Silicate and carbonate mineral weathering in soil profiles developed on Pleistocene glacial drift (Michigan, USA): Mass balances based on soil water geochemistry     

Lixin Jin  Erika L. Williams  Lynn M. Walter 《Geochimica et cosmochimica acta》2008,72(4):1027-1042

Geochemistry of soil, soil water, and soil gas was characterized in representative soil profiles of three Michigan watersheds. Because of differences in source regions, parent materials in the Upper Peninsula of Michigan (the Tahquamenon watershed) contain only silicates, while those in the Lower Peninsula (the Cheboygan and the Huron watersheds) have significant mixtures of silicate and carbonate minerals. These differences in soil mineralogy and climate conditions permit us to examine controls on carbonate and silicate mineral weathering rates and to better define the importance of silicate versus carbonate dissolution in the early stage of soil-water cation acquisition.Soil waters of the Tahquamenon watershed are the most dilute; solutes reflect amphibole and plagioclase dissolution along with significant contributions from atmospheric precipitation sources. Soil waters in the Cheboygan and the Huron watersheds begin their evolution as relatively dilute solutions dominated by silicate weathering in shallow carbonate-free soil horizons. Here, silicate dissolution is rapid and reaction rates dominantly are controlled by mineral abundances. In the deeper soil horizons, silicate dissolution slows down and soil-water chemistry is dominated by calcite and dolomite weathering, where solutions reach equilibrium with carbonate minerals within the soil profile. Thus, carbonate weathering intensities are dominantly controlled by annual precipitation, temperature and soil pCO₂. Results of a conceptual model support these field observations, implying that dolomite and calcite are dissolving at a similar rate, and further dissolution of more soluble dolomite after calcite equilibrium produces higher dissolved inorganic carbon concentrations and a Mg²⁺/Ca²⁺ ratio of 0.4.Mass balance calculations show that overall, silicate minerals and atmospheric inputs generally contribute <10% of Ca²⁺ and Mg²⁺ in natural waters. Dolomite dissolution appears to be a major process, rivaling calcite dissolution as a control on divalent cation and inorganic carbon contents of soil waters. Furthermore, the fraction of Mg²⁺ derived from silicate mineral weathering is much smaller than most of the values previously estimated from riverine chemistry.  相似文献   

Contrasting physical and chemical conditions of two rock glacier springs     

Stefano Brighenti  Michael Engel  Monica Tolotti  Maria Cristina Bruno  Geraldene Wharton  Francesco Comiti  Werner Tirler  Leonardo Cerasino  Walter Bertoldi 《水文研究》2021,35(4):e14159

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Constraining a Flow Model with Field Measurements to Assess Water Transit Time Through a Vadose Zone     

Lamine Boumaiza  Romain Chesnaux  Julien Walter  Christine Stumpp 《Ground water》2021,59(3):417-427

The modeling of thick vadose zones is particularly challenging because of difficulties in collecting a variety of measured sediment properties, which are required for parameterizing the model. Some models rely on synthetic data, whereas others are simplified by running as homogeneous sediment domains and relying on a single set of sediment properties. Few studies have simulated flow processes through a thick vadose zone using real and comprehensive data sets comprising multiple measurements. Here, we develop a flow model for a 7-m-thick vadose zone. This model, combining the numerical codes CTRAN/W with SEEP/W, includes the measured sediment hydraulic properties of the investigated vadose zone and incorporates the actual climate and subsurface conditions of the study site (precipitations, water-table elevations, and stable isotope data). The model is calibrated by fitting the simulated and measured vertical profiles of water content. Our flow model calculates a transit time of 1 year for the travel of water through the 7-m vadose zone; this estimate matches stable isotope-based results obtained previously for this site. A homogeneous sediment domain flow model, which considers only a single set of sediment properties, produces a transit time that is approximately half the duration of that of the heterogeneous flow model. This difference highlights the importance of assuming heterogeneous material within models of thick vadose zones and testifies to the advantage gained when using real sediment hydraulic properties to parametrize a flow model.  相似文献   

Preliminary gas hazard evaluation in Greece     

D’Alessandro  Walter  Kyriakopoulos  Konstantinos 《Natural Hazards》2013,69(3):1987-2004

Natural Hazards - Like other geodynamically active areas, Greece is also affected by a large number of geogenic gas manifestations. These occur either in the form of point sources (fumaroles,...  相似文献   

