Photochemical changes in chemical markers of sedimentary organic matter source and age     

Lawrence M. Mayer  Linda L. Schick  Thomas S. Bianchi  Laura A. Wysocki 《Marine Chemistry》2009,113(1-2):123-128

Several chemical markers of organic matter source and age are shown to be susceptible to light-induced alteration. To test for the photochemical lability of markers previously employed for sediments from the Louisiana coastal zone, we subjected sediments under resuspension conditions to simulated sunlight, and monitored changes in C:N and Br:OC ratios, δ¹³C, Δ¹⁴C, and lignin composition. Markers of terrigenous origin (high C:N, lignin) decreased and δ¹³C became enriched in sediments containing primarily terrigenous organic matter, while a marker of marine organic matter (Br:OC) decreased in samples containing significant contributions from this source. Preferential loss of ¹⁴C from all sediments indicated enhanced photochemical lability of organic matter of relatively recent origin, consistent with the changes in chemical markers. Most, but not all, experimental alterations are consistent with field distributions of these markers. Relatively small experimental changes in the markers in combination with confounding processes in the environment, however, prevent these parallel trends from providing any more than a consistency test for the importance of photochemical reactions in this region.  相似文献   

Remarks on the nomenclature of mercury     

Lawrence E. Krumenaker 《Icarus》1978,34(1):215-219

Longitudes of surface marking observed on Mercury by E.M. Antoniadi are determined. The most frequent of the locations are used to determine the most probable positions on Mercury's surface for the names defined on Antoniadi's 88-day planisphere. It is suggested that these locations can serve as a valid and accurate basis for Mercurian nomenclature.  相似文献   

Evidence for high‐temperature fractionation of lithium isotopes during differentiation of the Moon          下载免费PDF全文

James M. D. Day  Lin Qiu  Richard D. Ash  William F. McDonough  Fang‐Zhen Teng  Roberta L. Rudnick  Lawrence A. Taylor 《Meteoritics & planetary science》2016,51(6):1046-1062

Lithium isotope and abundance data are reported for Apollo 15 and 17 mare basalts and the LaPaz low‐Ti mare basalt meteorites, along with lithium isotope data for carbonaceous, ordinary, and enstatite chondrites, and chondrules from the Allende CV3 meteorite. Apollo 15 low‐Ti mare basalts have lower Li contents and lower δ⁷Li (3.8 ± 1.2‰; all uncertainties are 2 standard deviations) than Apollo 17 high‐Ti mare basalts (δ⁷Li = 5.2 ± 1.2‰), with evolved LaPaz mare basalts having high Li contents, but similar low δ⁷Li (3.7 ± 0.5‰) to Apollo 15 mare basalts. In low‐Ti mare basalt 15555, the highest concentrations of Li occur in late‐stage tridymite (>20 ppm) and plagioclase (11 ± 3 ppm), with olivine (6.1 ± 3.8 ppm), pyroxene (4.2 ± 1.6 ppm), and ilmenite (0.8 ± 0.7 ppm) having lower Li concentrations. Values of δ⁷Li in low‐ and high‐Ti mare basalt sources broadly correlate negatively with ¹⁸O/¹⁶O and positively with ⁵⁶Fe/⁵⁴Fe (low‐Ti: δ⁷Li ≤4‰; δ⁵⁶Fe ≤0.04‰; δ¹⁸O ≥5.7‰; high‐Ti: δ⁷Li >6‰; δ⁵⁶Fe >0.18‰; δ¹⁸O <5.4‰). Lithium does not appear to have acted as a volatile element during planetary formation, with subequal Li contents in mare basalts compared with terrestrial, martian, or vestan basaltic rocks. Observed Li isotopic fractionations in mare basalts can potentially be explained through large‐degree, high‐temperature igneous differentiation of their source regions. Progressive magma ocean crystallization led to enrichment in Li and δ⁷Li in late‐stage liquids, probably as a consequence of preferential retention of ⁷Li and Li in the melt relative to crystallizing solids. Lithium isotopic fractionation has not been observed during extensive differentiation in terrestrial magmatic systems and may only be recognizable during extensive planetary magmatic differentiation under volatile‐poor conditions, as expected for the lunar magma ocean. Our new analyses of chondrites show that they have δ⁷Li ranging between ?2.5‰ and 4‰. The higher δ⁷Li in planetary basalts than in the compilation of chondrites (2.1 ± 1.3‰) demonstrates that differentiated planetary basalts are, on average, isotopically heavier than most chondrites.  相似文献   

