Molecular-scale mechanisms of distribution and isotopic fractionation of molybdenum between seawater and ferromanganese oxides   总被引：1，自引：0，他引：1  

Teruhiko Kashiwabara  Yoshio Takahashi  Akira Usui 《Geochimica et cosmochimica acta》2011,75(19):5762-5784

The distribution of Mo between seawater and marine ferromanganese oxides has great impacts on concentration and isotopic composition of Mo in modern oxic seawater. To reveal the adsorption chemistry of Mo to ferromanganese oxides, we performed (i) detailed structural analyses of Mo surface complexes on δ-MnO₂, ferrihydrite, and hydrogenetic ferromanganese oxides by L₃- and K-edge XAFS, and (ii) adsorption experiments of Mo to δ-MnO₂ and ferrihydrite over a wide range of pHs, ionic strengths, and Mo concentrations. XAFS analyses revealed that Mo forms distorted octahedral (Oh) inner-sphere complexes on δ-MnO₂ whereas it forms a tetrahedral (Td) outer-sphere complex on ferrihydrite. In the hydrogenetic ferromanganese oxides, the dominant host phase of Mo was revealed to be δ-MnO₂. These structural information are consistent with the macroscopic behaviors of Mo in adsorption experiments, and Mo concentration in modern oxic seawater can be explained by the equilibrium adsorption reaction on δ-MnO₂. In addition, the large isotopic fractionation of Mo between seawater and ferromanganese oxides detected in previous studies can be explained by the structural difference between and adsorbed species on the δ-MnO₂ phase in ferromanganese oxides. In contrast, smaller fractionation of Mo isotopes on ferrihydrite is due to little change in the Mo local structures during its adsorption to ferrihydrite.The structures of Mo species adsorbed on crystalline Fe (oxyhydr)oxides, goethite, and hematite were also investigated at pH 8 and I = 0.70 M (NaNO₃). Our XAFS analyses revealed that Mo forms inner-sphere complexes on both minerals: Td edge-sharing (46%) and Oh double corner-sharing (54%) for goethite, and Td double corner-sharing (14%) and Oh edge-sharing (86%) for hematite. These structural information, combined with those for amorphous ferrihydrite and δ-MnO₂, show the excellent correlation with the magnitude of adsorptive isotopic fractionation of Mo reported in previous studies: the proportion of Oh species or their magnitude of distortion in Mo surface complexes become larger in the order of ferrihydrite < goethite < hematite < δ-MnO₂, a trend identical to the magnitude of isotopic fractionation.Based on the comparison with previous reports for Mo surface species on various oxides, the chemical factors that affect Mo surface complex structures were also discussed. The hydrolysis constant of cation in oxides, log K_OH (or the acidity of the oxide surfaces, PZC) is well correlated with the mode of attachment (inner- or outer-sphere) of Mo surface complexes. Furthermore, the symmetric change in Mo species from Td to Oh is suggested to be driven by the formation of inner-sphere complexes on specific sites of the oxide surfaces.  相似文献   

Importance of intracellular Fe pools on growth of marine diatoms by using unialgal cultures and on the Oyashio region phytoplankton community during spring     

Koji Sugie  Kenshi Kuma  Satoshi Fujita  Satomi Ushizaka  Koji Suzuki  Tsutomu Ikeda 《Journal of Oceanography》2011,67(2):183-196

We report on the ability for luxury Fe uptake and the potential for growth utilizing intracellular Fe pools for 4 coastal centric diatom isolates and in situ phytoplankton assemblages, mainly composed of diatoms. Iron uptake of the diatom isolates and natural phytoplankton assemblages in the Oyashio region during spring blooms were prevented by adding hydroxamate siderophore desferrioxamine B (DFB). After the addition of DFB, intracellular Fe in the diatom isolates supported 2.4–4.2 cell divisions with 1.2–2.6 Chl a doublings. The intracellular Fe was primarily used for cell generation rather than Chl a production, leading to a reduction in the Chl a cell quota in the Fe-starved cells with time. The metabolic properties of the Fe-starved cells with their cell morphologies were different among species or genera. An on-deck incubation experiment also exhibited 1.9 cell divisions and 0.81 Chl a doublings of phytoplankton after the addition of DFB, also indicating the preference of cell generation over Chl a production. A decrease in the level of cellular Chl a, a main light-harvesting pigment in Fe-starved diatoms, may become a superior survival strategy to protect the cells from high irradiance that can cause photo-oxidative damages through photosynthesis. Such relatively low-Fe with high-light conditions could often occur in surface waters of the Oyashio region from spring to summer.  相似文献   

Formation process of pyrite polyframboid based on the heavy-metal analysis by micro-PIXE     

Hisanari Sugawara  Masayuki Sakakibara  David Belton  Tetsuya Suzuki 《Environmental Earth Sciences》2013,69(3):811-819

