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691.
This paper presented chemical characteristics of wetland inflow diffuse dust and dirt. Single land use impervious areas (parking and roads) were observed and analyzed in commercial and residential areas for organic matters, phosphorus and heavy metals. The buildup data were collected for approximately six months from December to June. The frequency of monitoring was observed daily for the first two months, twice a week for the next two months and once a week for the last two months. The results indicated significant variations in the organic matters and heavy metals strength and total accumulation among the observed areas. High pollutants strength was associated with smaller dust and dirt (DD) particles. Concentrations of phosphorus varied between 5.1 μg/g and 8.3 μg/g in DD particle less than 75 μm and account for 35%-60% of the total phosphorus. The organic matter accumulation rate associated with particles less than 600 μm and greater than 600 μm was 0.1-1 g·(curb-m)-1·d-1 and 0.1-1.5 g·(curb-m)-1·d-1 , respectively. DD particles greater than 600 μm consist of 70%-90% of leaves and other plant residues. The strength of heavy metals was more at road compared to parking areas both in commercial and residential areas. Percentage of Zn, Cu and Pb attached with particles less than 200 μm were in the range of 50%-70% in parking, 45%-90% on smooth roads and 30%-80% on rough roads. All the dust and dirt exhibited rising trend with time. Dust and dirt buildup data follow a non-linear accumulation function and can be presented better either by an exponential or power function.  相似文献   
692.
The charged sites on soil particles are important for the retention/adsorption of metals. Metallic counterions can neutralize the intrinsic charges on the surfaces of soil particles by forming complexes. In this study, efforts have been made to determine the effect of surface potential, pH, and ionic strength on the adsorption of four metal ions, hexavalent chromium Cr(VI), trivalent chromium Cr(III), nickel Ni(II) and cadmium Cd(II), in glacial till soil. Batch tests were performed to determine the effect of pH (2–12) and ionic strength (0.001–0.1 M KCl) on zeta potential of the glacial till soil. The point of zero charge (pH PZC ) of glacial till was found to be 7.0±2.5. Surface charge experiments revealed the high buffering capacity of the glacial till. Batch adsorption experiments were conducted at natural pH (8.2) using various concentrations of selected metals. The adsorption data was described by the Freundlich adsorption model. Overall glacial till shows lower adsorption affinity to Cr(VI) as compared to cationic metals, Cr(III), Ni(II) and Cd(II).  相似文献   
693.
Air dispersion modeling by was recently conducted to predict the incremental ground level and inplant concentrations of toxic organic chemicals due to stack and fugitive emissions from Sama Jaya Free Industrial Zone (SJFIZ), Kuching, Sarawak, Malaysia. Simulations of organic air pollutants emitted from industrial facilities in SJFIZ from years 1996 to 2001 were carried out in September 2004 by members of Faculty of Engineering, Universiti Malaysia Sarawak (UNIMAS). The results indicated that there were negligible amount of maximum incremental ground level concentrations of less than 3×10?2 μg/m3 for 365-day average, and less than 18×10?2 μg/m3 for 24 h. average. For in-plant maximum incremental concentrations, it is found that the simulated results were much lower than TWA values, except xylene. The predicted in plant concentration of xylene was 119.21 (parts per million) ppm as compared to ACGIH TLV-TWA of 100 ppm approximately 19% higher than ACGIH recommended values. From this study, it was concluded that both nearby population and in plant workers were not potentially at risk to exposing organic chemicals far lower than the threshold limit levels set by ACGIH.  相似文献   
694.
Urbanization is an inevitable phenomena for the country like Bangladesh. The push and pull factors help to migrate people from rural area to urban area. As a result haphazard and unplanned urbanization create environmental degradation. Survey data reveals that inadequate solid waste disposal services, lack of adequate public water supply, traffic congestion, water logging, air pollution, noise pollution, hill cutting are the main problems in the city area. Concentration of dust as well as SOx, NOx exceeded the allowable limit at the selected points. Groundwater level of Sylhet city has a considerable lowering over the last few decades. It has lowered from 3380 mm below ground in 1982 to 7880 mm below ground. Sylhet is located in highly seismic risk zone but most of the buildings and other structures in this area are constructed without considering earthquake risk. Environmental degradation index was calculated based on economical condition of the country.  相似文献   
695.