The lunar rock and mineral characterization consortium: Deconstruction and integrated mineralogical,petrologic, and spectroscopic analyses of mare basalts     

Peter J. ISAACSON  Amit BASU SARBADHIKARI  Carlé M. PIETERS  Rachel L. KLIMA  Takahiro HIROI  Yang LIU  Lawrence A. TAYLOR 《Meteoritics & planetary science》2011,46(2):228-251

The lunar rock and mineral characterization consortium (LRMCC) has conducted coordinated mineralogy/petrography/spectroscopy analyses of a suite of pristine lunar basalts. Four basalt slabs (two low‐Ti, two high‐Ti) and paired thin sections were analyzed. Thin sections were analyzed for mineralogy/petrography, while the slabs were used to prepare particulate separates of major mineral phases and bulk samples. Mineral separates and particulate bulk samples were crushed to controlled grain sizes and their reflectance spectra measured in the NASA RELAB at Brown University. The resulting data set provides an essential foundation for spectral mixing models, offers valuable endmember constraints for space weathering analyses, and represents critical new ground truth results for lunar science and exploration efforts.  相似文献   

Origin of a metamorphosed lithic clast in CM chondrite Grove Mountains 021536     

Aicheng ZHANG  Yunbin GUAN  Weibiao HSU  Yang LIU  Lawrence A. TAYLOR 《Meteoritics & planetary science》2010,45(2):238-245

Abstract– A metamorphosed lithic clast was discovered in the CM chondrite Grove Mountains 021536, which was collected in the Antarctica by the Chinese Antarctic Research Exploration team. The lithic clast is composed mainly of Fe‐rich olivine (Fo₆₂) with minor diopside (Fs_9.7–11.1Wo_48.3–51.6), plagioclase (An_43–46.5), nepheline, merrillite, Al‐rich chromite (21.8 wt% Al₂O₃; 4.43 wt% TiO₂), and pentlandite. Δ¹⁷O values of olivine in the lithic clast vary from ?3.9‰ to ?0.8‰. Mineral compositions and oxygen isotopic compositions of olivine suggest that the lithic clast has an exotic source different from the CM chondrite parent body. The clast could be derived from strong thermal metamorphism of pre‐existing chondrule that has experienced low‐temperature anhydrous alteration. The lithic clast is similar in mineral assemblage and chemistry to a few clasts observed in oxidized CV3 chondrites (Mokoia and Yamato‐86009) and might have been derived from the interior of the primitive CV asteroid. The apparent lack of hydration in the lithic clast indicates that the clast accreted into the CM chondrite after hydration of the CM components.  相似文献   

Mechanisms of iron oxide transformations in hydrothermal systems   总被引：2，自引：0，他引：2  

Tsubasa Otake  David J. Wesolowski  Lawrence F. Allard 《Geochimica et cosmochimica acta》2010,74(21):6141-6156

