mars from SPICAM/MEX UV measurements. J. Geophys. Res. 111, E09S06. doi: 10.1029/2006JE002681]. In the considered set of data a maximum of the O2 emission is observed between 11 h and 15 h LT in the latitude range 70-85° during early spring on both hemispheres, while for the southern autumn-winter season a maximum is found between 50° and 60° in the southern hemisphere for MY28. Increase of intensity of the O2 emission observed from Ls 130° to 160° at southern high latitudes may be explained by increase of solar illumination conditions in the maps acquired during the considered period.Atmospheric waves crossing the terminator on the southern polar regions are observed for the first time during the MY28 early spring. The spatial scale of the waves ranges from 100 to 130 km, and the intensity fluctuations are of the order of 4MR.This study confirms the high potentiality of O2 (a1Δg) day glow as a passive tracer of the martian atmosphere dynamics at high latitudes.  相似文献   
84.
The study of the multiannual thermal dynamics of Lake Iseo, a deep lake in the Italian pre‐alpine area, is presented. Interflow was found to be the dominant river entrance mode, suggesting future susceptibility of the lake thermal structure to the overall effects of climate change expected in the upstream alpine watershed. A lake model employed the results of a long‐term hydrologic model to simulate the effects of a climate change scenario on the lake's thermal evolution for the period 2012–2050. The model predicts an overall average increase in the lake water temperature of 0.012 °C/year and a reinforced Schmidt thermal stability of the water column in the winter up to 800 J/m2. Both these effects may further hinder the deep circulation process, which is vital for the oxygenation of deep water. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
85.
Understanding the relationships between sedimentation, tectonics and magmatism is crucial to defining the evolution of orogens and convergent plate boundaries. Here, we consider the lithostratigraphy, clastic provenance, syndepositional deformation and volcanism of the Almagro‐El Toro basin of NW Argentina (24°30′ S, 65°50′ W), which experienced eruptive and depositional episodes between 14.3 and 6.4 Ma. Our aims were to elucidate the spatial and temporal record of the onset and style of the shortening and exhumation of the Eastern Cordillera in the frame of the Miocene evolution of the Central Andes foreland basin. The volcano‐sedimentary sequence of the Almagro‐El Toro basin consists of lower red floodplain sandstones and siltstones, medial non‐volcanogenic conglomerates with localised volcanic centres and upper volcanogenic coarse conglomerates and breccia. Coarse, gravity flow‐dominated (debris‐flow and sheet‐flow) alluvial fan systems developed proximal to the source area in the upper and medial sequence. Growing frontal and intrabasinal structures suggest that the Almagro‐El Toro portion of the foreland basin accumulated on top of the eastward‐propagating active thrust front of the Eastern Cordillera. Synorogenic deposits indicate that the shortening of the foreland deposits was occurring by 11.1 Ma, but conglomerates derived from the erosion of western sources suggest that the uplift and erosion of this portion of the Eastern Cordillera has occurred since ca.12.5 Ma. An unroofing reconstruction suggests that 6.5 km of rocks were exhumed. A tectono‐sedimentary model of an episodically evolving thick‐skinned foreland basin is proposed. In this frame, the NW‐trending, transtensive Calama–Olacapato–El Toro (COT) structures interacted with the orogen, influencing the deposition and deformation of synorogenic conglomerates, the location of volcanic centres and the differential tilt and exhumation of the foreland.  相似文献   
86.
During the full cycle of the emergency management, Civil Protection operative procedures involve many actors belonging to several institutions playing different roles. In this context the sharing of information is a vital requirement to make correct and effective decisions. Therefore a European-wide technological infrastructure providing a distributed and coordinated access to different kinds of resources (data, information, services, expertise, etc.) could enhance existing Civil Protection applications and even enable new ones. In the recent years Grid technologies have reached a mature state providing a platform for secure and coordinated resource sharing between the participants in the so-called Virtual Organizations. Moreover the Earth and Space Sciences Informatics provide the conceptual tools for modelling the geospatial information shared in Civil Protection applications during its entire life cycle. Therefore a European Civil Protection e-infrastructure could be based on a Grid platform enhanced with Earth Sciences specific services. However Civil Protection applications stress the requirements of Earth Sciences research applications, for example in terms of real-time support. Therefore a set of high-level services specifically tailored for such applications must be built on top of the Grid platform. As a result of a requirement analysis, the FP6 project CYCLOPS has proposed an architectural framework for the future European Civil Protection e-Infrastructure. In this architecture a layer of high-level services tailored to Civil Protection applications is built on top of the EGEE Grid middleware. This architectural approach has been tested implementing a prototype of a grid-enabled RISICO, the application for wild fire risk assessment used by the Italian Civil Protection.  相似文献   
87.
Material of low geometric albedo (pV?0.1) is found on many objects in the outer Solar System, but its distribution in the saturnian satellite system is of special interest because of its juxtaposition with high-albedo ice. In the absence of clear, diagnostic spectral features, the composition of this low-albedo (or “dark”) material is generally inferred to be carbon-rich, but the form(s) of the carbon is unknown. Near-infrared spectra of the low-albedo hemisphere of Saturn's satellite Iapetus were obtained with the Visible-Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft at the fly-by of that satellite of 31 December 2004, yielding a maximum spatial resolution on the satellite's surface of ∼65 km. The spectral region 3-3.6 μm reveals a broad absorption band, centered at 3.29 μm, and concentrated in a region comprising about 15% of the low-albedo surface area. This is identified as the CH stretching mode vibration in polycyclic aromatic hydrocarbon (PAH) molecules. Two weaker bands attributed to CH2 stretching modes in aliphatic hydrocarbons are found in association with the aromatic band. The bands most likely arise from aromatic and aliphatic units in complex macromolecular carbonaceous material with a kerogen- or coal-like structure, similar to that in carbonaceous meteorites. VIMS spectra of Phoebe, encountered by Cassini on 11 June 2004, also show the aromatic hydrocarbon band, although somewhat weaker than on Iapetus. The origin of the PAH molecular material on these two satellites is unknown, but PAHs are found in carbonaceous meteorites, cometary dust particles, circumstellar dust, and interstellar dust.  相似文献   
88.
