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31.
Abstract The chemical evolution of garnets from pelitic rocks of probable Palaeozoic age corresponds to a complex metamorphic evolution of the host rocks.
Among the almandine-rich garnets (Alm60–80), two main types of evolution can be distinguished. Early Mn-rich garnets coexisting with kyanite may be replaced by plagioclase and then, during a late stage, by biotite and/or sillimanite. The second type of evolution corresponds to an overgrowth of Mn-poor late-stage garnet on older Mn-rich garnets which corresponds to a thermal peak with sillimanite-type of metamorphism. This new garnet may appear either as an overgrowth with a strong discontinuity, or as small, new euhedral garnet or as skeletal garnet.
This chemical evolution of garnet corresponds to an early collisional stage of metamorphism (of high pressure type with high Mn values) of probable Ordovician age followed by uplift and a thermal peak (low Mn values) in Devonian times.  相似文献   
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Within the International Very Long Baseline Interferometry (VLBI) Service for Geodesy and Astrometry (IVS), long time-series of zenith wet and total troposphere delays have been combined at the level of parameter estimates. The data sets were submitted by eight IVS Analysis Centers (ACs) and cover January 1984 to December 2004. In this paper, the combination method is presented and the time-series submitted by the eight IVS ACs are compared with each other. The combined zenith delays are compared with time-series provided by the International Global Navigation Satellite System (GNSS) Service (IGS), and with zenith delays derived from the European Centre for Medium-Range Weather Forecasts (ECMWF). Before the combination, outliers are eliminated from the individual time-series using the robust BIBER (bounded influence by standardized residuals) estimator. For each station and AC, relative weight factors are obtained by variance component estimation. The mean bias of the IVS ACs’ time-series with respect to the IVS combined time-series is 0.89 mm and the mean root mean square is 7.67 mm. Small differences between stations and ACs can be found, which are due to the inhomogeneous analysis options, different parameterizations, and different treatment of missing in-situ pressure records. Compared to the IGS zenith total delays, the combined IVS series show small positive mean biases and different long-term trends. Zenith wet delays from the ECMWF are used to validate the IVS combined series. Inconsistencies, e.g., long-term inhomogeneity of the in-situ pressure data used for the determination of VLBI zenith delays, are identified.  相似文献   
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The computer model for near shore wave propagation,SWAN,was used to study wave climates in Liverpool Bay,northwest England with various input parameters,including bottom friction factor,white capping,wind drag formulation and effects of tidal modulations.Results were compared with in-situ measurements and reveal the impacts from these inputs on the predictions of wave height and propagation distributions.In particular,the model results were found very sensitive to different input formulations,and tend to underestimate the wave parameters under storm conditions in comparison with the observations.It is therefore important to further validate the model against detailed field measurements,particularly under large storms that are often of the primary concern.  相似文献   
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A large-scale numerical flow and transport model was developed for the central-eastern arid part of the Arabian Peninsula. The model was applied to a region with freshwater resources dating back to more humid periods of the past, which are faced with overexploitation today. Model inflow was based on infiltration around wadi beds and groundwater recharge. Inflow was balanced by natural outflows, such as evaporation from sabkhas, spring discharge, and discharge to the sea. Two models were developed: (1) a short-term present-day model to estimate effective model parameters, and (2) a long-term model to study the development of the groundwater resources during the Mid- and Late Holocene and the natural response of the groundwater system to changes in climate. Hydraulic model parameters (hydraulic conductivity and specific storage) were assigned with respect to geological structures. Hydraulic parameters were estimated with an inverse PEST model by calibrating against observed depression cones cause by groundwater abstraction. Sensitivity analysis demonstrated that estimated model parameters were associated with a high uncertainty at a certain distance from agricultural areas when calibration data were lacking. A long-term model starting 10,000 years BP was calibrated by spring discharge and palaeo-groundwater levels and validated using measured 14C groundwater ages. The long-model predicted that groundwater levels adapted in response to changes in precipitation. During the Mid-Holocene, which was characterized by an intensification of the monsoon season, groundwater levels increased by 10 m on the mainland within the shallow aquifers and adapted quickly to higher recharge rates. The deeper aquifers were less affected by changes in climate. Along the present-day coastline, the groundwater level rose by about 25 m due to the declined sea level in the Mid-Holocene. During this period, surface run-off was possible as groundwater levels temporarily reached the ground surface. The natural groundwater budget reacted sensitively to changes in climate. Between 10 and 3 ka, groundwater storage occurred. During the Late Holocene, at 3 ka, natural depletion of the groundwater system began, which still prevails today.  相似文献   
38.
A groundwater model characterized by a lack of field data about hydraulic model parameters and boundary conditions combined with many observation data sets for calibration purpose was investigated concerning model uncertainty. Seven different conceptual models with a stepwise increase from 0 to 30 adjustable parameters were calibrated using PEST. Residuals, sensitivities, the Akaike information criterion (AIC and AICc), Bayesian information criterion (BIC), and Kashyap's information criterion (KIC) were calculated for a set of seven inverse calibrated models with increasing complexity. Finally, the likelihood of each model was computed. Comparing only residuals of the different conceptual models leads to an overparameterization and certainty loss in the conceptual model approach. The model employing only uncalibrated hydraulic parameters, estimated from sedimentological information, obtained the worst AIC, BIC, and KIC values. Using only sedimentological data to derive hydraulic parameters introduces a systematic error into the simulation results and cannot be recommended for generating a valuable model. For numerical investigations with high numbers of calibration data the BIC and KIC select as optimal a simpler model than the AIC. The model with 15 adjusted parameters was evaluated by AIC as the best option and obtained a likelihood of 98%. The AIC disregards the potential model structure error and the selection of the KIC is, therefore, more appropriate. Sensitivities to piezometric heads were highest for the model with only five adjustable parameters and sensitivity coefficients were directly influenced by the changes in extracted groundwater volumes.  相似文献   
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Abstract— The distribution and petrography of surficial suevite breccias of the Ries impact crater in Southern Germany are reviewed, and the morphology, petrography and chemical composition of impact glasses in suevite breccias and their postdepositional devitrification is synthesized. Origin and thermal history of suevite breccia and suevite glasses are inferred from these data and from recent results of cooling and crystallization experiments with suevite glass melts under controlled conditions. In a montmorillonitic groundmass, the suevite breccia contains pieces of glass, up to some decimeters in size, and crystalline rock clasts of all stages of shock metamorphism. The glass particles originated in impact melt of basement gneisses and cooled by adiabatic pressure release from ~80 GPa to atmospheric pressure during ejection from the crater. They were deposited on the ground together with the other suevite components at a temperature of ~750 °C. Fractured glass pieces in the breccia show that during deposition of the suevite the temperature was below the temperature at which undercooled melt transforms to rigid glass. The suevite cooled after deposition mainly by convection of heat by emanating gases and vapors. In chilled layers at the base and at the top of suevite deposits, the glasses are preserved in vitreous state. Between these zones, the glasses were devitrified, yet crystallization of pyroxene, plagioclase and magnetite took place below the glass-transformation temperature. Annealing experiments show that this unusual devitrification below the transformation temperature can be explained by the impact origin of suevite glasses. Due to rapid adiabatic cooling on decompression, the glasses were oversaturated with water and internally strained. Under these conditions, devitrification, especially the formation of plagioclase, was possible at temperatures below the transformation range. The origin from adiabatically cooled impact melt of deep-seated rocks distinguishes water-bearing suevite glasses from the Ries-derived, water-free moldavite tektites, which are interpreted as condensates of vaporized, surficial sediments (Engelhardt et al., 1987).  相似文献   
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