Radio-colouration of diamond: a spectroscopic study     

Lutz Nasdala  Dieter Grambole  Manfred Wildner  Alexander M. Gigler  Thomas Hainschwang  Alexander M. Zaitsev  Jeffrey W. Harris  Judith Milledge  Daniel J. Schulze  Wolfgang Hofmeister  Walter A. Balmer 《Contributions to Mineralogy and Petrology》2013,165(5):843-861

We have undertaken a study of the common green or orange-brown spots at the surface of rough diamond specimens, which are caused by alpha particles emanating from radioactive sources outside the diamond. Richly coloured haloes represent elevated levels of structural damage, indicated by strong broadening of the main Raman band of diamond, intense strain birefringence, and up-doming of spots due to their extensive volume expansion. Green radio-colouration was analogously generated through the irradiation of diamond with 8.8 MeV helium ions. The generation of readily visible radio-colouration was observed after irradiating diamond with ≥10¹⁵ He ions per cm². The accumulation of such a high number of alpha particles requires irradiation of the diamond from a radioactive source over long periods of time, presumably hundreds of millions of years in many cases. In the samples irradiated with He ions, amorphisation was observed in volume areas where the defect density exceeded 5 × 10^?3 Å^?3 (or 0.03 dpa; displacements per target atom). In contrast, graphitisation as a direct result of the ion irradiation was not observed. The green colouration transformed to brown at moderate annealing temperatures (here 450 °C). The colour transformation is associated with only partial recovery of the radiation damage. The colour change is mainly due to the destruction of the GR1 centre, explained by trapping of vacancies at A defects to form the H3 centre. An activation energy of ~2.4 ± 0.2 eV was determined for the GR1 reduction. The H3 centre, in turn, causes intense yellowish-green photoluminescence under ultraviolet illumination. Radio-colouration and associated H3 photoluminescence are due to point defects created by the ions irradiated, whereas lattice ionisation is of minor importance. This is concluded from the depth distribution of the colouration and the photoluminescence intensity (which corresponds to the defect density but not the ionisation distribution pattern). The effect of the implanted He ions themselves on the colour and photoluminescence seems to be negligible, as radio-colouration and H3 emission were analogously produced through irradiation of diamond with C ions. The photoluminescence emission becomes observable at extremely low defect densities on the order of 10^?6 Å^?3 (or 0.000006 dpa) and is suppressed at moderate defect densities of ~5 × 10^?4 Å^?3 (or ~0.003 dpa). Intensely brown-coloured diamond hence does not show the H3 emission anymore. Anneals up to 1,600 °C has reduced considerably irradiation damage and radio-colouration, but the structural reconstitution of the diamond (and its de-colouration) was still incomplete.  相似文献   

Mapping diversified peri-urban agriculture – potential of object-based versus per-field land cover/land use classification     

Dionys Forster  Tobias Walter Kellenberger  Yves Buehler  Bernd Lennartz 《国际地球制图》2013,28(3):171-186

High spatial resolution satellite data contribute to improving land cover/land use (LCLU) classification in agriculture. A classification procedure based on Quickbird satellite image data was developed to map LCLU of diversified agriculture at sub-communal and communal level (7 km²). Segmentation performance of the panchromatic band in combination with high pass filters (HPF) was tested first. Accuracy of field boundary delineation was evaluated by an object-based segmentation, a per-field and a manual classification, along with a quantitative accuracy assessment. Sub-communal classification revealed an overall accuracy of 84% with a κ coefficient of 0.77 for the per-field vector segmentation compared to an overall accuracy of 56–60% and a κ coefficient of 0.37–0.42 for object-based approaches. Per-field vector segmentation was thus superior and used for LCLU classification at communal level. Overall accuracy scored 83% and the κ coefficient 0.7. In diversified agriculture, per-field vector segmentation and classification achieved higher classification results.  相似文献   

Environmental Impact Assessment of High Pressure Water Scrubbing Biogas Upgrading Technology     

Petronela Cozma  Cristina Ghinea  Ioan Mămăligă  Walter Wukovits  Anton Friedl  Maria Gavrilescu 《洁净——土壤、空气、水》2013,41(9):917-927

