Yearly changes in the seasonal frequency and duration of short-term acid pulses in some Nova Scotia, Canada streams   总被引：1，自引：0，他引：1  

T. A. Clair  A. Ghosh Bobba  Krista Miller 《Environmental Geology》2001,40(4-5):582-591

 The seasonal frequency and duration of low pH events at three sites located in southwestern Nova Scotia were analyzed using measured and synthetic daily pH data. The basins varied in size from 0.3 to 300 km² and were subject to frequent snowmelt events in winter and spring, as well as occasional runoff events during summer and fall. Results showed that, in order to fill in missing data from periods where collection was interrupted, statistical approximations using discharge were not totally acceptable, as generated data consistently missed the extreme values measured. Despite a lack of totally accurate event pH estimates for periods where daily data were missing, analysis showed that in this region, low pH episodes can occur year-round including summer. The highest probabilities of low pH episodes nevertheless occurred in the winter and spring when snowmelts were frequent. Received: 12 November 1999 · Accepted: 18 July 2000  相似文献   

Sources, distribution and storage of heavy metals in the Río Pilcomayo, Bolivia     

Karen A. Hudson-Edwards  Mark G. Macklin  Jerry R. Miller  Paul J. Lechler 《Journal of Geochemical Exploration》2001,72(3)

The Río Pilcomayo rises on the Cerro Rico de Potosí precious metal-polymetallic tin deposits of Bolivia, and flows in a southeasterly direction for ca. 600 km to Bolivia's southern border with Argentina. Mining of the Potosí deposits has occurred continuously since 1545, generating large quantities of waste materials in the headwater of the basin. In addition, a tailings dam breach at the Porco mine in 1996 released an estimated 235 000 m³ of tailings and fluid into the upper reaches of the Río Pilaya, the largest tributary to the Pilcomayo.Concentrations of As, Sb, Cd, Cu, Pb, Hg, Ag, Tl and Zn in contemporary channel sediments upstream of the Pilaya confluence are significantly elevated above background values. Elevated levels appear to be associated with pyrite- and other sulphide mineral-bearing tailings materials transported more than 200 km downstream of the Potosí mines. Significant downstream declines in elemental concentrations occur within 15 km, and again between 150 and 200 km, from the mines. The initial decrease in concentrations is due to the rapid dilution of nearly pure tailings effluent released to the river from milling facilities near Potosí. The latter decrease results from a combination of geomorphic processes including the storage of sediment-borne metals within the channel bed and the influx of ‘clean’ sediment from several large tributaries. Downstream of the Pilaya confluence, concentrations of Cu, Pb, Hg and Zn are only slightly elevated above background values, and Ag, Cd, Sb and Tl cannot be distinguished from background levels. These data suggest that while the Porco tailings spill may have had a significant short-term impact on sediment and water quality along the lower reaches of the Río Pilcomayo, its longer-term impacts were limited. Metals stored and eroded from alluvial deposits of historical age in upstream reaches appear to be an important source of metals to the river today. An additional, and perhaps more significant source, is the release of tailings effluent to the river from modern milling operations. The transport of these contaminants downstream of Icla (203 km from Potosí) appears to be restricted by aggradational processes occurring in the vicinity of Puente Sucre. In addition, downstream of the confluence of the Río Pilaya, inputs of large amounts of ‘clean’ sediment have caused dilution of the metal contaminants. Data from other studies where similar geomorphic processes have occurred suggest that the metals in the upper Pilcomayo may eventually be moved downvalley as the aggradational processes are reversed and channel stabilisation occurs. Thus, the most significant impacts of metal contamination may not be realised in downstream areas for decades.  相似文献   

Interactions of growing folds and coeval depositional systems   总被引：7，自引：0，他引：7  

Douglas Burbank  rew Meigs  & Nicholas Brozovi&#; 《Basin Research》1996,8(3):199-223