Pyrite framboid in sedimentary rocks could be concerned with arsenic contamination in groundwater of acidic environment and has been studied for the formation process of its unique morphology. However, not much has been discussed about the formation process based on the heavy-metal distribution in pyrite framboids and their aggregates. To reveal the formation process of pyrite framboids and their aggregates, mudstone from the Late Cretaceous Hakobuchi Group, central Hokkaido, Japan, are investigated for mode, petrographical, mineralogical, and micro-PIXE (particle-induced X-ray emission) analysis in this study. Spherical and sub-spherical pyrite framboids observed in polyframboids can be divided into two types based on the diameter of framboids (D) and the average diameter of microcrystals (d) within framboids: type 1, ranging from 2 to 9 μm and from 0.4 to 0.9 μm, respectively, and type 2, ranging from 8 to 50 μm and from 0.5 to 1.8 μm, respectively. Based on the quantitative traverse analyses and 2-D elemental mapping results by micro-PIXE, heterogeneities in the concentrations of heavy metals within the analyzed aggregations of pyrite are exhibited. On the basis of the As and Pb zoning patterns, the time range and chronological stages of pyrite-aggregation growth are revealed.  相似文献   

Crustal transect from the North Atlantic Knipovich Ridge to the Svalbard Margin west of Hornsund   总被引：1，自引：0，他引：1  

Frode Ljones  Asako Kuwano  Rolf Mjelde  Asbjrn Breivik  Hideki Shimamura  Yoshio Murai  Yuichi Nishimura 《Tectonophysics》2004,378(1-2):17-41

The crustal structure along a 312 km transect, stretching from the axial mountains of the North Atlantic Knipovich Ridge to the continental shelf of Svalbard, has been obtained using seismic reflection data and wide angle OBS data. The resulting seismic V_p and V_s models are further constrained by a 2-D-gravity model. The principal objective of this study is to describe and resolve the physical and compositional properties of the crust in order to understand the processes and creation of oceanic crust in this extremely slow-spreading counterpart of the North Atlantic Ridge Systems. V_p is estimated to be 3.50–6.05 km/s for the upper oceanic crust (oceanic layer 2), with a marked increase away from the ridge. The measured V_p of 6.55–6.95 km/s for oceanic layer 3A and 7.10–7.25 km/s for layer 3B, both with a V_p/V_s ratio of 1.81, except for slightly higher values at the ridge axis, does not allow a clear distinction between gabbro and mantle-derived peridotite (10–40% serpentized). The thickness of the oceanic crust varies a lot along the transect from the minimum of 5.6 km to a maximum of 8.1 km. The mean thickness of 6.7 km for the oceanic crust is well above the average thickness for slow-spreading ridges (<10 mm/year half-spreading rate). The areas of increased thickness could be explained by large magma production-rates found in the zones of axial highs at the ridge axis, which also have generated the off-axial highs adjacent the ridge. We suggest that these axial and off-axial highs along the ridge control the lithological composition of the oceanic crust. This approach suggests normal gabbroic oceanic crust to be found in the areas bound by the active magma segments (the axial and off-axial highs) and mantle-derived peridotite outside these zone.  相似文献   

A study of the morphology of winter sprites in the Hokuriku area of Japan in relation to cloud charge height     

K. Myokei  Y. Matsudo  T. Asano  T. Suzuki  Y. Hobara  K. Michimoto  M. Hayakawa 《Journal of Atmospheric and Solar》2009,71(5):597-602

Continuous observations of sprites in the Hokuriku area of Japan were performed from two optical sites during the three winter periods. The purpose of this observation is to study the major effect in the appearance of sprites and in determining the morphology of sprites (columns or carrots). Detailed analysis is performed based on the estimation of the height of ?10 °C at the time of sprite occurrence. When the height of ?10 °C is lower than 1800 m, the occurrence of sprites is infrequent, and the dominant shape is column. Then when it is increased (1800–3000 m), a new situation takes place, namely the occurrence of sprites is very enhanced and more spectacular shapes like carrots tend to be frequently observed in addition to column sprites. These sprite characteristics are first compared with those of parent lightning in the Hokuriku area and with our latest computer simulations on sprite initiation.  相似文献   

Three-dimensional EM computer simulation on sprite initiation above a horizontal lightning discharge     

T. Asano  T. Suzuki  M. Hayakawa  M.G. Cho 《Journal of Atmospheric and Solar》2009,71(8-9):983-990

The purpose of this paper is to study the three-dimensional (3D) effects of the source current and the electromagnetic (EM) pulse on the distribution of upper atmospheric electric field and ionization created. A new lightning model has been employed; i.e., we have included a horizontal channel in addition to the conventional vertical channel. The effects of the horizontal lightning channel are summarized as follows: (1) the effect of a vertical channel plays a fundamental role in the whole view of sprite initiation; (2) the position of a sprite is shifted from the position of its parent vertical channel in response to the length of a horizontal channel; and (3) we observe very fine structures with local maxima and minima in the “reduced” electric field (the electric field divided by the neutral gas density). These theoretical inferences are discussed and compared with the observational facts so far reported (such as lateral shift of sprites, morphological difference of sprites, etc.).  相似文献   

The Higo High-Grade Metamorphic Rocks in Japan as a Part of the Collisional Terrane Between the Sino-Korean and Yangtze Craton     