The aim of this work was to assess the burdens of a process in terms of environmental and health impacts, resource depletion issues, and energy demand based on the ability of the Life Cycle Assessment methodology to link the environmental impacts with the mass and energy flows. The analysis was done in terms of process and environmental performances of high pressure water scrubbing (HPWS) system applied for biogas upgrading. The application of process simulation based on the Aspen Plus® software has been considered as supportive for the calculation of mass and energy balances. Data processed using GaBi 4: Software showed that global warming, acidification, and human toxicity potentials were the main impact categories associated with the HPWS process. These indicators are largely related to the exhaust gas from the desorption column and the indirect emissions generated during energy consumption. The life cycle inventory study resulted in the development of a database with a vast inventory of data regarding HPWS technology. A basis for assessing potential improvements in the environmental performance of the system is provided. Future studies in this area will address the economical evaluation of the HPWS technology, so as to maximize economic efficiency and minimize environmental impacts.  相似文献   

Fluid-mediated modification of garnet interiors under ultrahigh-pressure conditions     

Alexei L. Perchuk  Michael Burchard  Walter V. Maresch  Hans-Peter Schertl 《地学学报》2005,17(6):545-553

We report the results of a novel experimental study on eclogitic garnets with abundant inclusions of clinozoisite, quartz and rutile subjected to temperatures (T) of 800–1100 °C and a pressure (P) of 4 GPa, representative of ultrahigh-pressure (UHP) metamorphic terranes such as the Kokchetav massif, Saxonian Erzgebirge, etc. The experiments reveal extremely rapid recrystallization and partial melting of garnet interiors controlled by fluids liberated from the breakdown of the hydrous mineral inclusions. The traditional assumption that inclusions of minerals and primary fluid inclusions should be representative of the peak or even earlier metamorphic history cannot be strictly applied in this case. We argue that inclusions in UHP garnets may mirror P–T conditions postdating growth of the host crystal or even P–T conditions never actually experienced by the rock itself. The above modification of garnet interiors produces a typical patchy microstructure that occurs in natural eclogitic garnet from the diamond-bearing UHP Kokchetav massif.  相似文献   

XMM–Newton observations of the black hole X-ray transient XTE J1650–500 in quiescence     

Jeroen Homan  Rudy Wijnands  Albert Kong  Jon M. Miller  Sabrina Rossi  Tomaso Belloni  Walter H. G. Lewin 《Monthly notices of the Royal Astronomical Society》2006,366(1):235-237

We report the result of an XMM–Newton observation of the black hole X-ray transient XTE J1650–500 in quiescence. The source was not detected, and we set upper limits on the 0.5–10 keV luminosity of  0.9–1.0 × 10³¹ erg s⁻¹  (for a newly derived distance of 2.6 kpc). These limits are in line with the quiescent luminosities of black hole X-ray binaries with similar orbital periods (∼7–8 h).  相似文献   

Development of Synthetic Fiber-Reinforced Electro-Optical-Mechanical Cables for Use With Moored Buoy Observatories     

Mark A. Grosenbaugh Walter Paul Dan Frye Norman Farr 《Oceanic Engineering, IEEE Journal of》2006,31(3):574-584

We consider an alternative to traditional high-modulus synthetic electro-optical-mechanical (EOM) mooring cables that are being used in single-point moorings for deep-ocean observatories. The alternative cable design is based on using low-modulus nylon or polyester fibers as the strength member. High-modulus EOM cables such as those that use Vectran fibers as the strength member are usually constructed with the conductors and optical fibers in the core and the strength member on the outside. The key aspect of the new design is that the strength member is placed in the center of the cable and the conductors and fibers are wrapped around the outside at a high helix angle to accommodate stretching of the center-strength-member. A comparison of the static and dynamic responses of moorings constructed with nylon, polyester, and Vectran EOM cables (for mooring scopes of 1.1 and 1.2 and deployment depths of 1800, 3000, and 5000 m) shows that the maximum total tensions of moorings made with nylon EOM cables are lowest under all conditions. Differences between the nylon and the Vectran EOM cable moorings are due principally to the differences in the dynamic tensions. Differences between the nylon and the polyester EOM cable moorings are due mainly to differences in static tensions caused by the higher specific gravity of polyester fibers. Reduction in the scope of all the moorings from 1.2 to 1.1 resulted in significantly higher tensions for the polyester and Vectran EOM cable moorings but only slightly higher tensions for the nylon EOM cable moorings  相似文献