Responses of both modern and ancient fluvial depositional systems to growing folds can be interpreted in terms of interactions among competing controlling variables which can be incorporated into simple conceptual models. The ratio of the rate of sediment accumulation to the rate of structural uplift determines whether a fold develops a topographic expression above local base level. The balance between (a) stream power and rates of upstream deposition vs. (b) bedrock resistance and rates of crestal uplift and of fold widening determines whether an antecedent stream maintains its course or is defeated by a growing structure. Modern drainage configurations in actively folding landscapes can often be interpreted in terms of these competing variables, and through analysis of digital topography, detailed topographic characteristics of these folds can be quantified. Modern examples of growing folds display both defeated and persistent antecedent rivers, deflected drainages and laterally propagating structures. The topography associated with a defeated antecedent river at Wheeler Ridge, California, is consistent with a model in which defeat results from forced aggradation in the piggyback basin, without the need to vary discharge or uplift rate. Reconstruction of the long-term interplay between a depositional system and evolving folds requires a stratigraphic perspective, such as that provided by syntectonic strata which are directly juxtaposed with ancient folds and faults. Analysis of Palaeogene growth strata bounding the Catalan Coastal Ranges of NE Spain demonstrates the synchronous growth and the kinematic history of multiple folds and faults in the proximal foreland basin. Although dominated by transverse rivers which crossed fold crests, palaeovalleys, interfan lows, structural re-entrants and saddles, and rising anticlines diverted flow and influenced local deposition. In the ancient record, drainage-network events, such as avulsion or defeat of a transverse stream, usually cannot be unambiguously attributed to a single cause. Examination of ancient syntectonic strata from a geomorphological perspective, however, permits successive reconstructions of synorogenic topography, landscapes and depositional systems.  相似文献   

Microphytobenthos: The ecological role of the “secret garden” of unvegetated,shallow-water marine habitats. II. role in sediment stability and shallow-water food webs     

Douglas C. Miller  Richard J. Geider  Hugh L. MacIntyre 《Estuaries and Coasts》1996,19(2):202-212

The microphytobenthos form an important component of all shallow-water ecosystems where enough light reaches the sediment surface to support appreciable primary production. Although less conspicuous than macroalgae or vascular plants, the microphytobenthos can contribute significantly to primary production and can modify habitat characteristics. The microphytobenthos alter sediment properties (e.g., erodibility) both directly, in the extreme forming a mat or scum on the sediment surface, and indirectly by modifying the activities of benthic infauna (e.g., pelletization, burrowing, tube building, and sediment tracking). Carbon dioxide fixed by the microphytobenthos supports higher, grazing trophic levels. These include deposit-feeding and suspension-feeding macrofauna as well as meiofauna and microfauna. Quantitative relations between the feeding and growth rates of macrofauna and the abundance of microphytobenthos and suspended organic matter (i.e., functional responses) are reviewed. Given the current state of knowledge of the direct and indirect interactions involving trophic dynamics, sediment properties, and benthic microalgae, we argue for reductionist studies of particular interactions as distinct entities. This is a prerequisite for the emergence of a comprehensive picture of unvegetated ecosystems and the ability to predict their responses to man’s activities. *** DIRECT SUPPORT *** A01BY074 00005  相似文献   

Stochastic perturbation analysis of groundwater flow. Spatially variable soils,semi-infinite domains and large fluctuations     

G. Christakos  C. T. Miller  D. Oliver 《Stochastic Environmental Research and Risk Assessment (SERRA)》1993,7(3):213-239

As is well known, a complete stochastic solution of the stochastic differential equation governing saturated groundwater flow leads to an infinite hierarchy of equations in terms of higher-order moments. Perturbation techniques are commonly used to close this hierarchy, using power-series expansions. These methods are applied by truncating the series after a finite number of terms, and products of random gradients of conductivity and head potential are neglected. Uncertainty regarding the number or terms required to yield a sufficiently accurate result is a significant drawback with the application of power series-based perturbation methods for such problems. Low-order series truncation may be incapable of representing fundamental characteristics of flow and can lead to physically unreasonable and inaccurate solutions of the stochastic flow equation. To support this argument, one-dimensional, steady-state, saturated groundwater flow is examined, for the case of a spatially distributed hydraulic conductivity field. An ordinary power-series perturbation method is used to approximate the mean head, using second-order statistics to characterize the conductivity field. Then an interactive perturbation approach is introduced, which yields improved results compared to low-order, power-series perturbation methods for situations where strong interactions exist between terms in such approximations. The interactive perturbation concept is further developed using Feynman-type diagrams and graph theory, which reduce the original stochastic flow problem to a closed set of equations for the mean and the covariance functions. Both theoretical and practical advantages of diagrammatic solutions are discussed; these include the study of bounded domains and large fluctuations.  相似文献   