We compare, for the overlapping time frame 1962–2000, the estimate of the northern hemisphere mid-latitude winter atmospheric variability within the available 20th century simulations of 19 global climate models included in the Intergovernmental Panel on Climate Change—4th Assessment Report with the NCEP-NCAR and ECMWF reanalyses. We compute the Hayashi spectra of the 500 hPa geopotential height fields and introduce an ad hoc integral measure of the variability observed in the Northern Hemisphere on different spectral sub-domains. The total wave variability is taken as a global scalar metric describing the overall performance of each model, while the total variability pertaining to the eastward propagating baroclinic waves and to the planetary waves are taken as scalar metrics describing the performance of each model phenomenologically in connection with the corresponding specific physical process. Only two very high-resolution global climate models have a good agreement with reanalyses for both the global and the process-oriented metrics. Large biases, in several cases larger than 20%, are found in all the considered metrics between the wave climatologies of most IPCC models and the reanalyses, while the span of the climatologies of the various models is, in all cases, around 50%. In particular, the travelling baroclinic waves are typically overestimated by the climate models, while the planetary waves are usually underestimated, in agreement with what found is past analyses performed on global weather forecasting models. When comparing the results of similar models, it is apparent that in some cases the vertical resolution of the model atmosphere, the adopted ocean model, and the advection schemes seem to be critical in the bulk of the atmospheric variability. The models ensemble obtained by arithmetic averaging of the results of all models is biased with respect to the reanalyses but is comparable to the best five models. Nevertheless, the models results do not cluster around their ensemble mean. This study suggests caveats with respect to the ability of most of the presently available climate models in representing the statistical properties of the global scale atmospheric dynamics of the present climate and, a fortiori, in the perspective of modeling climate change.  相似文献   
89.
Analysis of rainfall seasonality from observations and climate models   总被引:1,自引:0,他引:1  
Two new indicators of rainfall seasonality based on information entropy, the relative entropy (RE) and the dimensionless seasonality index (DSI), together with the mean annual rainfall, are evaluated on a global scale for recently updated precipitation gridded datasets and for historical simulations from coupled atmosphere–ocean general circulation models. The RE provides a measure of the number of wet months and, for precipitation regimes featuring a distinct wet and dry season, it is directly related to the duration of the wet season. The DSI combines the rainfall intensity with its degree of seasonality and it is an indicator of the extent of the global monsoon region. We show that the RE and the DSI are fairly independent of the time resolution of the precipitation data, thereby allowing objective metrics for model intercomparison and ranking. Regions with different precipitation regimes are classified and characterized in terms of RE and DSI. Comparison of different land observational datasets reveals substantial difference in their local representation of seasonality. It is shown that two-dimensional maps of RE provide an easy way to compare rainfall seasonality from various datasets and to determine areas of interest. Models participating to the Coupled Model Intercomparison Project platform, Phase 5, consistently overestimate the RE over tropical Latin America and underestimate it in West Africa, western Mexico and East Asia. It is demonstrated that positive RE biases in a general circulation model are associated with excessively peaked monthly precipitation fractions, too large during the wet months and too small in the months preceding and following the wet season; negative biases are instead due, in most cases, to an excess of rainfall during the premonsoonal months.  相似文献   
90.
The in vivo effects of 4-nonylphenol (NP) on functional responses of haemocytes from the cockle Cerastoderma glaucum were investigated after 7 days exposure to sublethal NP concentrations (0, 0+acetone, 0.0125, 0.025, 0.05 and 0.1 mg/l NP). Haemocytes from both controls and exposed cockles were collected, and the effects of NP on total haemocyte count (THC) and volume of circulating cells, intracellular superoxide anion () levels, acid phosphatase and lysozyme-like activities in both haemocyte lysate (HL) and cell-free haemolymph (CFH) were evaluated. Exposure of cockles to 0.1 mg/l NP significantly increased THC (p < 0.05) with respect to controls. Analysis of haemocyte size frequency distribution showed that the haemocyte fraction of about 7–8 μm in diameter and 250 femtolitres in volume increased markedly in cockles exposed to the highest NP concentration tested. Apoptosis resulting in cell volume reduction in NP-exposed animals cannot be excluded. No statistically significant variation in intracellular levels was observed. Conversely, significant increases (p < 0.05) in acid phosphatase activity were observed in CFH from 0.05 and 0.1 mg/l NP-exposed animals; no significant differences in enzyme activity were recorded in HL. Lysozyme-like activity also increased significantly in CFH from cockles exposed to 0.05 mg/l NP (p < 0.05) and 0.1 mg/l NP (p < 0.001). Instead, lysozyme-like activity decreased significantly (p < 0.05) in the HL of animals exposed to 0.05 mg/l NP. Our results suggest that NP induces variations in the functional responses of haemocytes of C. glaucum, mainly by reducing cell membrane stability and promoting cell degranulation.  相似文献   
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