Coexistence of magnetite and hematite in hydrothermal systems has often been used to constrain the redox potential of fluids, assuming that the redox equilibrium is attained among all minerals and aqueous species. However, as temperature decreases, disequilibrium mineral assemblages may occur due to the slow kinetics of reaction involving the minerals and fluids. In this study, we conducted a series of experiments in which hematite or magnetite was reacted with an acidic solution under H₂-rich hydrothermal conditions (T = 100-250 °C, ) to investigate the kinetics of redox and non-redox transformations between hematite and magnetite, and the mechanisms of iron oxide transformation under hydrothermal conditions. The formation of euhedral crystals of hematite in 150 and 200 °C experiments, in which magnetite was used as the starting material, indicates that non-redox transformation of magnetite to hematite occurred within 24 h. The chemical composition of the experimental solutions was controlled by the non-redox transformation between magnetite and hematite throughout the experiments. While solution compositions were controlled by the non-redox transformation in the first 3 days in a 250 °C experiment, reductive dissolution of magnetite became important after 5 days and affected the solution chemistry. At 100 °C, the presence of maghemite was indicated in the first 7 days. Based on these results, equilibrium constants of non-redox transformation between magnetite and hematite and those of non-redox transformation between magnetite and maghemite were calculated. Our results suggest that the redox transformation of hematite to magnetite occurs in the following steps: (1) reductive dissolution of hematite to and (2) non-redox transformation of hematite and to magnetite.  相似文献   

Postaudit evaluation of conceptual model uncertainty for a glacial aquifer groundwater flow and contaminant transport model     

Lawrence D. Lemke  Joseph A. Cypher 《Hydrogeology Journal》2010,18(4):945-958

Numerical groundwater flow and contaminant transport modeling incorporating three alternative conceptual models was conducted in 2005 to assess remedial actions and predict contaminant concentrations in an unconfined glacial aquifer located in Milford, Michigan, USA. Three alternative conceptual models were constructed and independently calibrated to evaluate uncertainty in the geometry of an aquitard underlying the aquifer and the extent to which infiltration from two manmade surface water bodies influenced the groundwater flow field. Contaminant transport for benzene, cis-DCE, and MTBE was modeled for a 5-year period that included a 2-year history match from July 2003 to May 2005 and predictions for a 3-year period ending in July 2008. A postaudit of model performance indicates that predictions for pumping wells, which integrated the transport signal across multiple model layers, were reliable but unable to differentiate between alternative conceptual model responses. In contrast, predictions for individual monitoring wells with limited screened intervals were less consistent, but held promise for evaluating alternative hydrogeologic models. Results of this study suggest that model conceptualization can have important practical implications for the delineation of contaminant transport pathways using monitoring wells, but may exert less influence on integrated predictions for pumping wells screened over multiple numerical model layers.  相似文献   

Interannual predictability of Arctic sea ice in a global climate model: regional contrasts and temporal evolution   总被引：1，自引：1，他引：0  

Agathe Germe  Matthieu Chevallier  David Salas y Mélia  Emilia Sanchez-Gomez  Christophe Cassou 《Climate Dynamics》2014,43(9-10):2519-2538

The predictability of the Arctic sea ice is investigated at the interannual time scale using decadal experiments performed within the framework of the fifth phase of the Coupled Model Intercomparison Project with the CNRM-CM5.1 coupled atmosphere–ocean global climate model. The predictability of summer Arctic sea ice extent is found to be weak and not to exceed 2 years. In contrast, robust prognostic potential predictability (PPP) up to several years is found for winter sea ice extent and volume. This predictability is regionally contrasted. The marginal seas in the Atlantic sector and the central Arctic show the highest potential predictability, while the marginal seas in the Pacific sector are barely predictable. The PPP is shown to decrease drastically in the more recent period. Regarding sea ice extent, this decrease is explained by a strong reduction of its natural variability in the Greenland–Iceland–Norwegian Seas due to the quasi-disappearance of the marginal ice zone in the center of the Greenland Sea. In contrast, the decrease of predictability of sea ice volume arises from the combined effect of a reduction of its natural variability and an increase in its chaotic nature. The latter is attributed to a thinning of sea ice cover over the whole Arctic, making it more sensitive to atmospheric fluctuations. In contrast to the PPP assessment, the prediction skill as measured by the anomaly correlation coefficient is found to be mostly due to external forcing. Yet, in agreement with the PPP assessment, a weak added value of the initialization is found in the Atlantic sector. Nevertheless, the trend-independent component of this skill is not statistically significant beyond the forecast range of 3 months. These contrasted findings regarding potential predictability and prediction skill arising from the initialization suggest that substantial improvements can be made in order to enhance the prediction skill.  相似文献   