Relations between metamorphism and orogeny in a typical section of the Indian Himalayas   总被引：3，自引：0，他引：3  

W. Frank  G. Hoinkes  Christine Miller  F. Purtscheller  W. Richter  M. Thöni 《Mineralogy and Petrology》1973,20(4):303-332

Summary A comprehensive geological and petrological investigation has been undertaken in an area of about 10 000 km² in the Indian Himalaya (S-Lahul, Himachal Pradesh). The development of mineral assemblages in metamorphic rocks of medium grade is considered to be a dominant Alpine event, although almost exclusively Paleozoic and Precambrian rocks have been involved. The Barrowian type of this metamorphism, ranging from the anchi- to the sillimanite zone, took place under the elavated T-gradient of about 4°C/100 m. It is suggested that normal geothermal conditions prevailed only in the outermost zone of this orogenic belt. In the Late Tertiary this metamorphic series has been moved as a huge nappe upon the Lower Himalaya. During this process a unique feature of reverse metamorphism has been formed. It can be shown that this feature was caused by a combination of metamorphism and very rapid tectonic movements.

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Beziehungen zwischen Metamorphose und Orogenese in einem typischen Querschnitt des Indischen Himalaya

Zusammenfassung Ein etwa 10 000 km² großes Gebiet des Indischen Himalaya (S-Lahul, Himachal Pradesh) wurde einer umfassenden geologischen und petrographischen Bearbeitung unterzogen. Die Ausbildung der in den mittelgradig metamorphen Gesteinen vorliegenden Mineralparagenesen wird als ein dominant alpines Ereignis betrachtet, obwohl fast nur paläozoische und präkambrische Gesteine einbezogen wurden. Die Metamorphose selbst ist von Barrow-Typus und reicht von der Anchi- bis zur Sillimanitzone. Sie fand unter einem erhöhten Temperaturgradienten von etwa 4°C/100 m statt. Nur in der äußersten Zone des Orogens entsprach der Gradient etwa normalen geothermischen Verhältnissen. Im Spättertiär wurde diese alpin-metamorphe Serie in Form einer mächtigen Kristallindecke dem Niedrigen Himalaya aufgeschoben. Dabei wurde eine einzigartige Zone inverser Metamorphose ausgebildet. Es konnte gezeigt werden, daß diese inverse Metamorphose durch das Zusammenwirken von Metamorphose und sehr rasch ablaufender Tektonik entstand.

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With 13 Figures

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Dedicated to Prof. Dr. Dr. h. c.B. Sander on the occasion of his 90th birthday.  相似文献   

Late Quaternary glacial and climatic history of northern Cumberland Peninsula,Baffin Island,N.W.T., Canada     

Gifford H. Miller 《Quaternary Research》1973,3(4):561-583

Radiocarbon dates on molluses in marine facies associated with glacial deposits in northern Cumberland Peninsula indicate both main fiord (Laurentide) ice and local glaciers remained at their late Wisconsin maxima until ca. 8000 BP. Essentially continuous deglaciation followed; local corrie glaciers melted out by 7100 BP and by 5500 BP fiord glaciers had receded behind the present margin of the Penny Ice Cap. The Hypsithermal warm interval probably lasted from ca. 8000 to 5000 BP. Lichenometry and radiocarbon dates on peat and buried organic horizons delimit a detailed Neoglacial chronology. Of 46 outlet and corrie glaciers investigated, the oldest Neoglacial moraines are dated lichenometrically at 3200 ± 600 BP. Subsequent advances terminated immediately prior to ca. 1650, 780, 350, and 65 yr BP, the most recent of which marked the most extensive ice coverage during the Neoglacial. The highest occurrence of lateral moraines from late Wisconsin advances of local and Laurentide ice suggest that at the late Wisconsin glacial maximum, depression of snowline varied from 450 m below present at the coast to 350 m below present level in the vicinity of the Penny Ice Cap. Moraines, surrounded by glacial ice and lying above the present steady-state ELA, suggest that during the Hypsithermal snowline was up to ca. 200 m above its present elevation. A radiometrically controlled reconstruction of relative summer paleotemperatures for the postglacial derived independently of lichenometry agrees well with the lichenometric age dating of moraines. The data suggest that between ca. 1650 and 900 BP climatic conditions were unfavorable for glacier growth, whereas the period ca. 800-65 yr BP was one of general glacial activity. During the last decade permanent snow cover has been increasing in the area. Previously reported data on climatic trends in the Canadian Arctic based on palynological analyses are similar to the chronology reported here.  相似文献   