Studies were conducted at a Livestock Farm in an arid region of Pakistan, to determine the uptake of mineral nutrients from the food of buffaloes. Samples of feed, water, forage, soil as well as blood, milk, urine, and faeces of the animals were collected and analysed for K+, Ca2+, and Fe2+ during summer and winter. The results showed that the concentrations of K+ and Ca2+ in plants were low, whereas that of Fe2+ was high. In animals, K+ was not found in the milk in significant amounts, rather it was excreted in the urine. The calcium taken in by the animals was used for the synthesis of milk, as a result of which low Ca2+ concentrations were detected in urine. Mineral nutrient concentrations (K+ and Ca2+) in forage plants and water were lower than the optimum requirement of the animals, as a result of which blood plasma contained lower amounts of minerals (K+ and Fe2+) than that of the normal animals or critical limits. From the findings of the present study, it can be concluded that the buffaloes raised at the livestock farm had a severe deficiency of mineral nutrients, particularly K+ in lactating and Fe2+ in both lactating and non-lactating animals. Feed supplements, that can overcome these deficiencies, should be used for the optimum growth, milk production and resistance to diseases.  相似文献   
696.
A study was undertaken in order to understand the kinetics and mechanism of the chemical oxidation of N,N-diethyl-m-toluamide, an insect repellent, by sulfate radical. In this experiment, sulfate radical was generated using peroxymonosulfate with iron(II) and cobalt(II) as activator. The second-order rate constant for the reaction of the sulfate radical with N,N-diethyl-m-toluamide was found to be (1.9 ± 0.1) × 109 M?1 s?1 at pH 7 and a temperature of 25 °C. Experiments for the chemical oxidation of N,N-diethyl-m-toluamide in river water and secondary wastewater revealed that the percentage of the removal of N,N-diethyl-m-toluamide was slightly influenced by the water matrices. However, the selected oxidation systems are not effective for the removal of N,N-diethyl-m-toluamide in seawater. Transformation by-products of N,N-diethyl-m-toluamide generated using peroxymonosulfate/iron(II) sulfate, peroxymonosulfate/iron(II) chloride, peroxymonosulfate/cobalt(II) sulfate and peroxymonosulfate/cobalt(II) chloride systems were identified. The results indicated that there are slight differences in the distributions of the transformation by-products detected depending on the activator. The common transformation by-products detected in all selected oxidation systems are N,N-diethylbenzamide, N-ethyl-m-toluamide, N,N-dimethyl-m-toluamide, N-ethyl-N-acetyl-m-toluamide, 2-(diethylamino)-1-m-tolylethanone, monohydroxylated N-ethyl-m-toluamide, and dihydroxylated N,N-diethyl-m-toluamide. Monohydroxylated N,N-diethyl-m-toluamide were detected only when the peroxymonosulfate/iron(II) system was applied. For the peroxymonosulfate/cobalt(II) systems, additional isomers of monohydroxylated N-ethyl-m-toluamide were detected. Peroxymonosulfate/cobalt(II) also transformed 2-(diethylamino)-1-m-tolylethanone into N-ethyl-N-(2-oxo-2-m-tolylethyl)acetamide and monohydroxylated 2-(ethyl(vinyl)amino)-1-m-tolylethanone as transformation by-products.  相似文献   
697.
698.
Waves propagating in the relativistic electron-positron or ions plasma are investigated in a frame of two-fluid equations using the 3+1 formalism of general relativity developed by Thorne, Price and Macdonald (TPM). The plasma is assumed to be freefalling in the radial direction toward the event horizon due to the strong gravitational field of a Schwarzschild black hole. The local dispersion relations for transverse and longitudinal waves have been derived, in analogy with the special relativistic formulation as explained in an earlier paper, to take account of relativistic effects due to the event horizon using WKB approximation.  相似文献   
699.
Rahman  Md. Mostafizur  Zhou  Deyi  Barua  Swarup  Farid  Md. Shaikh  Tahira  Khadija Tut 《GeoJournal》2021,86(4):1957-1967
GeoJournal - Vegetable farming in Northeast Bangladesh has developed rapidly over the last 10 years, with limitations to field management and marketing. A survey was conducted in...  相似文献   
700.
Discovery of the remains of belemnites referred to the Hibolithes sp. from the Jurassic–Cretaceous Pedawan Formation in Sarawak, on the island of Borneo(Malaysia) comprises four fragments of belemnite rostra. The specimens are characterized by multiple fractures and vein filling. Two fragments measuring about 130 mm are relatively intact, with only part of the alveolar region missing; a third piece represents the middle part of a rostrum, and the fourth specimen is too fragmentary to be assigned to any specific part of the rostrum. Based on specimen characteristics, a Tithonian–Hauterivian age is plausible. The sedimentary succession that yielded the belemnite material comprises thick shale that reflects the Te division of Bouma sequence. The occurrence of a Hibolithes taxon in the uppermost Jurassic to lowermost Cretaceous Pedawan Formation sediments in Borneo reflects a near to global palaeobiogeographic distribution of this genus.  相似文献   
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