Significance of Geological Parameters for Predicting Water Inflow in Hard Rock Tunnels     

K. H. Holmøy  B. Nilsen 《Rock Mechanics and Rock Engineering》2014,47(3):853-868

One of the most challenging aspects of tunnelling is prognostication of water inflows. More reliable prediction of groundwater inflow may give considerable economical saving for future tunnel projects and may also prevent damage of environment and installations on the surface. This paper is discussing the significance of eight hypotheses regarding geological parameters for predicting water inflow in tunnels. The respective hypotheses have been tested as part of a recent research project in Norway. Six Norwegian tunnels with different geological conditions were selected for the research; the Romeriksporten, Frøya, T-baneringen, Lunner, Skaugum, and Storsand tunnels. Based on detailed study of these tunnels, the hypotheses are tested by comparing water inflow with geological parameters and factors such as Q value, faulting, rock stress orientation, rock cover, thickness of permeable soil or depth of lake/sea above the tunnel, rock type, and width of weakness zones. It is found that four out of the eight tested hypotheses are supported, two have low to medium support and two are not supported. One unexpected result is that for the tunnels covered by this study, the water inflow was found to increase with rock cover.  相似文献   

Komsomolskaya diamondiferous eclogites: evidence for oceanic crustal protoliths     

John F. Pernet-Fisher  Geoffrey H. Howarth  Yang Liu  Peter H. Barry  Laura Carmody  John W. Valley  Robert J. Bodnar  Zdislav V. Spetsius  Lawrence A. Taylor 《Contributions to Mineralogy and Petrology》2014,167(3):1-17

The Komsomolskaya kimberlite is one of numerous (>1,000) kimberlite pipes that host eclogite xenoliths on the Siberian craton. Eclogite xenoliths from the adjacent Udachnaya kimberlite pipe have previously been geochemically well characterized; however, data from surrounding diamond-bearing kimberlite pipes from the center of the craton are relatively sparse. Here, we report major- and trace-element data, as well as oxygen isotope systematics, for mineral separates of diamondiferous eclogite xenoliths from the Komsomolskaya kimberlite, suggesting two distinct subgroups of a metamorphosed, subducted oceanic crustal protolith. Using almandine contents, this suite can be divided into two subgroups: group B1, with a high almandine component (>20 mol%) and group B2, with a low almandine component (<20 mol%). Reconstructed REE profiles for B1 eclogites overlap with typical oceanic basalts and lack distinct Eu anomalies. In addition, elevated oxygen isotope values, which are interpreted to reflect isotopic exchange with seawater at low temperatures (<350 °C), are consistent with an upper-oceanic crustal protolith. Reconstructed REE profiles for B2 eclogites are consistent with oceanic gabbros and display distinct Eu anomalies, suggesting a plagioclase-rich cumulate protolith. In contrast to B1, B2 eclogites do not display elevated oxygen isotope values, suggesting an origin deep within the crustal pile, where little-to-no interaction with hydrothermal fluids has occurred. Major-element systematics were reconstructed based on mineral modes; group B1 eclogites have higher MgO wt% and lower SiO₂ wt%, with respect to typical oceanic basalts, reflecting a partial melting event during slab subduction. Calculated residues from batch partial melt modeling of a range of Precambrian basalts overlap with group B1 trace-element chemistry. When taken together with the respective partial melt trajectories, these melting events are clearly linked to the formation of Tonalite–Trondhjemite–Granodiorite (TTG) complexes. As a result, we propose that many, if not all, diamondiferous eclogite xenoliths from Komsomolskaya represent mantle ‘restites’ that preserve chemical signatures of Precambrian oceanic crust.  相似文献