Yasuhito Osanai  Takuji Hamamoto  Hiroo Kagami  Kazuhiro Suzuki  Masaaki Owada  Atsushi Kamei   《Gondwana Research》1999,2(4):599-601

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Simulation of near source ground motion and its characteristics     

S. Suzuki  K. Asano 《Soil Dynamics and Earthquake Engineering》2000,20(1-4)

It is fact that the severe ground motions of shear waves have a strong effect on the dynamic behavior of buildings and civil structures. We simulate near source strong motions of a pure shear wave and synthesize small motions, using the parameters based on the recorded accelerograms at the site that is regarded as a base rock in the Osaka basin, Japan. By making use of a stochastic technique, we can easily introduce higher frequency contents in the motions and apply the technique to the synthesis of small waves regarding as a green function. We also introduce to the analysis the useful relationships among the time duration T_d, the seismic moment M₀, the corner frequency f_c and the high cutoff frequency f_max which were regressed by a simple representation scheme. Considering two active faults that may affect severe damage on buildings and civil structures, we try to predict strong ground motions in Osaka basin and show the characteristics of them.  相似文献   

Effects of Three-dimensional Inhomogeneous Viscoelastic Structures on Postseismic Surface Deformations Associated with the Great 1946 Nankaido Earthquake     

S. Yoshioka  H. Suzuki 《Pure and Applied Geophysics》1999,154(2):307-328

—We investigated the effects of various viscoelastic structures on postseismic surface displacement and principal strain fields associated with the great 1946 Nankaido earthquake, which occurred on the plate boundary between the subducting Philippine Sea plate and the continental Eurasian plate. For this purpose, we constructed two kinds of three-dimensional structural models using the finite element method one is the Layered Model, in which a semi-infinite Maxwell viscoelastic material is underlying an elastic layer, and the other is the more realistic Plate Model, in which the three-dimensional configuration of the subducted Philippine Sea plate is taken into account. We also considered two cases with different thicknesses of the elastic layer (50 and 33km) for the respective models. The difference between the two models in postseismic surface deformations is significant for the case with the thinner elastic layer. In this case the horizontal surface displacement and principal strain for the Layered Model is two to three times larger than those for the Plate Model. Downward surface deformation tends to be dominant for the Layered Model, while the change in the pattern for the Plate Model is less marked. The spatial extent of uplift and subsidence for the Plate Model is broader than that for the Layered Model. Postseismic vertical displacements in Shikoku were found to be strongly dependent on the viscoelastic structures. From these results, we suggest that the estimates of the viscosity of the uppermost mantle, interplate coupling, and the area and the amount of after-slip following the 1946 Nankaido earthquake, which have been estimated based on simple layered viscoelastic models, should be re-evaluated using realistic three-dimensionally heterogeneous viscoelastic structures.  相似文献   

Short term variability of Particle fluxes and its relation to variability in sea surface temperature and chlorophylla field detected by Ocean Color and Temperature Scanner (OCTS) off Sanriku, northwestern North Pacific in the spring of 1997     

Toshiro Saino  Shaoling Shang  Yoshihisa Mino  Koji Suzuki  Hideaki Nomura  Sei-ichi Saitoh  Hideo Miyake  Toshiyuki Masuzawa  Koh Harada 《Journal of Oceanography》1998,54(5):583-592

A sediment trap experiment was carried out in conjunction with an over flight of Ocean Color Temperature Scanner (OCTS) on board Advanced Earth Observing Satellite (ADEOS) at 40°N, 143°E off Sanriku in April to May 1997. Short term variability of particle fluxes was examined at depths of 450 m and 600 m from April 6 to May 1 with a sampling interval of two days, and at 450 m with one day interval from 2nd to 10th May. Daily averaged mass flux at 450 m and 600 m was 815 mg m⁻²d⁻¹ and 862 mg m⁻²d⁻¹, respectively. A sharp increase in mass flux was observed during the period from April 26 to April 29 with the highest mass flux of 8 g m⁻²d⁻¹. About 85% of the total mass flux for the entire duration (26 days) was collected within these 4 days. Trapped material during the peak flux period was mainly composed of diatoms dominated byThalassiosira spp. and resting spores ofChaetoceros spp. This suggested that the peak flux was the result of (a) diatom bloom(s) in the euphotic column. Current meter records at 420 m showed that on April 26 and 27, the period when the peak flux was observed, the southwestward current had diminished in strength and changed its direction northwestward. Low current speeds appeared to have enhanced trap efficiency to help form the peak flux. A time series of OCTS Intensive-LAC (Local Area Coverage: Region B) images from mid-March to early May was examined todetect phytoplankton bloom(s). In the March 26th Chl image, high concentration region was restricted to the southwest off Cape Erimo, but spread around the warm core ring (WCR) 93A by April 10. East of the WCR93A, high Chl concentration remained steady until May, but to the west of the WCR93A, Chl decreased rapidly before the 19th of April. From this observation we suspect that the peak flux observed at the end of April originated from a bloom, which ceased on the 17th or 18th of April, in the region north of 40°N and west of 143°E. Taking the current meter records into account, the source region for the trapped material is most likely around southwest of the Cape Erimo.  相似文献