Carbon monoxide on the primitive earth     

James E. Van Trump  Stanley L. Miller 《Earth and Planetary Science Letters》1973,20(1):145-150

The reaction of CO + OH^? in aqueous solution to give formate was studied as a carbon monoxide sink on the primitive earth and in the present ocean. The reaction is first order in OH^? and first order in the molar CO concentration. The second order rate constant is given by log k(M^?1hr^?1) = 15.83?4886/T between 25°C and 60°C. Using the solubility of CO in sea water, and assuming a pH of 8 for a primitive ocean of the present size, the halflife of CO in the atmosphere is calculated to be 12 × 10⁶ yr at 0°C and 5.5 × 10⁴ yr at 25°C.Three other CO sinks would have been important in the primitive atmosphere: CO + H₂ → H₂CO driven by various energy sources, CO + OH → CO₂ + H, and the Fischer-Tropsch reaction of CO + H₂ → hydrocarbons, etc. It is concluded that the lifetime of a CO atmosphere would have been very short on the geological time scale although the relative importance of these four CO sinks is difficult to estimate.The CO + OH^? reaction to give formate is a very minor CO sink on the earth at the present time.  相似文献   

Numerical experiments on the stability of preplanetary disks     

P.M. Cassen  B.F. Smith  R.H. Miller  R.T. Reynolds 《Icarus》1981,48(3):377-392

Gravitational stability of gaseous protostellar disks is relevant to theories of planetary formation. Stable gas disks favor formation of planetesimals by the accumulation of solid material; unstable disks allow the possibility of direct condensation of gaseous protoplanets. We present the results of numerical experiments designed to test the stability of thin disks against large-scale, self-gravitational disruption. The disks are represented by a distribution of about 6 × 10⁴ point masses on a two-dimensional (r, φ) grid. The motions of the particles in the self-consistent gravity field are calculated, and the evolving density distributions are examined for instabilities. Two parameters that have major influences on stability are varied: the initial temperature of the disk (represented by an imposed velocity dispersion), and the mass of the protostar relative to that of the disk. It is found that a disk as massive as 1M_⊙, surrounding a 1M_⊙ protostar, can be stable against long-wavelength gravitational disruption if its temperature is about 300°K or greater. Stability of a cooler disk requires that it be less massive, but even at 100°K a stable disk can have an appreciable fraction ($\text{～}\text{1}\text{3}$) of a solar mass.  相似文献   

A BME solution of the inverse problem for saturated groundwater flow   总被引：3，自引：3，他引：0  

M. L.?SerreEmail author  G.?Christakos  H.?Li  C. T.?Miller 《Stochastic Environmental Research and Risk Assessment (SERRA)》2003,17(6):354-369

In most real-world hydrogeologic situations, natural heterogeneity and measurement errors introduce major sources of uncertainty in the solution of the inverse problem. The Bayesian Maximum Entropy (BME) method of modern geostatistics offers an efficient solution to the inverse problem by first assimilating various physical knowledge bases (hydrologic laws, water table elevation data, uncertain hydraulic resistivity measurements, etc.) and then producing robust estimates of the subsurface variables across space. We present specific methods for implementing the BME conceptual framework to solve an inverse problem involving Darcys law for subsurface flow. We illustrate one of these methods in the case of a synthetic one-dimensional case study concerned with the estimation of hydraulic resistivity conditioned on soft data and hydraulic head measurements. The BME framework processes the physical knowledge contained in Darcys law and generates accurate estimates of hydraulic resistivity across space. The optimal distribution of hard and soft data needed to minimize the associated estimation error at a specified sampling cost is determined. This work was supported by grants from the National Institute of Environmental Health Sciences (Grant no. 5 P42 ES05948 and P30ES10126), the National Aeronautics and Space Administration (Grant no. 60-00RFQ041), the Army Research Office (Grant no. DAAG55-98-1-0289), and the National Science Foundation under Agreement No. DMS-0112069.  相似文献